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    • 62. 发明授权
    • Nano optical sensors via molecular self-assembly
    • 纳米光学传感器通过分子自组装
    • US06815706B2
    • 2004-11-09
    • US10323139
    • 2002-12-17
    • Zhiyong LiYong ChenSean Xiao-An Zhang
    • Zhiyong LiYong ChenSean Xiao-An Zhang
    • H01L2906
    • H01L51/42H01L51/005H01L51/0071H01L51/0077H01L51/428Y02E10/549Y10S977/954
    • An optical sensor is provided, comprising (a) a silicon nanowire of finite length having an electrical contact pad at each end thereof; and (b) a plurality of self-assembled molecules on a surface of the silicon nanowire, the molecules serving to modulate electrical conductivity of the silicon nanowire by either a reversible change in dipole moment of the molecules or by a reversible molecule-assisted electron/energy transfer from the molecules onto the silicon nanowire. Further, a method of making the optical sensor is provided. The concept of molecular self-assembly is applied in attaching functional molecules onto silicon nanowire surfaces, and the requirement of molecule modification (hydroxy group in molecules) is minimal from the point view of synthetic difficulty and compatibility. Self-assembly will produce well-ordered ultra-thin films with strong chemical bonding on a surface that cannot be easily achieved by other conventional methods.
    • 提供了一种光学传感器,其包括(a)有限长度的硅纳米线,其每端具有电接触焊盘; 和(b)在硅纳米线的表面上的多个自组装分子,所述分子用于通过分子的偶极矩的可逆变化或通过可逆分子辅助电子/分子调制硅纳米线的导电性, 能量从分子转移到硅纳米线上。 此外,提供了制造光学传感器的方法。 分子自组装的概念应用于将功能分子附着在硅纳米线表面上,从合成难度和相容性的观点来看,分子修饰(分子中的羟基)的要求是最小的。 自组装将产生在表面上具有强化学键合的良好有序的超薄膜,其不能通过其它常规方法实现。