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51. 发明申请

US20170233316A1 PROCESS FOR THE PRODUCTION OF FLUORINATED CYCLOBUTANE 有权
公开(公告)号：US20170233316A1
公开(公告)日：2017-08-17
申请号：US15582981
申请日：2017-05-01
申请人： Honeywell International Inc.
发明人： Haridasan K. Nair , Rajiv Banavali , Yian Zhai , Glenn Matthies
IPC分类号： C07C17/275
CPC分类号： C07C17/275 , C07C2601/04 , C07C23/06
摘要： The production of 1,1,2-trifluoro-2-(trifluoromethyl)cyclobutane (TFMCB). More specifically, the present invention relates to a process for making 1,1,2-trifluoro-2-(trifluoromethyl)cyclobutane via a continuous catalytic reaction from commercially available raw materials ethylene and hexafluoropropene.

52. 发明授权

US09598335B2 Method for producing fluorine-containing olefin 有权
公开(公告)号：US09598335B2
公开(公告)日：2017-03-21
申请号：US15056288
申请日：2016-02-29
申请人： Asahi Glass Company, Limited
发明人： Yusuke Takahira
IPC分类号： C07F15/00 , C07C17/275 , C07C41/30 , C07C43/17 , C07C43/176 , C07C17/37 , C07C41/22 , C07C17/272 , C07C41/18
CPC分类号： C07C41/30 , B01J31/2208 , B01J31/2291 , B01J31/2295 , B01J31/2404 , B01J2231/543 , B01J2531/821 , C07B2200/09 , C07C17/272 , C07C17/275 , C07C17/37 , C07C41/18 , C07C41/22 , C07C43/17 , C07C43/176 , C07F15/0046 , C07C22/08
摘要： A method for producing at least one compound selected from the group consisting of a compound represented by the following formula (10), a compound represented by the following formula (11), a compound represented by the following formula (12), and a compound represented by the following formula (13), which the method containing reacting a compound represented by the following formula (2) with a compound represented by the following formula (7), in the presence of at least one compound selected from the group consisting of a compound represented by the following formula (1), a compound represented by the following formula (3), a compound represented by the following formula (4), a compound represented by the following formula (8), and a compound represented by the following formula (9).

53. 发明申请

US20160264529A1 BENZOCYCLOBUTANE(THIO) CARBOXAMIDES 有权
标题翻译：苯并噻唑（THIO）CARBOXAMIDES
公开(公告)号：US20160264529A1
公开(公告)日：2016-09-15
申请号：US15031456
申请日：2014-10-28
申请人： BAYER CROPSCIENCE AKTIENGESELLSCHAFT
发明人： Christophe DUBOST , Ulrike WACHENDORFF-NEUMANN , Philipp WINTER , Stephane BRUNET , Jean-Pierre VORS , Cyril MONTAGNE
IPC分类号： C07D231/16 , A01N43/56 , C07D213/82 , C07C25/22 , C07C209/62 , C07C17/23 , C07C17/275 , C07D231/14 , A01N43/40
CPC分类号： C07D231/16 , A01N43/40 , A01N43/56 , A01N45/00 , C07C17/23 , C07C17/275 , C07C25/22 , C07C209/62 , C07C211/60 , C07C211/61 , C07C2602/06 , C07C2603/94 , C07D213/82 , C07D231/14
摘要： The present invention relates to novel benzocyclobutane(thio) carboxamides, to processes for preparing these compounds, to compositions comprising these compounds, and to the use thereof as biologically active compounds, especially for control of harmful microorganisms in crop protection and in the protection of materials.
摘要翻译：本发明涉及新型苯并环丁烷（硫代）甲酰胺，制备这些化合物的方法，包含这些化合物的组合物，以及其作为生物活性化合物的用途，特别是用于控制作物保护和材料保护中的有害微生物。

54. 发明授权

US09289758B2 Processes for producing chlorinated hydrocarbons and methods for recovering polyvalent antimony catalysts therefrom 有权
标题翻译：用于生产氯代烃的方法和从其中回收多价锑催化剂的方法
公开(公告)号：US09289758B2
公开(公告)日：2016-03-22
申请号：US14521449
申请日：2014-10-22
申请人： Axiall Ohio, Inc.
发明人： Scott A. Sherwood , Stephen Robert Lester
IPC分类号： C07C17/35 , B01J31/12 , C07C17/10 , C07C17/25 , C07C17/275 , B01J27/128 , B01J27/10
CPC分类号： C07C17/23 , B01J27/10 , B01J27/128 , B01J31/122 , C07C17/06 , C07C17/10 , C07C17/25 , C07C17/275 , C07C19/01 , C07C21/04
摘要： The preparation of chlorinated hydrocarbons, such as pentachloropropanes, such as 1,1,1,2,3-pentachloropropane, from tetrachloropropanes, such as 1,1,1,3-tetrachloropropane, in the presence of a polyvalent antimony compound that includes a pentavalent antimony compound, such as antimony pentachloride, is described. Also described are methods for preparing optionally chlorinated alkenes, such as, tetrachloropropenes, from chlorinated alkanes, such as pentachloropropanes, in the presence of polyvalent antimony compound that includes a pentavalent antimony compound, as well as methods for recovering polyvalent antimony compounds from such processes.
摘要翻译：四氯丙烷如1,1,1,3-四氯丙烷等氯代烃如五氯丙烷如1,1,1,2,3-五氯丙烷在多价锑化合物存在下的制备，包括描述了五价锑化合物，例如五氯化锑。还描述了在包括五价锑化合物的多价锑化合物存在下，从氯代烷烃如五氯丙烷中制备任选氯代烯烃如四氯丙烯的方法，以及从这些方法中回收多价锑化合物的方法。

55. 发明授权

US08877990B2 Process of making a chlorinated hydrocarbon 有权
标题翻译：制造氯化烃的工艺
公开(公告)号：US08877990B2
公开(公告)日：2014-11-04
申请号：US13319912
申请日：2010-06-17
申请人： Tadahiro Fukuju , Kikuo Yamamoto , Masayuki Moriwaki , Yasutaka Komatsu , Akihiro Saito , Shunsuke Hosaka , Dai Tsunoda , Jun Kawakami
发明人： Tadahiro Fukuju , Kikuo Yamamoto , Masayuki Moriwaki , Yasutaka Komatsu , Akihiro Saito , Shunsuke Hosaka , Dai Tsunoda , Jun Kawakami
IPC分类号： C07C17/25 , C07C17/275 , C01B7/04 , C01B7/01 , C07C17/278 , C07C17/04 , C01B7/07
CPC分类号： C07C17/04 , C01B7/01 , C01B7/04 , C01B7/0706 , C07C17/25 , C07C17/275 , C07C17/278 , C07C19/01 , C07C21/04
摘要： A process of making a chlorinated hydrocarbon through a thermal dehydrochlorination step in which an unsaturated compound represented by the following general formula (2) is obtained by thermally decomposing a saturated compound represented by the following general formula (1). CCl3—CCl2-mHm—CCl3-nHn (1) CCl2═CCl2-mHm-1—CCl3-nHn (2) (in the above formulas, m is 1 or 2, and n is an integer of 0 to 3.)
摘要翻译：通过热分解通过热分解由以下通式（1）表示的饱和化合物获得由以下通式（2）表示的不饱和化合物的热脱氯化氢步骤制备氯代烃的方法。 CCl3-CCl2-mHm-CCl3-nHn（1）CCl2 = CCl2-mHm-1-CCl3-nHn（2）（在上式中，m为1或2，n为0〜3的整数。

56. 发明申请

US20110127516A1 POLYMER COMPOUND AND LIGHT-EMITTING ELEMENT USING SAME 有权
标题翻译：聚合物化合物和使用相同的发光元件
公开(公告)号：US20110127516A1
公开(公告)日：2011-06-02
申请号：US13056227
申请日：2009-07-29
申请人： Tomoya Nakatani , Keiko Kawaguchi
发明人： Tomoya Nakatani , Keiko Kawaguchi
IPC分类号： H01L51/54 , C08G73/02 , C08L39/00 , C07C25/22 , C07C17/275 , C07C17/23
CPC分类号： H01L51/0036 , C07C25/22 , C07C25/24 , C07C309/65 , C07C2602/06 , C07C2603/18 , C08G61/02 , C08G61/12 , C08G61/124 , C08G2261/124 , C08G2261/135 , C08G2261/148 , C08G2261/3142 , C08G2261/316 , C08G2261/3241 , C08G2261/411 , C08G2261/76 , C08G2261/92 , C08L65/00 , C09K11/06 , C09K2211/1416 , C09K2211/1425 , C09K2211/145 , C09K2211/1458 , C09K2211/1466 , H01L51/0035 , H01L51/0039 , H01L51/5048 , Y02E10/549 , Y02P70/521 , Y10S428/917
摘要： A polymer compound including: the repeating unit shown in the following formula (I) (wherein: Ar1 represents an arylene group, a divalent heterocyclic group, or a divalent aromatic amine; J1 and J2 each represent a direct bond, an alkylene group, or a phenylene group, and X1 represents an oxygen atom or a sulfur atom; i is an integer from 0 to 3; j is 0 or 1; m is 1 or 2; and R1 represents a hydrogen atom, an alkyl group, an alkoxy group, or the like) and the repeating unit shown in the following formula (II) (wherein: Ar2 represents a fluorene-diyl group; J3 and J4 each represent a direct bond, an alkylene group, or a phenylene group; X2 represents an oxygen atom or a sulfur atom; k is an integer from 0 to 3; l is 0 or 1; and n is 1 or 2).
摘要翻译：一种高分子化合物，包括：下式（I）所示的重复单元（其中：Ar 1表示亚芳基，二价杂环基或二价芳香族胺; J 1和J 2各自表示直接键合，亚烷基或亚苯基，X1表示氧原子或硫原子，i表示0〜3的整数，j表示0或1，m表示1或2，R1表示氢原子，烷基，烷氧基等）和下式（II）所示的重复单元（其中：Ar2表示芴二基; J3和J4各自表示直接键合，亚烷基或亚苯基; X2表示氧原子或硫原子; k为0至3的整数; l为0或1; n为1或2）。

57. 发明申请

US20050250966A1 Metallic copper catalyst for polyfluoroalkylethyl iodide production and process for producing polyfluoroalkylethyl iodide 有权
标题翻译：用于制备多氟烷基乙基碘的金属铜催化剂及其制备多氟烷基乙基碘的方法
公开(公告)号：US20050250966A1
公开(公告)日：2005-11-10
申请号：US10516940
申请日：2003-06-17
申请人： Yoshirou Funakoshi , Jun Miki
发明人： Yoshirou Funakoshi , Jun Miki
IPC分类号： B30B15/14 , B01J23/72 , B30B1/14 , B30B1/26 , C07C17/266 , C07C17/275 , C07C17/278
CPC分类号： C07C17/266 , B01J23/72 , C07C17/275 , C07C17/278 , C07C19/16
摘要： The present invention provides a metallic copper catalyst for use in an ethylene addition reaction to polyfluoroalkyl iodides, a process for efficiently producing a polyfluoroalkylethyl iodide using such a metal copper catalyst in an ethylene addition reaction to a polyfluoroalkyl iodide, and a process for efficiently producing a polyfluoroalkylethyl iodide from a polyfluoroalkyl iodide using the same metallic copper catalyst in a telomerization reaction and a subsequent ethylene addition reaction.
摘要翻译：本发明提供了用于对多氟烷基碘化物进行乙烯加成反应的金属铜催化剂，使用这种金属铜催化剂在多氟烷基碘化物的乙烯加成反应中有效生产聚氟烷基乙基碘的方法，来自多氟烷基碘的多氟烷基乙基碘，使用相同的金属铜催化剂进行调聚反应和随后的乙烯加成反应。

58. 发明授权

US5674959A Peroxide curable fluoroelastomers, particularly suitable for manufacturing O-rings 失效
标题翻译：过氧化物固化的含氟弹性体，特别适用于制造O型圈
公开(公告)号：US5674959A
公开(公告)日：1997-10-07
申请号：US723928
申请日：1996-10-01
申请人： Vincenzo Arcella , Giulio Brinati , Margherita Albano , Vito Tortelli
发明人： Vincenzo Arcella , Giulio Brinati , Margherita Albano , Vito Tortelli
IPC分类号： F16J15/10 , C07C17/25 , C07C17/275 , C07C21/18 , C07C41/24 , C07C43/17 , C08F14/18 , C08F14/22 , C08F16/14 , C08F214/18 , C08F214/22 , C08F214/26 , C08F216/14 , C09K3/10 , C08F16/24
CPC分类号： C08F214/18 , C07C17/25 , C07C17/275
摘要： New fluoroelastomers are described, having iodine atoms in terminal position and monomeric units in the chain deriving from an iodinated olefin of formula: CHR.dbd.CH--Z--CH.sub.2 CHR--I (I) wherein: R is --H or --CH.sub.3 ; Z is a (per)fluoroalkylene radical C.sub.1 -C.sub.18, linear or branched, optionally containing one or more ether oxygen atoms, or a (per) fluoropolyoxyalkylene radical. These products, upon peroxide curing, require extremely short post-curing treatments (around 30-60 minutes at 180.degree.-230.degree. C.) and are characterized by compression set values lower than 25% (measured on O-rings at 200.degree. C. for 70 hours according to ASTM Standard D395 Method B).
摘要翻译：描述了新的含氟弹性体，其末端具有碘原子，并且衍生自下式的CH 2 CH = CH-Z-CH 2 CHR-I（I）的碘化烯烃链中的单体单元，其中：R为-H或-CH 3; Z是直链或支链（任选地含有一个或多个醚氧原子）或（全）氟聚氧亚烷基的（全）氟亚烷基C1-C18。过氧化物固化后，这些产品需要非常短的后固化处理（在180°-230℃下约30-60分钟），其特征在于压缩永久变形值低于25％（在200℃的O形环上测量）根据ASTM标准D395方法B）70小时。

59. 发明授权

US5633413A Continuous process for the production of vinylidene chloride telomers 失效
标题翻译：用于生产偏二氯乙烯调节剂的连续方法
公开(公告)号：US5633413A
公开(公告)日：1997-05-27
申请号：US512575
申请日：1995-08-08
申请人： Michael Van Der Puy , Timothy R. Demmin , David E. Bradley
发明人： Michael Van Der Puy , Timothy R. Demmin , David E. Bradley
IPC分类号： C07C17/278 , C07C17/08 , C07C17/266 , C07C17/275
CPC分类号： C07C17/278
摘要： A process for the continuous production of telomers CCl.sub.3 (CH.sub.2 CCl.sub.2).sub.n Cl where n=1-3 (Formula I) by the continuous reaction of CCl.sub.4 and vinylidene chloride in the presence of a solvent and a catalyst. The reaction to form CCl.sub.3 (CH.sub.2 CCl.sub.2)Cl proceeds at a reaction rate constant k.sub.1. If n=1, CCl.sub.3 (CH.sub.2 CCl.sub.2)Cl is continuously removed from the reactor. If n=2, the removed CCl.sub.3 (CH.sub.2 CCl.sub.2)Cl reacts similarly with CCl.sub.4 and CH.sub.2 .dbd.CCl.sub.2 in a second reactor to form and remove CCl.sub.3 (CH.sub.2 CCl.sub.2).sub.2 Cl under conditions to have a reaction rate constant k.sub.2, wherein the ratio of the molar amounts of CCl.sub.4 to CCl.sub.3 (CH.sub.2 CCl.sub.2)Cl reacted is greater than the ratio k.sub.2 /k.sub.1. If n=3, the removed CCl.sub.3 (CH.sub.2 CCl.sub.2).sub.2 Cl similarly reacts in a third reactor with CCl.sub.4 and CH.sub.2 .dbd.CCl.sub.2 to form CCl.sub.3 (CH.sub.2 CCl.sub.2).sub.3 Cl under conditions to have a reaction rate constant k.sub.3, wherein the ratio of the molar amounts of CCl.sub.4 to CCl.sub.3 (CH.sub.2 CCl.sub.2).sub.2 Cl reacted is greater than the ratio k.sub.3 /k.sub.2.
摘要翻译：在溶剂和催化剂存在下，通过CCl4和偏二氯乙烯的连续反应连续生产调节剂CCl 3（CH 2 Cl 2）n Cl，其中n = 1-3（式I）的方法。形成CCl 3（CH 2 Cl 2）Cl的反应以反应速率常数k1进行。如果n = 1，则从反应器中连续除去CCl 3（CH 2 Cl 2））Cl。如果n = 2，则在第二反应器中除去的CCl 3（CH 2 Cl 2 Cl 2）Cl类似地与CCl 4和CH 2 = CCl 2反应，以在具有反应速率常数k2的条件下形成和除去CCl 3（CH 2 Cl 2）2 Cl，其中摩尔量的CCl4至CCl3（CH2Cl2）Cl反应的比值大于k2 / k1的比例。如果n = 3，则除去的CCl 3（CH 2 Cl 2）2 Cl类似地在第三反应器中与CCl 4和CH 2 = CCl 2反应以在具有反应速率常数k 3的条件下形成CCl 3（CH 2 Cl 2）3 Cl，其中CCl 4的摩尔量至CCl 3（CH 2 Cl 2）2 Cl反应的比例大于k3 / k2的比例。

60. 发明授权

US5180872A Process for the preparation of styrene derivatives extended at the double bond by ethylene and having a double bond remaining in the extension chain formed and new styrene derivatives extended with ethylene 失效
标题翻译：制备苯乙烯衍生物的方法在乙烯双酚键上延伸，并且在延伸链形成的双键和新的苯乙烯衍生物中扩展乙烯
公开(公告)号：US5180872A
公开(公告)日：1993-01-19
申请号：US704751
申请日：1991-05-23
申请人： Karl-Heinz A. O. Starzewski
发明人： Karl-Heinz A. O. Starzewski
IPC分类号： B01J31/22 , B01J31/18 , B01J31/24 , C07B37/02 , C07B61/00 , C07C2/04 , C07C15/44 , C07C17/26 , C07C17/275 , C07C25/24 , C07C45/69 , C07C49/784 , C07C49/796 , C07C49/813 , C08F4/26 , C08F12/00 , C08F12/08
CPC分类号： C07C49/813 , B01J31/1875 , B01J31/2247 , B01J31/2295 , B01J31/24 , B01J31/2404 , C07B37/02 , C07C15/44 , C07C17/275 , C07C2/04 , C07C25/24 , C07C45/69 , C07C49/784 , C07C49/796 , B01J2531/847 , B01J31/2291 , C07C2531/22
摘要： The title compounds can be prepared by reaction of a styrene derivative with ethylene in the presence of a nickel catalyst which carries a phosphorus-oxygen chelate ligand, at a temperature of 20.degree.to 160.degree. C. and an ethylene pressure of 1 to 200 bar. Styrene derivatives extended with ethylene, of the formula ##STR1## in which R.sup.19 denotes hydrogen, C.sub.1 -C.sub.4 -alkyl, vinyl or chlorine and R.sup.38 denotes C.sub.1 -C.sub.4 -alkyl, C.sub.2 -C.sub.4 -alkenyl, C.sub.2 -C.sub.7 -acyl, flourine, chlorine or bromine andm assumes values of 4-104,with the exception of compounds wherein R.sup.19 denotes hydrogen and R.sup.38 denotes i-butyl or benzoyl, and m assumes the value 4, are new.
摘要翻译：标题化合物可以通过苯乙烯衍生物与乙烯在携带磷 - 氧螯合配体的镍催化剂存在下，在20至160℃的温度和1至200巴的乙烯压力下反应来制备。苯乙烯衍生物用乙烯延伸，其结构式为：其中R 19表示氢，C 1 -C 4烷基，乙烯基或氯，R 38表示C 1 -C 4烷基，C 2 -C 4链烯基，C 2 -C 7酰基，氯或溴，m为4-104的值，除了其中R 19表示氢，R 38表示异丁基或苯甲酰基，m为4的化合物是新的。

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