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51. 发明授权

US08642004B2 Process for the production of hydrogen from ethanol 有权
标题翻译：从乙醇生产氢气的方法
公开(公告)号：US08642004B2
公开(公告)日：2014-02-04
申请号：US13212772
申请日：2011-08-18
申请人： Roberto Carlos Pontes Bittencourt
发明人： Roberto Carlos Pontes Bittencourt
IPC分类号： C01B3/16 , C01B3/38
CPC分类号： C01B3/326 , B01J23/78 , B01J23/80 , B01J23/83 , B01J23/892 , B01J35/04 , B01J37/0201 , B01J37/18 , B01J2523/00 , C01B3/38 , C01B3/382 , C01B3/48 , C01B2203/0233 , C01B2203/0244 , C01B2203/0283 , C01B2203/0288 , C01B2203/043 , C01B2203/1058 , C01B2203/1082 , C01B2203/1229 , C01B2203/142 , C01B2203/143 , C01B2203/148 , Y02P20/52 , B01J2523/22 , B01J2523/31 , B01J2523/847 , B01J2523/23 , B01J2523/13 , B01J2523/47 , B01J2523/27
摘要： Using the process described in the present invention, a gas is produced that is rich in methane and hydrogen and has a content of olefins below 1% v/v, which fully meets the necessary requirements for raw materials used for large-scale production of hydrogen or synthesis gas, in steam reforming units that already exist in a great many oil refineries and petrochemical units. Starting from ethanol, steam, nickel-based catalysts and the use of appropriate conditions of temperature, and H2O/ethanol and H2/ethanol molar ratios, the invention teaches the production of hydrogen and synthesis gas from biomass, stably for long periods without loss of catalyst performance over time, permitting its industrial application in new units or in existing units. As a solution for the production of ethanol, the present invention claims the replacement of the ZnO-based and hydrofining catalysts of the feed pre-treatment section, with nickel-based catalysts and process conditions in accordance with the present invention.
摘要翻译：使用本发明所述的方法，生产富含甲烷和氢气并具有低于1％v / v的烯烃含量的气体，其完全满足用于大规模生产氢的原料的必要要求或合成气，在已经存在于许多炼油厂和石化装置中的蒸汽重整单元中。本发明从乙醇，蒸汽，镍基催化剂和适当的温度条件以及H 2 O /乙醇和H 2 /乙醇的摩尔比开始，教导了长时间稳定地生物质生物质的氢气和合成气，而不损失催化剂性能随时间推移，允许其在新设备或现有单元中的工业应用。作为生产乙醇的方法，本发明要求用本发明的镍基催化剂和工艺条件替代进料预处理段的ZnO基和加氢精制催化剂。

52. 发明授权

US08496909B2 Calcium looping process for high purity hydrogen production integrated with capture of carbon dioxide, sulfur and halides 有权
公开(公告)号：US08496909B2
公开(公告)日：2013-07-30
申请号：US13123746
申请日：2009-10-13
申请人： Shwetha Ramkumar , Liang-Shih Fan
发明人： Shwetha Ramkumar , Liang-Shih Fan
IPC分类号： C01B3/16 , C01B3/12
CPC分类号： C01B3/583 , B01D53/10 , B01D53/62 , B01D2253/112 , B01D2256/16 , B01D2257/204 , B01D2257/304 , B01D2257/504 , C01B3/344 , C01B3/48 , C01B2203/0283 , C01B2203/043 , C01B2203/0465 , C01B2203/047 , C01B2203/0475 , C01B2203/0485 , C01B2203/062 , C01B2203/0827 , C01B2203/148 , C01B2203/82 , C01B2203/84 , C01B2203/86 , C10G2300/1022 , C10J3/54 , C10J2300/1612 , C10J2300/1646 , C10J2300/1653 , C10J2300/1659 , C10K1/003 , C10K1/004 , C10K3/04 , Y02C10/04 , Y02C10/08 , Y02E20/16 , Y02E20/18 , Y02E20/185 , Y02P20/152 , Y02P30/30
摘要： A process for producing hydrogen comprising the steps of: (i) gasifying a fuel into a raw synthesis gas comprising CO, hydrogen, steam, sulfur and halide contaminants in the form of H2S, COS, and HX, wherein X is a halide; (ii) passing the raw synthesis gas through a water gas shift reactor (WGSR) into which CaO and steam are injected, the CaO reacting with the shifted gas to remove CO2, sulfur and halides in a solid-phase calcium-containing product comprising CaCO3, CaS and CaX2; (iii) separating the solid-phase calcium-containing product from an enriched gaseous hydrogen product; and (iv) regenerating the CaO by calcining the solid-phase calcium-containing product at a condition selected from the group consisting of: in the presence of steam, in the presence of CO2, in the presence of synthesis gas, in the presence of H2 and O2, under partial vacuum, and combinations thereof.

53. 发明授权

US08349290B2 Multi-fluidized bed water-gas shift reactor using syngas and production of hydrogen using the same 有权
标题翻译：使用合成气的多流化床水煤气变换反应器和使用其的氢气生产
公开(公告)号：US08349290B2
公开(公告)日：2013-01-08
申请号：US12615939
申请日：2009-11-10
申请人： See Hoon Lee , Jae Ho Kim , Jung Min Shon
发明人： See Hoon Lee , Jae Ho Kim , Jung Min Shon
IPC分类号： B01J8/28 , C01B3/12 , C01B3/16
CPC分类号： C01B3/30 , B01J8/0055 , B01J8/1836 , B01J8/28 , B01J2208/00203 , C10K3/04 , Y02P20/129
摘要： A multi-fluidized bed water-gas shift reactor wherein a specific syngas containing a high concentration of carbon monoxide produced by gasification of a heavy carbon source such as coal, vacuum residue, glycerin, etc., is in contact with water under a catalyst so as to produce hydrogen and, in addition, a method for production of hydrogen using the foregoing reactor are disclosed. In other words, the disclosure describes a multi-fluidized bed water-gas shift reactor containing low and high temperature catalysts as well as steam and a method for production of hydrogen using the same, wherein 30 to 70% carbon monoxide in the syngas as a gas mixture containing hydrogen, carbon monoxide, carbon dioxide, hydrogen sulfide, hydrogen monoxide, and the like, which are generated through partial oxidation and vapor gasification at 900 to 1,600° C., may be favorably converted into hydrogen without mixing both of the catalysts.
摘要翻译：一种多流化床水煤气变换反应器，其中通过气化煤，减压渣油，甘油等重质碳源产生的含有高浓度一氧化碳的特定合成气在催化剂下与水接触，为了产生氢，另外还公开了使用上述反应器生产氢的方法。换句话说，本公开内容描述了一种含有低温和高温催化剂以及蒸汽的多流化床水煤气变换反应器及其制备方法，其中合成气中的30-70％一氧化碳作为含有氢，一氧化碳，二氧化碳，硫化氢，一氧化碳等的气体混合物，其在900〜1600℃下通过部分氧化和气相气化而产生，可以有利地转化为氢气，而不会混合两种催化剂。

54. 发明申请

US20120128579A1 PROCESS TO PREPARE A HYDROGEN RICH GAS MIXTURE 有权
标题翻译：制备氢气混合物的方法
公开(公告)号：US20120128579A1
公开(公告)日：2012-05-24
申请号：US13377891
申请日：2010-06-28
申请人： Robert Van Den Berg , Matthieu Simon Henri Fleys , Frank Haiko Geuzebroek , Mark Jan Prins
发明人： Robert Van Den Berg , Matthieu Simon Henri Fleys , Frank Haiko Geuzebroek , Mark Jan Prins
IPC分类号： C01B3/16
CPC分类号： C01B3/32 , C01B3/16 , C01B3/52 , C01B2203/0294 , C01B2203/0415 , C01B2203/0465 , C01B2203/0475 , C01B2203/0485 , C01B2203/1041 , C01B2203/1052 , C01B2203/1076 , C01B2203/84 , C10J3/06 , C10J3/466 , C10J2300/093 , C10J2300/0956 , C10J2300/0959 , C10K3/04 , Y02E20/18
摘要： The invention is directed to a process to prepare a hydrogen rich gas mixture from a solid sulphur- and halogen-containing carbonaceous feedstock. The process involves the following steps. Step (a): gasification of the solid carbonaceous feedstock with an oxygen-containing gas to obtain a gas mixture comprising halogen compounds, sulphur compounds, hydrogen and at least 50 vol. % carbon monoxide, on a dry basis. Step (b): contacting the gas mixture with a quench gas or quench liquid to reduce the temperature of the gas mixture to below 900° C. Step (c) contacting the gas mixture with water having a temperature of between 150 and 250° C. to obtain a gas mixture comprising between 50 and 1000 ppm halogen and having a steam to carbon monoxide molar ratio of between 0.2:1 and 0.9:1. Step (d): subjecting the gas mixture obtained in step (c) to a water gas shift reaction wherein part or all of the carbon monoxide is converted with the steam to hydrogen and carbon dioxide in the presence of a catalyst as present in one fixed bed reactor or in a series of more than one fixed bed reactors and wherein the temperature of the gas mixture as it enters the reactor or reactors is between 190 and 230° C. Step (e): carbon dioxide and sulphur compounds are separated from the shifted gas mixture obtained in step (d) by contacting the shifted gas mixture with a solvent comprising dialkyl ethers of polyethylene glycol.
摘要翻译：本发明涉及从固体含硫和含卤素的碳质原料制备富氢气体混合物的方法。该过程涉及以下步骤。步骤（a）：用含氧气体气化固体碳质原料，得到包含卤素化合物，硫化合物，氢气和至少50体积％％一氧化碳。步骤（b）：使气体混合物与骤冷气体或骤冷液接触，以将气体混合物的温度降至900℃以下。步骤（c）将气体混合物与温度为150-250℃的水接触以获得包含50-1000ppm卤素并且蒸汽与一氧化碳摩尔比在0.2:1和0.9:1之间的气体混合物。步骤（d）：将步骤（c）中获得的气体混合物进行水煤气变换反应，其中部分或全部一氧化碳在蒸汽存在下以蒸汽转化为氢气和二氧化碳，存在于一个固定的床反应器或一系列多于一个的固定床反应器，并且其中气体混合物进入反应器或反应器时的温度为190-230℃。步骤（e）：二氧化碳和硫化合物与通过使转移的气体混合物与包含聚乙二醇的二烷基醚的溶剂接触，在步骤（d）中获得的转移气体混合物。

55. 发明授权

US08088708B2 Catalyst precursor substance, and catalyst using the same 有权
标题翻译：催化剂前体物质和使用其的催化剂
公开(公告)号：US08088708B2
公开(公告)日：2012-01-03
申请号：US12594983
申请日：2008-04-02
申请人： Kozo Takatsu , Yoshimi Kawashima , Satoshi Nakai
发明人： Kozo Takatsu , Yoshimi Kawashima , Satoshi Nakai
IPC分类号： B01J23/00 , B01J23/60 , B01J23/72 , B01J23/02 , B01J23/06 , B01J23/70 , H01M8/22 , H01M8/06 , C01B31/20 , C01B3/16 , C01B3/18 , C10G25/00 , C10G45/04 , C10G45/60 , C10G29/00
CPC分类号： B01J35/006 , B01J23/80 , B01J35/002 , B01J35/1019 , B01J37/0009 , B01J37/03 , C01B3/16 , C01B3/326 , C01B2203/0233 , C01B2203/0283 , C01B2203/066 , C01B2203/1076 , C01B2203/1223 , C01B2203/1288 , H01M8/0618 , H01M8/0668 , Y02P20/52
摘要： The present invention provides a catalyst precursor substance containing copper, zinc, and aluminum and exhibiting an X-ray diffraction pattern having a broad peak at a specific interplanar spacing d (Å). The present invention also provides a method for producing the catalyst precursor substance by mixing a solution containing a copper salt, a zinc salt, and an aluminum salt with a solution containing an alkali metal hydroxide or an alkaline earth metal hydroxide, thereby forming a precipitate. In the present invention, a catalyst is prepared through calcining of the catalyst precursor; the catalyst is employed for water gas shift reaction; and carbon monoxide conversion is carried out by use of the catalyst. Thus, the present invention also provides a catalyst useful for water gas shift reaction, which exhibits high activity and durability and which, even when applied to a fuel cell, can be used for a long period of time with reduction in activity being suppressed; a carbon monoxide conversion method employing the catalyst; and a fuel cell system employing hydrogen produced through the carbon monoxide conversion method.
摘要翻译：本发明提供了含有铜，锌和铝的催化剂前体物质，并且具有在特定的晶面间距d（）下具有宽峰的X射线衍射图。本发明还提供了通过将含有铜盐，锌盐和铝盐的溶液与含有碱金属氢氧化物或碱土金属氢氧化物的溶液混合从而形成沉淀物来制备催化剂前体物质的方法。在本发明中，通过煅烧催化剂前体制备催化剂; 催化剂用于水煤气变换反应; 并且通过使用催化剂进行一氧化碳转化。因此，本发明还提供了可用于水煤气变换反应的催化剂，其具有高活性和耐久性，并且甚至当应用于燃料电池时可以长时间使用，同时抑制活性的降低; 使用该催化剂的一氧化碳转化方法; 以及使用通过一氧化碳转化法生产的氢的燃料电池系统。

56. 发明申请

US20110305627A1 PROCESSES FOR HYDROGEN PRODUCTION AND CATALYSTS FOR USE THEREIN 审中-公开
标题翻译：氢生产工艺及其使用的催化剂
公开(公告)号：US20110305627A1
公开(公告)日：2011-12-15
申请号：US13141272
申请日：2009-12-17
申请人： Nikunj Gupta , Mahesh Venkataraman Iyer , Karel Martin Kapoun
发明人： Nikunj Gupta , Mahesh Venkataraman Iyer , Karel Martin Kapoun
IPC分类号： C01B3/16
CPC分类号： C01B3/384 , B01J23/755 , B01J23/83 , C01B3/323 , C01B3/48 , C01B2203/0233 , C01B2203/0283 , C01B2203/0288 , C01B2203/0405 , C01B2203/043 , C01B2203/0475 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/0883 , C01B2203/1047 , C01B2203/1058 , C01B2203/1094 , C01B2203/1217 , C01B2203/1223 , C01B2203/1229 , C01B2203/1288 , C01B2203/86 , Y02P20/128 , Y02P20/52 , Y02P30/30
摘要： This invention describes a process for producing hydrogen comprising: introducing a feedstream comprising a bio-based feedstock and water into a reformer and supplying heat to the reformer; contacting the feedstream with a steam reforming catalyst disposed within the reformer to form a reformate comprising hydrogen and carbon monoxide; recovering the reformate from the reformer; contacting the reformate with steam in the presence of a water-gas shift catalyst disposed within a water-gas shift reaction zone to form a water-gas shift product stream comprising hydrogen, and the water-gas shift product stream comprises hydrogen in a greater quantity than in the reformate; heating the feedstream by heat exchange contact of the feedstream with a product stream selected from the reformate, the water-gas shift product stream or combinations thereof to transfer heat from the product stream to the feedstream prior to introducing the feedstream into the reformer.
摘要翻译：本发明描述了一种生产氢的方法，包括：将包含基于生物的原料和水的进料流引入重整器并向重整器供应热量; 使进料流与设置在重整器内的蒸汽重整催化剂接触以形成包含氢和一氧化碳的重整产物; 从改革者中恢复重组; 在设置在水煤气变换反应区内的水煤气变换催化剂的存在下，将重整油与蒸汽接触以形成包含氢的水煤气变换产物流，并且水煤气变换产物流包含更大量的氢比在重组中; 通过进料流与选自重整产物流，水煤气变换产物流或其组合的产物流的热交换接触来加热进料流，以在将进料流引入重整器之前将热量从产物流转移到进料流。

57. 发明申请

US20110081291A1 MULTI WATER-GAS SHIFT MEMBRANE REACTOR FOR PRODUCING HIGH CONCENTRATION HYDROGEN AND METHOD FOR PRODUCING HYDROGEN USING THE SAME 有权
标题翻译：用于生产高浓度氢的多水气移动膜反应器和使用其制氢的方法
公开(公告)号：US20110081291A1
公开(公告)日：2011-04-07
申请号：US12715318
申请日：2010-03-01
申请人： Il Hyun BAEK , See Hoon LEE , Jeong Nam KIM
发明人： Il Hyun BAEK , See Hoon LEE , Jeong Nam KIM
IPC分类号： C01B3/16 , B01J8/04
CPC分类号： B01J8/009 , B01J8/0453 , B01J2208/00203 , B01J2208/0053 , C01B3/16 , C01B2203/0288 , C01B2203/041 , C01B2203/06
摘要： Disclosed are a multi water-gas shift membrane reactor for producing high-concentration hydrogen and a method for producing hydrogen using the same. More specifically, disclosed are a multi water-gas shift membrane reactor wherein high-concentration carbon monoxide, obtained by dry-gasification performed by reacting dry bituminous coal with water and oxygen, reacts with water gas in the presence of catalysts in a single reactor, to produce hydrogen and carbon dioxide and separate highly pure hydrogen and carbon dioxide through a separation membrane arranged in a low region, and a method for producing hydrogen.
摘要翻译：公开了一种用于生产高浓度氢的多水煤气变换膜反应器及其制造方法。更具体地，公开了一种多水煤气变换膜反应器，其中通过干燥的沥青煤与水和氧反应进行的干气化获得的高浓度一氧化碳在单一反应器中在催化剂存在下与水气反应，以产生氢气和二氧化碳，并通过布置在低区域中的分离膜分离出高纯度的氢和二氧化碳，以及生产氢气的方法。

58. 发明申请

US20110053020A1 CATALYSTS AND RELATED METHODS 审中-公开
标题翻译：催化剂及相关方法
公开(公告)号：US20110053020A1
公开(公告)日：2011-03-03
申请号：US12513524
申请日：2008-11-07
申请人： M. Grant Norton , David N. McIlroy
发明人： M. Grant Norton , David N. McIlroy
IPC分类号： H01M8/06 , F02B43/00 , C01B3/02 , C01B3/16 , C01B3/26 , B01J23/00 , B01J21/08 , B01J27/24 , B01J23/52 , B01J23/50 , B01J23/42 , B01J23/745 , B01J23/755 , B01J23/75 , B01J23/72 , B01J23/44 , B01J23/06 , B01J21/06 , C07C5/03 , B82Y30/00 , B82Y40/00
CPC分类号： B01J23/42 , B01J21/063 , B01J21/08 , B01J23/06 , B01J23/38 , B01J23/52 , B01J23/70 , B01J35/0013 , B01J35/06 , B01J37/0215 , B01J37/0238 , B01J37/0244 , C01B3/02 , C01B3/16 , C01B3/22 , C01B3/26 , Y02P20/52
摘要： Nanostructured catalysts and related methods are described. The nanostructured catalysts have a hierarchical structure that facilitates modification of the catalysts for use in particular reactions. Methods for generating hydrogen from a hydrogen-containing molecular species using a nanostructured catalyst are described. The hydrogen gas may be collected and stored, or the hydrogen gas may be collected and consumed for the generation of energy. Thus, the methods may be used as part of the operation of an energy-consuming device or system, e.g., an engine or a fuel cell. Methods for storing hydrogen by using a nanostructured catalyst to react a dehydrogenated molecular species with hydrogen gas to form a hydrogen-containing molecular species are also described.
摘要翻译：描述了纳米结构催化剂和相关方法。纳米结构催化剂具有促进用于特定反应的催化剂改性的分层结构。描述了使用纳米结构催化剂从含氢分子物质产生氢的方法。可以收集和储存氢气，或者可以收集和消耗氢气以产生能量。因此，该方法可以用作耗能装置或系统（例如发动机或燃料电池）的操作的一部分。还描述了通过使用纳米结构催化剂将脱氢的分子物质与氢气反应以形成含氢分子物种的方法。

59. 发明授权

US07824656B2 Catalysts for hydrogen production 有权
标题翻译：用于氢气生产的催化剂
公开(公告)号：US07824656B2
公开(公告)日：2010-11-02
申请号：US11375088
申请日：2006-03-14
申请人： Raphael Oyom Idem , Prashant Kumar , Yanping Sun
发明人： Raphael Oyom Idem , Prashant Kumar , Yanping Sun
IPC分类号： C01B3/16 , C01B3/26 , B01J23/72 , B01J23/755 , B01J23/76 , B01J23/78 , B01J23/83
CPC分类号： B01J23/83 , B01J21/066 , B01J23/002 , B01J23/72 , B01J23/755 , B01J35/002 , B01J37/0018 , B01J37/0236 , B01J37/03 , B01J37/036 , B01J37/06 , B01J37/088 , B01J37/14 , B01J2523/00 , C01B3/16 , C01B3/38 , C01B3/40 , C01B2203/0238 , C01B2203/0283 , C01B2203/1058 , C01B2203/1076 , C01B2203/1082 , H01M8/0631 , H01M8/0668 , Y02P20/52 , B01J2523/3712 , B01J2523/48 , B01J2523/847 , B01J2523/17 , B01J2523/3706
摘要： The present invention relates to catalysts for the production of hydrogen using the water gas shift reaction and the carbon dioxide reforming of hydrocarbon-containing fuels. The catalysts nickel and/or copper on a ceria/zirconia support, where the support is prepared using a surfactant templating method. The invention also includes processes for producing hydrogen, reactors and hydrogen production systems utilizing these catalysts.
摘要翻译：本发明涉及使用水煤气变换反应和含烃燃料的二氧化碳重整来生产氢的催化剂。在二氧化铈/氧化锆载体上的催化剂镍和/或铜，其中使用表面活性剂模板法制备载体。本发明还包括利用这些催化剂生产氢气，反应器和氢气生产系统的方法。

60. 发明授权

US07704486B2 Precious metal water-gas shift catalyst with oxide support modified with rare earth elements 失效
标题翻译：贵金属水煤气变换催化剂与稀土元素改性氧化物载体
公开(公告)号：US07704486B2
公开(公告)日：2010-04-27
申请号：US11059148
申请日：2005-02-16
申请人： Oleg Mikhailovich Ilinich , Robert J. Farrauto , Wolfgang Friedrich Ruettinger , Xiaolin Yang
发明人： Oleg Mikhailovich Ilinich , Robert J. Farrauto , Wolfgang Friedrich Ruettinger , Xiaolin Yang
IPC分类号： C01B3/16
CPC分类号： C01B3/16 , B01J23/63 , B01J37/0018 , B01J2523/00 , C01B2203/107 , C01B2203/1082 , Y02P20/52 , B01J2523/31 , B01J2523/3718 , B01J2523/828 , B01J2523/3725
摘要： A water gas shift catalyst comprising a platinum group metal dispersed on an inorganic oxide support modified with a carbon-containing burn-out additive and a rare earth oxide. A water gas shift catalyst containing alumina, a platinum group metal, and oxides of Pr and Nd are also disclosed.
摘要翻译：一种水煤气变换催化剂，其包含分散在用含碳燃烧添加剂和稀土氧化物改性的无机氧化物载体上的铂族金属。还公开了含有氧化铝，铂族金属和Pr和Nd的氧化物的水煤气变换催化剂。

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