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51. 发明授权

US07902291B2 Aqueous polyurethane resin composition and one-component adhesive agent and laminated body that use the same, and method for manufacturing aqueous polyurethane resin composition 有权
标题翻译：水性聚氨酯树脂组合物和使用它们的单组分粘合剂和层压体，以及水性聚氨酯树脂组合物的制造方法
公开(公告)号：US07902291B2
公开(公告)日：2011-03-08
申请号：US12310464
申请日：2008-03-27
申请人： Masakazu Nishino
发明人： Masakazu Nishino
IPC分类号： B32B27/00 , B32B27/40 , C08G18/08 , C08J3/00 , C08K3/20 , C08L75/00
CPC分类号： C09J175/06 , C08G18/0819 , C08G18/0823 , C08G18/0828 , C08G18/12 , C08G18/4202 , C08G18/4238 , C08G18/4263 , C08G18/4277 , C08G18/4676 , C08G18/6659 , C08G2170/80 , Y10T428/31551 , C08G18/3225
摘要： An aqueous polyurethane resin composition obtained by: obtaining a neutralized prepolymer having a terminal isocyanate group by reacting a polyisocyanate (A) and a polyfunctional compound (B) containing a polyester polyol (B1) having an acidic group and at least one member selected from the group consisting of other polyols (B2) and chain extenders (B3) so as to satisfy a condition expressed by the following mathematical formula (1); and subjecting the neutralized prepolymer having a terminal isocyanate group to a chain elongation reaction with the use of a polyamine (C) containing at least two groups selected from the group consisting of an amino group and an imino group and water (D) so as to satisfy conditions expressed by the following mathematical formulas (2) and (3) to obtain a elongated product, and then dispersing the elongated product into water: 100/80≦a/b≦100/40 (1) 100/98≦a/(b+c)≦100/80 (2) 100/105≦a/(b+c+2d)≦100/95 (3) (in formulas (1) to (3), a represents the number of isocyanate groups (NCO) contained in the polyisocyanate (A), b represents the number of hydroxyl groups (OH) contained in the polyfunctional compound (B), c represents the number of the groups selected from the group consisting of an amino group (NH2) and an imino group (NH) contained in the polyamine (C), and d represents the number of moles of the water (D)).
摘要翻译：一种水性聚氨酯树脂组合物，其通过以下方法获得：通过使多异氰酸酯（A）和含有具有酸性基团的聚酯多元醇（B1）和选自以下的至少一种成分的多官能化合物（B）反应，得到具有末端异氰酸酯基的中和预聚物：由其他多元醇（B2）和扩链剂（B3）组成，以满足下列数学式（1）表示的条件; 并使用含有至少两个选自氨基和亚氨基的基团和水（D）的多胺（C）将具有末端异氰酸酯基的中和预聚物进行链延长反应，以便满足由以下数学式（2）和（3）表示的条件以获得细长的产品，然后将细长的产品分散在水中：100/80＆amp; 100; a / b＆nlE; 100/40（1）100/98＆（b + c）＆nlE; 100/80（2）100/105＆nlE; a /（b + c + 2d）＆nlE; 100/95（3）（式（1）〜（3）多异氰酸酯（A）中含有的异氰酸酯基（NCO），b表示多官能化合物（B）中所含的羟基数（OH），c表示选自氨基（NH 2））和多胺（C）中所含的亚氨基（NH），d表示水的摩尔数（D））。

52. 发明申请

US20110052823A1 AQUEOUS COATING MATERIAL, A METHOD FOR THE PRODUCTION THEREOF AND THE USE THEREOF 审中-公开
标题翻译：水性涂料，其生产方法及其用途
公开(公告)号：US20110052823A1
公开(公告)日：2011-03-03
申请号：US12919564
申请日：2009-02-12
申请人： Bernhard Steinmetz , Nadia Emmerich , Matthias Wetterich
发明人： Bernhard Steinmetz , Nadia Emmerich , Matthias Wetterich
IPC分类号： C09D175/04 , B05D1/36
CPC分类号： C08L51/085 , C08F283/006 , C08G18/0823 , C08G18/10 , C08G18/12 , C08G18/4288 , C08G18/6659 , C08G18/765 , C08L71/02 , C09D5/024 , C09D7/65 , C09D151/085 , C09D175/04 , C08G18/3275 , C08G18/3831 , C08L2666/02 , C08L2666/22
摘要： An aqueous coating material comprising at least one ionically and/or nonionically stabilized polyurethane, which is saturated, unsaturated and/or grafted with olefinically unsaturated compounds, wherein said coating material contains between 0.5% and 30% by weight of polytetrahydrofuran, based on the total weight of the coating material.
摘要翻译：一种包含至少一种离子和/或非离子稳定化的聚氨酯的水性涂料，其是饱和的，不饱和的和/或与烯属不饱和化合物接枝的，其中所述涂料含有0.5重量％至30重量％的聚四氢呋喃，重量的涂料。

53. 发明授权

US07863374B2 Self-curable water-based solid adhesive and bonding method using the self-curable water-based solid adhesive 失效
标题翻译：自固化水性固体粘合剂和使用自固化水性固体粘合剂的粘合方法
公开(公告)号：US07863374B2
公开(公告)日：2011-01-04
申请号：US11434216
申请日：2006-05-16
申请人： Syunsuke Shibahara , Kuniharu Harada , Shinsa Hamada , Kenji Ueji , Kenji Idemoto
发明人： Syunsuke Shibahara , Kuniharu Harada , Shinsa Hamada , Kenji Ueji , Kenji Idemoto
IPC分类号： C08J3/00 , C08K3/20 , C08L75/00 , C08L83/00 , C08L83/04 , C08G18/08 , C08G18/28 , C08G77/04 , C08G77/06 , C08G77/26 , C09J4/00 , C09J7/02 , C09J101/00 , C09J201/00 , D06M15/643
CPC分类号： C09J175/04 , C08G18/0823 , C08G18/12 , C08G18/289 , C08G18/6659 , C08G18/6692 , C09J9/005
摘要： Self-curable water-based solid adhesives of this invention include the following components (A), (B), (C), and (D):(A) an anionic-group-containing polymer terminally having an alkoxysilyl group, the polymer being a reaction product of a compound (A1) containing no anionic group and having plural isocyanate-reactive groups, a compound (A2) having an anionic group and plural isocyanate-reactive groups, a polyisocyanate compound (A3), and an alkoxysilane compound (A4) containing an isocyanate-reactive group;(B) a basic compound;(C) water; and(D) a gelling agent.The self-curable water-based solid adhesives of the present invention can be applied with good workability, have good fitting after attachment, have good adhesion to plastics, metals and glass and exhibit excellent heat resistance and water resistance after curing. They are highly safe to humans and the environment. They also have excellent shape retention and slidability and can be easily applied. In addition, they can bond adherends by contact bonding despite that they are water-based solid adhesives. Accordingly, the self-curable water-based solid adhesives of this invention are very useful as stick adhesives.
摘要翻译：本发明的自固化水性固体粘合剂包括以下组分（A），（B），（C）和（D）：（A）具有烷氧基甲硅烷基末端的含阴离子基团的聚合物，聚合物作为不含阴离子性基团且具有多个异氰酸酯反应性基团的化合物（A1），具有阴离子性基团和多个异氰酸酯反应性基团的化合物（A2），多异氰酸酯化合物（A3）和烷氧基硅烷化合物（ A4）含有异氰酸酯反应性基团; （B）碱性化合物; （C）水; 和（D）胶凝剂。本发明的可固化水性固体粘合剂可以施加良好的加工性，附着后具有良好的贴合性，对塑料，金属和玻璃具有良好的粘附性，并且在固化后具有优异的耐热性和耐水性。它们对人类和环境非常安全。它们还具有优异的形状保持性和滑动性，并且可以容易地应用。此外，它们可以通过接触粘合来粘合粘合剂，尽管它们是水基固体粘合剂。因此，本发明的可固化水性固体粘合剂作为粘合剂是非常有用的。

54. 发明授权

US07855266B2 Method for multilayer coatings with self-crosslinking graft polyurethane copolymers, self-crosslinking polyurethanes and graft copolymers thereof 有权
标题翻译：具有自交联接枝聚氨酯共聚物，自交联聚氨酯及其接枝共聚物的多层涂料的方法
公开(公告)号：US07855266B2
公开(公告)日：2010-12-21
申请号：US11620146
申请日：2007-01-05
申请人： Stephan Schwarte , Egon Wegner , Harald Angermüller
发明人： Stephan Schwarte , Egon Wegner , Harald Angermüller
IPC分类号： C08G18/32 , C08G18/67 , C08G18/66
CPC分类号： C09J151/003 , C08F283/006 , C08F290/147 , C08G18/0823 , C08G18/12 , C08G18/4233 , C08G18/6659 , C08G18/675 , C08L51/003 , C08L51/08 , C08L2666/04 , C08L2666/14 , C09D151/003 , C09D151/08 , C09D175/14 , C09J151/08 , C08G18/3271 , C08G18/286 , C08L33/00
摘要： The invention relates to a method for producing chromophore and/or effect giving multilayer lacquers according to the wet-on-wet method. A water base lacquer is applied which contains at least one graft copolymer containing (A) at least one (meth)acrylate copolymer and (B) at least one polyurethane. The graft copolymer can be produced by (1) dispersing at least one hydrophilic or hydrophobic self cross-linking polyurethane (B) with a statistical average of at least one terminal and/or at least one lateral olefinically unsaturated group and at least one blocked isocyanate group per molecule in an aqueous medium. (2) A mixture of a at least one monomer (a1) with at least one isocyanate reactive functional group at last one monomer (a2) that can be copolymerised therewith is subsequently radically copolymerised in an emulsion in the presence of the polyurethane (B) or the polyurethanes (B). A powder slurry transparent lacquer layer is added to the resulting base lacquer layer. The base lacquer layer and the transparent lacquer layer are hardened together. The invention also relates to novel hydrophilic or hydrophobic self cross-linking polyurethanes (B) with at least one lateral and/or at least one terminal olefinically unsaturated group and at least one lateral blocked isocyanate group per molecule and graft copolymers on the basis of said polyurethanes (B) as well as the use thereof.
摘要翻译：本发明涉及一种根据湿法湿法生产发色团和/或产生多层漆的效果的方法。应用含有（A）至少一种（甲基）丙烯酸酯共聚物和（B）至少一种聚氨酯）的至少一种接枝共聚物的水基漆。接枝共聚物可以通过（1）分散至少一种具有至少一个末端和/或至少一个侧面烯属不饱和基团的统计平均值的至少一种亲水或疏水性自交联聚氨酯（B）和至少一种封端异氰酸酯每个分子在水性介质中。（2）在聚氨酯（B）的存在下，将至少一种单体（a1）与至少一种可与其共聚的单体（a2）的至少一种异氰酸酯反应性官能团的混合物随后在乳液中自由基共聚，或聚氨酯（B）。将粉末浆状透明漆层加入到所得的基漆层中。基底漆层和透明漆层一起硬化。本发明还涉及具有至少一个侧链和/或至少一个末端烯属不饱和基团和每个分子至少一个侧向封端异氰酸酯基团的新型亲水或疏水自交联聚氨酯（B）和基于所述聚氨酯（B）及其用途。

55. 发明授权

US07825210B2 Aqueous, highly cross-linked two-component polyurethane coating system, method for the production and use thereof 有权
标题翻译：水性高交联双组分聚氨酯涂料体系，其制备和使用方法
公开(公告)号：US07825210B2
公开(公告)日：2010-11-02
申请号：US10830743
申请日：2004-04-23
申请人： Norbert Steidl , Alois Maier , Franz Wolfertstetter
发明人： Norbert Steidl , Alois Maier , Franz Wolfertstetter
IPC分类号： C08G18/30 , C08G18/40 , C08G18/08
CPC分类号： C09D175/04 , C08G18/0823 , C08G18/12 , C08G18/4277 , C08G18/44 , C08G18/6659 , C08G18/792 , C08G18/3206 , C08G18/3275 , C08G18/348
摘要： An aqueous highly cross-linked two-component polyurethane coating system is described with reduced hydrophilicity and improved resistance to chemicals which can be obtained by a) producing a binder component based on an aqueous solution or dispersion of low-molecular hydroxyfunctional and/or aminofunctional oligourethanes or polyurethanes and b) by subsequently reacting the binder component a) with a cross-linking component (H) in a ratio of 3:1 to 5:1, wherein water-dispersible polyisocyanates are used as the cross-linking component (H).
摘要翻译：描述了一种水性高度交联的双组分聚氨酯涂料体系，其具有降低的亲水性和改善的抗化学药品性能，其可以通过以下方式获得：a）基于低分子羟基官能和/或氨基官能的低聚氨酯的水溶液或分散体生产粘合剂组分或聚氨酯，和b）通过随后使粘合剂组分a）与3:1至5:1的比例的交联组分（H）反应，其中使用水分散性多异氰酸酯作为交联组分（H）。

56. 发明申请

US20100233490A1 Surface-treated metal material and metal surface treatment agent 有权
标题翻译：表面处理金属材料和金属表面处理剂
公开(公告)号：US20100233490A1
公开(公告)日：2010-09-16
申请号：US12308538
申请日：2007-06-22
申请人： Atsushi Morishita , Masahiro Fuda , Hiroshi Kanai , Hiroshi Kosuge , Tsutomu Tawa
发明人： Atsushi Morishita , Masahiro Fuda , Hiroshi Kanai , Hiroshi Kosuge , Tsutomu Tawa
IPC分类号： B32B15/095 , C08L83/08 , C04B24/22 , C08K3/32
CPC分类号： C09D175/12 , C08G18/0823 , C08G18/12 , C08G18/4238 , C08G18/44 , C08G18/6659 , C08G18/758 , C08G2150/90 , C09D5/08 , C09D175/06 , C23C26/00 , C23C30/00 , Y10T428/31605 , C08G18/3231 , C08G18/289 , C08L2666/06
摘要： The present invention provides a surface-treated metal material having a film formed on at least a portion of a surface of a metal material, the film containing at least polyurethane resin and silicon oxide, and a metal surface treatment agent used to obtain the surface-treated metal material. The polyurethane resin contains one or more of siloxane bond, dehydration-condensation bond of silanol group and different functional group, and silanol moiety, and urea bond. The sum of the siloxane bond, the dehydration-condensation bond of silanol group and different functional group, total amount of the silanol moiety, and the silicon oxide falls within a range of equal to or more than 1.6 wt % to equal to or less than 25 wt % for solids of the film. The ratio of the total amount of urea bond and urethane bond to the total amount of resin components falls within a range of equal to or more than 0.1 wt % to equal to or less than 10 wt %.
摘要翻译：本发明提供了一种表面处理的金属材料，其具有形成在金属材料表面的至少一部分上的膜，所述膜至少含有聚氨酯树脂和氧化硅，以及用于获得表面处理金属的金属表面处理剂，处理过的金属材料。聚氨酯树脂含有一个或多个硅氧烷键，硅烷醇基和不同官能团的脱水缩合键，以及硅烷醇部分和脲键。硅氧烷键，硅烷醇基和不同官能团的脱水缩合键，硅烷醇部分的总量和氧化硅的总和在1.6重量％以上的范围内，等于或小于对于固体膜为25重量％。脲键和氨基甲酸酯键的总量与树脂组分的总量的比例落入等于或大于0.1重量％至等于或小于10重量％的范围内。

57. 再颁专利

USRE41615E1 Crosslinked, water-soluble or water-dispersible polyurethanes 有权
标题翻译：交联的水溶性或水分散性聚氨酯
公开(公告)号：USRE41615E1
公开(公告)日：2010-08-31
申请号：US11165555
申请日：2005-06-24
申请人： Son Nguyen Kim , Axel Sanner , Peter Hössel , Volker Schehlmann
发明人： Son Nguyen Kim , Axel Sanner , Peter Hössel , Volker Schehlmann
IPC分类号： C08G18/62
CPC分类号： A61K8/046 , A61K8/87 , A61Q5/06 , C08G18/0819 , C08G18/12 , C08G18/3212 , C08G18/4018 , C08G18/4216 , C08G18/4854 , C08G18/6229 , C08G18/6254 , C08G18/6283 , C08G18/6625 , C08G18/6659 , C08G18/6692 , C08G18/755 , C08G18/307
摘要： The present invention relates to crosslinked, water-soluble or water-dispersible polyurethanes of A) at least one water-soluble or water-dispersible polyurethane prepolymer having terminal isocyanate groups of a) at least one compound having a molecular weight in the range from 56 to 300 which contains two active hydrogen atoms per molecule, b) at least one polymer containing two active hydrogen atoms per molecule, c) at least one compound which contains two active hydrogen atoms and at least one ionogenic or ionic group per molecule, d) at least one diisocyanate, B) at least one polymer containing groups which are reactive toward isocyanate groups, chosen from hydroxyl, and primary and secondary amino and/or carboxyl groups, or the salts thereof.
摘要翻译：本发明涉及交联的水溶性或水分散性聚氨酯，A）至少一种具有末端异氰酸酯基团的水溶性或水分散性聚氨酯预聚物，其具有a）至少一种分子量范围为56 至300，每分子含有两个活性氢原子，b）每分子含有两个活性氢原子的至少一种聚合物，c）至少一种含有两个活性氢原子和每个分子至少一个离子基团或离子基团的化合物，d）至少一种二异氰酸酯，B）含有选自羟基，伯和仲氨基和/或羧基的异氰酸酯基反应性基团的至少一种聚合物或其盐。

58. 发明申请

US20100209697A1 METHODS FOR PRODUCING PHOTOSENSITIVE MICROPARTICLES, NON-AQUEOUS DISPERSIONS THEREOF AND ARTICLES PREPARED THEREWITH 有权
标题翻译：生产感光性微生物的方法及其制备的非水性分散体及其制备方法
公开(公告)号：US20100209697A1
公开(公告)日：2010-08-19
申请号：US12719293
申请日：2010-03-08
申请人： Steven E. Bowles , Anu Chopra , James P. Colton , Dennis L. Faler , M. Frank Haley , Paul H. Lamers , Yunyi Lu , Kevin J. Stewart , Cathy A. Taylor , Feng Wang , Elizabeth A. Zezinka
发明人： Steven E. Bowles , Anu Chopra , James P. Colton , Dennis L. Faler , M. Frank Haley , Paul H. Lamers , Yunyi Lu , Kevin J. Stewart , Cathy A. Taylor , Feng Wang , Elizabeth A. Zezinka
IPC分类号： G02B1/10 , H01F1/26 , H01B1/12 , G02B5/23 , C09K11/06 , C08K5/057 , C08K5/5419 , C08L75/00 , B32B5/16
CPC分类号： G02B1/10 , C08G18/3275 , C08G18/348 , C08G18/6659 , C08G18/672 , C08G18/755 , C08G18/758 , C09D175/16 , G02B1/11 , G03C1/733 , G03F7/002 , G03F7/038 , G03F7/105 , G11B7/242 , Y10T428/25 , C08G18/0823
摘要： Described are non-aqueous dispersions of photosensitive polymeric microparticles, comprising: a) an organic continuous phase comprising an organic solvent; and b) photosensitive polymeric microparticles dispersed in the organic continuous phase. The microparticles comprise an at least partially polymerized component having integral surface and interior domains, wherein the surface domain comprises a polymeric material that is solubilized by the organic solvent, the interior domain comprises a polymeric material that is insoluble in the organic solvent, and the surface domain and/or interior domain is photosensitive. Also described are methods of producing such non-aqueous dispersions, curable film-forming compositions containing them, and photosensitive coated substrates.
摘要翻译：描述的是光敏聚合物微粒的非水分散体，包括：a）包含有机溶剂的有机连续相; 和b）分散在有机连续相中的光敏聚合物微粒。微粒包括具有整体表面和内部结构域的至少部分聚合的组分，其中表面结构域包含由有机溶剂溶解的聚合材料，内部结构域包含不溶于有机溶剂的聚合材料，表面域和/或内部域是光敏的。还描述了制备这种非水分散体，含有它们的可固化成膜组合物和感光涂布基材的方法。

59. 发明授权

US07705087B2 Polyurethane/urea containing pendant alkoxysilane groups 失效
标题翻译：含有侧链烷氧基硅烷基团的聚氨酯/尿素
公开(公告)号：US07705087B2
公开(公告)日：2010-04-27
申请号：US11920390
申请日：2005-05-18
申请人： Richard R. Roesler , Lyubov K. Gindin
发明人： Richard R. Roesler , Lyubov K. Gindin
IPC分类号： C08G18/08 , C08G18/71 , C08G77/04 , C08G77/06 , C08J3/00 , C08K3/20 , C08L75/00 , C08L83/00 , C08L83/04 , D06M15/643
CPC分类号： C08G18/12 , C08G18/0823 , C08G18/0866 , C08G18/283 , C08G18/3275 , C08G18/4238 , C08G18/6659 , C08G18/718 , C08J3/03 , C08J2375/00 , C09D175/04 , C08G18/3893 , C08G18/3228
摘要： The present invention relates to polyurethane/ureas wherein the polyurethane/ureas contain 0.5 to 6% by weight, based on the weight of the polyurethane/ureas, of alkoxysilane groups (calculated as Si, MW 28), which have been incorporated by the reaction of isocyanate groups with a dihydroxy compound containing urea and alkoxysilane groups, and wherein the polyurethane/ureas optionally contain hydrophilic groups and are optionally dispersed in an aqueous medium.The present invention also relates to a process for preparing these polyurethane/urea and to their use for preparing coatings.
摘要翻译：本发明涉及聚氨酯/尿素，其中聚氨酯/尿素基于聚氨酯/脲的重量计含有0.5至6重量％的烷氧基硅烷基团（以Si计，MW 28计），其通过反应引入的异氰酸酯基团与含有脲和烷氧基硅烷基团的二羟基化合物反应，并且其中所述聚氨酯/脲包含任选地含有亲水基团并且任选地分散在水性介质中。本发明还涉及一种制备这些聚氨酯/尿素的方法及其用于制备涂料的方法。

60. 发明申请

US20100093926A1 Polyurethane Based Pigment Dispersants Which Contain Reactive Double Bonds 有权
标题翻译：含有活性双键的聚氨酯颜料分散剂
公开(公告)号：US20100093926A1
公开(公告)日：2010-04-15
申请号：US12637947
申请日：2009-12-15
申请人： Stuart N. Richards , Andrew J. Shooter , Deverakonda Sarma
发明人： Stuart N. Richards , Andrew J. Shooter , Deverakonda Sarma
IPC分类号： C09D175/04 , C08G18/32 , C08G18/67
CPC分类号： C08G18/4277 , C08G18/10 , C08G18/4275 , C08G18/6625 , C08G18/6648 , C08G18/6692 , C08G18/672 , C08G18/6795 , C08G18/68 , C08K7/20 , C09D7/45 , C09D11/101 , C09D11/326 , C08G18/3275 , C08G18/6688 , C08G18/0823 , C08G18/6655 , C08G18/3212 , C08G18/6674 , C08G18/664 , C08G18/6659 , C08G18/6681
摘要： Polymeric urethane dispersants with solubilizing polymer chains and with reactive carbon to carbon double bonds are described. The reactive double bonds facilitate molecular weight build-up of the dispersant on dispersed particles (enhancing colloidal stability) or enhance the ability of the dispersants to be crosslinked into a matrix material.
摘要翻译：描述了具有增溶聚合物链和反应性碳 - 碳双键的聚合氨基甲酸酯分散剂。反应性双键促进分散剂在分散颗粒上的分子量增加（增强胶体稳定性）或提高分散剂交联成基质材料的能力。

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