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1. 发明授权

US07863374B2 Self-curable water-based solid adhesive and bonding method using the self-curable water-based solid adhesive 失效
标题翻译：自固化水性固体粘合剂和使用自固化水性固体粘合剂的粘合方法
公开(公告)号：US07863374B2
公开(公告)日：2011-01-04
申请号：US11434216
申请日：2006-05-16
申请人： Syunsuke Shibahara , Kuniharu Harada , Shinsa Hamada , Kenji Ueji , Kenji Idemoto
发明人： Syunsuke Shibahara , Kuniharu Harada , Shinsa Hamada , Kenji Ueji , Kenji Idemoto
IPC分类号： C08J3/00 , C08K3/20 , C08L75/00 , C08L83/00 , C08L83/04 , C08G18/08 , C08G18/28 , C08G77/04 , C08G77/06 , C08G77/26 , C09J4/00 , C09J7/02 , C09J101/00 , C09J201/00 , D06M15/643
CPC分类号： C09J175/04 , C08G18/0823 , C08G18/12 , C08G18/289 , C08G18/6659 , C08G18/6692 , C09J9/005
摘要： Self-curable water-based solid adhesives of this invention include the following components (A), (B), (C), and (D):(A) an anionic-group-containing polymer terminally having an alkoxysilyl group, the polymer being a reaction product of a compound (A1) containing no anionic group and having plural isocyanate-reactive groups, a compound (A2) having an anionic group and plural isocyanate-reactive groups, a polyisocyanate compound (A3), and an alkoxysilane compound (A4) containing an isocyanate-reactive group;(B) a basic compound;(C) water; and(D) a gelling agent.The self-curable water-based solid adhesives of the present invention can be applied with good workability, have good fitting after attachment, have good adhesion to plastics, metals and glass and exhibit excellent heat resistance and water resistance after curing. They are highly safe to humans and the environment. They also have excellent shape retention and slidability and can be easily applied. In addition, they can bond adherends by contact bonding despite that they are water-based solid adhesives. Accordingly, the self-curable water-based solid adhesives of this invention are very useful as stick adhesives.
摘要翻译：本发明的自固化水性固体粘合剂包括以下组分（A），（B），（C）和（D）：（A）具有烷氧基甲硅烷基末端的含阴离子基团的聚合物，聚合物作为不含阴离子性基团且具有多个异氰酸酯反应性基团的化合物（A1），具有阴离子性基团和多个异氰酸酯反应性基团的化合物（A2），多异氰酸酯化合物（A3）和烷氧基硅烷化合物（ A4）含有异氰酸酯反应性基团; （B）碱性化合物; （C）水; 和（D）胶凝剂。本发明的可固化水性固体粘合剂可以施加良好的加工性，附着后具有良好的贴合性，对塑料，金属和玻璃具有良好的粘附性，并且在固化后具有优异的耐热性和耐水性。它们对人类和环境非常安全。它们还具有优异的形状保持性和滑动性，并且可以容易地应用。此外，它们可以通过接触粘合来粘合粘合剂，尽管它们是水基固体粘合剂。因此，本发明的可固化水性固体粘合剂作为粘合剂是非常有用的。

2. 发明授权

US07084203B2 Self-reactive/curable water-based solid adhesive and method of bonding with the self-reactive/curable water-based solid adhesive 失效
标题翻译：自反应/固化水性固体粘合剂和与自反应/固化水性固体粘合剂粘合的方法
公开(公告)号：US07084203B2
公开(公告)日：2006-08-01
申请号：US10473948
申请日：2002-09-26
申请人： Syunsuke Shibahara , Kuniharu Harada , Shinsa Hamada , Kenji Ueji , Kenji Idemoto
发明人： Syunsuke Shibahara , Kuniharu Harada , Shinsa Hamada , Kenji Ueji , Kenji Idemoto
IPC分类号： C08J3/00 , C08K3/20 , C08L75/00 , C08L83/00 , C08G77/04
CPC分类号： C09J175/04 , C08G18/0823 , C08G18/12 , C08G18/289 , C08G18/6659 , C08G18/6692 , C09J9/005
摘要： Self-curable water-based solid adhesives of this invention include the following components (A), (B), (C), and (D): (A) an anionic-group-containing polymer terminally having an alkoxysilyl group, the polymer being a reaction product of a compound (A1) containing no anionic group and having plural isocyanate-reactive groups, a compound (A2) having an anionic group and plural isocyanate-reactive groups, a polyisocyanate compound (A3), and an alkoxysilane compound (A4) containing an isocyanate-reactive group; (B) a basic compound; (C) water; and (D) a gelling agent. The self-curable water-based solid adhesives of the present invention can be applied with good workability, have good fitting after attachment, have good adhesion to plastics, metals and glass and exhibit excellent heat resistance and water resistance after curing. They are highly safe to humans and the environment. They also have excellent shape retention and slidability and can be easily applied. In addition, they can bond adherends by contact bonding despite that they are water-based solid adhesives. Accordingly, the self-curable water-based solid adhesives of this invention are very useful as stick adhesives.
摘要翻译：本发明的自固化水性固体粘合剂包括以下组分（A），（B），（C）和（D）：（A）具有烷氧基甲硅烷基末端的含阴离子基团的聚合物，聚合物作为不含阴离子性基团且具有多个异氰酸酯反应性基团的化合物（A1），具有阴离子性基团和多个异氰酸酯反应性基团的化合物（A2），多异氰酸酯化合物（A3）和烷氧基硅烷化合物（ A4）含有异氰酸酯反应性基团; （B）碱性化合物; （C）水; 和（D）胶凝剂。本发明的可固化水性固体粘合剂可以施加良好的加工性，附着后具有良好的贴合性，对塑料，金属和玻璃具有良好的粘附性，并且在固化后具有优异的耐热性和耐水性。它们对人类和环境非常安全。它们还具有优异的形状保持性和滑动性，并且可以容易地应用。此外，它们可以通过接触粘合来粘合粘合剂，尽管它们是水基固体粘合剂。因此，本发明的可固化水性固体粘合剂作为粘合剂是非常有用的。

3. 发明申请

US20060183845A1 Aqueous silylated urethane compositions, aqueous adhesives for wrapping, and aqueous contact adhesives 审中-公开
标题翻译：水性甲硅烷基化聚氨酯组合物，用于包装的水性粘合剂和水性接触粘合剂
公开(公告)号：US20060183845A1
公开(公告)日：2006-08-17
申请号：US10549706
申请日：2004-03-16
申请人： Kuniharu Harada , Shigeki Mori , Yoshio Fukumoto
发明人： Kuniharu Harada , Shigeki Mori , Yoshio Fukumoto
IPC分类号： C08L83/04 , C08G18/08
CPC分类号： C08G18/2875 , C08G18/0823 , C08G18/12 , C08G2170/80 , C08K5/17 , C08G18/289 , C08L75/04
摘要： A water-based silylated urethane composition is used as a water-based adhesive that has high safety, develops satisfactory tackiness in a short time and has excellent initial bond strength. The water-based silylated urethane composition contains following Components (A), (B) and (C): (A) a urethane prepolymer containing an anionic group and a tertiary amino group and having a terminal alkoxysilyl group, the urethane prepolymer (A) being a reaction product of an anionic-group-free polyol compound (A1), an anionic-group-containing polyol compound (A2), a compound (A3) containing a tertiary amino group and an isocyanate-reactive group, a polyisocyanate compound (A4), an alkoxysilane compound (A5) containing an isocyanate-reactive group, and an amine-based chain extender (A6); (B) a basic compound; and (C) water
摘要翻译：使用水性甲硅烷基化聚氨酯组合物作为具有高安全性的水性粘合剂，在短时间内产生令人满意的粘合性并且具有优异的初始粘结强度。水性甲硅烷基化氨基甲酸酯组合物含有下述成分（A），（B）和（C）：（A）含有阴离子性基团和叔氨基并具有末端烷氧基甲硅烷基的氨基甲酸酯预聚物，氨基甲酸酯预聚物（A）作为无阴离子性基团的多元醇化合物（A1），含阴离子性基团的多元醇化合物（A2），含有叔氨基的化合物（A3）和异氰酸酯反应性基团的反应产物，多异氰酸酯化合物 A4），含有异氰酸酯反应性基团的烷氧基硅烷化合物（A5）和胺类增链剂（A6）; （B）碱性化合物; 和（C）水

4. 发明申请

US20080119607A1 Self-curable water-based solid adhesive and bonding method using the self-curable water-based solid adhesive 失效
标题翻译：自固化水性固体粘合剂和使用自固化水性固体粘合剂的粘合方法
公开(公告)号：US20080119607A1
公开(公告)日：2008-05-22
申请号：US11434216
申请日：2006-05-16
申请人： Syunsuke Shibahara , Kuniharu Harada , Shinsa Hamada , Kenji Ueji , Kenji Idemoto
发明人： Syunsuke Shibahara , Kuniharu Harada , Shinsa Hamada , Kenji Ueji , Kenji Idemoto
IPC分类号： C08L83/04
CPC分类号： C09J175/04 , C08G18/0823 , C08G18/12 , C08G18/289 , C08G18/6659 , C08G18/6692 , C09J9/005
摘要： Self-curable water-based solid adhesives of this invention include the following components (A), (B), (C), and (D): (A) an anionic-group-containing polymer terminally having an alkoxysilyl group, the polymer being a reaction product of a compound (A1) containing no anionic group and having plural isocyanate-reactive groups, a compound (A2) having an anionic group and plural isocyanate-reactive groups, a polyisocyanate compound (A3), and an alkoxysilane compound (A4) containing an isocyanate-reactive group; (B) a basic compound; (C) water; and (D) a gelling agent. The self-curable water-based solid adhesives of the present invention can be applied with good workability, have good fitting after attachment, have good adhesion to plastics, metals and glass and exhibit excellent heat resistance and water resistance after curing. They are highly safe to humans and the environment. They also have excellent shape retention and slidability and can be easily applied. In addition, they can bond adherends by contact bonding despite that they are water-based solid adhesives. Accordingly, the self-curable water-based solid adhesives of this invention are very useful as stick adhesives.
摘要翻译：本发明的自固化水性固体粘合剂包括以下组分（A），（B），（C）和（D）：（A）具有烷氧基甲硅烷基末端的含阴离子基团的聚合物，聚合物作为不含阴离子性基团且具有多个异氰酸酯反应性基团的化合物（A1），具有阴离子性基团和多个异氰酸酯反应性基团的化合物（A2），多异氰酸酯化合物（A3）和烷氧基硅烷化合物（ A4）含有异氰酸酯反应性基团; （B）碱性化合物; （C）水; 和（D）胶凝剂。本发明的可固化水性固体粘合剂可以施加良好的加工性，附着后具有良好的贴合性，对塑料，金属和玻璃具有良好的粘附性，并且在固化后具有优异的耐热性和耐水性。它们对人类和环境非常安全。它们还具有优异的形状保持性和滑动性，并且可以容易地应用。此外，它们可以通过接触粘合来粘合粘合剂，尽管它们是水基固体粘合剂。因此，本发明的可固化水性固体粘合剂作为粘合剂是非常有用的。

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