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51. 发明授权

US07214736B2 Fluorochemical composition for treatment of a fibrous substrate 有权
标题翻译：用于处理纤维基材的氟化合物组合物
公开(公告)号：US07214736B2
公开(公告)日：2007-05-08
申请号：US10444713
申请日：2003-05-23
申请人： Frans A. Audenaert , Rudolf J. Dams , Richard S. Buckanin , Cheryl L. S. Elsbernd , Chetan P. Jariwala , E. Steven McAlister , Pierre J. Vander Elst
发明人： Frans A. Audenaert , Rudolf J. Dams , Richard S. Buckanin , Cheryl L. S. Elsbernd , Chetan P. Jariwala , E. Steven McAlister , Pierre J. Vander Elst
IPC分类号： C08J3/00 , C08K3/20 , C08L75/00 , C08G18/28 , B05D3/04
CPC分类号： C08G18/3876 , C08G18/2825 , C08G18/283 , C08G18/2885 , C08G18/3812 , C08G18/3857 , C08G18/3861 , C08G18/4833 , C08G18/5015 , C08G18/6212 , C08G18/71 , C08G18/792 , D06M15/53 , D06M15/576 , Y10T442/172 , Y10T442/198 , Y10T442/20 , Y10T442/2189
摘要： Fluorochemical composition for rendering fibrous substrates oil repellent, water repellent, and/or stain or soil repellent. The composition comprises a dispersion or a solution of a fluorinated compound which comprises the reaction product of the following combination of reactants: (i) a fluorinated polyether according to the formula: Rf—Q—Tk (I) wherein Rf represents a monovalent perfluorinated polyether group having a molecular weight of at least 750 g/mol, Q represents a chemical bond or a divalent or trivalent organic linking group, T represents a functional group capable of reacting with an isocyanate and k is 1 or 2; (ii) an isocyanate component selected from a polyisocyanate compound that has at least 3 isocyanate groups or a mixture of polyisocyanate compounds wherein the average number of isocyanate groups per molecule is more than 2; and (iii) optionally one or more co-reactants capable of reacting with an isocyanate group.
摘要翻译：用于使纤维基质防油，防水和/或染色或防污的氟化合物。该组合物包含含氟化合物的分散体或溶液，其包含以下反应物组合的反应产物：（i）根据下式的含氟聚醚：<？in-line-formula description =“In-Line Formulas” end =“lead”？？？？？？？？？？？？？？？？？？？？？？？？？？？？在线公式描述=“内联公式”end =“tail”？其中R≠表示分子量为至少750g / mol的一价全氟化聚醚基团，Q表示化学键或二价或三价有机连接基团，T表示可以与异氰酸酯反应，k为1或2; （ii）选自具有至少3个异氰酸酯基团的多异氰酸酯化合物的异氰酸酯成分或每分子的异氰酸酯基平均数大于2的多异氰酸酯化合物的混合物; 和（iii）任选的一种或多种能够与异氰酸酯基反应的共反应物。

52. 发明授权

US07141537B2 Mixture of fluorinated polyethers and use thereof as surfactant 失效
标题翻译：氟化聚醚的混合物及其作为表面活性剂的用途
公开(公告)号：US07141537B2
公开(公告)日：2006-11-28
申请号：US10696950
申请日：2003-10-30
申请人： Frans A. Audenaert , Rudolf J. Dams , Lian S. Tan
发明人： Frans A. Audenaert , Rudolf J. Dams , Lian S. Tan
IPC分类号： C11D17/00
CPC分类号： C08G65/007 , C08G65/08 , C08G65/329 , C08L71/00 , C08L71/02
摘要： The present invention provides the use of a fluorinated polyether composition as a surfactant, said fluorinated polyether composition comprising a mixture of fluorinated polyethers of the formula: (Rf)n—Xw—Z (I) wherein n is 1 or 2, w is 0 or 1, X is a divalent or trivalent organic linking group, Z is a polar group selected from the group consisting of an acid group or a salt thereof, an ammonium group, an amine-oxide group and an amphoteric group, and Rf represents a perfluorinated polyether group of the formula: CF3CF2CF2—O—[CF(CF3)CF2O]k—CF(CF3)— wherein k is at least 1; said mixture of fluorinated polyethers having a weight average molecular weight between 750 g/mol and 5000 g/mol and the amount of perfluorinated polyether groups in said mixture where k is 2 or less, is not more than 10% by weight of the total amount of perfluorinated polyether groups in said mixture.
摘要翻译：本发明提供氟化聚醚组合物作为表面活性剂的用途，所述氟化聚醚组合物包含下列化学式的氟化聚醚的混合物：<？in-line-formula description =“In-line Formulas”end =“lead”？（R>）））-X -X -X w w w <<<<<<<<<<<<<<<<<<<<<<<<<<<“”“”“”“”“”“”“”“ 其中n为1或2，w为0或1，X为二价或三价有机连接基团，Z为选自酸基或其盐的极性基团，铵基团，氧化胺基团和两性基团，R f表示下式的全氟化聚醚基团：<？in-line-formula description =“In-line Formulas”end =“ CF 3 CF 3 CF 2 CF 2 CF 2 CF 2 CF 2 CF 2 CF 2 CF 3 > 2 -CF（CF 3） - <？in-line-formula description =“In-line Formulas”end =“tail” 其中k至少为1; 所述重均分子量在750g / mol至5000g / mol之间的所述氟化聚醚的混合物和所述混合物中的全氟化聚醚基团的量不超过总量的10重量％的全氟化聚醚基团。

53. 发明授权

US07097910B2 Coating composition comprising fluorochemical polyether silane polycondensate and use thereof 失效
公开(公告)号：US07097910B2
公开(公告)日：2006-08-29
申请号：US10701748
申请日：2003-11-05
申请人： George G. I. Moore , Rudolf J. Dams , Franceska M. Fieuws , Guido P. Piessens
发明人： George G. I. Moore , Rudolf J. Dams , Franceska M. Fieuws , Guido P. Piessens
IPC分类号： B32B27/00 , B05D3/02 , C08G77/24 , C08L83/00
CPC分类号： C08G65/007 , C08G65/336 , Y10T428/31612 , Y10T428/31663
摘要： A composition comprising the condensation product of a least one fluorochemical polyether silane compound having a polyfluoropolyether segment and at least two hydrolysable silane groups per molecule, with one or more non-fluorinated compounds having at least two hydrolysable groups per molecule, and the reaction product thereof, is disclosed. The composition provides durable water, oil and stain repellency to a substrate.

54. 发明授权

US07094829B2 Fluorochemical composition comprising a fluorinated polymer and treatment of a fibrous substrate therewith 有权
标题翻译：含氟化合物的氟化合物组合物和其纤维基质的处理
公开(公告)号：US07094829B2
公开(公告)日：2006-08-22
申请号：US10444878
申请日：2003-05-23
申请人： Frans A. Audenaert , Rudolf J. Dams , Richard S. Buckanin
发明人： Frans A. Audenaert , Rudolf J. Dams , Richard S. Buckanin
IPC分类号： C08K3/00
CPC分类号： C08G65/007 , C08G2650/48 , C08L71/02 , C08L2205/05 , D06M15/256 , D06M15/277 , D06M15/295 , D06M15/568 , D06M15/576 , D06M2200/01 , D06M2200/10 , D06M2200/11 , D06M2200/12 , C08L2666/22
摘要： A fluorochemical composition for rendering fibrous substrates oil repellent, water repellent, and/or stain repellent and comprising a fluorinated polymer dispersed in water or dissolved or dispersed in an organic solvent, the fluorinated polymer comprising units derived from (i) a mixture of two or more fluorinated polyether monomers that differ in at least their molecular weight, the fluorinated polyether monomers having an ethylenically unsaturated group and a perfluorinated polyether group and wherein at least 90% by weight of the mixture consists of fluorinated polyether monomers that have a perfluorinated polyether group having a molecular weight of at least 750 g/mol and (ii) one or more units derived from one or more co-monomers other than a fluorinated polyether monomer and wherein the co-monomers comprise at least one non-fluorinated monomer. Also, method for treating fibrous substrate with such composition, fluorinated polyether monomers, and fluorinated polymers derived from such monomers.
摘要翻译：一种氟化合物，用于使纤维基质具有防油性，防水性和/或防污性，并且包含分散在水中或溶解或分散在有机溶剂中的氟化聚合物，所述氟化聚合物包含衍生自（i）两种或至少其分子量不同的氟化聚醚单体，具有烯属不饱和基团的氟化聚醚单体和全氟化聚醚基团，其中至少90重量％的混合物由具有全氟化聚醚基团的氟化聚醚单体组成，至少750g / mol的分子量和（ii）一种或多种衍生自除氟化聚醚单体之外的一种或多种共聚单体的单元，其中共聚单体包含至少一种非氟化单体。此外，用这种组合物处理纤维基材的方法，氟化聚醚单体和衍生自这些单体的氟化聚合物。

55. 发明授权

US09499737B2 Method for treating hydrocarbon-bearing formations with fluorinated amine 有权
标题翻译：用氟化胺处理含烃地层的方法
公开(公告)号：US09499737B2
公开(公告)日：2016-11-22
申请号：US13996863
申请日：2011-12-21
申请人： Jimmie R. Baran, Jr. , George G. I. Moore , Nathan E. Schultz , Dean M. Moren , Yu Yang , Rudolf J. Dams
发明人： Jimmie R. Baran, Jr. , George G. I. Moore , Nathan E. Schultz , Dean M. Moren , Yu Yang , Rudolf J. Dams
IPC分类号： C09K8/60 , E21B43/16 , E21B43/26 , C07C303/40 , C07C311/08 , C09K8/68 , C09K8/88
CPC分类号： C09K8/602 , C07C303/40 , C07C311/08 , C09K8/68 , C09K8/88 , E21B43/26
摘要： A method of modifying a surface of a hydrocarbon-bearing formation is disclosed. The method includes contacting the surface of the hydrocarbon-bearing formation with a fluorinated amine, and the surface of the hydrocarbon-bearing formation includes a carbonate. The method can typically include introducing a treatment composition comprising solvent and at least one of the fluorinated amine or a salt thereof into the carbonate hydrocarbon-bearing formation. Hydrocarbon-bearing formations treated according to the method are also disclosed. Certain fluorinated amines useful for treating carbonate hydrocarbon-bearing formations and methods of making them are also disclosed.
摘要翻译：公开了一种改变含烃地层表面的方法。该方法包括使含烃地层的表面与氟化胺接触，并且含烃地层的表面包括碳酸盐。该方法通常可以包括将包含溶剂和至少一种氟化胺或其盐的处理组合物引入含碳酸盐烃的地层中。还公开了根据该方法处理的含烃地层。还公开了可用于处理碳酸盐含烃地层的某些氟化胺及其制备方法。

56. 发明申请

US20150259450A1 FLUOROPOLYETHER-BASED ELASTOMERS HAVING LOW GLASS TRANSITION TEMPERATURE 有权
标题翻译：具有低玻璃化转变温度的基于荧光玻璃的弹性体
公开(公告)号：US20150259450A1
公开(公告)日：2015-09-17
申请号：US14433005
申请日：2013-09-30
申请人： Steven G. CORVELEYN , Gregg D. DAHLKE , Rudolf J. DAMS , Werner M.A. GROOTAERT , Miguel A. GUERRA , Anthony P. MANZARA , Tom OPSTAL , 3M INNOVATIVE PROPERTIES COMPANY
发明人： Steven G. Corveleyn , Gregg D. Dahlke , Rudolf J. Dams , Werner M.A. Grootaert , Miguel A. Guerra , Anthony P. Manzara , Tom Opstal
IPC分类号： C08F122/38 , C09K3/10 , C08K3/16 , C08G65/00 , C08K3/36
CPC分类号： C08F122/38 , C08G18/5015 , C08G18/807 , C08G65/00 , C08G65/007 , C08G65/325 , C08G65/332 , C08G65/333 , C08G65/33365 , C08K3/16 , C08K3/36 , C08K5/0025 , C08K5/28 , C09K3/1009 , C09K2003/1053
摘要： A curable precursor composition for a fluoroelastomers, methods of making fluoroelastomers, shaped articles and methods of making shaped articles.
摘要翻译：用于含氟弹性体的可固化前体组合物，制备含氟弹性体的方法，成形制品以及制造成型制品的方法。

57. 发明授权

US08678090B2 Methods for treating hydrocarbon-bearing formations with fluorinated polymer compositions 有权
标题翻译：用含氟聚合物组合物处理含烃地层的方法
公开(公告)号：US08678090B2
公开(公告)日：2014-03-25
申请号：US12809683
申请日：2008-12-18
申请人： Jimmie R. Baran, Jr. , Michael S. Terrazas , Rudolf J. Dams , George G. I. Moore
发明人： Jimmie R. Baran, Jr. , Michael S. Terrazas , Rudolf J. Dams , George G. I. Moore
IPC分类号： E21B43/16
CPC分类号： C09K8/80 , C09K8/604
摘要： A method of treating a hydrocarbon-bearing formation and treated hydrocarbon-bearing formations. The method includes contacting the hydrocarbon-bearing formation with a composition having solvent and a fluorinated polymer. The fluorinated polymer has units having formula (I): A method for making a composition containing these units is also disclosed.
摘要翻译：一种处理含烃地层和经处理的含烃地层的方法。该方法包括使含烃地层与具有溶剂和含氟聚合物的组合物接触。氟化聚合物具有式（I）的单元：还公开了制备含有这些单元的组合物的方法。

58. 发明申请

US20140073737A1 TRIAZINE CONTAINING FLUOROPOLYETHER ELASTOMERS HAVING LOW GLASS TRANSITION TEMPERATURE 有权
标题翻译：含有低玻璃化转变温度的氟乙烯弹性体的TRIAZINE
公开(公告)号：US20140073737A1
公开(公告)日：2014-03-13
申请号：US14003141
申请日：2012-02-24
申请人： Miguel A. Guerra , Rudolf J. Dams , Steven G. Corveleyn
发明人： Miguel A. Guerra , Rudolf J. Dams , Steven G. Corveleyn
IPC分类号： C08L71/00 , C08G65/00
CPC分类号： C08G65/00 , C08G65/007 , C08G2650/48 , C08L71/00
摘要： There is provided a curable composition comprising: a) fluoropolyethers having a molecular weight of from about 400 g/mole up to about 20,000 g/mole and containing moieties selected from (—(CF2)4O—), (—(CF2)2O—), (—CF2O—) or combinations thereof and further containing at least one nitrile group at a terminal position or at a position that is adjacent to the terminal position; and b) one or more curing agents selected from non-fluorinated compounds containing one or more functional group linked to a common residue, said residue containing at least three carbon atoms wherein the functional groups are selected from primary amines, secondary amines and functional groups that generate primary or secondary amines upon heat treatment, wherein the composition can be cured by generating groups having a triazine structure. Also provided are cured composition, methods of making cured compositions, articles made by curing the cured compositions and methods of making articles using the curable composition.
摘要翻译：提供了一种可固化组合物，其包含：a）具有约400g / mol至约20,000g / mol的分子量的含氟聚醚，并且含有选自（ - （CF 2）4 O-），（ - （CF 2）），（-CF 2 O-）或其组合，并且在末端位置或与末端位置相邻的位置还含有至少一个腈基; 和b）一种或多种选自含有一个或多个与普通残基连接的官能团的非氟化合物的固化剂，所述残基含有至少三个碳原子，其中官能团选自伯胺，仲胺和官能团，其中在热处理时产生伯胺或仲胺，其中组合物可以通过产生具有三嗪结构的基团来固化。还提供固化组合物，固化组合物的制备方法，固化组合物固化的制品以及使用该可固化组合物制造制品的方法。

59. 发明授权

US08663741B2 Method for treating wheel rims and composition for use therein 有权
标题翻译：用于处理轮辋和组合物的方法
公开(公告)号：US08663741B2
公开(公告)日：2014-03-04
申请号：US13062233
申请日：2009-09-23
申请人： Rudolf J. Dams , Bernd Kuehneweg , Leonardus Doelen , Frank Koehler , Christoph Furtak , Frans A. Audenaert
发明人： Rudolf J. Dams , Bernd Kuehneweg , Leonardus Doelen , Frank Koehler , Christoph Furtak , Frans A. Audenaert
IPC分类号： B05D3/02
CPC分类号： C08G77/458 , C08G77/442 , C08L83/10 , C09D4/00 , C09D183/10 , C08L83/00
摘要： There is provided a method of treatment including (i) applying a treatment composition to at least a portion of the surface of a wheel rim and (ii) allowing a thus applied treatment composition to cure. There is also provided compounds and compositions useful in the method.
摘要翻译：提供了一种处理方法，包括（i）将处理组合物施加到轮缘表面的至少一部分，和（ii）允许如此施加的处理组合物固化。还提供了在该方法中有用的化合物和组合物。

60. 发明授权

US08629089B2 Method of contacting hydrocarbon-bearing formations with fluorinated ether compositions 失效
标题翻译：将含烃地层与氟化醚组合物接触的方法
公开(公告)号：US08629089B2
公开(公告)日：2014-01-14
申请号：US13140242
申请日：2009-12-17
申请人： Rudolf J. Dams
发明人： Rudolf J. Dams
IPC分类号： C09K8/60
CPC分类号： C09K8/80 , C08G65/007 , C09K8/584 , C09K8/602 , C09K8/88
摘要： Method comprising contacting a hydrocarbon-bearing formation with a composition comprising solvent and a fluoropolyether compound, wherein the fluoropolyether compound comprises at least one first divalent unit represented by formula: Each Rf is independently selected from the group consisting of Rfa—(O)t—CHL′-(CF2)n—; [Rfa—(O)t—C(L)H—CF2)—O]m—W—; Rfb—O—(CF2)p-; F(CkF2k)—(O—CkF2K(p—O—CF2—; and CF3—O—(CF2)3—OCF(CF3)—CF2)z—O-L1-. Treated hydrocarbon-bearing formations are also disclosed.
摘要翻译：方法包括使含烃地层与包含溶剂和含氟聚醚化合物的组合物接触，其中所述含氟聚醚化合物包含至少一个由式表示的第一二价单元：每个Rf独立地选自Rfa-（O）t- CHL' - （CF2）n-; [Rfa-（O）t -C（L）H-CF 2）-O] m -W-; Rfb-O-（CF2）p-; F（CkF2k） - （O-CkF2K（p-O-CF2-;和CF3-O-（CF2）3-OCF（CF3）-CF2）z-O-L1-也讨论了处理的含烃地层。

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