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1. 发明授权

US09023977B2 Triazine containing fluoropolyether elastomers having very low glass transition temperatures, compositions containing them and methods of making them 有权
标题翻译：含有玻璃化转变温度非常低的含氟聚醚弹性体的三嗪，含有它们的组合物及其制备方法
公开(公告)号：US09023977B2
公开(公告)日：2015-05-05
申请号：US13500526
申请日：2010-10-05
申请人： Steven G. Corveleyn , Rudolf J. Dams , Werner M. A. Grootaert , Gregg D. Dahlke , Miguel A. Guerra
发明人： Steven G. Corveleyn , Rudolf J. Dams , Werner M. A. Grootaert , Gregg D. Dahlke , Miguel A. Guerra
IPC分类号： C08G65/00
CPC分类号： C08G65/007
摘要： A method of making a fluoropolyether elastomer containing triazine groups and having a glass transition temperature of less than −40° C., including providing (i) one or more saturated fluoropolyethers containing repeating moieties selected from (—C4F8O—), (—C3F6O—), (—C2F4O—), (—CF2O—) and combinations thereof and further containing at least one functional group at a terminal carbon atom of the backbone chain, or of a side chain if present, wherein the terminal carbon atom may be a primary or secondary carbon atom and wherein the functional group is capable of reacting with a functional group of the fluorinated compound according to (ii) below to form a triazine ring, (ii) one or more fluorinated compound containing at least one perfluorinated alkyl or perfluorinated alkylene moiety wherein the carbon atoms of the perfluorinated alkyl or alkylene moiety may be interrupted by one or more oxygen atoms and wherein the fluorinated compound further contains at least one functional group capable of reacting with the functional group of the one or more fluoropolyethers to form a triazine; curing the components according to (i) and (ii) to form triazines. Further provided are cured compositions, articles comprising the cured compositions and methods of making articles.
摘要翻译：包括制备含有三嗪基并具有小于-40℃的玻璃化转变温度的氟聚醚弹性体的方法，包括提供（i）一种或多种含有重复部分的饱和含氟聚醚，所述重复部分选自（-C 4 F 8 O - ），（-C 3 F 6 O- ），（-C 2 F 4 O-），（-CF 2 O-）及其组合，并且在主链的末端碳原子或侧链（如果存在）中还含有至少一个官能团，其中末端碳原子可以是伯或仲碳原子，其中所述官能团能够与根据下述（ii）的氟化化合物的官能团反应以形成三嗪环，（ii）一种或多种含有至少一种全氟化烷基或全氟化的含氟化合物亚烷基部分，其中全氟烷基或亚烷基部分的碳原子可被一个或多个氧原子间隔，并且其中所述氟化化合物还含有至少一个f 能够与一种或多种含氟聚醚的官能团反应以形成三嗪的官能团; 根据（i）和（ii）固化组分以形成三嗪。还提供了固化组合物，包含固化组合物的制品和制造制品的方法。

2. 发明授权

US09290619B2 Triazine containing fluoropolyether elastomers having low glass transition temperature 有权
标题翻译：具有低玻璃化转变温度的含氟聚醚弹性体的三嗪
公开(公告)号：US09290619B2
公开(公告)日：2016-03-22
申请号：US14003141
申请日：2012-02-24
申请人： Miguel A. Guerra , Rudolf J. Dams , Steven G. Corveleyn
发明人： Miguel A. Guerra , Rudolf J. Dams , Steven G. Corveleyn
IPC分类号： C08G67/02 , C08K5/16 , B01J8/36 , C08G73/24 , C08G65/00 , C08L71/00
CPC分类号： C08G65/00 , C08G65/007 , C08G2650/48 , C08L71/00
摘要： There is provided a curable composition comprising: a) fluoropolyethers having a molecular weight of from about 400 g/mole up to about 20,000 g/mole and containing moieties selected from (—(CF2)4O—), (—(CF2)2O—), (—CF2O—) or combinations thereof and further containing at least one nitrile group at a terminal position or at a position that is adjacent to the terminal position; and b) one or more curing agents selected from non-fluorinated compounds containing one or more functional group linked to a common residue, said residue containing at least three carbon atoms wherein the functional groups are selected from primary amines, secondary amines and functional groups that generate primary or secondary amines upon heat treatment, wherein the composition can be cured by generating groups having a triazine structure. Also provided are cured composition, methods of making cured compositions, articles made by curing the cured compositions and methods of making articles using the curable composition.
摘要翻译：提供了一种可固化组合物，其包含：a）具有约400g / mol至约20,000g / mol的分子量的含氟聚醚，并且含有选自（ - （CF 2）4 O-），（ - （CF 2）），（-CF 2 O-）或其组合，并且在末端位置或与末端位置相邻的位置还含有至少一个腈基; 和b）一种或多种选自含有一个或多个与普通残基连接的官能团的非氟化合物的固化剂，所述残基含有至少三个碳原子，其中官能团选自伯胺，仲胺和官能团，其中在热处理时产生伯胺或仲胺，其中组合物可以通过产生具有三嗪结构的基团来固化。还提供固化组合物，固化组合物的制备方法，固化组合物固化的制品以及使用该可固化组合物制造制品的方法。

3. 发明申请

US20120220719A1 TRIAZINE CONTAINING FLUOROPOLYETHER ELASTOMERS HAVING VERY LOW GLASS TRANSITION TEMPERATURES, COMPOSITIONS CONTAINING THEM AND METHODS OF MAKING THEM 有权
标题翻译：含有非常低的玻璃态过渡温度的含氟荧光体弹性体的TRIAZINE，包含它们的组合物及其制备方法
公开(公告)号：US20120220719A1
公开(公告)日：2012-08-30
申请号：US13500526
申请日：2010-10-05
申请人： Steven G. Corveleyn , Rudolf J. Dams , Werner M.A. Grootaert , Gregg D. Dahlke , Miguel A. Guerra
发明人： Steven G. Corveleyn , Rudolf J. Dams , Werner M.A. Grootaert , Gregg D. Dahlke , Miguel A. Guerra
IPC分类号： C08G63/44 , B29C45/00 , B29C43/00 , C08K9/04
CPC分类号： C08G65/007
摘要： A method of making a fluoropolyether elastomer containing triazine groups and having a glass transition temperature of less than −40° C., including providing (i) one or more saturated fluoropolyethers containing repeating moieties selected from (—C4F8O—), (—C3F6O—), (—C2F4O—), (—CF2O—) and combinations thereof and further containing at least one functional group at a terminal carbon atom of the backbone chain, or of a side chain if present, wherein the terminal carbon atom may be a primary or secondary carbon atom and wherein the functional group is capable of reacting with a functional group of the fluorinated compound according to (ii) below to form a triazine ring, (ii) one or more fluorinated compound containing at least one perfluorinated alkyl or perfluorinated alkylene moiety wherein the carbon atoms of the perfluorinated alkyl or alkylene moiety may be interrupted by one or more oxygen atoms and wherein the fluorinated compound further contains at least one functional group capable of reacting with the functional group of the one or more fluoropolyethers to form a triazine; curing the components according to (i) and (ii) to form triazines. Further provided are cured compositions, articles comprising the cured compositions and methods of making articles.
摘要翻译：包括制备含有三嗪基并具有小于-40℃的玻璃化转变温度的氟聚醚弹性体的方法，包括提供（i）一种或多种含有重复部分的饱和含氟聚醚，所述重复部分选自（-C 4 F 8 O - ），（-C 3 F 6 O- ），（-C 2 F 4 O-），（-CF 2 O-）及其组合，并且在主链的末端碳原子或侧链（如果存在）中还含有至少一个官能团，其中末端碳原子可以是伯或仲碳原子，其中所述官能团能够与根据下述（ii）的氟化化合物的官能团反应以形成三嗪环，（ii）一种或多种含有至少一种全氟化烷基或全氟化的含氟化合物亚烷基部分，其中全氟烷基或亚烷基部分的碳原子可被一个或多个氧原子间隔，并且其中所述氟化化合物还含有至少一个f 能够与一种或多种含氟聚醚的官能团反应以形成三嗪的官能团; 根据（i）和（ii）固化组分以形成三嗪。还提供了固化组合物，包含固化组合物的制品和制造制品的方法。

4. 发明授权

US07507444B2 Method of bonding a fluoropolymer to a silicone layer 失效
标题翻译：将含氟聚合物粘合到硅氧烷层的方法
公开(公告)号：US07507444B2
公开(公告)日：2009-03-24
申请号：US11424633
申请日：2006-06-16
申请人： Steven G. Corveleyn , Eduard M. Horemans
发明人： Steven G. Corveleyn , Eduard M. Horemans
IPC分类号： B05D3/02
CPC分类号： B32B25/08 , B32B25/20 , B32B27/08 , B32B27/322 , B32B2038/0076 , B32B2264/101 , B32B2305/72 , C08J5/12 , Y10T428/3154 , Y10T428/31663
摘要： The present invention relates to a method of bonding a fluoropolymer layer to a silicone layer by (i) providing a fluoropolymer layer comprising a fluoropolymer capable of being dehydrofluorinated (ii) providing a silicone layer comprising a curable silicone composition comprising (a) an organopolysiloxane compound having SiH groups, (b) an organopolysiloxane compound having aliphatic carbon-carbon unsaturated bonds, (c) a hydrosilylation catalyst and (d) an amino compound having (1) an amine function of the formula —NHR wherein R is hydrogen or an organic group and (2) a silyl group of the formula —SiR1n(OR2)3—n wherein R1 represents an alkyl or aryl group, R2 represents an alkyl group of 2 to 6 carbon atoms and n is 1 or 2 and (iii) contacting said silicone layer and said fluoropolymer layer and causing said curable silicone composition of said silicone layer to cure.
摘要翻译：本发明涉及通过（i）提供包含能够脱氟化氢的含氟聚合物的含氟聚合物层（ii）提供含有可固化的有机硅组合物的硅氧烷层的含氟聚合物层与硅氧烷层的粘合方法，所述可固化的有机硅组合物包含（a）有机聚硅氧烷化合物具有SiH基团，（b）具有脂族碳 - 碳不饱和键的有机聚硅氧烷化合物，（c）氢化硅烷化催化剂和（d）具有（1）式-NHR的胺官能团的氨基化合物，其中R是氢或有机基团和（2）式-SiR1n（OR2）3-n的甲硅烷基，其中R1表示烷基或芳基，R2表示2至6个碳原子的烷基，n表示1或2，（iii）所述硅氧烷层和所述氟聚合物层，并使所述硅氧烷层的所述可固化硅氧烷组合物固化。

5. 发明授权

US09902836B2 Fluoropolyether elastomer compositions having low glass transition temperatures 有权
公开(公告)号：US09902836B2
公开(公告)日：2018-02-27
申请号：US14009929
申请日：2012-03-13
申请人： Steven G. Corveleyn , Miguel A. Guerra , Rudolf J. Dams , Tom Opstal
发明人： Steven G. Corveleyn , Miguel A. Guerra , Rudolf J. Dams , Tom Opstal
IPC分类号： C08K5/14 , C08K5/06 , C08G65/00 , C08L71/00
CPC分类号： C08K5/14 , C08G65/007 , C08G2650/48 , C08L71/00
摘要： A curable composition is provided. The curable composition has at least one functionalized fluoropolyether and at least one radical curing system. Further provided are fluoroelastomer compositions having a glass transition temperature of less than −40° C. and shaped articles comprising fluoroelastomers having glass transition temperatures of less than −40° C. obtained by curing the curable compositions. Also described are methods of making fluoroelastomer compositions having glass transition temperatures of less than −40° C.

6. 发明申请

US20140066572A1 FLUOROPOLYETHER ELASTOMER COMPOSITIONS HAVING LOW GLASS TRANSITION TEMPERATURES 有权
标题翻译：具有低玻璃化转变温度的氟聚乙烯弹性体组合物
公开(公告)号：US20140066572A1
公开(公告)日：2014-03-06
申请号：US14009929
申请日：2012-03-13
申请人： Steven G. Corveleyn , Miguel A. Guerra , Rudolf J. Dams , Tom Opstal
发明人： Steven G. Corveleyn , Miguel A. Guerra , Rudolf J. Dams , Tom Opstal
IPC分类号： C08K5/14
CPC分类号： C08K5/14 , C08G65/007 , C08G2650/48 , C08L71/00
摘要： A curable composition is provided. The curable composition has at least one functionalized fluoropolyether and at least one radical curing system. Further provided are fluoroelastomer compositions having a glass transition temperature of less than −40° C. and shaped articles comprising fluoroelastomers having glass transition temperatures of less than −40° C. obtained by curing the curable compositions. Also described are methods of making fluoroelastomer compositions having glass transition temperatures of less than −40° C.
摘要翻译：提供可固化组合物。可固化组合物具有至少一种官能化氟聚醚和至少一种自由基固化体系。还提供了玻璃化转变温度低于-40℃的含氟弹性体组合物和通过固化可固化组合物获得的包含玻璃化转变温度低于-40℃的含氟弹性体的成型制品。还描述了制备玻璃化转变温度低于-40℃的含氟弹性体组合物的方法。

7. 发明授权

US07091268B2 Fluoroelastomer composition comprising a mineral oil 失效
公开(公告)号：US07091268B2
公开(公告)日：2006-08-15
申请号：US10009353
申请日：2001-06-08
申请人： Steven G. Corveleyn
发明人： Steven G. Corveleyn
IPC分类号： C08K3/20 , C08L91/06
CPC分类号： C08K9/12 , C08K3/04 , C08L27/16 , C08L91/00 , C08L27/12
摘要： The present invention provides the use of a mineral oil in a fluoroelastomer composition comprising a fluoroelastomer to improve the flow of said composition during processing to form an article therefrom and/or to improve the release from a mold of a vulcanized article produced from said fluoroelastomer composition. Further provide are a fluoroelastomer composition that includes a mineral oil, a method of making an article therewith and a method of preparing the fluoroelastomer composition.

8. 发明申请

US20150259450A1 FLUOROPOLYETHER-BASED ELASTOMERS HAVING LOW GLASS TRANSITION TEMPERATURE 有权
标题翻译：具有低玻璃化转变温度的基于荧光玻璃的弹性体
公开(公告)号：US20150259450A1
公开(公告)日：2015-09-17
申请号：US14433005
申请日：2013-09-30
申请人： Steven G. CORVELEYN , Gregg D. DAHLKE , Rudolf J. DAMS , Werner M.A. GROOTAERT , Miguel A. GUERRA , Anthony P. MANZARA , Tom OPSTAL , 3M INNOVATIVE PROPERTIES COMPANY
发明人： Steven G. Corveleyn , Gregg D. Dahlke , Rudolf J. Dams , Werner M.A. Grootaert , Miguel A. Guerra , Anthony P. Manzara , Tom Opstal
IPC分类号： C08F122/38 , C09K3/10 , C08K3/16 , C08G65/00 , C08K3/36
CPC分类号： C08F122/38 , C08G18/5015 , C08G18/807 , C08G65/00 , C08G65/007 , C08G65/325 , C08G65/332 , C08G65/333 , C08G65/33365 , C08K3/16 , C08K3/36 , C08K5/0025 , C08K5/28 , C09K3/1009 , C09K2003/1053
摘要： A curable precursor composition for a fluoroelastomers, methods of making fluoroelastomers, shaped articles and methods of making shaped articles.
摘要翻译：用于含氟弹性体的可固化前体组合物，制备含氟弹性体的方法，成形制品以及制造成型制品的方法。

9. 发明申请

US20140073737A1 TRIAZINE CONTAINING FLUOROPOLYETHER ELASTOMERS HAVING LOW GLASS TRANSITION TEMPERATURE 有权
标题翻译：含有低玻璃化转变温度的氟乙烯弹性体的TRIAZINE
公开(公告)号：US20140073737A1
公开(公告)日：2014-03-13
申请号：US14003141
申请日：2012-02-24
申请人： Miguel A. Guerra , Rudolf J. Dams , Steven G. Corveleyn
发明人： Miguel A. Guerra , Rudolf J. Dams , Steven G. Corveleyn
IPC分类号： C08L71/00 , C08G65/00
CPC分类号： C08G65/00 , C08G65/007 , C08G2650/48 , C08L71/00
摘要： There is provided a curable composition comprising: a) fluoropolyethers having a molecular weight of from about 400 g/mole up to about 20,000 g/mole and containing moieties selected from (—(CF2)4O—), (—(CF2)2O—), (—CF2O—) or combinations thereof and further containing at least one nitrile group at a terminal position or at a position that is adjacent to the terminal position; and b) one or more curing agents selected from non-fluorinated compounds containing one or more functional group linked to a common residue, said residue containing at least three carbon atoms wherein the functional groups are selected from primary amines, secondary amines and functional groups that generate primary or secondary amines upon heat treatment, wherein the composition can be cured by generating groups having a triazine structure. Also provided are cured composition, methods of making cured compositions, articles made by curing the cured compositions and methods of making articles using the curable composition.
摘要翻译：提供了一种可固化组合物，其包含：a）具有约400g / mol至约20,000g / mol的分子量的含氟聚醚，并且含有选自（ - （CF 2）4 O-），（ - （CF 2）），（-CF 2 O-）或其组合，并且在末端位置或与末端位置相邻的位置还含有至少一个腈基; 和b）一种或多种选自含有一个或多个与普通残基连接的官能团的非氟化合物的固化剂，所述残基含有至少三个碳原子，其中官能团选自伯胺，仲胺和官能团，其中在热处理时产生伯胺或仲胺，其中组合物可以通过产生具有三嗪结构的基团来固化。还提供固化组合物，固化组合物的制备方法，固化组合物固化的制品以及使用该可固化组合物制造制品的方法。

10. 发明申请

US20120009438A1 TRIAZINE CONTAINING FLUOROELASTOMERS HAVING LOW GLASS TRANSITION TEMPERATURE 审中-公开
标题翻译：含有低玻璃化转变温度的含荧光物质的TRIAZINE
公开(公告)号：US20120009438A1
公开(公告)日：2012-01-12
申请号：US12833522
申请日：2010-07-09
申请人： Rudolf J. Dams , Steven G. Corveleyn , Werner M. A. Grootaert , Gregg D. Dahlke , Miguel A. Guerra
发明人： Rudolf J. Dams , Steven G. Corveleyn , Werner M. A. Grootaert , Gregg D. Dahlke , Miguel A. Guerra
IPC分类号： B32B9/00 , C08L27/12 , C08F214/18
CPC分类号： C08G65/007 , C08G2650/48 , C08L71/00 , C08L27/12
摘要： There is provided a curable fluoroelastomer composition comprising i. a first compound which comprising repeating units derived from a fluorinated olefin and further comprising at least one functional group, ii. a second compound comprising repeating units selected from (—C4F8O—), (—C2F4O—) or (—CF2O) or a combination thereof and further containing at least one functional group capable of reacting with the at least one functional group of the first compound either directly or in the presence of a curing compound to form a triazine unit, wherein the composition after curing by forming triazine units has a glass transition temperature of less than −60° C. Also provided are shaped articles comprising the cured compositions, methods of making cured compositions and methods for making shaped articles.
摘要翻译：提供了可固化的含氟弹性体组合物，其包含i。包含衍生自氟化烯烃的重复单元并且还包含至少一个官能团的第一化合物，ii。包含选自（-C 4 F 8 O-），（-C 2 F 4 O-）或（-CF 2 O）的重复单元或其组合的第二化合物，并且还含有至少一个能够与第一化合物的至少一个官能团反应的官能团直接或在固化化合物存在下形成三嗪单元，其中通过形成三嗪单元固化后的组合物具有小于-60℃的玻璃化转变温度。还提供了包含固化组合物的成型制品，制成固化组合物和制造成型制品的方法。

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