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51. 发明授权

US4726838A 3H imidazo[1'2':2,2]pyrrolo[3,4-b]pyridine-2,5-dione, useful as herbicidal agents 失效
标题翻译： 3H咪唑并[1'2“：2,2]吡咯并[3,4-b]吡啶-2,5-二酮，可用作除草剂
公开(公告)号：US4726838A
公开(公告)日：1988-02-23
申请号：US936216
申请日：1986-12-01
申请人： Dieter Durr , Hans-Georg Brunner , Henry Szczepanski
发明人： Dieter Durr , Hans-Georg Brunner , Henry Szczepanski
IPC分类号： A01N43/90 , C07D471/14 , A01N43/36 , A01N43/40
CPC分类号： C07D471/14 , A01N43/90
摘要： This continuation-in-part is directed to novel pyridine compounds of formula I below have good selective herbicidal properties pre- and postemergence and also influence or inhibit plant growth. The compounds are of formula I ##STR1## wherein each of X, Y and Z independently of one another is hydrogen or a C.sub.1 -C.sub.4 alkyl group, or two adjacent substituents together also form a saturated or unsaturated 3- or 4-membered alkylene chain or alkenyl chain, each of which chains may in turn by substituted by one to four C.sub.1 -C.sub.4 alkyl groups and R is a C.sub.1 -C.sub.4 nitroalkyl group.
摘要翻译：这部分继续部分是针对以下式I的新型吡啶化合物在芽前和芽后具有良好的选择性除草性质，并且还影响或抑制植物生长。所述化合物具有式I（I）其中X，Y和Z各自独立地为氢或C 1 -C 4烷基，或两个相邻取代基一起也形成饱和或不饱和的3-或4- 每个链可以依次被1-4个C1-C4烷基取代，R是C1-C4烷基。

52. 发明授权

US4715883A Thiadiazolyl-glyoxylonitrile-2-oxime ether derivatives for protecting plant crops 失效
标题翻译：噻二唑基 - 乙醛腈-2-肟醚衍生物，用于保护植物作物
公开(公告)号：US4715883A
公开(公告)日：1987-12-29
申请号：US423354
申请日：1982-09-24
申请人： Alfons Lukaszczyk , Henry Martin , Peter J. Diel , Werner Fory , Karl Gotzi , Haukur Kristinsson , Beat Muller , Rene Muntwyler , Johannes P. Pachlatko , Hermann Rempfler , Rolf Schurter , Henry Szczepanski
发明人： Alfons Lukaszczyk , Henry Martin , Peter J. Diel , Werner Fory , Karl Gotzi , Haukur Kristinsson , Beat Muller , Rene Muntwyler , Johannes P. Pachlatko , Hermann Rempfler , Rolf Schurter , Henry Szczepanski
IPC分类号： A01N25/32 , A01N43/824 , C07C251/32 , C07C259/10 , C07C311/16 , C07C317/32 , C07C317/44 , C07C317/46 , C07C317/48 , C07C323/47 , C07C327/20 , C07D213/53 , C07D213/61 , C07D213/64 , C07D213/65 , C07D213/69 , C07D213/70 , C07D213/79 , C07D215/32 , C07D215/34 , C07D233/26 , C07D233/86 , C07D235/14 , C07D235/16 , C07D249/06 , C07D263/56 , C07D263/58 , C07D277/64 , C07D285/12 , C07D285/125 , C07D285/13 , C07D307/20 , C07D307/52 , C07D309/20 , C07D309/32 , C07D311/58 , C07D317/58 , C07D335/06 , C07D339/06 , C07D339/08 , A01N43/82
CPC分类号： C07D213/53 , C07D213/61 , C07D213/64 , C07D213/65 , C07D213/69 , C07D213/70 , C07D213/79 , C07D215/32 , C07D215/34 , C07D233/26 , C07D233/86 , C07D235/14 , C07D235/16 , C07D249/06 , C07D263/56 , C07D277/64 , C07D285/12 , C07D285/125 , C07D285/13 , C07D307/20 , C07D307/52 , C07D309/20 , C07D309/32 , C07D311/58 , C07D317/58 , C07D335/06 , C07D339/06 , C07D339/08 , Y10S47/03
摘要： A process for protecting cultivated plants against aggressive agricultural chemicals is described in which oxide derivatives of the formula ##STR1## are used as antidotes. Either the cultivated area for the cultivated plants or the cultivated plants themselves or parts of the plant (seeds, tubers, stem parts, and the like), as desired, can be treated with these oxide derivatives, which are used as a dressing.
摘要翻译：描述了保护栽培植物免受侵袭性农药的方法，其中使用式（IMAGE）的氧化物衍生物作为解毒剂。根据需要，可以用用作敷料的这些氧化物衍生物来处理栽培植物或栽培植物本身或植物的部分（种子，块茎，茎部等）的栽培面积。

53. 发明授权

US4497648A Oxime derivatives for protecting plant crops 失效
标题翻译：用于保护植物作物的肟衍生物
公开(公告)号：US4497648A
公开(公告)日：1985-02-05
申请号：US407668
申请日：1982-08-12
申请人： Henry Szczepanski
发明人： Henry Szczepanski
IPC分类号： A01N25/32 , A01N37/50 , A01N43/28 , A01N43/32 , C07C275/50 , C07D263/14 , C07D295/185 , C07D317/18 , C07D319/06 , A01N37/34
CPC分类号： C07D295/185 , A01N25/32 , A01N37/50 , A01N43/28 , A01N43/32 , C07C275/50 , C07D263/14 , C07D317/18 , C07D319/06
摘要： The invention relates to novel oxime ethers of the formula ##STR1## R.sub.1 is hydrogen, methyl, methoxy, chlorine, cyano or trifluoromethyl, R.sub.2 is hydrogen or chlorine, orR.sub.1 and R.sub.2 taken together is --CH.dbd.CH--CH.dbd.CH-- attached to adjacent carbon atoms in the ring,a is 1 or 2, andR.sub.19 and R.sub.20 are each methyl or ethyl, orR.sub.19 and R.sub.20 taken together is C.sub.2 -C.sub.7 alkylene having 2 or 3 carbon atoms in its principal chain,to their various uses as antidotes for herbicides and to compositions containing them. The invention also relates to plant seed treated with said antidotes.
摘要翻译：本发明涉及下式的新型肟醚：R 1是氢，甲基，甲氧基，氯，氰基或三氟甲基，R 2是氢或氯，或者R 1和R 2一起是-CH = CH-CH = CH-连接的到环中的相邻碳原子，a为1或2，R 19和R 20各自为甲基或乙基，或R 19和R 20一起为其主链中具有2或3个碳原子的C 2 -C 7亚烷基，其各种用途作为除草剂的解毒剂和含有它们的组合物。本发明还涉及用所述解毒剂处理的植物种子。

54. 发明授权

US4412856A Herbicidal heterocyclic and substituted phenyl phenylacetylene amines 失效
标题翻译：除草杂环和取代的苯基苯乙炔胺
公开(公告)号：US4412856A
公开(公告)日：1983-11-01
申请号：US266264
申请日：1981-05-22
申请人： Hans-Georg Brunner , Rolf Schurter , Henry Szczepanski
发明人： Hans-Georg Brunner , Rolf Schurter , Henry Szczepanski
IPC分类号： A01N33/08 , A01N37/34 , A01N43/08 , C07C67/00 , C07C213/00 , C07C217/18 , C07C239/00 , C07C239/20 , C07C253/00 , C07C255/54 , C07C313/00 , C07C323/47 , C07C323/48 , C07C323/62 , C07C323/66 , C07C323/67 , C07D213/30 , C07D213/61 , C07D213/73 , C07D213/76 , C07D213/80 , C07D213/85 , C07D239/26 , C07D239/30 , C07D251/16 , C07D251/18 , C07D251/20 , C07D263/32 , C07D277/24 , C07D285/08 , C07D295/092 , C07D307/42 , C07D333/16 , A01N33/10 , A01N43/10 , A01N43/54 , A01N43/66 , A01N43/78 , C07C93/06
CPC分类号： C07D213/30 , C07D213/61 , C07D213/73 , C07D213/76 , C07D213/80 , C07D213/85 , C07D239/26 , C07D239/30 , C07D251/16 , C07D251/18 , C07D251/20 , C07D263/32 , C07D277/24 , C07D285/08 , C07D295/088 , C07D307/42 , C07D333/16
摘要： The novel compounds of the formula I are useful selective herbicides for postemergence application in crops of cereals, maize and rice.In formula I, ##STR1## A is an unsubstituted or substituted amino group, Q is a C.sub.2 -C.sub.6 alkylene bridge, Y is an oxygen or sulfur atom or an unsubstituted or substituted nitrogen atom, and Z is an unsubstituted or substituted phenyl, naphthyl or heterocyclic radical, which phenyl radical, containing the bridge member Y, can additionally carry one to four further substituents.
摘要翻译：式I的新化合物是用于谷物，玉米和水稻作物中芽后施用的有用的选择性除草剂。在式I中，A是未取代或取代的氨基，Q是C 2 -C 6亚烷基桥，Y是氧或硫原子或未取代或取代的氮原子，Z是未取代或取代的苯基，萘基或杂环基，其中含有桥结构Y的苯基可另外携带一至四个其它取代基。

55. 发明授权

US4347372A Benzoxazolyl-glyoxylonitrile-2-oxime ether derivatives 失效
标题翻译：苯并恶唑基 - 乙醛腈-2-肟醚衍生物
公开(公告)号：US4347372A
公开(公告)日：1982-08-31
申请号：US70288
申请日：1979-08-28
申请人： Alfons Lukaszczyk , Henry Martin , Peter J. Diel , Werner Fory , Karl Gatzi , Haukur Kristinsson , Beat Muller , Rene Muntwyler , Johannes P. Pachlatko , Hermann Rempfler , Rolf Schurter , Henry Szczepanski
发明人： Alfons Lukaszczyk , Henry Martin , Peter J. Diel , Werner Fory , Karl Gatzi , Haukur Kristinsson , Beat Muller , Rene Muntwyler , Johannes P. Pachlatko , Hermann Rempfler , Rolf Schurter , Henry Szczepanski
IPC分类号： A01N25/32 , A01N43/824 , C07C251/32 , C07C259/10 , C07C311/16 , C07C317/32 , C07C317/44 , C07C317/46 , C07C317/48 , C07C323/47 , C07C327/20 , C07D213/53 , C07D213/61 , C07D213/64 , C07D213/65 , C07D213/69 , C07D213/70 , C07D213/79 , C07D215/32 , C07D215/34 , C07D233/26 , C07D233/86 , C07D235/14 , C07D235/16 , C07D249/06 , C07D263/56 , C07D263/58 , C07D277/64 , C07D285/12 , C07D285/125 , C07D285/13 , C07D307/20 , C07D307/52 , C07D309/20 , C07D309/32 , C07D311/58 , C07D317/58 , C07D335/06 , C07D339/06 , C07D339/08 , A01N43/76
CPC分类号： C07D213/53 , C07D213/61 , C07D213/64 , C07D213/65 , C07D213/69 , C07D213/70 , C07D213/79 , C07D215/32 , C07D215/34 , C07D233/26 , C07D233/86 , C07D235/14 , C07D235/16 , C07D249/06 , C07D263/56 , C07D277/64 , C07D285/12 , C07D285/125 , C07D285/13 , C07D307/20 , C07D307/52 , C07D309/20 , C07D309/32 , C07D311/58 , C07D317/58 , C07D335/06 , C07D339/06 , C07D339/08 , Y10S47/03
摘要： A process for protecting cultivated plants against aggressive agricultural chemicals is described in which oxime derivatives of the formula ##STR1## are used as antidotes. Either the cultivated area for the cultivated plants or the cultivated plants themselves or parts of the plant (seeds, tubers, stem parts and the like), as desired, can be treated with these oxime derivatives, which are used as a dressing.
摘要翻译：描述了用于保护栽培植物免受侵袭性农药的方法，其中使用式“IMAGE”的肟衍生物作为解毒剂。根据需要，可以用这些用作敷料的肟衍生物来处理栽培植物或栽培植物本身或植物的部分（种子，块茎，茎部等）的栽培面积。

56. 发明授权

US07605111B2 Herbicides 失效
标题翻译：除草剂
公开(公告)号：US07605111B2
公开(公告)日：2009-10-20
申请号：US11083415
申请日：2005-03-18
申请人： Thomas Maetzke , André Stoller , Sebastian Wendeborn , Henry Szczepanski
发明人： Thomas Maetzke , André Stoller , Sebastian Wendeborn , Henry Szczepanski
IPC分类号： A01N31/06 , C07D321/00
CPC分类号： C07D221/20 , A01N35/06 , A01N43/08 , A01N43/10 , A01N43/16 , A01N43/18 , A01N43/36 , A01N43/38 , A01N43/40 , A01N43/42 , A01N43/56 , A01N43/72 , A01N43/80 , A01N43/82 , A01N43/86 , A01N43/90 , A01N47/06 , A01N47/18 , C07C25/02 , C07C49/747 , C07C49/753 , C07C69/013 , C07C69/708 , C07C323/22 , C07D207/38 , C07D209/54 , C07D209/96 , C07D211/86 , C07D231/32 , C07D231/34 , C07D231/36 , C07D237/04 , C07D265/02 , C07D279/06 , C07D303/32 , C07D307/60 , C07D307/94 , C07D309/32 , C07D309/38 , C07D311/74 , C07D311/94 , C07D311/96 , C07D333/32 , C07D333/50 , C07D335/02 , C07D403/12 , C07D409/12 , C07D413/12 , C07D417/12 , C07D471/04 , C07D487/04 , C07D487/08 , C07D487/10 , C07D491/10 , C07D491/14 , C07D493/10 , A01N25/32 , A01N2300/00
摘要： Compounds of formula wherein the substituents have the meanings given in claim 1, and agronomically tolerable salts, isomers and enantiomers of those compounds, are suitable for use as herbicides.
摘要翻译：下式的化合物，其中取代基具有权利要求1中给出的含义，并且这些化合物的农学上可耐受的盐，异构体和对映异构体适合用作除草剂。

57. 发明申请

US20070055063A1 PREPARATION OF THIAZOLES 失效
标题翻译：制备THIAZOLES
公开(公告)号：US20070055063A1
公开(公告)日：2007-03-08
申请号：US11552255
申请日：2006-10-24
申请人： Thomas Pitterna , Henry Szczepanski , Peter Maienfisch , Ottmar Huter , Thomas Rapold , Marcel Senn , Thomas Gobel , Anthony O'Sullivan
发明人： Thomas Pitterna , Henry Szczepanski , Peter Maienfisch , Ottmar Huter , Thomas Rapold , Marcel Senn , Thomas Gobel , Anthony O'Sullivan
IPC分类号： C07D417/02
CPC分类号： C07D277/32 , C07D277/16 , C07D277/36 , C07D277/70 , C07D277/74
摘要： A process for the preparation of a compound of the formula and, where applicable, its E/Z-isomers, mixtures of E/Z-isomers and/or tautomers and acid addition products thereof, in each case in free form or in salt form, wherein: R is unsubstituted or substituted C1-C12alkyl, unsubstituted or substituted C2-C4alkenyl, unsubstituted or substituted C2-C4alkynyl, unsubstituted or substituted C3-C6cycloalkyl, unsubstituted or substituted aryl, unsubstituted or substituted heteroaryl, or —SR1; R1 is unsubstituted or substituted C1-C12alkyl, unsubstituted or substituted C2-C4alkenyl, unsubstituted or substituted C2-C4alkynyl, unsubstituted or substituted cycloalkyl, unsubstituted or substituted aryl or unsubstituted or substituted heteroaryl; and X is a leaving group; The process comprises reacting a compound of the formula: with a halogenating agent or a sulfonylating agent. Alternatively, when X is a selected halogen, the process can comprise reacting a compound of the formula with a compound having a formula selected from the group consisting of halogen-C(═O)—O—C1-C8alkyl; halogen-C(═O)—O-aryl; and halogen-C(═O)—O-benzyl.
摘要翻译：制备下式化合物及其E / Z-异构体的方法，E / Z-异构体和/或互变异构体的混合物及其酸加成产物，各自为游离形式或盐形式，其中：R是未取代或取代的C 1 -C 12烷基，未取代或取代的C 2 -C 4 烯基，未取代或取代的C 2 -C 4炔基，未取代或取代的C 3 -C 6环烷基，未取代或取代的芳基，未取代或取代的杂芳基或-SR 1 N; R 1是未取代或取代的C 1 -C 12烷基，未取代或取代的C 2 -C 3 未取代或取代的C 2 -C 4炔基，未取代或取代的环烷基，未取代或取代的芳基或未取代或取代的杂芳基; X为离去群; 该方法包括使下式化合物与卤化剂或磺酰化剂反应。或者，当X是选择的卤素时，该方法可以包括使下式的化合物与具有选自以下的式的化合物反应：卤素-C（ - ） - O-C 1 -C 烷基; 卤素-C（ - ） - O-芳基; 和卤素-C（ - ） - O-苄基。

58. 发明授权

US06894005B1 Herbicides 有权
标题翻译：除草剂
公开(公告)号：US06894005B1
公开(公告)日：2005-05-17
申请号：US10070767
申请日：2000-09-05
申请人： Thomas Maetzke , André Stoller , Sebastian Wendeborn , Henry Szczepanski
发明人： Thomas Maetzke , André Stoller , Sebastian Wendeborn , Henry Szczepanski
IPC分类号： A01N35/06 , A01N43/08 , A01N43/10 , A01N43/16 , A01N43/18 , A01N43/36 , A01N43/38 , A01N43/40 , A01N43/42 , A01N43/56 , A01N43/72 , A01N43/80 , A01N43/82 , A01N43/86 , A01N43/90 , A01N47/06 , A01N47/18 , C07C25/02 , C07C49/747 , C07C49/753 , C07C69/013 , C07C69/708 , C07C323/22 , C07D207/38 , C07D209/54 , C07D209/96 , C07D211/86 , C07D221/20 , C07D231/32 , C07D231/34 , C07D231/36 , C07D237/04 , C07D265/02 , C07D279/06 , C07D303/32 , C07D307/60 , C07D307/94 , C07D309/32 , C07D309/38 , C07D311/74 , C07D311/94 , C07D311/96 , C07D333/32 , C07D333/50 , C07D335/02 , C07D403/12 , C07D409/12 , C07D413/12 , C07D417/12 , C07D471/04 , C07D487/04 , C07D487/08 , C07D487/10 , C07D491/10 , C07D491/14 , C07D491/20 , C07D493/10 , A01N31/06 , C07C49/537
CPC分类号： C07D221/20 , A01N35/06 , A01N43/08 , A01N43/10 , A01N43/16 , A01N43/18 , A01N43/36 , A01N43/38 , A01N43/40 , A01N43/42 , A01N43/56 , A01N43/72 , A01N43/80 , A01N43/82 , A01N43/86 , A01N43/90 , A01N47/06 , A01N47/18 , C07C25/02 , C07C49/747 , C07C49/753 , C07C69/013 , C07C69/708 , C07C323/22 , C07D207/38 , C07D209/54 , C07D209/96 , C07D211/86 , C07D231/32 , C07D231/34 , C07D231/36 , C07D237/04 , C07D265/02 , C07D279/06 , C07D303/32 , C07D307/60 , C07D307/94 , C07D309/32 , C07D309/38 , C07D311/74 , C07D311/94 , C07D311/96 , C07D333/32 , C07D333/50 , C07D335/02 , C07D403/12 , C07D409/12 , C07D413/12 , C07D417/12 , C07D471/04 , C07D487/04 , C07D487/08 , C07D487/10 , C07D491/10 , C07D491/14 , C07D493/10 , A01N25/32 , A01N2300/00
摘要： Compounds of formula wherein the substituents have the meanings given in claim 1, and agronomically tolerable salts, isomers and enantiomer of those compounds, are suitable for use as herbicides.
摘要翻译：式的化合物，其中取代基具有权利要求1中给出的含义，并且这些化合物的农学上可耐受的盐，异构体和对映异构体适合用作除草剂。

59. 发明授权

US06677457B2 Process for the preparation of thiazole derivatives 失效
标题翻译：噻唑衍生物的制备方法
公开(公告)号：US06677457B2
公开(公告)日：2004-01-13
申请号：US10047807
申请日：2002-01-15
申请人： Thomas Pitterna , Henry Szczepanski , Peter Maienfisch , Ottmar Franz Hüter , Thomas Rapold , Marcel Senn , Thomas Göbel , Anthony Cornelius O'Sullivan , Gottfried Seifert
发明人： Thomas Pitterna , Henry Szczepanski , Peter Maienfisch , Ottmar Franz Hüter , Thomas Rapold , Marcel Senn , Thomas Göbel , Anthony Cornelius O'Sullivan , Gottfried Seifert
IPC分类号： C07D27716
CPC分类号： C07D277/32 , C07D277/16 , C07D277/36 , C07D417/06
摘要： The invention relates to a process for the preparation of a compound of the formula wherein Q, Y, Z, R1, R2, R3, R4 and R5 are as defined in the specification, which comprises a) reacting a compound of the formula with a halogenating agent to form a compound of the formula or b) converting a compound of formula (II) by means of a halogenating agent into a compound of the formula optionally c) converting the compound of formula (IV) into a compound of formula (III); d) converting a compound of formula (III) by means of a compound of the formula into a compound of the formula or e) converting a compound (IV) by means of a compound (V) into a compound (VI); and f) converting a compound (VI) by means of a chlorinating agent into a compound (I); a compound (IV); to a process for the preparation of a compound (III) and to a process for the preparation of a compound (IV).
摘要翻译：本发明涉及制备糠醛的化合物的方法，其中Q，Y，Z，R 1，R 2，R 3，R 4和R 5如本说明书中所定义，其包括：a）将卤化剂的化合物与将式（II）化合物通过卤化剂转化成式（Ⅲ）的化合物，将式（Ⅳ）化合物转化为式（Ⅳ）化合物; d）将化合物通过化学式（Ⅳ）将化合物（Ⅳ）转化为化合物（Ⅵ）;将式（Ⅳ）化合物与式和（f）通过氯化剂将化合物（VI）转化为化合物（I）;化合物（IV）; 涉及制备化合物（III）的方法和制备化合物（IV）的方法。

60. 发明授权

US06552187B1 Process for the preparation of herbicidal derivatives 有权
标题翻译：制备除草衍生物的方法
公开(公告)号：US06552187B1
公开(公告)日：2003-04-22
申请号：US09980240
申请日：2001-11-29
申请人： Thomas Maetzke , René Mutti , Henry Szczepanski
发明人： Thomas Maetzke , René Mutti , Henry Szczepanski
IPC分类号： C07D49802
CPC分类号： C07D498/04 , C07C233/11
摘要： A process for the preparation of compounds of formula (I), which process comprises reacting a compound of formula (II), in an inert organic solvent, optionally in the presence of a base, with a compound of formula (IV), (IVa) or (IVb), and optionally converting the resulting compound of formula (I) wherein G is a metal ion equivalent or an ammonium cation, by salt conversion into the corresponding salt of formula (I) wherein G is a sulfonium or phosphonium cation, or by treatment with a Brönsted acid into the corresponding compound of formula (I) wherein G is hydrogen, and ‘in situ’ conversion of compounds of formula (I) with an electrophile of formula (XII) or (XIId) G0—L (XII) or R32—N═C═X3 (XIId), optionally in the presence of an acid-binding agent or a catalyst, to the compounds of formula (Ia).
摘要翻译：一种制备式（I）化合物的方法，该方法包括使式（II）化合物在惰性有机溶剂中任选在碱存在下与式（IV）化合物，（Ⅳa））或（IVb），并且任选地通过盐转化将所得到的式（I）化合物（其中G是金属离子当量或铵阳离子）转化成其中G是锍或鏻阳离子的式（I）的相应盐，或通过用布朗斯台德酸处理成相应的式（I）化合物，其中G是氢，并且通过式（I）化合物与式（XII）或（XIId）G0-L（ XII）或R32-N = C = X3（XIId），任选在酸结合剂或催化剂存在下，与式（Ia）化合物反应。

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