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51. 发明申请

US20050264811A1 Three dimensional engineering of planar optical structures 有权
公开(公告)号：US20050264811A1
公开(公告)日：2005-12-01
申请号：US11192159
申请日：2005-07-28
申请人： Xiangxin Bi , Elizabeth Nevis , Ronald Mosso , Michael Chapin , Shivkumar Chiruvolu , Sardar Khan , Sujeet Kumar , Herman Lopez , Nguyen Huy , Craig Horne , Michael Bryan , Eric Euvrard
发明人： Xiangxin Bi , Elizabeth Nevis , Ronald Mosso , Michael Chapin , Shivkumar Chiruvolu , Sardar Khan , Sujeet Kumar , Herman Lopez , Nguyen Huy , Craig Horne , Michael Bryan , Eric Euvrard
IPC分类号： H01S3/063 , H01S3/0941 , H01S3/17 , G01N21/00
CPC分类号： H01S3/0632 , H01S3/0635 , H01S3/0637 , H01S3/0941 , H01S3/176 , H01S3/2308
摘要： Three dimensional optical structures are described that can have various integrations between optical devices within and between layers of the optical structure. Optical turning elements can provide optical pathways between layers of optical devices. Methods are described that provide for great versatility on contouring optical materials throughout the optical structure. Various new optical devices are enabled by the improved optical processing approaches.

52. 发明授权

US06508855B2 Aerosol delivery apparatus for chemical reactions 有权
标题翻译：用于化学反应的气溶胶输送装置
公开(公告)号：US06508855B2
公开(公告)日：2003-01-21
申请号：US09753484
申请日：2001-01-03
申请人： James T. Gardner , Sujeet Kumar , Ronald M. Cornell , Ronald J. Mosso , Xiangxin Bi
发明人： James T. Gardner , Sujeet Kumar , Ronald M. Cornell , Ronald J. Mosso , Xiangxin Bi
IPC分类号： C22C105
CPC分类号： B01J4/00 , B01J10/002 , B01J19/088 , B01J19/10 , B01J19/12 , B01J19/121 , B01J19/26 , B01J2219/0869 , B01J2219/0884 , Y10T428/2982
摘要： An aerosol delivery apparatus is used to deliver an aerosol into a reaction chamber for chemical reaction to produce reaction products such as nanoparticles. A variety of improved aerosol delivery approaches provide for the production of more uniform reaction products. In preferred embodiments, a reaction chamber is used that has a cross section perpendicular to the flow of reactant having a dimension along a major axis greater than a dimension along a minor axis. The aerosol preferably is elongated along the major axis of the reaction chamber.
摘要翻译：气溶胶输送装置用于将气溶胶输送到用于化学反应的反应室中以产生诸如纳米颗粒的反应产物。各种改进的气溶胶递送方法提供了更均匀的反应产物的生产。在优选实施例中，使用具有垂直于反应物流的横截面的反应室，其具有沿着短轴的尺寸大于沿着短轴的尺寸。气溶胶优选沿着反应室的长轴细长。

53. 发明授权

US09139441B2 Porous silicon based anode material formed using metal reduction 有权
标题翻译：使用金属还原形成多孔硅基阳极材料
公开(公告)号：US09139441B2
公开(公告)日：2015-09-22
申请号：US13354096
申请日：2012-01-19
申请人： Yogesh Kumar Anguchamy , Charan Masarapu , Haixia Deng , Yongbong Han , Subramanian Venkatachalam , Sujeet Kumar , Herman A. Lopez
发明人： Yogesh Kumar Anguchamy , Charan Masarapu , Haixia Deng , Yongbong Han , Subramanian Venkatachalam , Sujeet Kumar , Herman A. Lopez
IPC分类号： H01M4/525 , C01B33/023 , H01M4/134 , H01M4/38 , B82Y30/00 , H01M4/36 , H01M4/505 , H01M4/62 , H01M10/052 , H01M4/02 , H01M10/42
CPC分类号： C01B33/023 , B82Y30/00 , H01M4/134 , H01M4/362 , H01M4/366 , H01M4/386 , H01M4/505 , H01M4/525 , H01M4/622 , H01M4/625 , H01M10/052 , H01M2004/021 , H01M2010/4292 , Y02E60/122 , Y02T10/7011
摘要： A porous silicon based material comprising porous crystalline elemental silicon formed by reducing silicon dioxide with a reducing metal in a heating process followed by acid etching is used to construct negative electrode used in lithium ion batteries. Gradual temperature heating ramp(s) with optional temperature steps can be used to perform the heating process. The porous silicon formed has a high surface area from about 10 m2/g to about 200 m2/g and is substantially free of carbon. The negative electrode formed can have a discharge specific capacity of at least 1800 mAh/g at rate of C/3 discharged from 1.5V to 0.005V against lithium with in some embodiments loading levels ranging from about 1.4 mg/cm2 to about 3.5 mg/cm2. In some embodiments, the porous silicon can be coated with a carbon coating or blended with carbon nanofibers or other conductive carbon material.
摘要翻译：使用包含在加热过程中随后用酸蚀刻还原二氧化硅形成的多孔结晶元素硅的多孔硅基材料来构造用于锂离子电池的负极。可以使用温度逐渐升温的温度梯度来进行加热过程。形成的多孔硅具有约10m 2 / g至约200m 2 / g的高表面积，并且基本上不含碳。形成的负极可以具有至少1800mAh / g的放电比容量，其相对于锂从1.5V至0.005V释放的C / 3的速率，在一些实施方案中负载水平为约1.4mg / cm 2至约3.5mg / cm2。在一些实施例中，多孔硅可以涂覆有碳涂层或与碳纳米纤维或其它导电碳材料混合。

54. 发明授权

US08394534B2 Layer-layer lithium rich complex metal oxides with high specific capacity and excellent cycling 有权
标题翻译：具有高比容量和优异循环性能的多层富锂复合金属氧化物
公开(公告)号：US08394534B2
公开(公告)日：2013-03-12
申请号：US12869976
申请日：2010-08-27
申请人： Herman A. Lopez , Subramanian Venkatachalam , Deepak Kumaar Kandasamy Karthikeyan , Sujeet Kumar
发明人： Herman A. Lopez , Subramanian Venkatachalam , Deepak Kumaar Kandasamy Karthikeyan , Sujeet Kumar
IPC分类号： H01M4/13
CPC分类号： H01M4/366 , C01D15/08 , C01G45/1257 , C01G51/50 , C01G53/50 , C01P2002/52 , C01P2004/80 , C01P2006/10 , C01P2006/40 , H01M4/131 , H01M4/505 , H01M4/525 , H01M10/0525 , H01M10/056
摘要： Lithium rich and manganese rich lithium metal oxides are described that provide for excellent performance in lithium-based batteries. The specific compositions can be engineered within a specified range of compositions to provide desired performance characteristics. Selected compositions can provide high values of specific capacity with a reasonably high average voltage. Compositions of particular interest can be represented by the formula, xLi2MnO3.(1−x)LiNiu+ΔMnu−ΔCowAyO2. The compositions undergo significant first cycle irreversible changes, but the compositions cycle stably after the first cycle.
摘要翻译：描述了富锂和富锰的锂金属氧化物，其在锂基电池中具有优异的性能。特定组合物可以在指定范围的组合物内进行工程化以提供所需的性能特征。所选组合物可以以相当高的平均电压提供较高的比容量值。特别感兴趣的组合可以由下式表示：xLi2MnO3（1-x）LiNiu +＆Dgr; Mnu-＆Dgr; CowAyO2。组合物经历显着的第一循环不可逆变化，但组合物在第一循环后稳定循环。

55. 发明申请

US20130004847A1 HIGH ENERGY LITHIUM ION BATTERIES WITH PARTICULAR NEGATIVE ELECTRODE COMPOSITIONS 有权
公开(公告)号：US20130004847A1
公开(公告)日：2013-01-03
申请号：US13612132
申请日：2012-09-12
申请人： Sujeet Kumar , James P. Buckley
发明人： Sujeet Kumar , James P. Buckley
IPC分类号： H01M4/38 , H01B1/02 , H01M4/583 , B32B5/16 , B82Y30/00
CPC分类号： H01M4/808 , B22F3/1146 , C22C1/08 , C22C19/00 , H01M4/134 , H01M4/364 , H01M4/386 , H01M4/387 , H01M4/485 , H01M4/625 , H01M10/052 , Y10T428/12 , Y10T428/2982
摘要： Combinations of materials are described in which high energy density active materials for negative electrodes of lithium ion batteries. In general, metal alloy/intermetallic compositions can provide the high energy density. These materials can have moderate volume changes upon cycling in a lithium ion battery. The volume changes can be accommodated with less degradation upon cycling through the combination with highly porous electrically conductive materials, such as highly porous carbon and/or foamed current collectors. Whether or not combined with a highly porous electrically conductive material, metal alloy/intermetallic compositions with an average particle size of no more than a micron can be advantageously used in the negative electrodes to improve cycling properties.

56. 发明授权

US08187752B2 High energy lithium ion secondary batteries 有权
标题翻译：高能锂离子二次电池
公开(公告)号：US08187752B2
公开(公告)日：2012-05-29
申请号：US12403521
申请日：2009-03-13
申请人： James P. Buckley , Sujeet Kumar
发明人： James P. Buckley , Sujeet Kumar
IPC分类号： H01M4/13 , H01M4/58 , H01M4/62 , H01M4/00 , H01M4/50
CPC分类号： H01M2/1653 , H01M4/131 , H01M4/1315 , H01M4/485 , H01M4/505 , H01M4/525 , H01M4/621 , H01M4/622 , H01M10/0525 , Y02T10/7011 , Y10T29/49108 , Y10T29/49115
摘要： Lithium ion secondary batteries are described that have high total energy, energy density and specific discharge capacity upon cycling at room temperature and at a moderate discharge rate. The improved batteries are based on high loading of positive electrode materials with high energy capacity. This capability is accomplished through the development of positive electrode active materials with very high specific energy capacity that can be loaded at high density into electrodes without sacrificing performance. The high loading of the positive electrode materials in the batteries are facilitated through using a polymer binder that has an average molecular weight higher than 800,000 atomic mass unit.
摘要翻译：描述了在室温和适度的放电速率下循环时具有高的总能量，能量密度和比放电容量的锂离子二次电池。改进的电池基于具有高能量容量的正极材料的高负载。该能力通过开发具有非常高比能量容量的正极活性材料来实现，其可以以高密度加载到电极中而不牺牲性能。通过使用平均分子量高于800,000原子质量单位的聚合物粘合剂，可以促进电池中正极材料的高负荷。

57. 发明申请

US20120056590A1 Very Long Cycling of Lithium Ion Batteries with Lithium Rich Cathode Materials 有权
标题翻译：锂离子电池与锂离子电池极长循环
公开(公告)号：US20120056590A1
公开(公告)日：2012-03-08
申请号：US13213756
申请日：2011-08-19
申请人： Shabab Amiruddin , Bing Li , Sujeet Kumar
发明人： Shabab Amiruddin , Bing Li , Sujeet Kumar
IPC分类号： H02J7/00 , H01M10/44 , H01M10/0525
CPC分类号： H01M10/0525 , H01M4/366 , H01M4/505 , H01M4/525 , H01M10/0567 , H01M10/44 , Y02E60/122 , Y02T10/7011
摘要： Lithium ion batteries can be activated and then cycled to exploit a moderate fraction of the discharge cycling capacity such that the discharge capacity and average discharge voltage stay within initial values for thousands of cycles. The superior cycling performance has been achieved at relatively high discharge rates and for practical battery formats. Lithium ion battery performance can also be achieved with superior cycling performance with partially activated batteries such that good discharge capacities can be exploited for many thousands of cycles before the discharge capacity and average discharge voltage drops more than 20% from initial values. The positive electrode active material can be a lithium rich metal oxide. The activation of the battery can comprise phase changes of the active materials. As described herein, the phase changes can be manipulated to exploit a reasonable fraction of the available high capacity of the material while providing outstanding cycling stability.
摘要翻译：锂离子电池可以被激活，然后循环以利用放电循环能力的中等部分，使得放电容量和平均放电电压保持在数千个周期的初始值内。在相对较高的放电率和实际的电池格式下，已经实现了优越的循环性能。锂离子电池的性能也可以通过部分活化的电池实现优异的循环性能，从而在放电容量和平均放电电压从初始值下降超过20％之前可以利用良好的放电容量达数千个循环。正极活性物质可以是富锂金属氧化物。电池的激活可以包括活性材料的相变。如本文所述，可以操纵相位变化以利用材料的可用高容量的合理分数，同时提供优异的循环稳定性。

58. 发明授权

US07722787B2 Metal vanadium oxide particles 有权
标题翻译：金属氧化钒颗粒
公开(公告)号：US07722787B2
公开(公告)日：2010-05-25
申请号：US09757519
申请日：2001-01-09
申请人： Craig R. Horne , Sujeet Kumar , James P. Buckley , Xiangxin Bi
发明人： Craig R. Horne , Sujeet Kumar , James P. Buckley , Xiangxin Bi
IPC分类号： H01B1/02
CPC分类号： H01B1/122 , B82Y30/00 , C01G31/00 , C01G31/02 , C01P2002/72 , C01P2004/04 , C01P2004/51 , C01P2004/54 , C01P2004/62 , C01P2004/64 , H01M4/136 , H01M4/58 , H01M4/62 , H01M2004/021 , Y10T428/2982
摘要： Metal vanadium oxide particles have been produced with an average diameter less than about 500 nm. The particles are produced from nanocrystalline vanadium oxide particles. Silver vanadium oxide particles, for example, can be formed by the heat treatment of a mixture of nanoscale vanadium oxide and a silver compound. Other metal vanadium oxide particles can be produced by similar processes. The metal vanadium oxide particles have very uniform properties.
摘要翻译：已经生产了平均直径小于约500nm的金属氧化钒颗粒。颗粒由纳米晶体氧化钒颗粒制成。例如，可以通过对纳米级钒氧化物和银化合物的混合物进行热处理来形成银氧化钒颗粒。其他金属氧化钒颗粒可以通过类似的方法生产。金属氧化钒颗粒具有非常均匀的性质。

59. 发明申请

US20100086853A1 POSITIVE ELECTRODE MATERIALS FOR LITHIUM ION BATTERIES HAVING A HIGH SPECIFIC DISCHARGE CAPACITY AND PROCESSES FOR THE SYNTHESIS OF THESE MATERIALS 有权
标题翻译：具有高特异性放电容量的锂离子电池的正极电极材料和用于合成这些材料的方法
公开(公告)号：US20100086853A1
公开(公告)日：2010-04-08
申请号：US12246814
申请日：2008-10-07
申请人： Subramanian Venkatachalam , Herman Lopez , Sujeet Kumar
发明人： Subramanian Venkatachalam , Herman Lopez , Sujeet Kumar
IPC分类号： H01M4/00 , H01M4/58
CPC分类号： H01M4/1391 , C01G45/1228 , C01G51/50 , C01G53/50 , C01P2002/52 , C01P2002/72 , C01P2004/84 , C01P2006/40 , H01M4/362 , H01M4/505 , H01M4/525 , H01M4/582 , H01M4/62 , H01M10/052 , H01M10/4235 , H01M2004/021
摘要： Positive electrode active materials are described that have a very high specific discharge capacity upon cycling at room temperature and at a moderate discharge rate. Some materials of interest have the formula Li1+xNiαMnβCOγO2, where x ranges from about 0.05 to about 0.25, α ranges from about 0.1 to about 0.4, β ranges from about 0.4 to about 0.65, and γ ranges from about 0.05 to about 0.3. The materials can be coated with a metal fluoride to improve the performance of the materials especially upon cycling. Also, the coated materials can exhibit a very significant decrease in the irreversible capacity lose upon the first charge and discharge of the cell. Methods for producing these materials include, for example, a co-precipitation approach involving metal hydroxides and sol-gel approaches.
摘要翻译：描述了在室温和适度的放电速率下循环时具有非常高的比放电容量的正极活性材料。一些感兴趣的材料具有式Li1 + xNi1Mn＆bgr;COγO2，其中x为约0.05至约0.25，α为约0.1至约0.4，bgr; 范围为约0.4至约0.65，γ为约0.05至约0.3。这些材料可以用金属氟化物涂覆，以改善材料的性能，特别是在循环时。此外，涂覆的材料可以表现出在电池的第一次充电和放电时不可逆容量损失的非常显着的降低。制备这些材料的方法包括例如涉及金属氢氧化物和溶胶 - 凝胶方法的共沉淀方法。

60. 发明授权

US07575784B1 Coating formation by reactive deposition 失效
标题翻译：通过反应沉积形成涂层
公开(公告)号：US07575784B1
公开(公告)日：2009-08-18
申请号：US09715935
申请日：2000-11-17
申请人： Xiangxin Bi , Ronald J. Mosso , Shivkumar Chiruvolu , Sujeet Kumar , James T. Gardner , Seung M. Lim , William E. McGovern
发明人： Xiangxin Bi , Ronald J. Mosso , Shivkumar Chiruvolu , Sujeet Kumar , James T. Gardner , Seung M. Lim , William E. McGovern
IPC分类号： B05D3/06 , C23C16/00 , B05D1/04 , B05D1/40
CPC分类号： C23C16/483 , C23C16/402 , C23C16/56
摘要： Light reactive deposition uses an intense light beam to form particles that are directly coated onto a substrate surface. In preferred embodiments, a coating apparatus comprising a noncircular reactant inlet, optical elements forming a light path, a first substrate, and a motor connected to the apparatus. The reactant inlet defines a reactant stream path. The light path intersects the reactant stream path at a reaction zone with a product stream path continuing from the reaction zone. The substrate intersects the product stream path. Also, operation of the motor moves the first substrate relative to the product stream. Various broad methods are described for using light driven chemical reactions to produce efficiently highly uniform coatings.
摘要翻译：光反应沉积使用强光束形成直接涂覆在基底表面上的颗粒。在优选实施方案中，包括非圆形反应物入口，形成光路的光学元件，第一基底和连接到该装置的马达的涂覆设备。反应物入口限定反应物流路径。光路在与反应区连续的产物流路径的反应区与反应物流路相交。基板与产品流路相交。此外，电动机的操作使第一衬底相对于产品流移动。描述了使用光驱化学反应来产生高效均匀的涂层的各种广泛的方法。

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