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51. 发明申请

US20140309339A1 Mixtures Of Diphosphinic Acids And Alkylphosphinic Acids, A Process For The Preparation Thereof And The Use Thereof 审中-公开
标题翻译：二膦酸和烷基次膦酸的混合物，其制备方法及其用途
公开(公告)号：US20140309339A1
公开(公告)日：2014-10-16
申请号：US14364827
申请日：2012-12-08
申请人： Fabian Schneider , Frank Osterod , Harald Bauer , Martin Sicken
发明人： Fabian Schneider , Frank Osterod , Harald Bauer , Martin Sicken
IPC分类号： C08K5/5317 , C09K21/12 , C08K5/5313
CPC分类号： C08K5/5317 , C07F9/305 , C07F9/3808 , C08K5/5313 , C09K21/12
摘要： Mixtures of diphosphinic acids and alkylphosphonic acids, a process for preparation thereof and use thereof.The invention relates to mixtures of at least one diphosphinic acid of the formula (I) in which R1, R2 are each H, C1-C18-alkyl, C2-C18-alkenyl, C6-C18-aryl, C7-C18-alkylaryl R4 is C1-C18-alkylene, C2-C18-alkenylene, C6-C18-arylene, C7-C18-alkylarylene with at least one alkylphosphonic acid of the formula (II) in which R3 is H, C1-C18-alkyl, C2-C18-alkenyl, C6-C18-aryl and/or C7-C18-alkylaryl; a process for preparation thereof and use thereof.
摘要翻译：二次膦酸和烷基膦酸的混合物，其制备方法和用途。本发明涉及式（I）的至少一种二次膦酸的混合物，其中R 1，R 2各自为H，C 1 -C 18 - 烷基，C 2 -C 18 - 链烯基，C 6 -C 18 - 芳基，C 7 -C 18 - 烷基芳基R 4 是具有式（II）的至少一种烷基膦酸的C 1 -C 18亚烷基，C 2 -C 18亚烯基，C 6 -C 18亚芳基，C 7 -C 18亚烷基亚芳基，其中R 3是H，C 1 -C 18烷基， C18-烯基，C6-C18-芳基和/或C7-C18-烷基芳基; 其制备方法和用途。

52. 发明申请

US20110251315A1 Method for the Production of Monofunctionalized Dialkylphosphinic Acids, Esters and Salts, and Use Thereof 有权
标题翻译：单官能二烷基次膦酸，酯和盐的制备方法及其用途
公开(公告)号：US20110251315A1
公开(公告)日：2011-10-13
申请号：US13140555
申请日：2009-10-06
申请人： Michael Hill , Harald Bauer , Werner Krause , Martin Sicken
发明人： Michael Hill , Harald Bauer , Werner Krause , Martin Sicken
IPC分类号： C08K5/5313 , C07F9/32 , C07F9/30
CPC分类号： C09K21/12 , C07F9/301 , C07F9/3211 , C08K5/5313
摘要： The invention relates to a method for producing monofunctionalized dialkylphosphinic acids, esters, and salts, characterized in that a phosphinic acid source (I) is reacted with olefins (IV) in the presence of a catalyst A to obtain an alkylphosphonous acid, the salt or ester thereof, whereupon said alkylphosphonous acid, the salt or ester (II) thereof is reacted with compounds containing C═C, C═O, or C═N double bonds to obtain compounds of type (III), wherein R1, R2, R3, R4, R5, R6 are identical or different from each other and independently represent, inter alia, H, C1-C18-alkyl, C6-C18-aryl, C6-C18-aralkyl, X represents, inter alia, H, C1-C18-alkyl, C6-C18-aryl, and/or Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K, H, and wherein A represents OH, NH2, NHR, NR2, or O—CO—R8, and W represents a mineral acid, carboxylic acid, Lewis acid, or organic acid, wherein n is a whole or a fractional number from 0 to 4, and catalyst A represents transition metals and/or transition metal compounds and/or catalyst systems composed of a transition metal and/or a transition metal compound and at least one ligand. The use of said dialkylphosphonic acids, esters, and salts is also disclosed.
摘要翻译：本发明涉及一种制备单官能化二烷基次膦酸，酯和盐的方法，其特征在于，在催化剂A存在下，次膦酸源（I）与烯烃（Ⅳ）反应得到烷基亚磷酸，其盐或酯，因此所述烷基亚膦酸，其盐或酯（II）与含有C = C，C = O或C = N双键的化合物反应，得到式（III）化合物，其中R1，R2，R3 ，R 4，R 5，R 6彼此相同或不同，并且独立地代表H，C 1 -C 18 - 烷基，C 6 -C 18 - 芳基，C 6 -C 18 - 芳烷基，X尤其表示H， C18烷基，C6-C18-芳基和/或Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Zn，Ce，Bi，Sr，Mn，Cu，Ni，Li，Na，K ，H，其中A表示OH，NH2，NHR，NR2或O-CO-R8，W表示无机酸，羧酸，路易斯酸或有机酸，其中n为0或分数至4，催化剂A代表转化我 tals和/或过渡金属化合物和/或由过渡金属和/或过渡金属化合物和至少一种配体组成的催化剂体系。还公开了所述二烷基膦酸，酯和盐的用途。

53. 发明申请

US20110245386A1 Method for the Production of Mixed-Substituted Dialkylphosphinic Acids, Esters, and Salts, and Use Thereof 审中-公开
标题翻译：混合取代的二烷基次膦酸，酯和盐的制备方法及其用途
公开(公告)号：US20110245386A1
公开(公告)日：2011-10-06
申请号：US13140236
申请日：2009-10-06
申请人： Michael Hill , Werner Krause , Martin Sicken
发明人： Michael Hill , Werner Krause , Martin Sicken
IPC分类号： C08K5/5313 , C07F9/30 , C07F9/32 , C08L67/02 , C08L77/06
CPC分类号： C09K21/12 , C07F9/301 , C07F9/306 , C07F9/3211 , C07F9/4816 , C07F9/4866 , C08K5/5313
摘要： The invention relates to a method for producing mixed-substituted dialkyiphosphinic acids, esters, and salts, characterized in that a) a phosphinic acid source (I) is reacted with olefins (IV) in the presence of a catalyst A to obtain an alkylphosphonous acid, the salt or ester (II) thereof, b) the obtained alkylphosphonous acid, the salt or ester (II) thereof is reacted with an olefin (IV) in the presence of a catalyst B to obtain the mixed-substituted dialkylphosphinic acid derivative (III), wherein R1, R2, R3, R4, R11, R12, R13, R14 are identical or different from each other and independently represent, inter alia, H, C1-C18-alkyl, C6-C18-aryl, C6-C18-aralkyl, C6-C18-alkylaryl, X represents H, C1-C18-alkyl, C8-C18-aryl, C6-C18-aralkyl, C8-C18-alkylaryl, Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K and/or a protonated nitrogenous base, catalyst A represents transition metals and/or transition metal compounds and/or catalyst systems composed of a transition metal and/or a transition metal compound and at least one ligand, and catalyst B represents compounds forming peroxides, and/or peroxo compounds, and/or azo compounds.
摘要翻译：本发明涉及一种制备混合取代二亚磷酸，酯和盐的方法，其特征在于a）在催化剂A存在下，使次膦酸源（I）与烯烃（Ⅳ）反应得到烷基亚磷酸，其盐或酯（II），b）在催化剂B存在下，将得到的烷基亚膦酸，其盐或酯（II）与烯烃（IV）反应，得到混合取代的二烷基次膦酸衍生物 III），其中R 1，R 2，R 3，R 4，R 11，R 12，R 13，R 14彼此相同或不同，并且独立地表示H，C 1 -C 18烷基，C 6 -C 18 - 芳基，C 6 -C 18 - 烷基，C 6 -C 18烷基芳基，X代表H，C 1 -C 18烷基，C 8 -C 18 - 芳基，C 6 -C 18 - 芳烷基，C 8 -C 18烷基芳基，Mg，Ca，Al，Sb，Sn，Ge，Ti ，Fe，Zr，Zn，Ce，Bi，Sr，Mn，Cu，Ni，Li，Na，K和/或质子化的含氮碱，催化剂A表示过渡金属和/或过渡金属化合物和/ 一个过境 n金属和/或过渡金属化合物和至少一种配体，催化剂B表示形成过氧化物的化合物，和/或过氧化合物和/或偶氮化合物。

54. 发明申请

US20110237722A1 Method for Producing Mono-Hydroxy-Functionalized Dialkylphosphinic Acids, Esters and Salts Using a Vinyl Ester of a Carobxylic Acid and The Use Thereof 有权
标题翻译：使用木瓜酸乙酯生产单羟基官能化二烷基次膦酸，酯和盐的方法及其用途
公开(公告)号：US20110237722A1
公开(公告)日：2011-09-29
申请号：US13132170
申请日：2009-10-06
申请人： Michael Hill , Werner Krause , Martin Sicken
发明人： Michael Hill , Werner Krause , Martin Sicken
IPC分类号： C08K5/5313 , C07F9/30 , C07F9/32 , C08L67/02 , C08L77/06
CPC分类号： C09K21/12 , C07F9/301 , C07F9/3211 , C08K5/5313
摘要： The invention relates to a method for producing mono-hydroxy-functionalized dialkylphosphinic acids, esters and salts. The method is characterized by the following steps: a) reacting a phosphinic acid source (I) with olefins (IV) in the presence of a catalyst A to give an alkylphosphonous acid, the salt or the ester (II) thereof, b) reacting the alkylphosphonous acid so obtained, the salt or the ester (II) thereof with a vinyl ester of a carboxylic acid of formula (V) in the presence of a catalyst B to give a mono-functionalized dialkylphosphinic acid derivative (VI) and c) reacting the mono-functionalized dialkylphosphinic acid derivative (VI) so obtained in the presence of a catalyst C to give a mono-hydroxy-functionalized dialkylphosphinic acid derivative (III), wherein R1, R2, R3, R4, R5, R6, R7 are the same or different and independently of each other inter alia represent H, C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl and X represents H, C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl C6-C18 alkylaryl, Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K and/or a protonated nitrogen base and the catalyst A is a transition metal and/or a transition metal compound and/or a catalyst system which is composed of a transition metal and/or a transition metal compound and at least one ligand, and the catalyst B is a peroxide-forming compound and/or a peroxo compound and/or an azo compound, and the catalyst C is an acid or a base.
摘要翻译：本发明涉及单羟基官能化二烷基次膦酸，酯和盐的制备方法。该方法的特征在于以下步骤：a）在催化剂A存在下使次膦酸源（I）与烯烃（IV）反应，得到烷基亚磷酸，其盐或其酯（II），b）使如此得到的烷基亚磷酸，其盐或其酯（II）与式（V）的羧酸的乙烯基酯在催化剂B的存在下反应，得到单官能化二烷基次膦酸衍生物（Ⅵ），和c）使在催化剂C存在下得到的单官能化二烷基次膦酸衍生物（Ⅵ）反应，得到单羟基官能化二烷基次膦酸衍生物（Ⅲ），其中R 1，R 2，R 3，R 4，R 5，R 6，R 7为相同或不同且彼此独立地特别表示H，C 1 -C 18烷基，C 6 -C 18芳基，C 6 -C 18芳烷基，C 6 -C 18烷基芳基，X代表H，C 1 -C 18烷基，C 6 -C 18芳基， C18芳烷基C6-C18烷芳基，Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Zn，Ce，Bi，Sr，Mn，Cu，Ni，Li，Na，K和/ 催化剂A是由过渡金属和/或过渡金属化合物和至少一种配体组成的过渡金属和/或过渡金属化合物和/或催化剂体系，催化剂B为过氧化物形成化合物和/或过氧化合物和/或偶氮化合物，催化剂C是酸或碱。

55. 发明申请

US20110237721A1 Method for Producing Mono-Carboxy-Functionalized Dialkylphosphinic Acids, Esters and Salts Using a Vinyl Ester of a Carboxylic Acid and the Use Thereof 有权
公开(公告)号：US20110237721A1
公开(公告)日：2011-09-29
申请号：US13132153
申请日：2009-10-06
申请人： Michael Hill , Mathias Dietz , Werner Krause , Martin Sicken
发明人： Michael Hill , Mathias Dietz , Werner Krause , Martin Sicken
IPC分类号： C08K5/5313 , C07F9/30 , C07F9/32
CPC分类号： C09K21/12 , C07F9/301 , C07F9/4816 , C07F9/4866 , C08K5/5313
摘要： The invention relates to a method for producing mono-carboxy-functionalized dialkyiphosphinic acids, esters and salts using a vinyl ester of a carboxylic acid. The method is characterized by the following steps: a) reacting a phosphinic acid source (I) with olefins (IV) in the presence of a catalyst A to give an alkylphosphinic acid, the salt or the ester (II) thereof, b) reacting the alkylphosphinic acid so obtained, the salt or the ester (II) thereof with a vinyl ester of a carboxylic acid of formula (V) in the presence of a catalyst B to give a mono-functionalized dialkylphosphinic acid derivative (VI) and c) reacting the mono-functionalized dialkyiphosphinic acid derivative (VI) so obtained in the presence of a catalyst C to give a mono-functionalized dialkylphosphinic acid derivative (VII) and d) reacting the mono-functionalized dialkyiphosphinic acid derivative (VII); with an oxidant or in the presence of a catalyst D to give a mono-carboxy-functionalized dialkylphosphinic acid derivative (III), wherein R1, R2, R3, R4, R5, R6 are the same or different and independently of each other inter alia represent H, C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl and X and Y are the same or different and independently of each other represent H, C1-C18 alkyl, C8-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl, Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K and/or a protonated nitrogen base and the catalysts A and D are transition metals and/or transition metal compounds and/or catalyst systems which are composed of a transition metal and/or a transition metal compound and at least one ligand, and the catalyst B is a peroxide-forming compound and/or a peroxo compound and/or an azo compound, and the catalyst C is an acid or a base.

56. 发明申请

US20110213079A1 Method for Producing Monoamino-Functionalised Dialkylphosphinite Acids Esters and Salts and Use Thereof 有权
标题翻译：单氨基官能化二烷基磷酸酯酯和盐的制备方法及用途
公开(公告)号：US20110213079A1
公开(公告)日：2011-09-01
申请号：US13127105
申请日：2009-10-06
申请人： Michael Hill , Werner Krause , Martin Sicken
发明人： Michael Hill , Werner Krause , Martin Sicken
IPC分类号： C08L67/02 , C07F9/30 , C07F9/32 , C07F5/06 , C07F7/28 , C08G63/183 , C08G69/26 , C08L77/06
CPC分类号： C09K21/12 , C07F9/301 , C07F9/3211 , C08K5/5313
摘要： The invention relates to method for producing mono amino-functionalised dialkylphosphonic acids esters and salts, characterised in that a) a phosphinic acid source (I) is reacted with olefins (IV) in the presence of a catalyst A to give an alkylphosphonous acid, the salt or ester thereof (II), b) the alkylphosphonous acid, the salt or ester thereof (II) produced above is reacted with an allylamine of formula (V) in the presence of a catalyst B to give mono amino-functionalised dialkylphosphinic acid derivatives (III) where, R1, R2, R3, R4, R5, R6, R7, R8, R9 independently=amongst others, H, C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl and X═H, C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl, Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K and/or a protonated nitrogen base and Y=a mineral acid, a carboxylic acid, a Lewis acid or organic acid, where n=a whole or fractional number from 0 to 4, catalyst A is a transition metal and/or transition metal compound and/or catalyst system comprising a transition metal and/or a transition metal compound and at least one ligand and catalyst B is compounds forming peroxides and/or peroxide compounds and/or azo compounds.
摘要翻译：本发明涉及用于制备单氨基官能化二烷基膦酸酯和盐的方法，其特征在于a）在催化剂A存在下，使次膦酸源（I）与烯烃（Ⅳ）反应得到烷基亚磷酸，其盐或酯（II），b）在催化剂B的存在下，将上述制备的烷基亚膦酸，其盐或酯（II）与式（V）的烯丙胺反应，得到单氨基官能化的二烷基次膦酸衍生物（III）其中，R1，R2，R3，R4，R5，R6，R7，R8，R9独立地为H，C1-C18烷基，C6-C18芳基，C6-C18芳烷基，C6-C18烷基芳基和X C 1 -C 18烷基，C 6 -C 18芳基，C 6 -C 18烷基芳基，Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Zn，Ce，Bi，Sr，Mn ，Cu，Ni，Li，Na，K和/或质子化的氮碱，Y =无机酸，羧酸，路易斯酸或有机酸，其中n = 0至4的整数或分数，催化剂A 是过渡金属和/或t 包含过渡金属和/或过渡金属化合物和至少一种配体和催化剂B的过渡金属化合物和/或催化剂体系是形成过氧化物和/或过氧化物和/或偶氮化合物的化合物。

57. 发明申请

US20110213060A1 Method for Producing Dialkylphosphinic Acids and Esters and Salts Thereof by Means of Acrylnitriles and Use Thereof 有权
标题翻译：通过丙烯腈生产二烷基次膦酸及其酯及其盐的方法及用途
公开(公告)号：US20110213060A1
公开(公告)日：2011-09-01
申请号：US13127069
申请日：2009-10-06
申请人： Michael Hill , Werner Krause , Martin Sicken
发明人： Michael Hill , Werner Krause , Martin Sicken
IPC分类号： C08K5/5313 , C07F9/32 , C07F9/30
CPC分类号： C08K5/5313 , C07F9/301 , C07F9/3211 , C07F9/4816 , C07F9/4866 , C09K21/12
摘要： The invention relates to a method for producing mono-carboxyfunctionalized dialkylphosphinic acids and esters and salts thereof, characterized in that a) a phosphinic acid source (I) is reacted with olefins (IV) to yield an alkylphosphonic acid, salt or ester (H) thereof in the presence of a catalyst A, b) the thus obtained alkylphosphonic acid, salt or ester (II) thereof is reacted with compounds of formula (V) to yield mono-functionalized dialkylphosphinic acid derivatives (VI) in the presence of a catalyst B, and c) the thus obtained mono-functionalized dialkylphosphinic acid derivatives (VI) are reacted to yield a mono-carboxyfunctionalized diakylphosphinic acid derivative (III) in the presence of a catalyst C, wherein R1, R2, R3, R4, R5, R6, R7 are the same or different and stand independently of each other, among other things, for H, C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl and X and Y are the same or different and stand independently of each for H, C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl, Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K and/or a protonized nitrogen base, and the catalyst A is formed by transition metals and/or transition metal compounds and/or catalyst systems composed of a transition metal and/or a transition metal compound and at least one ligand, and catalyst B is formed by compounds forming peroxides and/or peroxo compounds and/or azo compounds and/or alkali metals and/or alkaline earth metals, alkali hydrides, alkaline earth hydrides and/or alkali alcoholates and alkaline earth alcoholates, and catalyst C is an acid or a base.
摘要翻译：本发明涉及一种用于制备单羧基官能化二烷基次膦酸及其酯和盐的方法，其特征在于：a）将次膦酸源（I）与烯烃（Ⅳ）反应，得到烷基膦酸，盐或酯（H）在催化剂A存在下，将由此得到的烷基膦酸，其盐或酯（II）与式（Ⅴ）化合物反应得到单官能化二烷基次膦酸衍生物（Ⅵ），在催化剂存在下 B和c）由此得到的单官能化二烷基次膦酸衍生物（Ⅵ）在催化剂C存在下反应得到单羧基官能化二烷基次膦酸衍生物（Ⅲ），其中R1，R2，R3，R4，R5，对于H，C 1 -C 18烷基，C 6 -C 18芳基，C 6 -C 18芳烷基，C 6 -C 18烷基芳基，X和Y相同或不同，R 6，R 7相同或不同，彼此独立地相互独立地表示并独立于H，C1-C18烷基 1，C 6 -C 18芳基，C 6 -C 18芳烷基，C 6 -C 18烷基芳基，Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Zn，Ce，Bi，Sr，Mn，Cu，Ni，Li ，Na，K和/或质子化的氮碱，并且催化剂A由过渡金属和/或过渡金属化合物和/或由过渡金属和/或过渡金属化合物和至少一种配体组成的催化剂体系形成，催化剂B由形成过氧化物和/或过氧化合物和/或偶氮化合物和/或碱金属和/或碱土金属，碱金属氢化物，碱土金属氢化物和/或碱金属醇盐和碱土金属醇盐的化合物和催化剂C形成是酸或碱。

58. 发明申请

US20110213059A1 Method for Producing Mono-Carboxyfunctionalized Dialkylphosphinic Acids and Esters and Salts Thereof by means of Vinylenes-Nitriles and Use Thereof 审中-公开
标题翻译：通过乙烯基腈制备单羧基官能化二烷基次膦酸及其酯及其盐的方法及用途
公开(公告)号：US20110213059A1
公开(公告)日：2011-09-01
申请号：US13125363
申请日：2009-10-06
申请人： Michael Hill , Werner Krause , Martin Sicken
发明人： Michael Hill , Werner Krause , Martin Sicken
IPC分类号： C08K5/5313 , C07F9/30 , C07F9/32
CPC分类号： C07F9/3217 , C07F9/301 , C07F9/302 , C07F9/306 , C07F9/3211 , C07F9/3241 , C07F9/3264 , C07F9/4816 , C07F9/4866 , C08K5/5313 , C09K21/12
摘要： The invention relates to a method for producing mono-carboxyfunctional zed dialkylphosphinic acids and esters and salts thereof by means of vinylenes/nitriles, characterized in that a) a phosphinic acid source (I) is reacted with olefins (IV) to yield an alkylphosphonic acid, salt or ester (II) thereof in the presence of a catalyst A, b) the thus obtained alkylphosphonic acid, salt or ester (II) thereof is reacted with acetylenic compounds of formula (V) to yield a mono-functionalized dialkylphosphinic acid derivative (VI) in the presence of a catalyst B, and c) the thus obtained mono-functionalized dialkylphosphinic acid derivative (VI) is reacted with a hydrogen cyanide source to yield a mono-functionalized dialkylphosphinic acid derivative (VII) in the presence of a catalyst C, and d) the thus obtained monofunctionalized dialkylphosphinic acid derivative (VII); is reacted to yield a monocarboxyfunctionalized dialkylphosphinic acid derivative (III) in the presence of a catalyst D, wherein R1, R2, R3, R4, R5, R6 are the same or different and stand independently of each other, among other things, for H, C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl, and X and Y are the same or different and stand independently of each other for H, C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl, Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K and/or a protonized nitrogen base, and the catalysts A, B and C are formed by transition metals and/or transition metal compounds and/or catalyst systems composed of a transition metal and/or a transition metal compound and at least one ligand, and the catalyst D is an acid or a base.
摘要翻译：本发明涉及通过乙烯/腈制备单羧基官能化的二烷基次膦酸及其酯和盐的方法，其特征在于a）将次膦酸源（I）与烯烃（Ⅳ）反应，得到烷基膦酸，其盐或酯（II），b）将如此得到的烷基膦酸，其盐或酯（II）与式（V）的炔属化合物反应，得到单官能化二烷基次膦酸衍生物（Ⅵ）在催化剂B存在下反应，和c）将由此得到的单官能化二烷基次膦酸衍生物（Ⅵ）与氰化氢源反应，得到单官能化二烷基次膦酸衍生物（Ⅶ）催化剂C，和d）由此获得的单官能二烷基次膦酸衍生物（VII）; 在催化剂D的存在下反应得到单羧基官能化的二烷基次膦酸衍生物（III），其中R1，R2，R3，R4，R5，R6相同或不同，彼此独立地表示H ，C 1 -C 18烷基，C 6 -C 18芳基，C 6 -C 18芳烷基，C 6 -C 18烷基芳基，X和Y相同或不同，H，C 1 -C 18烷基，C 6 -C 18芳基，C 6 -C 18芳烷基，C 6 -C 18烷基芳基，Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Zn，Ce，Bi，Sr，Mn，Cu，Ni，Li，Na，K和/ 质子化的氮碱，并且催化剂A，B和C由过渡金属和/或过渡金属化合物和/或由过渡金属和/或过渡金属化合物和至少一种配体组成的催化剂体系形成，催化剂D 是酸或碱。

59. 发明申请

US20110213052A1 Method for Producing Dialkylphosphinic Acids and Esters and Salts Thereof by Means of Acrylic Acid Derivatives and Use Thereof 有权
标题翻译：通过丙烯酸衍生物生产二烷基次膦酸及其酯及其盐的方法及用途
公开(公告)号：US20110213052A1
公开(公告)日：2011-09-01
申请号：US13127102
申请日：2009-10-06
申请人： Michael Hill , Harald Bauer , Werner Krause , Martin Sicken
发明人： Michael Hill , Harald Bauer , Werner Krause , Martin Sicken
IPC分类号： C08L63/00 , C07F9/30 , C07F9/32 , C07F5/06 , C07F7/28 , C08G63/183 , C08L67/02 , C08G59/02 , C08G69/26 , C08L77/06
CPC分类号： C09K21/12 , C07F9/301 , C07F9/3211 , C08K5/5313
摘要： The invention relates to a method for producing mono-carboxyfunctionalized dialkylphosphinic acids and esters and salts thereof, characterized in that a) a phosphinic acid source (I) is reacted with olefins (IV) to yield an alkylphosphonic acid, salt or ester (II) thereof in the presence of a catalyst A, b) the alkylphosphonic acid thus obtained, salt or ester (II) thereof is reacted with an α,β-unsaturated carboxylic acid derivative (V) to yield a mono-carboxyfunctionalized dialkylphosphinic acid derivative (III) in the presence of a catalyst B, wherein R1, R2, R3, R4, R5, R6, R7 are the same or different and stand independently of each other, among other things, for H, C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl, and X and Y are the same or different and stand independently of each other for H, C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl, Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K and/or a protonized nitrogen base, and the catalyst A is formed by transition metals and/or transition metal compounds and/or catalyst systems composed of a transition metal and/or a transition metal compound and at least one ligand, and catalyst B is formed by compounds forming peroxides and/or peroxo compounds and/or azo compounds and/or alkali metals and/or alkaline earth metals, alkali hydrides, alkaline earth hydrides and/or alkali alcoholates and alkaline earth alcoholates.
摘要翻译：本发明涉及一种用于制备单羧基官能化二烷基次膦酸及其酯和盐的方法，其特征在于a）将次膦酸源（I）与烯烃（Ⅳ）反应得到烷基膦酸，盐或酯（Ⅱ）在催化剂A存在下，将所得的烷基膦酸，其盐或酯（II）与α，β-不饱和羧酸衍生物（V）反应，得到单羧基官能化的二烷基次膦酸衍生物（ III）在催化剂B存在下，其中R 1，R 2，R 3，R 4，R 5，R 6，R 7相同或不同，彼此独立地表示H，C 1 -C 18烷基， C18芳基，C6-C18芳烷基，C6-C18烷基芳基，X和Y相同或不同，并且H，C1-C18烷基，C6-C18芳基，C6-C18芳烷基，C6-C18烷基芳基，Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Zn，Ce，Bi，Sr，Mn，Cu，Ni，Li，Na，K和/或质子化氮碱催化剂A由过渡金属和/或过渡金属化合物和/或由过渡金属和/或过渡金属化合物和至少一种配体组成的催化剂体系形成，催化剂B由形成过氧化物和/或过氧化合物和/或偶氮化合物和/或碱金属和/或碱土金属，碱金属氢化物，碱土金属氢化物和/或碱金属醇盐和碱土金属盐。

60. 发明申请

US20090136440A1 Mixtures of phosphorus-containing compounds, a process for their preparation, and their use as flame retardants 审中-公开
标题翻译：含磷化合物的混合物，其制备方法及其作为阻燃剂的用途
公开(公告)号：US20090136440A1
公开(公告)日：2009-05-28
申请号：US12313542
申请日：2008-11-21
申请人： Wiebke Maas , Mathias Dietz , Martin Sicken
发明人： Wiebke Maas , Mathias Dietz , Martin Sicken
IPC分类号： A61K31/765 , C08L85/02 , C08L77/00 , C08L67/00 , H01M10/02 , A01P3/00 , A01P13/00 , C10L1/04 , A01P21/00 , A01P7/04 , H01G9/004 , C11D3/36 , C08L1/02 , A01N57/20
CPC分类号： C08K5/5317 , C08K2201/014
摘要： The invention relates to mixtures of compounds of the formulae (I), (III), (IV), and/or (V), in which n is an average chain length of from 0 to 10, A1 and A2 are identical or different and, independently of one another, are C(═O)NHR5, C(═O)R5, CH3, CH2CH3, CH2CH2CH3, CH(CH3)2, CH2(CH2)2CH3, CH2CH(CH3)2, C(CH3)3, C6H5, and/or CH2—C6H5, R1 is a moiety of the formula (II), in which k is an average chain length of from 0 to 5; R2 is CH3, CH2CH3, CH2CH2CH3, CH2(CH3)2, CH2(CH2)2CH3, CH2CH(CH3)2, C(CH3)3, C6H5, or CH2—C6H5; OCH3, OCH2CH3, O(CH2)2CH3, OCH(CH3)2, O(CH2)3CH3, OCH2CH(CH3)2, OC(CH3)3, O—C6H5, or O—CH2—C6H4, R3, R4, R5 are identical or different and, independently of one another, are CH3, CH2CH3, CH2CH2CH3, CH(CH3)2, CH2(CH2)2CH3, CH2Ch(CH3)2, C(CH3)3, C6H5, and/or CH2—C6H5 and where at least 2 compounds of the formulae (I), (III), (IV), or (V) are simultaneously present in the mixture; to a process for their preparation, and to their use as flame retardants.
摘要翻译：本发明涉及式（I），（III），（IV）和/或（V）的化合物的混合物，其中n是0至10的平均链长，A1和A2相同或不同并且彼此独立地为C（= O）NHR 5，C（-O）R 5，CH 3，CH 2 CH 3，CH 2 CH 2 CH 3，CH（CH 3）2，CH 2（CH 2）2 CH 3，CH 2 CH（CH 3）2，C（CH 3） 3，C 6 H 5和/或CH 2 -C 6 H 5，R 1是式（II）的部分，其中k是0至5的平均链长度; R 2是CH 3，CH 2 CH 3，CH 2 CH 2 CH 3，CH 2（CH 3）2，CH 2（CH 2）2 CH 3，CH 2 CH（CH 3）2，C（CH 3）3，C 6 H 5或CH 2 -C 6 H 5; OCH 3 CH 3，OCH（CH 3）2，O（CH 2）3 CH 3，OCH 2 CH（CH 3）2，OC（CH 3）3，O-C 6 H 5或O-CH 2 -C 6 H 4，是CH 3，CH 2 CH 3，CH 2 CH 2 CH 3，CH（CH 3）2，CH 2（CH 2）2 CH 3，CH 2 CH（CH 3）2，C（CH 3）3，C 6 H 5和/或CH 2 -C 6 H 5 并且其中至少2种式（I），（III），（IV）或（V）化合物同时存在于混合物中; 作为其制备方法，并用作阻燃剂。

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