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    • 58. 发明授权
    • Substituted tricyclodecane derivatives, processes for producing same and
organoleptic uses thereof
    • 取代的三环癸烷衍生物,其制备方法和感官用途
    • US4318863A
    • 1982-03-09
    • US220632
    • 1980-12-29
    • Mark A. SpreckerJohn B. Hall
    • Mark A. SpreckerJohn B. Hall
    • A24B15/34C07C29/09C07C29/17C07C29/70C07C35/37C07C35/46C07C45/29C07C49/643C11B9/00C07C69/96
    • C11B9/0042A24B15/345C07C29/095C07C29/17C07C29/70C07C35/37C07C35/46C07C45/29C07C49/643C07C2103/66
    • Described are substituted tricyclodecane derivatives having the generic structure: ##STR1## wherein Y is a moiety having a structure selected from the group consisting of: ##STR2## wherein one of the dashed lines represents a carbon-carbon single bond and the other of the dashed lines represents a carbon-carbon double bond; wherein R.sub.1 and R.sub.2 represent hydrogen or methyl with the proviso that one of R.sub.1 and R.sub.2 is hydrogen and the other of R.sub.1 and R.sub.2 is methyl; wherein R.sub.3 is hydrogen, C.sub.1 -C.sub.3 acyl, C.sub.3 or C.sub.4 alkyl or C.sub.3 or C.sub.4 alkenyl; wherein R.sub.4, R.sub.5 and R.sub.6 represent hydrogen or methyl with the additional proviso that one of R.sub.4, R.sub.5 and R.sub.6 is methyl and the other two of R.sub.4, R.sub.5 and R.sub.6 is hydrogen. Also described are processes for preparing such substituted tricyclodecane derivatives and processes for using the above defined substituted tricyclodecane derivatives for their organoleptic properties and compositions containing said substituted tricyclodecane derivatives including perfumes, perfumed articles, such as solid or liquid anionic, cationic, nonionic and zwitterionic detergents, fabric softeners and cosmetic powders; foodstuffs, chewing gums, toothpastes, medicinal products and chewing tobaccos; smoking tobacco compositions and smoking tobacco flavoring compositions and smoking tobacco articles containing such smoking tobacco compositions.
    • 描述了具有以下通用结构的取代的三环癸烷衍生物:其中Y是具有选自以下的结构的部分:其中一条虚线表示碳 - 碳单键,另一条为虚线 线代表碳 - 碳双键; 其中R1和R2表示氢或甲基,条件是R1和R2之一是氢,R1和R2中的另一个是甲基; 其中R3是氢,C1-C3酰基,C3或C4烷基或C3或C4链烯基; 其中R4,R5和R6代表氢或甲基,另外条件是R4,R5和R6之一是甲基,R4,R5和R6中的另外两个是氢。 还描述了制备这种取代的三环癸烷衍生物的方法和使用上述定义的取代的三环癸烷衍生物的感官特性的方法和含有所述取代的三环癸烷衍生物的组合物,包括香料,加香制品如固体或液体阴离子,阳离子,非离子和两性离子洗涤剂 ,织物柔软剂和化妆粉; 食品,口香糖,牙膏,药用产品和咀嚼烟草; 吸烟烟草组合物和吸烟烟草调味组合物和含有烟草烟草组合物的烟草制品。
    • 59. 发明授权
    • Benzodioxanones and organoleptic uses thereof
    • 苯并二恶烷酮及其感官用途
    • US4294266A
    • 1981-10-13
    • US145985
    • 1980-05-02
    • Mark A. SpreckerJohn B. HallFrederick L. Schmitt
    • Mark A. SpreckerJohn B. HallFrederick L. Schmitt
    • A23L27/20A24B15/40C07D319/20A24B3/12
    • C07D319/20A23L27/2052A24B15/403
    • Described are the bicyclic compounds having the generic structure: ##STR1## wherein Z is benzo or cyclohexano and processes for preparing same and compositions containing same for use in augmenting or enhancing the aroma and/or taste of foodstuffs, chewing gums, toothpastes and medicinal products; tobacco; perfumes, colognes and perfumed articles, produced by a process described by the reaction: ##STR2## wherein X is chloro or bromo; Y is chloro, bromo or OR; R is C.sub.1 -C.sub.3 lower alkyl, that is: methyl, ethyl, n-propyl or i-propyl; B is MOH, MH, MOR', trialkylamine, or M.sub.2 --CO.sub.3 (wherein M is alkali metal such as sodium or potassium); and R' is C.sub.1 -C.sub.5 lower alkyl, such as methyl, ethyl, n-propyl, i-propyl and t-butyl with the proviso that B is trialkylamine or an alkali metal carbonate when Y is chloro or bromo and B is MOH, MH or MOR' when Y is OR.The above mentioned compounds produce:A. In foodstuffs, chewing gums and medicinal products, a sweet, green, fruity, coumarinic, marzipan-like aroma and taste.B. In tobacco, a sweet, spicy, vanilla-like, woody, hay, tobacco-like aroma prior to smoking and a sweet, spicy, hay, tobacco-like aroma on smoking.C. In perfumes, colognes and perfumed articles, sweet, fruity, and green aroma nuances.
    • 描述了具有以下通用结构的双环化合物:其中Z是苯并或环己烷,其制备方法和含有其的组合物用于增强或增强食品,口香糖,牙膏和药用产品的香气和/或味道 ; 烟草; 香料,古龙水和香料制品,其通过以下反应描述的方法制备:其中X为氯或溴; Y是氯,溴或OR; R是C 1 -C 3低级烷基,即:甲基,乙基,正丙基或异丙​​基; B是MOH,MH,MOR',三烷基胺或者M2-CO 3(其中M是碱金属如钠或钾); 并且R'为C1-C5低级烷基,例如甲基,乙基,正丙基,异丙基和叔丁基,条件是当Y为氯或溴且B为MOH时,B为三烷基胺或碱金属碳酸盐, MH或MOR'。 上述化合物产生:A.在食品,口香糖和药用产品中,甜,绿,水果,香豆素,杏仁糖样香气和味道。 B.在烟草中,一种甜味,辛辣,香草般,木质,干草,烟草般的香气,吸烟之前是一种甜,辣,干草,烟草般的吸烟香气。