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1. 发明授权

US4259214A Benzodioxanones and organoleptic uses thereof 失效
公开(公告)号：US4259214A
公开(公告)日：1981-03-31
申请号：US145986
申请日：1980-05-02
申请人： Mark A. Sprecker , John B. Hall , Frederick L. Schmitt
发明人： Mark A. Sprecker , John B. Hall , Frederick L. Schmitt
IPC分类号： A23L27/20 , C07D319/20 , C11B9/00
CPC分类号： C11B9/008 , A23L27/2052 , C07D319/20 , Y10S514/974
摘要： Described are the bicyclic compounds having the generic structure: ##STR1## wherein Z is benzo or cyclohexano and processes for preparing same and compositions containing same for use in augmenting or enhancing the aroma and/or taste of foodstuffs, chewing gums, toothpastes and medicinal products; tobacco; perfumes, colognes and perfumed articles, produced by a process described by the reaction: ##STR2## wherein X is chloro or bromo; Y is chloro, bromo or OR; R is C.sub.1 -C.sub.3 lower alkyl, that is: methyl, ethyl, n-propyl or i-propyl; B is MOH, MH, MOR', trialkylamine, or M.sub.2 -CO.sub.3 (wherein M is alkali metal such as sodium or potassium); and R' is C.sub.1 -C.sub.5 lower alkyl, such as methyl, ethyl, n-propyl, i-propyl and t-butyl with the proviso that B is trialkylamine or an alkali metal carbonate when Y is chloro or bromo and B is MOH, MH or MOR' when Y is OR.The above mentioned compounds produce:A. In foodstuffs, chewing gums and medicinal products, a sweet, green, fruity, coumarinic, marzipan-like aroma and taste.B. In tobacco, a sweet, spicy, vanilla-like, woody, hay, tobacco-like aroma prior to smoking and a sweet, spicy, hay, tobacco-like aroma on smoking.C. In perfumes, colognes and perfumed articles, sweet, fruity, and green aroma nuances.

2. 发明授权

US4241097A Use of benzodionones in augmenting or enhancing the aroma and taste of a foodstuff 失效
标题翻译：使用苯并二氢醌来增强或增强食品的香气和味道
公开(公告)号：US4241097A
公开(公告)日：1980-12-23
申请号：US75071
申请日：1979-09-13
申请人： Mark A. Sprecker , John B. Hall , Frederick L. Schmitt
发明人： Mark A. Sprecker , John B. Hall , Frederick L. Schmitt
IPC分类号： A23L27/20 , C07D319/20 , A23L1/226
CPC分类号： C07D319/20 , A23L27/2052
摘要： Described are the bicyclic compounds having the generic structure: ##STR1## (Z is benzo or cyclohexano) and compositions containing same for use in augmenting or enhancing the aroma and/or taste of foodstuffs, chewing gums, toothpastes and medicinal products. These compounds produce in foodstuffs, chewing gums, toothpastes and medicinal products having a sweet, green, fruity, coumarinic, marzipan-like aroma and taste.
摘要翻译：描述了具有以下通用结构的双环化合物：其中Z是苯并或环己烷，以及包含其的组合物，用于增强或增强食品，口香糖，牙膏和药用产品的香气和/或味道。这些化合物在食品，口香糖，牙膏和具有甜，绿，水果，香豆素，杏仁糖样香气和味道的药用产品中产生。

3. 发明授权

US4155867A Substituted dimethyl dihydroxy benzene and cyclohexadiene compounds and uses thereof for augmenting or enhancing the taste and/or aroma of consumable materials including tobaccos, perfumes and perfumed articles 失效
标题翻译：取代的二甲基二羟基苯和环己二烯化合物及其用途，用于增强或增强消耗材料的味道和/或香气，包括烟草，香水和香料
公开(公告)号：US4155867A
公开(公告)日：1979-05-22
申请号：US913716
申请日：1978-06-08
申请人： John B. Hall , Mark A. Sprecker , Edward J. Shuster , Frederick L. Schmitt , Joaquin F. Vinals
发明人： John B. Hall , Mark A. Sprecker , Edward J. Shuster , Frederick L. Schmitt , Joaquin F. Vinals
IPC分类号： A24B15/30 , A24B15/34 , C07C37/50 , C07C45/42 , C07C49/603 , C07C255/49 , C11B9/00 , C11D3/50
CPC分类号： C07C255/00 , A24B15/301 , A24B15/34 , C07C37/50 , C07C45/42 , C07C49/603 , C11B9/0061 , C11D3/50
摘要： A process for augmenting or enhancing the organoleptic properties of a consumable material such as soaps and detergents by admixing a substituted dimethyl dihydroxy benzene or cyclo-hexadiene.

4. 发明授权

US4264456A Benzodioxanones and organoleptic uses thereof 失效
公开(公告)号：US4264456A
公开(公告)日：1981-04-28
申请号：US145984
申请日：1980-05-02
申请人： Mark A. Sprecker , John B. Hall , Frederick L. Schmitt
发明人： Mark A. Sprecker , John B. Hall , Frederick L. Schmitt
IPC分类号： A23L27/20 , A24B15/40 , C07D319/20 , C11B9/00 , A23L1/226
CPC分类号： C11B9/008 , A23L27/2052 , A24B15/403 , C07D319/20
摘要： Described are the bicyclic compounds having the generic structure: ##STR1## wherein Z is benzo or cyclohexano and processes for preparing same and compositions containing same for use in augmenting or enhancing the aroma and/or taste of foodstuffs, chewing gums, toothpastes and medicinal products; tobacco; perfumes, colognes and perfumed articles, produced by a process described by the reaction: ##STR2## wherein X is chloro or bromo; Y is chloro, bromo or OR; R is C.sub.1 -C.sub.3 lower alkyl, that is: methyl, ethyl, n-propyl or i-propyl; B is MOH, MH, MOR', trialkylamine, or M.sub.2 -CO.sub.3 (wherein M is alkali metal such as sodium or potassium); and R' is C.sub.1 -C.sub.5 lower alkyl, such as methyl, ethyl, n-propyl, i-propyl and t-butyl with the proviso that B is trialkylamine or an alkali metal carbonate when Y is chloro or bromo and B is MOH, MH or MOR' when Y is OR.The above mentioned compounds produce:A. In foodstuffs, chewing gums and medicinal products, a sweet, green, fruity, coumarinic, marzipan-like aroma and taste.B. In tobacco, a sweet, spicy, vanilla-like, woody, hay, tobacco-like aroma prior to smoking and a sweet, spicy, hay, tobacco-like aroma on smoking.C. In perfumes, colognes and perfumed articles, sweet, fruity, and green aroma nuances.

5. 发明授权

US4173982A Use of substituted dimethyl dihydroxy benzene and cyclohexadiene compounds for augmenting or enhancing the taste and/or aroma of smoking tobaccos 失效
标题翻译：使用取代的二甲基二羟基苯和环己二烯化合物来增强或增强吸烟烟草的味道和/或香味
公开(公告)号：US4173982A
公开(公告)日：1979-11-13
申请号：US913717
申请日：1978-06-08
申请人： John B. Hall , Mark A. Sprecker , Edward J. Shuster , Frederick L. Schmitt , Joaquin F. Vinals
发明人： John B. Hall , Mark A. Sprecker , Edward J. Shuster , Frederick L. Schmitt , Joaquin F. Vinals
IPC分类号： A24B15/34 , C07C37/50 , C07C45/42 , C11B9/00 , A24B3/12 , A24D1/00
CPC分类号： C07C255/00 , A24B15/34 , C07C37/50 , C07C45/42 , C11B9/0061
摘要： Described is a process for augmenting or enhancing the aroma or taste of a smoking tobacco comprising the step of intimately admixing an organoleptic property modifying quantity of a substituted dimethyl dihydroxy benzene or cyclohexadiene represented by the equilibrium mixture of a constituent thereof: ##STR1## wherein R.sub.1 is selected from the group consisting of acetyl having the structure: ##STR2## and nitrile having the structure:--C.tbd.N]and wherein the dashed line represents a carbon-carbon single bond or a carbon-carbon double bond with the proviso that when the dashed line represents a carbon-carbon single bond R.sub.1 is only nitrile with a material selected from the group consisting of tobacco and at least one other tobacco flavoring adjuvant; and smoking articles containing said smoking tobacco.
摘要翻译：描述了一种用于增强或增强烟草香气或味道的方法，其包括将由其组成的平衡混合物表示的感官特性改性量的取代的二甲基二羟基苯或环己二烯密切混合的步骤：其中R1 选自具有以下结构的乙酰基：具有以下结构的结构：具有以下结构的结构：-C 3 N N]，其中虚线表示碳 - 碳单键或碳 - 碳双键，条件是当虚线表示碳 - 碳单键，R1仅为具有选自烟草和至少一种其它烟草调味佐剂的材料的腈; 以及含有所述吸烟烟草的吸烟物品。

6. 发明授权

US4147727A 1-Butenoyl-3,3-dimethylcyclohexane mixtures 失效
标题翻译： 1-丁烯酰基-3,3-二甲基环己烷混合物
公开(公告)号：US4147727A
公开(公告)日：1979-04-03
申请号：US851726
申请日：1977-11-15
申请人： Mark A. Sprecker , Manfred H. Vock , Frederick L. Schmitt , John B. Hall , James M. Sanders
发明人： Mark A. Sprecker , Manfred H. Vock , Frederick L. Schmitt , John B. Hall , James M. Sanders
IPC分类号： A23G3/00 , A23G3/36 , A23G4/00 , A23G4/06 , A23G4/12 , A24B15/30 , A24B15/34 , C07C45/62 , C07C45/68 , C07C47/21 , C07C47/232 , C07C49/303 , C07C49/557 , C07C49/647 , C07C403/00 , C11B9/00 , C07C49/61
CPC分类号： A23G3/36 , A23G4/06 , A23G4/126 , A24B15/30 , A24B15/34 , C07C403/16 , C07C45/62 , C07C45/68 , C07C47/21 , C07C47/232 , C07C49/303 , C07C49/557 , C07C49/647 , C11B9/0015 , C11B9/0034 , C11D3/0084 , C07C2101/14
摘要： 1-BUTENOYL-3,3-DIMETHYLCYCLOHEXANE MIXTURES HAVING A SWEET ROOTBEER-LIKE, CEDARWOOD FLAVOR USEFUL AS FLAVORANTS IN FOODSTUFFS ARE DESCRIBED.
摘要翻译： 1-BUTENOYL-3,3-DIMETHYLCYCLOHEXANE混合物，具有甜菜类，如果用作食用油中的香料，则可以使用CEDARWOOD FLAVOR。

7. 发明授权

US4294266A Benzodioxanones and organoleptic uses thereof 失效
标题翻译：苯并二恶烷酮及其感官用途
公开(公告)号：US4294266A
公开(公告)日：1981-10-13
申请号：US145985
申请日：1980-05-02
申请人： Mark A. Sprecker , John B. Hall , Frederick L. Schmitt
发明人： Mark A. Sprecker , John B. Hall , Frederick L. Schmitt
IPC分类号： A23L27/20 , A24B15/40 , C07D319/20 , A24B3/12
CPC分类号： C07D319/20 , A23L27/2052 , A24B15/403
摘要： Described are the bicyclic compounds having the generic structure: ##STR1## wherein Z is benzo or cyclohexano and processes for preparing same and compositions containing same for use in augmenting or enhancing the aroma and/or taste of foodstuffs, chewing gums, toothpastes and medicinal products; tobacco; perfumes, colognes and perfumed articles, produced by a process described by the reaction: ##STR2## wherein X is chloro or bromo; Y is chloro, bromo or OR; R is C.sub.1 -C.sub.3 lower alkyl, that is: methyl, ethyl, n-propyl or i-propyl; B is MOH, MH, MOR', trialkylamine, or M.sub.2 --CO.sub.3 (wherein M is alkali metal such as sodium or potassium); and R' is C.sub.1 -C.sub.5 lower alkyl, such as methyl, ethyl, n-propyl, i-propyl and t-butyl with the proviso that B is trialkylamine or an alkali metal carbonate when Y is chloro or bromo and B is MOH, MH or MOR' when Y is OR.The above mentioned compounds produce:A. In foodstuffs, chewing gums and medicinal products, a sweet, green, fruity, coumarinic, marzipan-like aroma and taste.B. In tobacco, a sweet, spicy, vanilla-like, woody, hay, tobacco-like aroma prior to smoking and a sweet, spicy, hay, tobacco-like aroma on smoking.C. In perfumes, colognes and perfumed articles, sweet, fruity, and green aroma nuances.
摘要翻译：描述了具有以下通用结构的双环化合物：其中Z是苯并或环己烷，其制备方法和含有其的组合物用于增强或增强食品，口香糖，牙膏和药用产品的香气和/或味道 ; 烟草; 香料，古龙水和香料制品，其通过以下反应描述的方法制备：其中X为氯或溴; Y是氯，溴或OR; R是C 1 -C 3低级烷基，即：甲基，乙基，正丙基或异丙基; B是MOH，MH，MOR'，三烷基胺或者M2-CO 3（其中M是碱金属如钠或钾）; 并且R'为C1-C5低级烷基，例如甲基，乙基，正丙基，异丙基和叔丁基，条件是当Y为氯或溴且B为MOH时，B为三烷基胺或碱金属碳酸盐， MH或MOR'。上述化合物产生：A.在食品，口香糖和药用产品中，甜，绿，水果，香豆素，杏仁糖样香气和味道。 B.在烟草中，一种甜味，辛辣，香草般，木质，干草，烟草般的香气，吸烟之前是一种甜，辣，干草，烟草般的吸烟香气。

8. 发明授权

US4255275A Benzodioxanones and organoleptic uses thereof 失效
标题翻译：苯并二恶烷酮及其感官用途
公开(公告)号：US4255275A
公开(公告)日：1981-03-10
申请号：US146321
申请日：1980-05-02
申请人： Mark A. Sprecker , John B. Hall , Frederick L. Schmitt
发明人： Mark A. Sprecker , John B. Hall , Frederick L. Schmitt
IPC分类号： C11D3/50 , C11D9/44
CPC分类号： C11D3/50 , C11D9/44
摘要： Described is a process for augmenting or enhancing the aroma of a solid or liquid anionic, cationic or nonionic detergent comprising the step of intimately admixing with said solid and liquid anionic, cationic or nonionic detergent base at least one cyclic chemical compound having the structure: ##STR1## wherein Z represents benzo or cyclohexano.
摘要翻译：描述了用于增强或增强固体或液体阴离子，阳离子或非离子洗涤剂的香味的方法，其包括与所述固体和液体阴离子，阳离子或非离子洗涤剂基质紧密混合的步骤，至少一种具有以下结构的环状化合物：其中Z代表苯并或环己烷。

9. 发明授权

US4175569A Substituted-1-ocetyl-3,3-dimethylcyclohexane employed in flavoring tobacco compositions 失效
标题翻译：用于调味烟草组合物中的取代的1-辛基-3,3-二甲基环己烷
公开(公告)号：US4175569A
公开(公告)日：1979-11-27
申请号：US834501
申请日：1977-09-19
申请人： John B. Hall , Mark A. Sprecker , Frederick L. Schmitt , Manfred H. Vock
发明人： John B. Hall , Mark A. Sprecker , Frederick L. Schmitt , Manfred H. Vock
IPC分类号： A23G3/00 , A23G3/36 , A23G4/00 , A23G4/06 , A23G4/12 , A24B15/30 , A24B15/34 , C07C45/62 , C07C45/68 , C07C47/21 , C07C47/232 , C07C49/303 , C07C49/557 , C07C49/647 , C11B9/00 , A24B3/12 , A24D1/00 , A24D1/18
CPC分类号： A23G3/36 , A23G4/06 , A23G4/126 , A24B15/30 , A24B15/34 , C07C403/16 , C07C45/62 , C07C45/68 , C07C47/21 , C07C47/232 , C07C49/303 , C07C49/557 , C07C49/647 , C11B9/0015 , C11B9/0034 , C11D3/0084 , C07C2101/14
摘要： Described is a genus of substituted 1-acetyl-3,3-dimethylcyclohexanes having the structure: ##STR1## wherein R.sub.1 is methyllyl, R.sub.2 is hydrogen and R.sub.3 is hydrogen, or wherein R.sub.1 is hydrogen, R.sub.2 is methyllyl and R.sub.3 is methyllyl. The above compound is employed in combination with smoking tobacco.
摘要翻译：描述了具有以下结构的取代的1-乙酰基-3,3-二甲基环己烷的属性：其中R1是甲基，R2是氢，R3是氢，或者其中R1是氢，R2是甲基，R3是甲基。上述化合物与吸烟烟草组合使用。

10. 发明授权

US4169072A Substituted dimethyl dihydroxy benzene and cyclohexadiene compounds in perfumery 失效
标题翻译：在香料中取代二甲基二羟基苯和环己二烯化合物
公开(公告)号：US4169072A
公开(公告)日：1979-09-25
申请号：US913715
申请日：1978-06-08
申请人： John B. Hall , Mark A. Sprecker , Edward J. Shuster , Frederick L. Schmitt , Joaquin F. Vinals
发明人： John B. Hall , Mark A. Sprecker , Edward J. Shuster , Frederick L. Schmitt , Joaquin F. Vinals
IPC分类号： A24B15/34 , C07C37/50 , C07C45/42 , C11B9/00
CPC分类号： C07C255/00 , A24B15/34 , C07C37/50 , C07C45/42 , C11B9/0034 , C11B9/0061
摘要： Processes and compositions are described for the use in perfume aroma augmenting, modifying, enhancing and imparting compositions of one or more substituted dimethyl dihydroxy benzene and/or cyclohexadiene compounds, represented either by the equilibrium mixture: ##STR1## (and other tautomers) or by one of the components of the equilibrium mixture wherein the dashed line is a carbon-carbon single bond or a carbon-carbon double bond.The above-mentioned compounds, taken alone or in combination, provide and/or enhance and/or enrich "Oak Moss" notes in perfumes such as "Mousse de Chene".
摘要翻译：描述了用于香料香气增强，改性，增强和赋予一种或多种取代的二甲基二羟基苯和/或环己二烯化合物的组合物的方法和组合物，其由平衡混合物（或其它互变异构体）或由平衡混合物的组分之一，其中虚线是碳 - 碳单键或碳 - 碳双键。

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