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51. 发明授权

US5284851A 1-alkoxy-1,3-diazacycloalkane derivatives and their use as pesticides 失效
标题翻译： 1-烷氧基-1,3-二氮杂环烷烃衍生物及其作为农药的用途
公开(公告)号：US5284851A
公开(公告)日：1994-02-08
申请号：US866591
申请日：1992-04-10
申请人： Wolfgang Von Deyn , Albrecht Harreus , Uwe Kardorff , Christoph Kuenast
发明人： Wolfgang Von Deyn , Albrecht Harreus , Uwe Kardorff , Christoph Kuenast
IPC分类号： A01N43/50 , A01N43/54 , C07C239/20 , C07D213/30 , C07D213/61 , C07D233/20 , C07D233/22 , C07D233/52 , C07D239/06 , C07D239/20 , C07D239/30 , C07D261/08 , C07D401/06 , C07D401/12 , C07D403/12 , C07D407/12 , C07D409/12 , C07D413/06 , C07D413/12 , C07D417/12 , C07D233/02
CPC分类号： C07D213/30 , A01N43/50 , A01N43/54 , C07C239/20 , C07D213/61 , C07D233/20 , C07D239/06 , C07D261/08 , C07D401/06 , C07D413/06
摘要： 1-Alkoxy-1,3-diazacycloalkane derivatives of the formula I ##STR1## where: n is 0 or 1;R.sup.1 is substituted or unsubstituted alkyl, alkylcarbonyl, cycloalkylcarbonyl, alkenyl or alkynyl, a substituted or unsubstituted heterocyclic radical or a group --C(.dbd.O)--R, where R is substituted or unsubstituted phenyl or a substituted or unsubstituted aliphatic or aromatic heterocyclic structure,X ishydrogen; halogen; alkoxy; alkylthio; alkylcarbonyl; haloalkylcarbonyl; alkoxycarbonyl;substituted or unsubstituted alkyl, phenyl, phenoxy, phenylthio, benzoyl or phenyloxycarbonyl; andR.sup.2 ishydrogen or alkyl,processes and intermediates for their manufacture, and their use in pesticides.
摘要翻译：式I的1-烷氧基-1,3-二氮杂环烷烃衍生物其中：n为0或1; R 1是取代或未取代的烷基，烷基羰基，环烷基羰基，烯基或炔基，取代或未取代的杂环基或基团-C（= O）-R，其中R是取代或未取代的苯基或取代或未取代的脂族或芳族杂环结构 X是氢; 卤素; 烷氧基烷硫基烷基羰基; 卤代烷基羰基烷氧基羰基取代或未取代的烷基，苯基，苯氧基，苯硫基，苯甲酰基或苯氧基羰基; 并且R2是氢或烷基，其制备方法和中间体及其在农药中的用途。

52. 发明授权

US5284821A Oxazole- and thiazolecarboxamides 失效
标题翻译：恶唑和噻唑甲酰胺
公开(公告)号：US5284821A
公开(公告)日：1994-02-08
申请号：US919457
申请日：1992-07-27
申请人： Klaus Ditrich , Volker Maywald , Gerhard Hamprecht , Albrecht Harreus , Bruno Wuerzer , Karl-Otto Westphalen
发明人： Klaus Ditrich , Volker Maywald , Gerhard Hamprecht , Albrecht Harreus , Bruno Wuerzer , Karl-Otto Westphalen
IPC分类号： A01N43/74 , C07D263/34 , C07D277/56 , C07D417/04 , A01N43/76
CPC分类号： C07D263/34 , A01N43/74 , C07D277/56 , C07D417/04
摘要： Oxazole- and thiazolecarboxamides of the formulae Ia and Ib ##STR1## where the substituents have the following meanings: X oxygen or sulfur;R.sup.1 hydrogen; halogen; substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl, benzyl, cycloalkyl, alkenyl, alkynyl, phenyl, phenoxy or phenylthio; alkoxy; alkylthio; haloalkoxy; haloalkylthio; or a substituted or unsubstituted 5- or 6-membered heterocyclic radical;R.sup.2 formyl, 4,5-dihydrooxazol-2-yl or --COYR.sup.5 ;Y oxygen or sulfur;R.sup.5 hydrogen; cycloalkyl; substituted or unsubstituted alkyl, phenyl, benzyl, alkenyl, cycloalkenyl or alkynyl; a substituted or unsubstituted 5- or 6-membered heterocyclic radical; phthalimido; tetrahydrophthalimido; succinimido; maleiimido; one equivalent of a cation; or--N.dbd.CR.sup.6 R.sup.7 ; R.sup.6, R.sup.7 hydrogen; alkyl; cycloalkyl; phenyl; furyl or together a methylene chain of 4 to 7 members;R.sup.3 hydrogen or substituted or unsubstituted alkyl or cycloalkyl;R.sup.4 hydroxy; alkoxy; substituted or unsubstituted alkyl, cycloalkyl, alkenyl, alkynyl, phenyl or naphthyl; a substituted or unsubstituted 5- or 6-membered heterocyclic radical; or R.sup.3 and R.sup.4 together are --(CH.sub.2).sub.n --Y.sub.p --(CH.sub.2).sub.q --, where n and q are 1, 2 or 3, p is 0 or 1 and Y is oxygen, sulfur or N-methyl, or form a radical of the formula --(CH.sub.2).sub.3 --CO--, and their environmentally tolerated salts,X in formula Ib not being sulfur when R.sup.1 is 3-pyridyl, R.sup.2 is CO.sub.2 CH.sub.2 CH.sub.3 or R.sup.3 is hydrogen, and X in formula Ia X not being sulfur and R.sup.1 not being thien-2-yl when YR.sup.5 is OH, R.sup.3 is hydrogen and R.sup.4 is methyl, processes for manufacturing such compounds and herbicidal agents containing compounds of the formulae Ia or Ib as active ingredients.
摘要翻译：式Ia和Ib的恶唑和噻唑甲酰胺其中取代基具有以下含义：X氧或硫; R1氢; 卤素; 取代或未取代的C 1 -C 6烷基，苄基，环烷基，烯基，炔基，苯基，苯氧基或苯硫基; 烷氧基烷硫基卤代烷氧基卤代烷硫基; 或取代或未取代的五元或六元杂环基; R2甲酰基，4,5-二氢恶唑-2-基或-COYR 5; Y氧或硫; R5氢; 环烷基取代或未取代的烷基，苯基，苄基，烯基，环烯基或炔基; 取代或未取代的5或6元杂环基; 邻苯二甲酰亚氨基四氢邻苯二甲酰亚胺琥珀酰亚胺马来西亚一个阳离子; 或-N = CR 6 R 7; R6，R7氢; 烷基; 环烷基苯基; 呋喃基或一起形成4至7个成员的亚甲基链; R3氢或取代或未取代的烷基或环烷基; R4羟基烷氧基取代或未取代的烷基，环烷基，烯基，炔基，苯基或萘基; 取代或未取代的5或6元杂环基; 或者R 3和R 4一起是 - （CH 2）n -Yp-（CH 2）q - ，其中n和q是1,2或3，p是0或1，Y是氧，硫或N-甲基，或形成式（（CH2）3-CO-）及其环境耐受盐的基团，当R1为3-吡啶基时，式Ib中的X不为硫，R2为CO2CH2CH3或R3为氢，式Ia中的X为硫，并且当YR 5是OH时，R 1不是噻吩-2-基，R 3是氢，R 4是甲基，制备这种化合物的方法和含有式Ia或Ib化合物的除草剂作为活性成分。

53. 发明授权

US5229530A 2,2-dialkyl-2,3-dihydro-6-bromobenzofuran 失效
标题翻译： 2,2-二烷基-2,3-二氢-6-溴苯并呋喃
公开(公告)号：US5229530A
公开(公告)日：1993-07-20
申请号：US956090
申请日：1992-10-02
申请人： Albrecht Harreus , Bernd Wolf , Jochen Wild
发明人： Albrecht Harreus , Bernd Wolf , Jochen Wild
IPC分类号： C07C39/24 , C07C45/54 , C07C49/825 , C07D307/79
CPC分类号： C07D307/79 , C07C39/245 , C07C45/54 , C07C49/825
摘要： A process for the preparation of a 2,3-dihydrobenzofuran I ##STR1## or a derivative thereof, where R.sup.a and R.sup.b are C-organic radicals, involves reacting a 2-hydroxybenzyl alcohol II ##STR2## in the presence of an acidic ion exchanger resin and in the presence of an inert dehydrating substance. Novel 2,3-dihydrobenzofurans Ia, 2-acylphenols IVa and 2-hydrox-ybenzyl alcohols IIa, a process for their preparation, and their use as intermediates are also described.
摘要翻译：制备2,3-二氢苯并呋喃I或其衍生物的方法，其中Ra和Rb是C-有机基团，包括在酸性存在下使2-羟基苄醇II II 离子交换树脂，并在惰性脱水物质的存在下进行。还描述了新的2,3-二氢苯并呋喃Ia，2-酰基苯酚IVa和2-羟基 - 苄基醇IIa，其制备方法及其作为中间体的用途。

54. 发明授权

US5081301A Hydroxylamine derivatives which are intermediates for making herbicidal compounds 失效
标题翻译：作为制造除草剂化合物的中间体的羟甲基胺衍生物
公开(公告)号：US5081301A
公开(公告)日：1992-01-14
申请号：US429160
申请日：1989-10-30
申请人： Jochen Wild , Albrecht Harreus , Ulrich Schirmer , Norbert Meyer , Juergen Kast , Dieter Kolassa
发明人： Jochen Wild , Albrecht Harreus , Ulrich Schirmer , Norbert Meyer , Juergen Kast , Dieter Kolassa
IPC分类号： C07C239/20 , C07C323/19 , C07D209/48
CPC分类号： C07D209/48 , C07C239/20
摘要： Hydroxylamine derivatives have the general formula IAryl--A--O--B IwhereAryl is an unsubstituted or substituted, mononuclear or binuclear, isocyclic radical;A is a 1,4-butenylene group of the general formulae IIa or IIb ##STR1## where R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are each hydrogen, halogen, C.sub.1 -C.sub.6 -alkyl or C.sub.1 -C.sub.6 -alkenyl;B is NH.sub.2 or a dicarboximide group of the general formula III ##STR2## where Z is unsubstituted or substituted phenylene, naphthylene, pyridinylene, cyclopentylene, cyclohexylene, cyclohexenylene, C.sub.2 -C.sub.4 -alkenylene or C.sub.2 -C.sub.4 -alkylene. The dicarboximides are intermediates for the compounds wherein B is NH.sub.2. The latter are used in synthesizing herbicidal compounds.
摘要翻译：羟胺衍生物具有通式I Aryl-A-O-B I，其中芳基是未取代或取代的单核或双核，环状基团; A是通式IIa或IIb的1,4-亚丁烯基IIa其中R 1，R 2，R 3，R 4和R 5各自是氢，卤素，C 1 -C 6烷基或C 1 -C 6 - 烯基; B是NH 2或通式III III的二羧酰亚胺基，其中Z是未取代或取代的亚苯基，亚萘基，亚
苄基，亚环戊基，亚环己基，亚环己烯基，C 2 -C 4亚烯基或C 2 -C 4亚烷基。二羧酰亚胺是其中B是NH 2的化合物的中间体。后者用于合成除草化合物。

55. 发明授权

US4542178A Plasticizer-containing polyvinyl alcohol granules 失效
标题翻译：含增塑剂的聚乙烯醇颗粒
公开(公告)号：US4542178A
公开(公告)日：1985-09-17
申请号：US558546
申请日：1983-12-02
申请人： Wolfgang Zimmermann , Albrecht Harreus
发明人： Wolfgang Zimmermann , Albrecht Harreus
IPC分类号： C08L29/00 , C08J3/12 , C08J3/16 , C08J3/18 , C08K5/00 , C08K5/05 , C08L29/02 , C08L29/04 , C08K5/06 , C08L31/04
CPC分类号： C08J3/18 , C08J3/12 , C08K5/0016 , C08J2329/04
摘要： For the thermoplastic processing of polyvinyl alcohol, the processing temperature must be below the decomposition temperature of the polyvinyl alcohol; this is attained by incorporating plasticizers. For preparing a plasticizer-containing granular polyvinyl alcohol wherein the plasticizer is homogeneously distributed, there is used as starting material a granular polyvinyl alcohol consisting substantially of particles having a definite diameter. The plasticizer is incorporated in the presence of a small amount of water insufficient to dissolve the polyvinyl alcohol, and the temperature is adjusted in a definite manner during the mixing operation. Simultaneous presence of fine particles of a high molecular weight organic compound soluble or dispersible in water is advantageous. The plasticizer-containing granular polyvinyl alcohol is suitable for the manufacture of any shaped articles, especially films and sheets.
摘要翻译：对于聚乙烯醇的热塑性加工，加工温度必须低于聚乙烯醇的分解温度; 这是通过加入增塑剂来实现的。为了制备含增塑剂的粒状聚乙烯醇，其中增塑剂均匀分布，用作基本上由具有一定直径的颗粒组成的颗粒状聚乙烯醇作为原料。在不足以溶解聚乙烯醇的少量水的存在下引入增塑剂，并且在混合操作期间以一定的方式调节温度。同时存在可溶于或可分散在水中的高分子量有机化合物的细颗粒是有利的。含增塑剂的颗粒状聚乙烯醇适用于任何成型制品，特别是薄膜和片材的制造。

56. 发明授权

US4009135A Additive for mortar and concrete 失效
标题翻译：砂浆和混凝土添加剂
公开(公告)号：US4009135A
公开(公告)日：1977-02-22
申请号：US512097
申请日：1974-10-04
申请人： Albrecht Harreus , Eberhard Muller , Gerhart Schultz
发明人： Albrecht Harreus , Eberhard Muller , Gerhart Schultz
IPC分类号： C04B24/30 , C04B28/02 , C08L61/20
CPC分类号： C04B28/02
摘要： The properties of mortar and concrete are improved by the addition to the fresh mortar or concrete of an aqueous dispersion of a plastic obtained by the emulsion polymerization of olefinically unsaturated monomers, and of a polycondensate of formaldehyde and an amino-s-triazine modified with sulfite or sulfonic acid. A well-balanced relation between the compressive strength, the tensile strength in bending, and the adhesion to aged and hardened mortar or concrete is thus obtained.
摘要翻译：通过加入通过烯属不饱和单体的乳液聚合得到的塑料的水分散体和用亚硫酸盐改性的甲醛和氨基-s-三嗪的缩聚物，添加到新鲜的砂浆或混凝土中，改善了砂浆和混凝土的性能或磺酸。因此获得了抗压强度，弯曲拉伸强度和对老化硬化砂浆或混凝土的粘合性之间的平衡关系。

57. 发明授权

US06656884B2 3-(4-cyanophenyl) uracils 失效
标题翻译： 3-（4-氰基苯基）尿嘧啶
公开(公告)号：US06656884B2
公开(公告)日：2003-12-02
申请号：US10323931
申请日：2002-12-20
申请人： Ralf Klintz , Peter Schäfer , Gerhard Hamprecht , Elisabeth Heistracher , Christoph-Sweder von dem Bussche-Hünnefeld , Norbert Götz , Albrecht Harreus , Karl-Otto Westphalen , Helmut Walter , Ulf Misslitz
发明人： Ralf Klintz , Peter Schäfer , Gerhard Hamprecht , Elisabeth Heistracher , Christoph-Sweder von dem Bussche-Hünnefeld , Norbert Götz , Albrecht Harreus , Karl-Otto Westphalen , Helmut Walter , Ulf Misslitz
IPC分类号： C07D23954
CPC分类号： C07D239/54 , A01N43/54 , C07C255/60 , C07C275/42
摘要： 3-(4-Cyanophenyl)uracils of the formula I wherein A is hydrogen, methyl or amino; Y is oxygen or sulfur; R1 is hydrogen or halogen; R2 is hydrogen, halogen, alkyl, haloalkyl, alkylthio, alkylsulfenyl or alkylsulfonyl; R3 is hydrogen, halogen or alkyl; R4 is hydrogen, haloalkyl; or unsubstituted or substituted alkyl, cycloalkyl, alkenyl, alkynyl, alkylcarbonyl, alkenylcarbonyl, alkynylcarbonyl or alkylsulfonyl, methods and intermediates for their manufacture, and their use as herbicides or for the desiccation or defoliation of plants.
摘要翻译：式I的3-（4-氰基苯基）尿嘧啶，其中A是氢，甲基或氨基; Y是氧或硫; R 1是氢或卤素; R 2是氢，卤素，烷基，卤代烷基，烷硫基，或烷基磺酰基; R 3是氢，卤素或烷基; R 4是氢，卤代烷基; 或未取代或取代的烷基，环烷基，烯基，炔基，烷基羰基，烯基羰基，炔基羰基或烷基磺酰基，用于制备的方法和中间体，以及它们作为除草剂的用途或用于植物的干燥或脱叶。

58. 发明授权

US6153759A Heterocyclic benzoyl intermediates for herbicidal compounds 失效
标题翻译：用于除草化合物的杂环苯甲酰中间体
公开(公告)号：US6153759A
公开(公告)日：2000-11-28
申请号：US226142
申请日：1999-01-07
申请人： Wolfgang von Deyn , Regina Luise Hill , Uwe Kardorff , Stefan Engel , Martina Otten , Marcus Vossen , Peter Plath , Harald Rang , Albrecht Harreus , Franz Rohl , Helmut Walter , Karl-Otto Westphalen , Ulf Misslitz
发明人： Wolfgang von Deyn , Regina Luise Hill , Uwe Kardorff , Stefan Engel , Martina Otten , Marcus Vossen , Peter Plath , Harald Rang , Albrecht Harreus , Franz Rohl , Helmut Walter , Karl-Otto Westphalen , Ulf Misslitz
IPC分类号： C07D239/26 , A01N43/08 , A01N43/10 , A01N43/74 , A01N43/80 , C07D207/333 , C07D213/50 , C07D213/57 , C07D213/63 , C07D213/70 , C07D213/74 , C07D215/14 , C07D231/12 , C07D231/14 , C07D231/20 , C07D235/18 , C07D261/04 , C07D261/08 , C07D263/14 , C07D263/32 , C07D271/06 , C07D271/10 , C07D275/02 , C07D277/10 , C07D277/20 , C07D277/26 , C07D277/30 , C07D277/32 , C07D277/34 , C07D277/36 , C07D277/66 , C07D279/06 , C07D285/00 , C07D285/08 , C07D285/125 , C07D285/13 , C07D307/46 , C07D317/26 , C07D319/06 , C07D327/06 , C07D333/22 , C07D333/28 , C07D335/02 , C07D339/06 , C07D405/10 , C07D407/10 , C07D409/10 , C07D413/10 , C07D417/10 , C07D307/42 , C07D261/12 , C07D263/20 , C07D271/08 , C07D333/32
CPC分类号： C07D271/06 , A01N43/08 , A01N43/10 , A01N43/74 , A01N43/80 , C07D261/04 , C07D261/08 , C07D263/14 , C07D263/32 , C07D277/26 , C07D307/46 , C07D333/22
摘要： Heterocyclic substituted benzoyl derivatives of the formula ##STR1## where Z is a 5-membered or 6-membered heterocyclic, saturated or unsaturated radical containing one to three hetero atoms selected from the group consisting of oxygen, sulfur and nitrogen, useful as intermediates for herbicidal compounds.
摘要翻译： Z是下式的杂环取代的苯甲酰基衍生物，其中Z是含有1至3个选自氧，硫和氮的杂原子的5元或6元杂环，饱和或不饱和基团，可用作除草化合物的中间体。

59. 发明授权

US5846907A Herbicidally active pyrazol-4-ylbenzoyl compounds 失效
标题翻译：除草活性吡唑-4-基苯甲酰化合物
公开(公告)号：US5846907A
公开(公告)日：1998-12-08
申请号：US875664
申请日：1997-07-30
申请人： Wolfgang von Deyn , Regina Luise Hill , Uwe Kardorff , Stefan Engel , Martina Otten , Marcus Vossen , Peter Plath , Harald Rang , Albrecht Harreus , Hartmann Konig , Helmut Walter , Karl-Otto Westphalen , Ulf Misslizt
发明人： Wolfgang von Deyn , Regina Luise Hill , Uwe Kardorff , Stefan Engel , Martina Otten , Marcus Vossen , Peter Plath , Harald Rang , Albrecht Harreus , Hartmann Konig , Helmut Walter , Karl-Otto Westphalen , Ulf Misslizt
IPC分类号： C07D231/20 , A01N43/56 , A01N43/74 , A01N43/76 , A01N43/78 , A01N43/80 , C07D231/24 , C07D277/22 , C07D401/10 , C07D403/10 , C07D405/10 , C07D409/10 , C07D411/10 , C07D413/10 , C07D417/10 , C07D261/10 , C07D263/30 , C07D307/38 , C07D521/00
CPC分类号： C07D401/10 , A01N43/56 , A01N43/74 , A01N43/80 , C07D231/24 , C07D403/10 , C07D405/10 , C07D409/10 , C07D411/10 , C07D413/10 , C07D417/10
摘要： Pyrazol-4-ylbenzoyl compounds of the formula I ##STR1## where Z is a 5- or 6-membered heterocyclic saturated or unsaturated radical, Q is a pyrazole ring and L and M are as defined in the specification, their use as herbicidal compounds and to processes for preparing the compounds.
摘要翻译： PCT No.PCT / EP96 / 00635 Sec。 371日期1997年7月30日 102（e）1997年7月30日PCT PCT 1996年2月14日PCT公布。公开号WO96 / 26206 PCT。日期：1996年8月29日式I的吡唑-4-基苯甲酰基化合物其中Z是5-或6-元杂环饱和或不饱和基团，Q是吡唑环，L和M如说明书中所定义，它们作为除草化合物的用途以及制备化合物的方法。

60. 发明授权

US5834402A Isoxazolylbenzoyl derivatives 失效
标题翻译：异恶唑基苯甲酰基衍生物
公开(公告)号：US5834402A
公开(公告)日：1998-11-10
申请号：US894481
申请日：1997-08-22
申请人： Wolfgang Von Deyn , Regina Luise Hill , Uwe Kardorff , Stefan Engel , Martina Otten , Marcus Vossen , Peter Plath , Harald Rang , Albrecht Harreus , Franz Rohl , Helmut Walter , Karl-Otto Westphalen , Ulf Misslitz
发明人： Wolfgang Von Deyn , Regina Luise Hill , Uwe Kardorff , Stefan Engel , Martina Otten , Marcus Vossen , Peter Plath , Harald Rang , Albrecht Harreus , Franz Rohl , Helmut Walter , Karl-Otto Westphalen , Ulf Misslitz
IPC分类号： A01N43/80 , C07D261/08 , C07D413/10 , C07D417/10 , C07D261/06 , C07D275/02
CPC分类号： C07D413/10 , A01N43/80 , C07D261/08 , C07D417/10
摘要： Isoxazol-4-ylbenzoyl derivatives of the formula I ##STR1## where the substituents have the meanings described in the specification; and agriculturally customary salts thereof.
摘要翻译： PCT No.PCT / EP96 / 00592 Sec。 371日期1997年8月22日 102（e）日期1997年8月22日PCT提交1996年2月13日PCT公布。出版物WO96 / 26192 日期：1996年8月29日式I的异恶唑-4-基苯甲酰基衍生物，其中取代基具有说明书中描述的含义; 及其农业惯用盐。

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