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51. 发明申请

US20050113597A1 Method for producing 2-chloromethylphenyl acetic acid derivatives 失效
标题翻译： 2-氯甲基苯基乙酸衍生物的制备方法
公开(公告)号：US20050113597A1
公开(公告)日：2005-05-26
申请号：US10505475
申请日：2003-02-06
申请人： Guido Mayer , Oliver Cullmann , Bernd Wolf , Michael Keil
发明人： Guido Mayer , Oliver Cullmann , Bernd Wolf , Michael Keil
IPC分类号： C07C249/12 , C07B61/00 , C07C251/38 , C07C251/48
CPC分类号： C07C249/12 , C07C251/48
摘要： A process for preparing 2-(chloromethyl)phenylacetic acid derivatives of the formula I, where X is C1-C4-alkoxy or methylamino, by ether cleavage of compounds of the formula II, where R is C1-C4-alkyl, C1-C4-alkoxy, C1-C2-haloalkyl, C1-C4-alkylcarbonyl, C1-C4-alkylcarbonyloxy, halogen, nitro or cyano and X is as defined above comprises carrying out the reaction in the presence of hydrogen chloride and an inert solvent, and adding a catalyst to the reaction mixture selected from the group consisting of iron, indium and halides, oxides and triflates thereof.
摘要翻译：一种制备式I的2-（氯甲基）苯乙酸衍生物的方法，其中X是C 1 -C 4 - 烷氧基或甲基氨基，通过醚式II，其中R是C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，C 1 -C 2 - 卤代烷基，C 1 -C 4 - 烷基羰基，C 1 烷基羰基氧基，卤素，硝基或氰基，X如上定义，包括在氯化氢和惰性溶剂的存在下进行反应，并将催化剂加入到反应混合物选自铁，铟和卤化物，氧化物和三氟甲磺酸盐。

52. 发明授权

US5780665A Preparation of halomethylbenzoyl cyanides 失效
标题翻译：卤甲基苯甲酰氰的制备
公开(公告)号：US5780665A
公开(公告)日：1998-07-14
申请号：US836209
申请日：1997-05-06
申请人： Heinz Isak , Michael Keil , Bernd Wolf , Horst Wingert , Thomas Wettling
发明人： Heinz Isak , Michael Keil , Bernd Wolf , Horst Wingert , Thomas Wettling
IPC分类号： C07B61/00 , C07C253/14 , C07C255/40 , C07C253/30
CPC分类号： C07C253/14
摘要： Halomethylbenzoyl cyanides I PH--CO--CN (I) where Ph is phenyl which is substituted by chloromethyl or bromomethyl and may cary 1-4 other rradicals, are prepared from halomethylbenzoyl chlorides II PH--CO--Cl (II), by reacting II with a cyanide-donating compound in the presence of a Lewis acid, if required in an inert organic solvent or diluent, and then isolating the product. The halomethylbenzoyl cyanides I are important intermediates for synthesizing crop protection agents.
摘要翻译： PCT No.PCT / EP95 / 04463。 371日期：1997年5月6日 102（e）日期1997年5月6日PCT提交1995年11月14日PCT公布。公开号WO96 / 16023 日期：1996年5月30日由甲基苯甲酰氯II PH-CO-Cl（II）制备苯甲酰基苯甲酰氰I PH-CO-CN（I），其中Ph是被氯甲基或溴甲基取代并且可以被1-4个其它取代基取代的苯基，通过在路易斯酸存在下使II与氰化物供体化合物反应，如果需要，在惰性有机溶剂或稀释剂中，然后分离产物。卤代甲基苯甲酰氰I是合成作物保护剂的重要中间体。

53. 发明授权

US5510528A Preparation of halomethylbenzoly cyanides and novel halomethylbenzoyl cyanides 失效
标题翻译：卤代甲基苯并氰化物和新型卤代甲基苯甲酰氰的制备
公开(公告)号：US5510528A
公开(公告)日：1996-04-23
申请号：US406056
申请日：1995-03-17
申请人： Heinz Isak , Thomas Wettling , Michael Keil , Bernd Wolf , Reinhard Doetzer
发明人： Heinz Isak , Thomas Wettling , Michael Keil , Bernd Wolf , Reinhard Doetzer
IPC分类号： C07C253/14 , C07C255/32 , C07C255/40
CPC分类号： C07C255/40 , C07C253/14
摘要： A process for preparing halomethylbenzoyl cyanides IPh-CO-CN I(Ph=phenyl radical substituted by chloromethyl or bromomethyl which, if desired, can additionally carry 1-4 further radicals) by reacting halomethylbenzoyl chlorides IIPh-CO-Cl IIwith an alkali metal cyanide or transition metal cyanide, if appropriate in an organic diluent, and novel halomethylbenzoyl cyanides I' ##STR1## (X=halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, CF.sub.3, C.sub.1 -C.sub.5 -alkyl-(C.sub.1 -C.sub.5 -alkyl)hydroxyimino or C.sub.1 -C.sub.5 -alkyl-(C.sub.2 -C.sub.5 -alkenyl)hydroxyimino; m=0 to 4 and Y=chloromethyl or bromomethyl) are described.The halomethylbenzoyl cyanides I are important intermediates for the synthesis of plant protection agents.
摘要翻译：制备卤代甲基苯甲酰氰的方法I Ph-CO-CN I（Ph =被氯甲基或溴甲基取代的苯基，如果需要，可另外加入1-4个其它基团），卤代甲基苯甲酰氯II Ph-CO-Cl II与碱金属氰化物或过渡金属氰化物（如果合适的话）在有机稀释剂中，和新的卤代甲基苯甲酰氰I'（X =卤素，C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，CF 3，C 1 -C 5 - 烷基 - （C 1 -C 5 - 烷基）羟基亚氨基或C 1 -C 5 - 烷基 - （C 2 -C 5 - 烯基）羟基亚氨基; m = 0至4，Y =氯甲基或溴甲基）。卤代甲基苯甲酰氰I是合成植物保护剂的重要中间体。

54. 发明授权

US5482610A Cathode for coating a substrate 失效
标题翻译：用于涂覆基材的阴极
公开(公告)号：US5482610A
公开(公告)日：1996-01-09
申请号：US20361
申请日：1993-02-22
申请人： Bernd Wolf , Juergen Mueller , Hans Neudert
发明人： Bernd Wolf , Juergen Mueller , Hans Neudert
IPC分类号： C23C14/34 , H01J37/34
CPC分类号： H01J37/3497 , C23C14/3407 , H01J37/3408 , H01J37/3455 , H01J37/3458
摘要： In a cathode system for coating a substrate (46), having a cathode which is connected to a direct-current and/or alternating-current source (high-frequency source) and is disposed in an evacuable coating chamber (2), and is electrically connected to a target (29) which is sputtered and whose sputtered particles deposit themselves on the substrate, a process gas is brought into the coating chamber. The cathode is formed from a substantially pot-like housing (3) whose solid bottom (39) is fixedly joined to the target (29) and whose open end facing away from the target (29) is sealingly held in an opening (49) in the outer wall (30) of the coating chamber such that the interior (49) of the housing (3) is exposed to atmospheric pressure, while the target (29) and the outer surface of the shell-like part of the housing (3) joined thereto are affected by the pressure prevailing in the coating chamber.
摘要翻译：在用于涂覆基板（46）的阴极系统中，具有连接到直流和/或交流电源（高频源）的阴极并设置在可抽真空的涂覆室（2）中，并且是电连接到溅射的靶（29），并且其溅射的颗粒自身沉积在基板上，处理气体被引入涂覆室。阴极由基本上为盆状的外壳（3）形成，其实体底部（39）固定地连接到靶（29），并且其开口端远离靶（29）被密封地保持在开口（49）中，在涂覆室的外壁（30）中，使得壳体（3）的内部（49）暴露于大气压力的同时，靶（29）和壳体的壳状部分的外表面（ 3）受涂层室压力的影响。

55. 发明授权

US5147645A Pyrethroids and their use for controlling pests 失效
标题翻译：吡咯烷酮及其用于控制PESTS的用途
公开(公告)号：US5147645A
公开(公告)日：1992-09-15
申请号：US590690
申请日：1990-10-01
申请人： Bernd Wolf , Hans Theobald , Winfried Zombik , Norbert Goetz , Jochen Wild , Albrecht Harreus , Peter Hofmeister , Christoph Kuenast , Jacobus J. DeKramer
发明人： Bernd Wolf , Hans Theobald , Winfried Zombik , Norbert Goetz , Jochen Wild , Albrecht Harreus , Peter Hofmeister , Christoph Kuenast , Jacobus J. DeKramer
IPC分类号： C07D207/325 , A01N43/36 , A01N53/00 , A01N53/06 , C07C33/20 , C07C33/30 , C07C33/46 , C07C33/50 , C07C69/007 , C07C69/65 , C07C69/734 , C07C69/743 , C07C69/747 , C07C229/18 , C07C255/36 , C07C255/41 , C07D207/32 , C07D207/337
CPC分类号： C07D207/337 , A01N43/36 , A01N53/00 , C07C255/36 , C07C33/20 , C07C33/30
摘要： Benzyl esters of the formula I ##STR1## where R.sup.1 is methyl, ethyl, halogen, methoxy or ethoxy, R.sup.2 is alkyl, alkenyl, cycloalkyl, cycloalkenyl, bicycloalkyl, bicycloalkenyl, C.sub.1 -C.sub.5 -alkyl-substituted cycloalkyl, C.sub.1 -C.sub.5 -substituted cycloalkenyl, C.sub.1 -C.sub.5 -alkyl-substituted bicycloalkyl or C.sub.1 -C.sub.5 -alkyl-substituted bicycloalkenyl, R.sup.3 is hydrogen, cyano, C.sub.2 -C.sub.4 -alkynyl, C.sub.2 -C.sub.4 -alkenyl or C.sub.1 -C.sub.4 -alkyl, A is the carboxylate radical of an acid component typical for pyrethroids and X is hydrogen or halogen, with the proviso that R.sup.2 is not CH.sub.2 --CH.dbd.CH--B when B is hydrogen, alkyl or alkenyl and at the same time R.sup.1 is methyl or halogen, and furthermore with the proviso that R.sup.2 is not methyl when R.sup.1 is methyl, their manufacture, their use for combating pests, and precursors for manufacturing the benzyl esters.
摘要翻译：式I的苄酯（I）其中R1是甲基，乙基，卤素，甲氧基或乙氧基，R2是烷基，烯基，环烷基，环烯基，双环烷基，双环烯基，C1-C5-烷基取代的环烷基，C1- C 5 - 取代的环烯基，C 1 -C 5 - 烷基取代的双环烷基或C 1 -C 5 - 烷基取代的双环烯基，R 3是氢，氰基，C 2 -C 4 - 炔基，C 2 -C 4 - 烯基或C 1 -C 4烷基，A是典型的拟除虫菊酯的酸成分的羧酸酯基，X是氢或卤素，条件是当B是氢，烷基或烯基时，R2不是CH2-CH = CH-B，同时R1是甲基或卤素，以及此外，条件是当R1是甲基时，R2不是甲基，它们的制备，它们用于防治害虫的用途和用于制备苄基酯的前体。

56. 发明授权

US5101061A Novel benzonitriles, benzaldehydes and benzyl alcohols 失效
标题翻译：新型苯并噻唑，苄二醇和苄基醇
公开(公告)号：US5101061A
公开(公告)日：1992-03-31
申请号：US520459
申请日：1990-05-08
申请人： Bernd Wolf , Hans Theobald , Norbert Goetz
发明人： Bernd Wolf , Hans Theobald , Norbert Goetz
IPC分类号： C07C29/136 , C07C25/02 , C07C25/18 , C07C25/22 , C07C25/24 , C07C27/00 , C07C29/16 , C07C33/20 , C07C33/22 , C07C33/30 , C07C33/34 , C07C33/46 , C07C33/50 , C07C35/21 , C07C35/50 , C07C45/00 , C07C45/44 , C07C47/542 , C07C47/546 , C07C47/548 , C07C47/55 , C07C67/00 , C07C255/50
CPC分类号： C07C33/34 , C07C25/02 , C07C25/18 , C07C25/22 , C07C25/24 , C07C255/50 , C07C33/20 , C07C33/30 , C07C33/46 , C07C33/50 , C07C45/44 , C07C47/542 , C07C47/546 , C07C47/548 , C07C47/55 , C07C2101/02 , C07C2101/08 , C07C2101/10 , C07C2101/14 , C07C2101/16 , C07C2101/18 , C07C2102/42
摘要： Novel benzonitriles, benzaldehydes and benzyl alcohols of the formula I ##STR1## where R.sup.1 is methyl or ethyl, R.sup.2 is alkyl, alkenyl, cycloalkyl, cycloalkenyl, bicycloalkyl, bicycloalkenyl, or C.sub.1 -C.sub.5 -alkyl-substituted cycloalkyl, cycloalkenyl, bicycloalkyl or bicycloalkenyl, X is hydrogen, chlorine or fluorine and Z is --CN, CHO or ##STR2## where R.sup.3 is hydrogen, cyano, C.sub.2 -C.sub.4 -alkynyl, C.sub.2 -C.sub.4 -alkenyl or C.sub.1 -C.sub.4 -alkyl, with the proviso that R.sup.2 is not --CH.sub.2 -CH.dbd.CH--B when B is hydrogen, alkyl or alkenyl and at the same time R.sup.1 is methyl and Z is ##STR3## and with the proviso that R.sup.2 is not methyl or ethyl when R.sup.1 is methyl and at the same time Z is ##STR4## and further more with the proviso that R.sup.2 is not methyl when R.sup.1 is methyl or ethyl and at the same time Z is --CN or --CHO.

57. 发明授权

US5066673A Substituted benzyl 2-phenyl-1-alk(en)ylcyclopropane-carboxylates and the use thereof for controlling pests 失效
标题翻译：取代苄基2-苯乙烯-1-碱（EN）YLCYCLOPROPANE-CARBOXYLATES及其用于控制PESTS的用途
公开(公告)号：US5066673A
公开(公告)日：1991-11-19
申请号：US482890
申请日：1990-02-22
申请人： Winfried Zombik , Hans Theobald , Bernd Wolf , Ludwig Schuster , Peter Hofmeister , Christoph Kuenast
发明人： Winfried Zombik , Hans Theobald , Bernd Wolf , Ludwig Schuster , Peter Hofmeister , Christoph Kuenast
IPC分类号： C07C69/743 , A01N53/00 , A01N53/06 , C07C67/00 , C07C69/753 , C07C255/39
CPC分类号： A01N53/00
摘要： Substituted benzyl 2-phenylalk(en)-1-ylcyclopropanecarboxylates of the general formula I ##STR1## where R.sup.1 is halogen or in each case low molecular weight, alkyl, alkoxy, haloalkyl or haloalkoxy (n=1 to 5),R.sup.2 is halogen or, in each case low molecular weight, alkyl or haloalkyl,R.sup.3, R.sup.4 are halogen or each is an electron in a double bond formed by them together,R.sup.5 is hydrogen or, in each case low molecular weight, alkyl, alkenyl, alkynyl or cyano,R.sup.6 is halogen or alkyl (n=1 to 4),R.sup.7 is halogen (p=0 to 25),and their use for combating pests.
摘要翻译：烷基，烷氧基，卤代烷基或卤代烷氧基（n = 1-5），其中R 1是卤素，或者在各种情况下都是低分子量的取代的通式I（I）的2-苯基（en）-1-基环丙烷羧酸苄酯， R 2是卤素，或者在各种情况下都是低分子量的烷基或卤代烷基，R 3，R 4是卤素，或者各自是由它们一起形成的双键中的电子，R 5是氢或在各种情况下都是低分子量的烷基，烯基，炔基或氰基，R6是卤素或烷基（n = 1-4），R7是卤素（p = 0-25））及其用于防治害虫的用途。

58. 发明授权

US4810346A Magnetron type sputtering cathode 失效
标题翻译：磁控溅射阴极
公开(公告)号：US4810346A
公开(公告)日：1989-03-07
申请号：US111207
申请日：1987-10-21
申请人： Bernd Wolf , Peter Wirz
发明人： Bernd Wolf , Peter Wirz
IPC分类号： H01J37/34 , C23C14/34
CPC分类号： H01J37/3405
摘要： Sputtering cathode (1) according to the magnetron principle, having a target (11) of the material to be sputtered, which consists of at least one piece. Behind the target (11) there is a magnet system with a plurality of endless magnet units (14, 15, 16) of alternately different polarity, one inside the other. An endless magnetic tunnel (20) of arcuately curved lines of force is thereby formed. Those poles of the magnet units (14, 15, 16) which are turned away from the target (11) are connected together through a magnet yoke (19) of soft magnetic material. To achieve an especially good target utilization, the geometry and the amount of the magnetic field forming a magnetic tunnel (20) are variable relative to the magnetic field strength of another magnetic field through an electromagnetic (17), the current for the electromagnet (17) being variable in frequency, amplitude and pulse shape.
摘要翻译：溅射阴极（1）根据磁控管原理，具有由至少一块构成的要溅射的材料的靶（11）。在目标（11）的后方，存在具有交替不同极性的多个无限磁体单元（14,15,16）的磁体系统，一个在另一个内部。由此形成弓形弯曲线的无尽磁通（20）。离开靶（11）转动的磁体单元（14,15,16）的极通过软磁材料的磁轭（19）连接在一起。为了实现特别好的目标利用，形成磁通道（20）的磁场的几何形状和量相对于通过电磁（17）的另一磁场的磁场强度是可变的，电磁体（17）的电流）在频率，幅度和脉冲形状上是可变的。

59. 发明授权

US08586750B2 Method for the production of halogen-substituted 2-(aminomethylidene)-3-oxobutyric acid esters 有权
标题翻译：卤素取代的2-（氨基亚甲基）-3-氧代丁酸酯的制备方法
公开(公告)号：US08586750B2
公开(公告)日：2013-11-19
申请号：US12990364
申请日：2009-04-30
申请人： Thomas Zierke , Volker Maywald , Michael Rack , Sebastian Peer Smidt , Michael Keil , Bernd Wolf , Christopher Koradin
发明人： Thomas Zierke , Volker Maywald , Michael Rack , Sebastian Peer Smidt , Michael Keil , Bernd Wolf , Christopher Koradin
IPC分类号： C07D295/145 , C07D211/34 , C07D265/30
CPC分类号： C07D295/145 , C07D231/14
摘要： The present invention relates to a process for preparing 2-(aminomethylidene)-4,4-dihalo-3-oxobutyric esters of the formula (I), wherein R1, R2, R3 are C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C3-C10-cycloalkyl or benzyl, and/or R2 together with R3 and the nitrogen atom to which the two radicals are attached are a heterocyclic radical, in which a corresponding 3-aminoacrylic ester is reacted with a halogen-substituted acetyl fluoride in the presence of at least one alkali or alkaline earth metal fluoride; and the further conversion of halogen-substituted 2-(aminomethylidene)-3-oxobutyric esters of the formula (I) to halomethyl-substituted pyrazol-4-ylcarboxylic acids and their esters.
摘要翻译：本发明涉及制备式（I）的2-（氨基亚甲基）-4,4-二卤代-3-氧代丁酸酯的方法，其中R1，R2，R3是C1-C6-烷基，C1-C6-卤代烷基，C 2 -C 6 - 烯基，C 3 -C 10 - 环烷基或苄基，和/或R 2与R 3和两个基团所连接的氮原子是杂环基团，其中相应的3-氨基丙烯酸酯与卤素取代的乙酰氟在至少一种碱金属或碱土金属氟化物的存在下; 以及将式（I）的卤素取代的2-（氨基亚甲基）-3-氧代丁酸酯进一步转化为卤代甲基取代的吡唑-4-基羧酸及其酯。

60. 发明授权

US08357695B2 Hydrates of 2-chloro-5-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1-(2H)-pyrimidinyl]-4-fluoro-N-[[methyl(1-methylethyl)amino]sulfonyl]benzamide 有权
标题翻译： 2-氯-5- [3,6-二氢-3-甲基-2,6-二氧代-4-（三氟甲基）-1-（2H） - 嘧啶基] -4-氟-N - [[甲基（ 1-甲基乙基）氨基]磺酰基]苯甲酰胺
公开(公告)号：US08357695B2
公开(公告)日：2013-01-22
申请号：US12444651
申请日：2007-10-12
申请人： Thomas Schmidt , Joachim Gebhardt , Sandra Löhr , Michael Keil , Jan Hendrik Wevers , Peter Erk , Heidi Emilia Saxell , Gerhard Hamprecht , Guido Mayer , Bernd Wolf , Gerhard Cox , Alfred Michel , Werner Seitz , Cyrill Zagar , Robert Reinhard , Bernd Sievernich
发明人： Thomas Schmidt , Joachim Gebhardt , Sandra Löhr , Michael Keil , Jan Hendrik Wevers , Peter Erk , Heidi Emilia Saxell , Gerhard Hamprecht , Guido Mayer , Bernd Wolf , Gerhard Cox , Alfred Michel , Werner Seitz , Cyrill Zagar , Robert Reinhard , Bernd Sievernich
IPC分类号： A01N43/54 , A61K31/505
CPC分类号： C07D239/54 , A01N43/54
摘要： The present invention relates to hydrates of 2-chloro-5-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1-(2H)pyrimidinyl]-4-fluoro-N-[[methyl(1-methylethyl)amino]-sulfonyl]benzamide. The invention also relates to a process for the preparation of these hydrates and to plant protection formulations which comprise hydrates of the phenyluracil I.
摘要翻译：本发明涉及2-氯-5- [3,6-二氢-3-甲基-2,6-二氧代-4-（三氟甲基）-1-（2H）嘧啶基] -4-氟-N- [[甲基（1-甲基乙基）氨基] - 磺酰基]苯甲酰胺。本发明还涉及制备这些水合物的方法以及包含苯基尿嘧啶I的水合物的植物保护制剂。

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