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41. 发明申请

US20110223406A1 Impact Resistant LLDPE Composition and Films Made Thereof 有权
公开(公告)号：US20110223406A1
公开(公告)日：2011-09-15
申请号：US13119655
申请日：2009-09-22
申请人： Fabiana Fantinel , Gerd Mannebach , Shahram Mihan , Gerhardus Meier , Iakovos Vittorias
发明人： Fabiana Fantinel , Gerd Mannebach , Shahram Mihan , Gerhardus Meier , Iakovos Vittorias
IPC分类号： B32B3/00 , C08F210/14 , C08F4/72 , C08L23/20 , C08F4/80 , B01J31/12
CPC分类号： C08J5/18 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F10/00 , C08F210/16 , C08J2323/06 , C08F4/61904 , C08F210/14 , C08F2500/08 , C08F2500/05 , C08F2500/12 , C08F2500/10 , C08F2500/19 , C08F2500/20 , C08F2500/17 , C08F2500/26 , C08F4/7042
摘要： A novel PE material is devised showing excellent mechanical/optical properties and process ability, e.g. for film extrusion. The polyethylene of the invention is produced in one single e.g. gas phase reactor.

42. 发明授权

US08017706B2 Process for production of polymers with iron complex catalyst 有权
标题翻译：用铁络合物催化剂生产聚合物的方法
公开(公告)号：US08017706B2
公开(公告)日：2011-09-13
申请号：US12921652
申请日：2008-03-10
申请人： Hidetomo Kai , Akane Sasamoto , Hitoshi Hayakawa
发明人： Hidetomo Kai , Akane Sasamoto , Hitoshi Hayakawa
IPC分类号： C08F4/70 , C08F4/80 , C07F15/02
CPC分类号： C07F15/025 , B01J31/1805 , B01J2231/122 , B01J2531/0238 , B01J2531/842 , C07D255/02 , C08F10/00 , C08F12/08 , C08F293/005
摘要： The present invention relates to a novel iron complex having a cyclic amine compound as a ligand and a method for producing polymers by polymerizing a radical polymerizable monomer in the presence of the iron complex and a radical generator. The problem for the present invention is providing a method capable of producing a polymer or block copolymer having a chemically convertible functional group at the end from a radical polymerizable monomer and providing a method for recovering the iron complex in a solvent with a high recovery rate after the polymerization reaction. This problem is solved by providing a novel iron complex, a method for producing a polymer in the presence of a radical polymerization initiator that uses the iron complex as a polymerization catalyst and a method for simply and easily recovering the iron complex. The present invention can provide an iron complex useful for the method for producing a polymer by polymerizing a radical polymerizable monomer and a method for producing the polymer using that iron complex.
摘要翻译：本发明涉及一种具有环胺化合物作为配体的新型铁络合物和通过在铁络合物和自由基发生剂的存在下使可自由基聚合的单体聚合制备聚合物的方法。本发明的问题在于提供一种能够从可自由基聚合的单体制造具有化学上可转换的官能团的聚合物或嵌段共聚物的方法，并提供一种在溶剂中回收铁络合物的方法，其中回收率高聚合反应。通过提供新的铁络合物，在使用铁络合物作为聚合催化剂的自由基聚合引发剂的存在下制备聚合物的方法以及简单且容易地回收铁络合物的方法来解决该问题。本发明可以提供一种可用于聚合自由基聚合性单体的聚合物的制造方法的铁络合物和使用该铁络合物的聚合物的制造方法。

43. 发明授权

US08017541B2 Catalyst components based on ferrocenyl complexes used for olefin polymerisation 失效
标题翻译：基于用于烯烃聚合的二茂铁基络合物的催化剂组分
公开(公告)号：US08017541B2
公开(公告)日：2011-09-13
申请号：US12295464
申请日：2007-03-27
申请人： Cyril Revault , Olivier Lavastre , Sabine Sirol
发明人： Cyril Revault , Olivier Lavastre , Sabine Sirol
IPC分类号： B01J31/22 , C08F4/80
CPC分类号： C07F17/02 , C08F4/61912 , C08F4/61925 , C08F10/00 , C08F10/06 , C08F110/06 , C08F2410/03 , C08F4/613 , C08F4/69 , C08F4/61904
摘要： The present invention discloses catalyst components based on ferrocenyl ligands, their method of preparation and their use in the polymerization of olefins.
摘要翻译：本发明公开了基于二茂铁基配体的催化剂组分及其制备方法及其在烯烃聚合中的应用。

44. 发明授权

US07964680B2 Method for polymerizing cyclic olefin having polar functional group, olefin polymer produced thereby, optical anisotropic film comprising the same, and catalyst composition for polymerizing the cyclic olefin 有权
标题翻译：用于聚合具有极性官能团的环烯烃的方法，由此制备的烯烃聚合物，包含该烯烃聚合物的光学各向异性膜和用于使环烯烃聚合的催化剂组合物
公开(公告)号：US07964680B2
公开(公告)日：2011-06-21
申请号：US12308399
申请日：2007-06-15
申请人： Dai-Seung Choi , Young-Whan Park , Sung-Ho Chun , Sung Cheol Yoon , Young-Chul Won
发明人： Dai-Seung Choi , Young-Whan Park , Sung-Ho Chun , Sung Cheol Yoon , Young-Chul Won
IPC分类号： C08F4/70 , C08F4/80 , C08F132/04
CPC分类号： C08F32/00
摘要： Disclosed is a method of producing a cyclic olefin polymer having a polar functional group, an olefin polymer produced by using the method, an optical anisotropic film including the olefin polymer, and a catalyst composition for producing the cyclic olefin polymer. In the olefin polymerization method and the catalyst composition for polymerization, since deactivation of the catalyst due to polar functional groups of monomers is capable of being suppressed, it is possible to produce polyolefins having a high molecular weight at high polymerization yield during polyolefin polymerization. Furthermore, the cyclic olefin having the polar functional groups has excellent polymerization reactivity and the activity of the catalyst composition including the same is maintained under a variable polymerization condition. Accordingly, the present invention is very useful for a mass-production process.
摘要翻译：公开了一种制备具有极性官能团的环烯烃聚合物，使用该方法制备的烯烃聚合物，包含烯烃聚合物的光学各向异性膜和用于制备环烯烃聚合物的催化剂组合物的方法。在烯烃聚合方法和聚合用催化剂组合物中，由于能够抑制由于单体的极性官能团导致的催化剂的失活，因此可以在聚烯烃聚合期间以高聚合率产生高分子量聚烯烃。此外，具有极性官能团的环状烯烃具有优异的聚合反应性，并且包含其的催化剂组合物的活性在可变的聚合条件下保持。因此，本发明对于批量生产方法是非常有用的。

45. 发明申请

US20110015336A1 Curable Silicone Compositions 审中-公开
标题翻译：可固化硅酮组合物
公开(公告)号：US20110015336A1
公开(公告)日：2011-01-20
申请号：US12835871
申请日：2010-07-14
申请人： Andreas Koellnberger
发明人： Andreas Koellnberger
IPC分类号： C08L43/04 , C08F4/80
CPC分类号： C08L83/04 , C08G77/12 , C08G77/20 , C08K5/05 , C08K5/14 , C08K5/5425 , C08L2205/02 , C08L2205/03 , C09D183/04 , C09K3/1018 , C08L83/00
摘要： The present invention relates to silicone compositions which can be crosslinked thermally by hydrosilylation, processes for producing them and also the use of the crosslinkable compositions.
摘要翻译：本发明涉及可通过氢化硅烷化热交联的硅氧烷组合物，其制备方法以及可交联组合物的用途。

46. 发明申请

US20100234546A1 DIENE POLYMER AND PRODUCTION PROCESS THEREOF 失效
标题翻译：二烯聚合物及其生产方法
公开(公告)号：US20100234546A1
公开(公告)日：2010-09-16
申请号：US12787553
申请日：2010-05-26
申请人： Kohtaro OSAKADA , Daisuke TAKEUCHI , Yusuke FUKUDA , Osamu IHATA , Hiroshi KURIBAYASHI
发明人： Kohtaro OSAKADA , Daisuke TAKEUCHI , Yusuke FUKUDA , Osamu IHATA , Hiroshi KURIBAYASHI
IPC分类号： C08F4/80
CPC分类号： C08F36/20 , C08F4/7098
摘要： A polymer comprising a unit represented by the following formula (1); and a process for producing the polymer comprising the step of polymerizing a diene compound such as 9,9-diallylfluorene in the presence of a polymerization catalyst formed by contacting a nickel compound with an organoaluminum compound and/or a boron compound:
摘要翻译：包含由下式（1）表示的单元的聚合物; 以及一种制备聚合物的方法，包括在通过使镍化合物与有机铝化合物和/或硼化合物接触而形成的聚合催化剂的存在下聚合二烯化合物如9,9-二烯丙基芴的步骤：

47. 发明申请

US20100113719A1 OLEFIN METATHESIS PROCESS EMPLOYING BIMETALLIC RUTHENIUM COMPLEX WITH BRIDGING HYDRIDO LIGANDS 失效
标题翻译：使用具有桥梁配置的双金属复合材料的OLEFIN METATHESIS工艺
公开(公告)号：US20100113719A1
公开(公告)日：2010-05-06
申请号：US12606532
申请日：2009-10-27
申请人： Jasson T. Patton , Francis J. Timmers
发明人： Jasson T. Patton , Francis J. Timmers
IPC分类号： C08F4/52 , C07C2/00 , C08F4/80 , B01J31/12 , C07C69/347
CPC分类号： B01J31/2295 , B01J31/121 , B01J31/122 , B01J31/1845 , B01J31/24 , B01J2231/543 , B01J2531/0208 , B01J2531/821 , C07F15/0046 , C07F17/02 , C08G61/08 , C08G2261/3322 , C08G2261/3323 , C08G2261/418
摘要： An olefin metathesis process for converting a reactant olefin or a mixture of reactant olefins into one or more product olefins that are different from the reactant olefin(s). The process employs a catalyst system containing a carbene-generating agent and a bimetallic ruthenium complex comprising one or more μ-hydrido bridging ligands, and optionally containing di(t-butyl)phosphine. The catalyst system is advantageously active at process temperatures greater than 90° C. Cyclization metathesis and ring-opening polymerization metathesis are preferred olefin metathesis processes.
摘要翻译：用于将反应物烯烃或反应物烯烃的混合物转化成不同于反应物烯烃的一种或多种产物烯烃的烯烃复分解方法。该方法采用含有卡宾产生剂和双金属钌配合物的催化剂体系，所述双金属钌配合物包含一个或多个μ-氢化桥连配体，并且任选地含有二（叔丁基）膦。催化剂体系有利于在大于90℃的工艺温度下活化。环化复分解和开环聚合复分解是优选的烯烃复分解方法。

48. 发明授权

US07683148B2 Metathesis-curable composition with a reaction control agent 有权
标题翻译：具有反应控制剂的易位固化组合物
公开(公告)号：US07683148B2
公开(公告)日：2010-03-23
申请号：US11428105
申请日：2006-06-30
申请人： Christos Angeletakis
发明人： Christos Angeletakis
IPC分类号： C08F4/80
CPC分类号： A61K6/10 , B01J31/2265 , B01J31/2273 , B01J2231/122 , B01J2231/54 , B01J2531/821 , B01J2531/825 , C08G61/08 , C08G77/20
摘要： A composition curable by a metathesis reaction upon mixing its components and comprising an olefin-containing substrate, a metathesis catalyst, and a reaction control agent for slowing the progress of the metathesis reaction. The metathesis catalyst is a ruthenium or osmium carbene complex catalyst having high activity and good air stability. In one embodiment, the catalyst is free of phosphine ligands. The reaction control agent is an organic compound that contains carbon-carbon double and/or triple bonds and one or more Group 14 atoms and is present in an amount effective to slow the progress of the metathesis reaction. In one embodiment, the olefin-containing substrate may comprise one or more oligomers or polymers having a >20 wt. % linear siloxane (Si—O—Si) backbone tethered and/or end-capped with functional olefin groups, such as cycloalkenyl group.
摘要翻译：通过复分解反应混合其组分可固化的组合物，其包含含烯烃的底物，复分解催化剂和用于减缓复分解反应进程的反应控制剂。复分解催化剂是具有高活性和良好的空气稳定性的钌或咔啉络合物催化剂。在一个实施方案中，催化剂不含膦配体。反应控制剂是含有碳 - 碳双键和/或三键和一个或多个第14族原子并且以有效减缓复分解反应进程的量存在的有机化合物。在一个实施方案中，含烯烃的底物可以包含一种或多种低聚物或具有> 20wt。用线性硅氧烷（Si-O-Si）骨架连接和/或用功能烯烃基团例如环烯基封端的（或）封端的直链硅氧烷（Si-O-Si）骨架。

49. 发明申请

US20100029874A1 PROCESS FOR PRODUCTION OF HYDROGENATED POLYMERS AND HYDROGENATED POLYMERS 有权
标题翻译：生产氢化聚合物和加氢聚合物的方法
公开(公告)号：US20100029874A1
公开(公告)日：2010-02-04
申请号：US12442305
申请日：2007-09-20
申请人： Hideharu Iwasaki , Yasutaka Inubushi
发明人： Hideharu Iwasaki , Yasutaka Inubushi
IPC分类号： C08F4/80
CPC分类号： C08G61/08
摘要： Provision of, in a process of producing a hydrogenated polymer, which comprises steps of sequentially performing, in the presence of a ruthenium carbene complex, a ring-opening metathesis polymerization reaction of a cyclic olefin and a hydrogenation reaction of a ring-opening metathesis polymer produced by the polymerization reaction to give a hydrogenated polymer, a simple and economic process of obtaining a hydrogenated polymer having an extremely small content of residual ruthenium derived from the ruthenium carbene complex.A process of producing a hydrogenated polymer, which comprises, in the presence of a ruthenium carbene complex, subjecting a cyclic monoolefin and/or a cyclic diolefin to a ring-opening metathesis polymerization, hydrogenating the resulting ring-opening metathesis polymer to give a hydrogenated polymer, and bringing the hydrogenated polymer in contact with a poor solvent of the hydrogenated polymer in the presence of dissolved hydrogen to allow precipitation. As the poor solvent of the hydrogenated polymer, alcohol having 1 to 6 carbon atoms, ketone having 3 to 6 carbon atoms and the like are preferable.
摘要翻译：在生产氢化聚合物的方法中提供了包括以下步骤：在钌卡宾络合物的存在下，环烯烃的开环易位聚合反应和开环易位聚合物的氢化反应通过聚合反应生成氢化聚合物，获得氢化聚合物的简单且经济的方法，该氢化聚合物的钌卡宾络合物的残余钌含量极少。一种制备氢化聚合物的方法，其包括在钌卡宾络合物的存在下，使环状单烯烃和/或环状二烯烃进行开环易位聚合，将所得开环易位聚合物氢化，得到氢化聚合物，并使氢化聚合物与氢化聚合物的不良溶剂在溶解的氢气存在下接触以允许沉淀。作为氢化聚合物的不良溶剂，优选具有1〜6个碳原子的醇，具有3〜6个碳原子的酮等。

50. 发明申请

US20090306319A1 Highly Organized Polyolefin Structures 失效
标题翻译：高度组织的聚烯烃结构
公开(公告)号：US20090306319A1
公开(公告)日：2009-12-10
申请号：US12298584
申请日：2007-04-23
申请人： Kenneth Boone Wagener , Travis W. Baughman
发明人： Kenneth Boone Wagener , Travis W. Baughman
IPC分类号： C08F4/80 , C08F20/28
CPC分类号： C08F210/02 , C08F220/06 , Y10S525/919 , C08F220/10
摘要： A method of preparing periodic, semi-periodic, or semi-random polyethylene-co-acrylic acid or polyethylene-co-methacrylic acid involves polymerizing 1-alkoxyalkyl ester substituted α,Ω-dienes, and/or 1-alkoxyalkyl ester substituted cycloalkenes via olefin metathesis reactions followed by hydrogenation of the alkylene units and subsequently hydrolyzed to the desired polyethylene-co-acrylic acid or polyethylene-co-methacrylic acid. The polyethylene-co-acrylic acid or polyethylene-co-methacrylic acid can then be converted to ionomers by exchange with a monomeric carboxylate salt.
摘要翻译：制备周期，半周期或半随机聚乙烯 - 共 - 丙烯酸或聚乙烯 - 共 - 甲基丙烯酸的方法包括通过以下方法聚合1-烷氧基烷基酯取代的α，ω-二烯和/或1-烷氧基烷基酯取代的环烯烃烯烃复分解反应，然后氢化亚烷基单元，随后水解成所需的聚乙烯 - 共 - 丙烯酸或聚乙烯 - 共 - 甲基丙烯酸。聚乙烯 - 共 - 丙烯酸或聚乙烯 - 共 - 甲基丙烯酸可以通过与单体羧酸盐交换而转化为离聚物。

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