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41. 发明授权

US4599465A Process for producing orthoalkylphenols 失效
标题翻译：生产正烷基苯酚的方法
公开(公告)号：US4599465A
公开(公告)日：1986-07-08
申请号：US741361
申请日：1985-06-05
申请人： Akio Tamaru , Yoshiaki Izumisawa , Hidekichi Hashimoto , Kiyoji Kuma , Takashi Komaya , Masanobu Minagawa
发明人： Akio Tamaru , Yoshiaki Izumisawa , Hidekichi Hashimoto , Kiyoji Kuma , Takashi Komaya , Masanobu Minagawa
IPC分类号： B01J21/00 , B01J21/04 , C07B61/00 , C07C27/00 , C07C37/14 , C07C37/74 , C07C39/06 , C07C67/00
CPC分类号： C07C37/14 , C07C37/74 , Y02P20/582
摘要： A process for producing an orthoalkylphenol which comprises reacting phenol with an olefin in a liquid phase in the presence of an alumina catalyst, characterized in that the water content in the liquid phase of the reaction system is maintained at a level of not higher than 250 ppm.
摘要翻译：一种生产邻苯基苯酚的方法，其包括在氧化铝催化剂存在下使液相中的苯酚与烯烃反应，其特征在于反应体系的液相中的水含量保持在不高于250ppm 。

42. 发明授权

US4594460A Process for selective C-alkylation of phenols 失效
标题翻译：苯酚选择性C烷基化方法
公开(公告)号：US4594460A
公开(公告)日：1986-06-10
申请号：US713691
申请日：1985-03-19
申请人： Gerard Mignani , Didier Morel
发明人： Gerard Mignani , Didier Morel
IPC分类号： C07C39/06 , B01J31/00 , C07B37/02 , C07B61/00 , C07C27/00 , C07C37/14 , C07C39/08 , C07C39/19 , C07C39/225 , C07C39/24 , C07C41/00 , C07C41/30 , C07C43/23 , C07C43/315 , C07C45/00 , C07C47/27 , C07C47/565 , C07C49/835 , C07C67/00 , C07C69/013 , C07C69/732 , C07C69/84 , C07C69/92 , C07C201/00 , C07C205/22 , C07C213/08 , C07C215/76 , C07C253/00 , C07C255/36
CPC分类号： C07C67/343 , C07C213/08 , C07C37/14 , C07C41/30
摘要： Substituted phenols of formula ##STR1## in which R.sub.1 is in an ortho or para position relative to the phenol function and denotes ##STR2## R.sub.2 denotes an acyclic radical optionally substituted by alkyl, hydroxy, alkoxycarbonyl, cyano or formyl, or a phenyl or naphthyl radical, and R denotes hydrogen or 1 to 4 substituents chosen from halogen, OH optionally in the form of ether or ester, alkyl, NO.sub.2, CHO optionally in the form of acetal, CH.sub.3 CO--, C.sub.6 H.sub.5 CO--, NH.sub.2, alkylamino, dialkylamino or alkoxycarbonyl, it being understood that 2 symbols R may form with the phenyl nucleus a condensed aromatic ring, which comprises reacting a butadiene of formula ##STR3## with a phenol for formula ##STR4## in water in the presence of a rhodium-based catalyst, a water-soluble phosphine and optionally an inorganic or organic base. The products of formula (I) are intermediates for the synthesis of vitamin E, antioxidants, perfumes or insecticides.
摘要翻译：其中R 1相对于苯酚官能团为邻位或对位的式（I）的取代酚，表示任选被烷基，羟基，烷氧基羰基，氰基或甲酰基取代的无环基，或苯基或萘基，R表示氢或1至4个选自卤素，任选以醚或酯形式的OH的取代基，烷基，NO 2，CHO，任选以缩醛，CH 3 CO-，C 6 H 5 CO-，NH 2，烷基氨基，二烷基氨基或烷氧基羰基，应理解为可以与苯基一起形成2个符号R的稠合芳香环，其包括在式（III）中的水中使式（VIII）的二醇与式存在铑基催化剂，水溶性膦和任选的无机或有机碱。式（I）的产物是用于合成维生素E，抗氧化剂，香料或杀虫剂的中间体。

43. 发明授权

US4568778A Process for producing tert-amylphenols 失效
标题翻译：叔戊基苯酚的制备方法
公开(公告)号：US4568778A
公开(公告)日：1986-02-04
申请号：US699130
申请日：1985-02-07
申请人： Makoto Imanari , Hiroshi Iwane , Takahiro Sugawara , Tadashi Ayusawa , Tadamichi Aoki
发明人： Makoto Imanari , Hiroshi Iwane , Takahiro Sugawara , Tadashi Ayusawa , Tadamichi Aoki
IPC分类号： B01J21/00 , B01J29/00 , B01J31/00 , C07B61/00 , C07C27/00 , C07C37/14 , C07C39/06 , C07C67/00
CPC分类号： C07C37/14
摘要： A process for producing tert-amylphenols is described, comprising reacting isoamylene with phenols in the presence of an inorganic solid acid catalyst or an acidic ion exchange resin catalyst. This process permits efficient production of tert-amylphenols, i.e., 2,4-di-tert-amylphenol and p-tert-amylphenol. These tert-amylphenols are useful as starting materials for preparation of color formers for color photography, additives for resins, oil-soluble dyes, additives for lubricating oils, etc.
摘要翻译：描述了生产叔戊基酚的方法，包括在无机固体酸催化剂或酸性离子交换树脂催化剂存在下使异戊烯与酚反应。该方法可有效生产叔戊基苯酚，即2,4-二叔戊基苯酚和对叔戊基苯酚。这些叔戊基酚可用作制备用于彩色摄影的成色剂，树脂添加剂，油溶性染料，润滑油添加剂等的起始原料。

44. 发明授权

US4510337A Process for production of 1,1-dimethyl-6-hydroxyindans 失效
标题翻译：生产1,1-二甲基-6-羟基茚满的方法
公开(公告)号：US4510337A
公开(公告)日：1985-04-09
申请号：US575593
申请日：1984-01-31
申请人： Raymond L. Cobb
发明人： Raymond L. Cobb
IPC分类号： C07C37/14 , C07C39/14 , C07C39/12
CPC分类号： C07C37/14 , C07C37/74 , C07C37/86 , C07C2102/08
摘要： In the production of 1,1-dimethyl-6-hydroxyindans through the reaction of phenols with isoprene or 2,3-dimethyl-1,3-butadiene in the presence of phosphoric acid, an improvement is comprised of using a phosphoric acid concentration of about 100% instead of 85% or less and also of the distillation of the product mixture from a solution containing phosphoric acid of about 95% concentration.
摘要翻译：在通过酚与异戊二烯或2,3-二甲基-1,3-丁二烯在磷酸存在下的反应生产1,1-二甲基-6-羟基茚满时，改进之处在于使用磷酸浓度约100％而不是85％或更少，以及从含有约95％浓度的磷酸的溶液中蒸馏产物混合物。

45. 发明授权

US4423254A Superacid catalyzed preparation of resorcinol from meta-isopropylphenol 失效
标题翻译：超临界催化从间 - 异丙基苯酚制备间苯二酚
公开(公告)号：US4423254A
公开(公告)日：1983-12-27
申请号：US383941
申请日：1982-06-01
申请人： George A. Olah
发明人： George A. Olah
IPC分类号： C07C37/00 , C07C37/055 , C07C37/08 , C07C37/14 , C07C37/16 , C07C37/18 , C07C37/48 , C07C39/06
CPC分类号： C07C37/08 , C07C37/055 , C07C37/0555 , C07C37/14 , C07C37/16 , C07C37/18 , C07C37/48
摘要： Resorcinol is prepared by an improved process through superacid (such as perfluorinated alkanesulfonic superacids of one to eighteen carbon atoms or polymeric perfluorinated resinsulfonic acids, such as Nafion-H catalyzed cleavage-rearrangement reaction of meta-isopropylphenol hydroperoxide in the form of its protected ether or ester derivatives, including readily cleavable and reusable trimethylsilyl and trifluoromethanesulfonyl derivates. Part of the process is the preparation of needed meta-isopropylphenol in high purity free of other isomers by treating any mixture of isopropylphenol isomers in an excess of anhydrous hydrogen fluoride or a perfluorinated alkanesulfonic superacid of one to eighteen carbon atoms and a Lewis acid fluoride or by alkylating (transalkylating) phenol with a propyl alkylating agent in the presence of the aforementioned superacid systems.
摘要翻译：间苯二酚通过超强酸（例如1至18个碳原子的全氟化烷烃磺酸超强酸或聚合全氟磺酸磺酸）的改进方法制备，例如Nafion-H催化的经受保护的醚形式的间异丙基苯酚氢过氧化物的裂解重排反应，或酯衍生物，包括易裂解和可重复使用的三甲基甲硅烷基和三氟甲磺酰基衍生物。该方法的一部分是通过将过量无水氟化氢或全氟化烷烃磺酸的异丙基苯酚异构体的任何混合物处理，制备所需的高纯度的不含异构体的间异丙基苯酚通过在上述超酸体系的存在下，使用丙烷基化剂将烷基化（烷基转移）苯酚与1至18个碳原子的超酸和路易斯酸氟化物反应。

46. 发明授权

US4414161A Process for producing low temperature stable tert-butylphenyl diphenyl phosphate 失效
标题翻译：生产低温稳定性叔丁基苯基二苯基磷酸酯的方法
公开(公告)号：US4414161A
公开(公告)日：1983-11-08
申请号：US279389
申请日：1981-07-01
申请人： Silvio L. Giolito
发明人： Silvio L. Giolito
IPC分类号： C07C37/14 , C07C37/48 , C07F9/12 , C07F9/09
CPC分类号： C07F9/12 , C07C37/00 , C07C37/14
摘要： A process for producing tert-butylphenyl diphenyl phosphate which is stable at low temperature by a process wherein phenol is butylated to produce tert-butylphenol which is isomerized to produce mixed meta and para isomers thereof, and which thereafter is alkylated with isobutylene to produce tert-butylphenol having a C.sub.4 /.phi. ratio of about 0.62. The tert-butylphenol is then phosphorylated to the tert-butylphenyl diphenyl phosphate meta/para mixture with phosphorus oxychloride. The disclosed process provides a tert-butylphenyl diphenyl phosphate which will not freeze or gel at low temperatures.
摘要翻译：一种制备叔丁基苯基二苯基磷酸酯的方法，该方法通过以下方法在低温下稳定，其中苯酚被丁基化以产生叔丁基苯酚，其被异构化以产生其混合的间位和对位异构体，然后用异丁烯进行烷基化， C4 / Phi比为约0.62的丁基苯酚。然后将叔丁基苯酚用磷酰氯磷酸化成叔丁基苯基二苯基磷酸酯/对 - 混合物。所公开的方法提供了在低温下不会冷冻或凝胶化的叔丁基苯基二苯基磷酸酯。

47. 发明授权

US4408086A Oligomerization of m-isopropenylphenol 失效
标题翻译：间 - 异丙烯基苯酚的低聚
公开(公告)号：US4408086A
公开(公告)日：1983-10-04
申请号：US212511
申请日：1980-12-03
申请人： Shunsuke Matsushima , Kazuhiko Hata , Kentaro Mashita , Shuichi Kanagawa , Shinji Nakao , Kiyoshi Nakai , Kunimasa Kamio
发明人： Shunsuke Matsushima , Kazuhiko Hata , Kentaro Mashita , Shuichi Kanagawa , Shinji Nakao , Kiyoshi Nakai , Kunimasa Kamio
IPC分类号： C07C37/14 , C07C39/17 , C08G64/14 , C07C39/14
CPC分类号： C07C37/14 , C08G64/14 , C07C2102/08
摘要： m-Isopropenylphenol oligomer which is useful for the production of synthetic resins such as epoxy resins is produced by polyermizing m-isopropenylphenol at a temperature of 135.degree. to 230.degree. C. using a catalytic amount of an acid catalyst in the presence or absence of a solvent, or freezing m-isopropenylphenol in the presence or absence of an acid catalyst.
摘要翻译：可用于生产合成树脂如环氧树脂的间 - 异丙烯基苯酚低聚物是通过在135℃至230℃的温度下，使用催化量的酸催化剂在存在或不存在的情况下将m-异丙烯基苯酚溶剂或冷冻的异丙烯基苯酚在酸催化剂存在或不存在下进行。

48. 发明授权

US4398048A Preparation of 2,4,6-trialkylphenols 失效
标题翻译：制备2,4,6-三烷基苯酚
公开(公告)号：US4398048A
公开(公告)日：1983-08-09
申请号：US313899
申请日：1981-10-21
申请人： Bruce E. Firth
发明人： Bruce E. Firth
IPC分类号： C07C37/14 , C07C37/48
CPC分类号： C07C37/14
摘要： Substantially improved yields of 2,4,6-trialkylphenols result from alkylating a mixture of phenol and 2,6-dialkylphenol, the latter being a by-product of the alkylation reaction. This results flows from an unexpected synergistic effect accompanying transalkylation. The continuous method of making 2,4,6-trialkylphenol based on this property affords the highly desirable trialkylated phenols in high yield.
摘要翻译：通过烷基化苯酚和2,6-二烷基苯酚的混合物，后者是烷基化反应的副产物，可以显着提高2,4,6-三烷基苯酚的产率。该结果源自伴随烷基转移的意想不到的协同效应。基于该性质制备2,4,6-三烷基苯酚的连续方法以高产率提供高度希望的三烷基化酚。

49. 发明授权

US4323714A Alkylation of hydroxy-substituted aromatic compounds 失效
标题翻译：羟基取代的芳族化合物的烷基化
公开(公告)号：US4323714A
公开(公告)日：1982-04-06
申请号：US208953
申请日：1980-11-20
申请人： Thomas P. Malloy , Dusan J. Engel
发明人： Thomas P. Malloy , Dusan J. Engel
IPC分类号： C07C37/14 , C07C37/16 , C07C37/11 , C07C39/08
CPC分类号： C07C37/16 , C07C37/14 , C07C2103/26
摘要： Hydroxy-substituted aromatic compounds may be alkylated by treatment with an alkylating agent such as an olefin or an alcohol at a temperature in the range of from about 50.degree. to about 200.degree. C. and a pressure in the range of from about atmospheric to about 100 atmospheres in the presence of a fluoro-substituted resin. The resulting product will comprise both mono- and di-alkylated hydroxy-substituted aromatic compounds.
摘要翻译：羟基取代的芳族化合物可以通过用烷基化剂如烯烃或醇在约50至约200℃的温度范围内处理并且在约大气压至约200℃范围内的压力下进行烷基化在氟取代树脂存在下100个大气压。所得产物将包含单烷基化和二烷基化羟基取代的芳族化合物。

50. 发明授权

US4323713A Preparation of mono-tertiary butylhydroquinone 失效
标题翻译：单叔丁基氢醌的制备
公开(公告)号：US4323713A
公开(公告)日：1982-04-06
申请号：US208952
申请日：1980-11-20
申请人： Dusan J. Engel
发明人： Dusan J. Engel
IPC分类号： C07C37/14 , C07C37/16 , C07C37/11 , C07C39/08
CPC分类号： C07C37/16 , C07C37/14
摘要： Hydroquinone is subjected to an alkylation reaction utilizing isobutylene or t-butyl alcohol as the alkylating agent to obtain t-butyl hydroquinone. The alkylation reaction is effected in the presence of an acidic catalyst such as phosphoric acid at temperatures ranging from about 75.degree. to about 200.degree. C. and a pressure in the range of from about atmospheric to about 100 atmospheres. By employing a mixture of a nonpolar hydrocarbon solvent such as xylene and an aliphatic ketone such as 2-heptanone, it is possible to obtain a greater ratio of mono-alkylated product to di-alkylated product.
摘要翻译：使用异丁烯或叔丁醇作为烷基化剂对对苯二酚进行烷基化反应，得到叔丁基氢醌。烷基化反应在酸性催化剂如磷酸的存在下，在约75至约200℃的温度和约大气至约100大气压的范围内进行。通过使用非极性烃溶剂如二甲苯和诸如2-庚酮的脂族酮的混合物，可以获得更大的单烷基化产物与二烷基化产物的比例。

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