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1. 发明授权

US4323714A Alkylation of hydroxy-substituted aromatic compounds 失效
标题翻译：羟基取代的芳族化合物的烷基化
公开(公告)号：US4323714A
公开(公告)日：1982-04-06
申请号：US208953
申请日：1980-11-20
申请人： Thomas P. Malloy , Dusan J. Engel
发明人： Thomas P. Malloy , Dusan J. Engel
IPC分类号： C07C37/14 , C07C37/16 , C07C37/11 , C07C39/08
CPC分类号： C07C37/16 , C07C37/14 , C07C2103/26
摘要： Hydroxy-substituted aromatic compounds may be alkylated by treatment with an alkylating agent such as an olefin or an alcohol at a temperature in the range of from about 50.degree. to about 200.degree. C. and a pressure in the range of from about atmospheric to about 100 atmospheres in the presence of a fluoro-substituted resin. The resulting product will comprise both mono- and di-alkylated hydroxy-substituted aromatic compounds.
摘要翻译：羟基取代的芳族化合物可以通过用烷基化剂如烯烃或醇在约50至约200℃的温度范围内处理并且在约大气压至约200℃范围内的压力下进行烷基化在氟取代树脂存在下100个大气压。所得产物将包含单烷基化和二烷基化羟基取代的芳族化合物。

2. 发明授权

US5350879A Transesterification using metal oxide solid solutions as the basic catalyst 失效
标题翻译：使用金属氧化物固溶体作为碱性催化剂进行酯交换
公开(公告)号：US5350879A
公开(公告)日：1994-09-27
申请号：US153409
申请日：1993-11-17
申请人： Dusan J. Engel , Thomas P. Malloy , Peter K. Nickl
发明人： Dusan J. Engel , Thomas P. Malloy , Peter K. Nickl
IPC分类号： C07C27/02 , C07C29/128 , C07C67/03 , C07C67/02 , C07C27/10
CPC分类号： C07C29/1285 , C07C67/03
摘要： Base-catalyzed transesterification may be effected in the presence of certain metal oxide solid solutions and layered double hydroxides as the basic catalyst. Use of the latter materials as the base catalyst readily permits one to conduct transesterification in a continuous manner. Such a continuous process is applicable to esters generally and is not limited to any particular structural types of esters or alcohols. Transesterification of detergent range alkyl acetates by this method leads to the formation of the corresponding detergent range alcohols in excellent yield and with quite high selectivity.
摘要翻译：碱催化的酯交换可以在某些金属氧化物固溶体和层状双氢氧化物作为碱性催化剂的存在下进行。使用后一种材料作为碱催化剂容易使其以连续的方式进行酯交换。这种连续方法通常适用于酯，并不限于任何特定结构类型的酯或醇。通过该方法的洗涤剂范围的烷基乙酸酯的酯交换导致相当的洗涤剂范围的醇的形成，其产率和产率都非常高，并具有相当高的选择性。

3. 发明授权

US4499300A 4-Vinylbenzeneacetic acid 失效
标题翻译： 4-乙烯基苯乙酸
公开(公告)号：US4499300A
公开(公告)日：1985-02-12
申请号：US566007
申请日：1983-12-27
申请人： Thomas P. Malloy , Dusan J. Engel
发明人： Thomas P. Malloy , Dusan J. Engel
IPC分类号： C07C45/36 , C07C51/00 , C07C51/363 , C07C51/377 , C07C63/64
CPC分类号： C07C51/363 , C07C45/36 , C07C51/00 , C07C51/377
摘要： A multi-step preparation of 4-vinylbenzeneacetic acid from the readily available 1,4-diethylbenzene is described. The method uses cobalt (II) catalyzed oxidation of 1,4-diethylbenzene to 4-ethylacetophenone followed by oxidative rearrangement of the latter to 4-ethylbenzeneacetic acid, selective photochlorination to produce 4-(1'-chloroethyl)benzeneacetic acid, and finally base-catalyzed dehydrochlorination of the latter to afford the title compound.
摘要翻译：描述了从容易获得的1,4-二乙基苯中多步制备4-乙烯基苯乙酸。该方法使用1,4-二乙基苯（II）催化氧化成4-乙基苯乙酮，随后将其氧化重排为4-乙基苯乙酸，进行选择性光氯化，得到4-（1'-氯乙基）苯乙酸，最后碱将其催化脱氯化氢，得到标题化合物。

4. 发明授权

US4323715A Preparation of mono-tertiary butylhydroquinone 失效
标题翻译：单叔丁基氢醌的制备
公开(公告)号：US4323715A
公开(公告)日：1982-04-06
申请号：US208954
申请日：1980-11-20
申请人： Dusan J. Engel , Thomas P. Malloy
发明人： Dusan J. Engel , Thomas P. Malloy
IPC分类号： C07C37/14 , C07C37/11 , C07C39/08
CPC分类号： C07C37/14
摘要： Mono-tertiary butylhydroquinone may be prepared in a continuous method of operation by reacting hydroquinone with isobutylene in the presence of an acidic alumina catalyst. The alkylation is effected in a reaction medium which comprises an ether, and particularly a polyether such as the dimethyl ether of triethylene glycol.
摘要翻译：单叔丁基氢醌可以通过在酸性氧化铝催化剂存在下使氢醌与异丁烯反应而以连续的操作方法制备。烷基化反应在包括醚，特别是聚醚如三甘醇的二甲醚的反应介质中进行。

5. 发明授权

US4973782A Preparation of 2,2-diethyltoluene 失效
标题翻译：制备2,2-二乙基甲苯
公开(公告)号：US4973782A
公开(公告)日：1990-11-27
申请号：US419182
申请日：1989-10-10
申请人： Dusan J. Engel , Thomas P. Malloy
发明人： Dusan J. Engel , Thomas P. Malloy
IPC分类号： C07C2/86
CPC分类号： C07C2/864 , C07C2521/12 , C07C2529/18
摘要： A diethyltoluene mixture rich in 2,5-diethyltoluene and containing less tha 5% of the 3,5-diethyltoluene can be prepared by methylating 1,4-diethylbenzene with an excess of methanol in the presence of amorphous silica-alumina catalysts. The most desirable catalysts have a silica:alumina ratio from about 2:1 through about 9:1. Methylation is conveniently effected in a temperature range between about 300.degree. C. and about 450.degree. C. and most desirably in a hydrogen atmosphere.
摘要翻译：富含2,5-二乙基甲苯并且少于5％的3,5-二乙基甲苯的二乙基甲苯混合物可以通过在无定形二氧化硅 - 氧化铝催化剂存在下用过量的甲醇甲基化1,4-二乙基苯来制备。最理想的催化剂的二氧化硅：氧化铝比例为约2:1至约9:1。甲基化方便地在约300℃至约450℃的温度范围内进行，最理想的是在氢气氛中进行。

6. 发明授权

US5296632A Continuous reduction of a hindered nitro moiety in aliphatic nitro polyamines 失效
标题翻译：脂肪族硝基多胺中受阻硝基的连续还原
公开(公告)号：US5296632A
公开(公告)日：1994-03-22
申请号：US908199
申请日：1992-07-02
申请人： Dusan J. Engel , Thomas P. Malloy , Steven R. Paeschke
发明人： Dusan J. Engel , Thomas P. Malloy , Steven R. Paeschke
IPC分类号： C07C209/34
CPC分类号： C07C209/34
摘要： Nitro polyamines, and especially dinitro polyamines, can be readily reduced by a catalyst of zerovalent nickel on silica where the silica contains not more than 10% alumina and where the nickel content of the finished catalyst may be as high as 85%. The reductions can be performed under relatively low temperatures between 40.degree. and 120.degree. C. to avoid the problem of heat lability of the reactant nitro polyamines. Hydrogenations proceed with good conversion as well as good selectivity and the method offers a means of continuous hydrogenation of nitro polyamines.
摘要翻译：硝基多胺，特别是二硝基多胺可以通过二氧化硅上的零价镍的催化剂容易地还原，其中二氧化硅含有不超过10％的氧化铝，其中最终催化剂的镍含量可高达85％。可以在40摄氏度和120摄氏度之间的相对低的温度下进行降低，以避免反应物硝基多胺的热不稳定性问题。氢化进行良好的转化以及良好的选择性，并且该方法提供硝基多胺的连续氢化的方法。

7. 发明授权

US4503269A Isomerization of cresols 失效
标题翻译：甲酚异构化
公开(公告)号：US4503269A
公开(公告)日：1985-03-05
申请号：US534225
申请日：1983-09-21
申请人： Dusan J. Engel , Thomas P. Malloy , James P. Shoffner
发明人： Dusan J. Engel , Thomas P. Malloy , James P. Shoffner
IPC分类号： C07C37/00 , C07C37/50 , C07C37/48
CPC分类号： C07C37/00 , B01J29/40
摘要： An improvement in a process for the isomerization of cresols may be obtained by effecting the isomerization reaction of a cresol in the presence of a crystalline aluminosilicate zeolite catalyst and added hydrogen. The added hydrogen will provide stability and longer life to the catalyst as well as a more stable selectivity to the desired isomers. The isomerization reaction is effected at temperatures ranging from about 250.degree. to about 450.degree. C. and pressures ranging from 2 to about 75 atmospheres in the presence of added hydrogen, said hydrogen being present in a mole ratio in the range of from about 1:1 to about 10:1 moles of hydrogen per mole of cresol.
摘要翻译：通过在结晶硅铝酸盐沸石催化剂和加入的氢的存在下进行甲酚的异构化反应，可以获得甲酚异构化方法的改进。添加的氢气将为催化剂提供稳定性和更长的寿命以及对所需异构体的更稳定的选择性。异构化反应在约250至约450℃的温度和在加入的氢气存在下从2至约75个大气压的压力下进行，所述氢以约1：1的摩尔比存在，每摩尔甲酚1至约10：1摩尔氢。

8. 发明授权

US4691063A Isomerization of cresols 失效
标题翻译：甲酚异构化
公开(公告)号：US4691063A
公开(公告)日：1987-09-01
申请号：US874780
申请日：1986-06-16
申请人： Dusan J. Engel , Jean-Pierre Gilson
发明人： Dusan J. Engel , Jean-Pierre Gilson
IPC分类号： C07C37/00 , C07C37/48 , C07C39/06
CPC分类号： C07C37/00 , B01J29/40
摘要： An improvement in a process for the isomerization of cresols may be obtained by effecting the isomerization reaction of a cresol in the presence of a phosphorous containing crystalline aluminosilicate zeolite catalyst. The added phosphorous provides stability and longer life to the catalyst as well as more stable selectivity to the desired isomers. The isomerization reaction is effected at temperatures ranging from about 350.degree. C. to about 500.degree. C., pressures ranging from about 1 to about 60 atmospheres, a Liquid Hourly Space Velocity that ranges from 1 to about 5 hours.sup.-1, with the abovementioned catalyst containing from about 1% to about 8% by weight phosphorous.
摘要翻译：通过在含磷结晶硅铝酸盐沸石催化剂的存在下进行甲酚的异构化反应，可以获得甲酚异构化方法的改进。添加的磷提供催化剂的稳定性和更长的寿命以及对所需异构体的更稳定的选择性。异构化反应在约350℃至约500℃的温度下进行，约1至约60个大气压，约1至约5小时-1的液体小时空间速度与上述催化剂含有约1％至约8％重量的磷。

9. 发明授权

US4124643A Preparation of 3-fluorosalicylaldehyde 失效
标题翻译： 3-氟水杨醛的制备
公开(公告)号：US4124643A
公开(公告)日：1978-11-07
申请号：US821364
申请日：1977-08-03
申请人： Michael Martan , Dusan J. Engel
发明人： Michael Martan , Dusan J. Engel
IPC分类号： C07C37/00 , C07C37/055 , C07C43/225 , C07C45/40 , C07C45/84 , C07C47/56 , C07C47/565 , C07C45/00
CPC分类号： C07C47/565 , C07C37/001 , C07C37/055 , C07C41/16 , C07C45/40 , C07C45/84 , C07C47/56
摘要： 3-Fluorosalicylaldehyde may be prepared in a more economical manner by alkylating o-fluorophenol with an allyl halide such as allyl chloride, thereafter rearranging the resultant o-fluorophenyl allyl ether to form allyl-o-fluorophenol. The latter compound is then isomerized to form propenyl-o-fluorophenol. Thereafter this compound is subjected to ozonolysis at a subambient temperature to form the desired compound, namely, 3-fluorosalicylaldehyde.
摘要翻译：可以以更经济的方式通过用烯丙基卤如烯丙基氯烷基化邻氟苯酚，然后重新排列所得的邻氟苯基烯丙基醚以形成烯丙基 - 邻 - 氟苯酚，从而制备3-氟水杨醛。然后将后一种化合物异构化形成丙烯基邻氟苯酚。此后，该化合物在低于环境温度下进行臭氧分解以形成所需化合物，即3-氟水杨醛。

10. 发明授权

US4806616A N-N'-dialkylphenylenediamines as curing agents in polyurethane and polyurea manufacture by reaction injection molding 失效
标题翻译： N-N'-二烷基苯二胺作为聚氨酯和聚脲的固化剂通过反应注射成型制备
公开(公告)号：US4806616A
公开(公告)日：1989-02-21
申请号：US130838
申请日：1987-12-09
申请人： William M. Baumann , Ray V. Scott, Jr. , David W. House , Dusan J. Engel
发明人： William M. Baumann , Ray V. Scott, Jr. , David W. House , Dusan J. Engel
IPC分类号： C08G18/32 , C08G18/65 , C08G18/30 , C08G18/34
CPC分类号： C08G18/6529 , C08G18/325 , C08G2120/00
摘要： N,N'-dialkyl- and diaylphenylenediamines are effective curing agents in combination with other polyamines and polyols in reaction injection molding for a diverse class of polyisocyanates. The diamines provide a broad spectrum of cure times, as well as giving elastomers an interesting and useful diversity of properties. Such polyamines may be used as a constituent in a blend of polyamines as the isocyanate-reactive component, in which case the elastomer may be viewed as predominantly a polyurea, or as a constituent in a blend with polyols, in which case the elastomer may be viewed as an elastomer with both urethane and urea segments.
摘要翻译： N，N'-二烷基和二亚苯基二胺是在多种多异氰酸酯的反应注射成型中与其它多胺和多元醇组合的有效固化剂。二胺提供广泛的固化时间，以及赋予弹性体一种有趣和有用的多样性。这种多胺可以作为多胺的混合物中的组分用作异氰酸酯反应性组分，在这种情况下，弹性体可以主要看作聚脲，或作为与多元醇的共混物中的组分，在这种情况下，弹性体可以是被视为具有氨基甲酸酯和尿素段的弹性体。

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