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41. 发明授权

US5885439A Catalytic reforming process with multiple zones 失效
标题翻译：催化重整过程与多个区域
公开(公告)号：US5885439A
公开(公告)日：1999-03-23
申请号：US963739
申请日：1997-11-04
申请人： Bryan K. Glover
发明人： Bryan K. Glover
IPC分类号： B01J23/62 , B01J29/62 , C07B61/00 , C07C5/41 , C07C15/04 , C07C15/06 , C07C15/067 , C10G31/00 , C10G35/09 , C10G35/095 , C10G59/02 , C10G35/04 , C10G35/06
CPC分类号： C10G59/02
摘要： A hydrocarbon feedstock is catalytically reformed in a sequence comprising a first bifunctional-catalyst reforming zone, a zeolitic-reforming zone containing a catalyst comprising a platinum-group metal and a nonacidic zeolite, and a terminal bifunctional catalyst reforming zone. The process combination permits higher severity, higher aromatics yields and/or increased throughput relative to the known art, and is particularly useful in connection with moving-bed reforming facilities with continuous catalyst regeneration.
摘要翻译：烃原料以包含第一双官能催化剂重整区，含有包含铂族金属和非酸性沸石的催化剂的沸石重整区和末端双官能催化剂重整区的顺序进行催化重整。相对于已知技术，该方法组合允许更高的苛刻度，更高的芳族化合物产率和/或增加的产量，并且在连续催化剂再生的移动床重整设备中特别有用。

42. 发明授权

US5750800A Process for producing diisopropyl ether from propane 失效
标题翻译：从丙烷生产二异丙醚的方法
公开(公告)号：US5750800A
公开(公告)日：1998-05-12
申请号：US556117
申请日：1995-11-09
申请人： Terry L. Marker , Brian S. Muldoon , Bryan K. Glover , Bipin V. Vora
发明人： Terry L. Marker , Brian S. Muldoon , Bryan K. Glover , Bipin V. Vora
IPC分类号： C07C5/333 , C07C41/05 , C07C41/00
CPC分类号： C07C41/05 , C07C5/333 , Y02P20/125
摘要： An integrated process to produce diisopropyl ether from propane has been developed. In a first reaction zone the propane in a feedstock, after any hydrocarbons containing four or more carbon atoms are removed from the feedstock via fractionation, is dehydrogenated in the presence of a dehydrogenation catalyst to form propylene. After removing hydrogen, the propane and propylene mixture generated in the first reaction zone is separated into a propane enriched stream and a propylene enriched stream where the propylene enriched stream contains at least 65 mass % propylene. The propane enriched stream is recycled to the feedstock fractionation unit, and the propylene of the propylene enriched stream is reacted with water in a second reaction zone in the presence of an acidic catalyst to form isopropyl alcohol which is concurrently reacted with propylene to produce diisopropyl ether. A portion of the second reaction zone effluent is recycled to the second reaction zone, and the remainder may be collected or further separated to provide a high purity diisopropyl ether product. A variant to produce high purity propylene as well as diisopropyl ether is also discussed.
摘要翻译：已经开发了从丙烷生产二异丙醚的综合方法。在第一反应区中，原料中的丙烷在含有四个或更多个碳原子的烃通过分馏从原料中除去后，在脱氢催化剂存在下脱氢形成丙烯。除去氢气后，在第一反应区产生的丙烷和丙烯混合物分离成富丙烷流和富丙烯流，其中富含丙烯的料流含有至少65质量％的丙烯。将富丙烷流再循环至原料分馏装置，在酸性催化剂存在下，使丙烯富集物流的丙烯与第二反应区中的水反应形成异丙醇，同时与丙烯反应产生二异丙醚。第二反应区流出物的一部分再循环至第二反应区，其余部分可以被收集或进一步分离以提供高纯度的二异丙醚产物。还讨论了生产高纯度丙烯以及二异丙基醚的变体。

43. 发明授权

US09394215B2 Processes for making Cx-Cy olefins from C5 and C6 paraffins 有权
标题翻译：从C5和C6链烷烃制备Cx-Cy烯烃的方法
公开(公告)号：US09394215B2
公开(公告)日：2016-07-19
申请号：US13186205
申请日：2011-07-19
申请人： Debarshi Majumder , Stephen Wayne Sohn , Bryan K. Glover , Andrea G. Bozzano
发明人： Debarshi Majumder , Stephen Wayne Sohn , Bryan K. Glover , Andrea G. Bozzano
IPC分类号： C07C2/64 , C07C2/04 , C07C2/54 , C07C2/56 , C07C2/72 , C07C6/04 , C07C303/06 , C07C2/06 , C07C5/32 , C10G50/00 , C10G69/12
CPC分类号： C07C6/04 , C07C2/06 , C07C2/64 , C07C5/32 , C07C303/06 , C10G50/00 , C10G69/126 , C07C11/02 , C07C11/10 , C07C11/107 , C07C15/107 , C07C309/31
摘要： Processes for making CX to CY olefins are provided. The processes include reacting a feedstock comprising C5 and C6 olefins under dimerization or oligomerization conditions to provide a dimerization or oligomerization product. The product is separated into a stream comprising unreacted C5 and C6 paraffins, a stream comprising C10 to CX-1 olefins, and a stream comprising CX to CY olefins, wherein X is at least 14 and Y is greater than X and less than or equal to 36.
摘要翻译：提供了制备CX至CY烯烃的方法。该方法包括在二聚或低聚条件下使包含C5和C6烯烃的原料反应以提供二聚或低聚产物。将产物分离成包含未反应的C5和C6链烷烃的流，包含C10至CX-1烯烃的流和包含CX至CY烯烃的流，其中X为至少14且Y大于X且小于或等于到36。

44. 发明授权

US08747768B2 Screenless internals for radial flow reactors 有权
标题翻译：径向流动反应器的无屏蔽内部件
公开(公告)号：US08747768B2
公开(公告)日：2014-06-10
申请号：US12711278
申请日：2010-02-24
申请人： Bryan K. Glover , Guy B. Woodle , Joseph E. Zimmermann , John J. Senetar
发明人： Bryan K. Glover , Guy B. Woodle , Joseph E. Zimmermann , John J. Senetar
IPC分类号： B01J8/12
CPC分类号： B01J8/12 , B01J8/008 , B01J8/085
摘要： An apparatus for contacting a bed of particulate material with a cross flowing fluid, which maintains the bed of particulate material within a retention volume. The apparatus includes partitions for retaining particles, with apertures disposed within the partitions. The apertures are covered by louvers that extend above the edges of the apertures to prevent solid particles from spilling through inlet apertures.
摘要翻译：用于使颗粒材料床与交叉流动流体接触的装置，其将颗粒材料床保持在保持体积内。该装置包括用于保持颗粒的分隔物，孔中设置在隔板内。这些孔由在孔的边缘上方延伸的百叶窗覆盖以防止固体颗粒溢出入口孔。

45. 发明申请

US20110071328A1 Selective Hydrogenation of Dienes in the Manufacture of MLAB 有权
标题翻译：二烯在MLAB制造中的选择性氢化
公开(公告)号：US20110071328A1
公开(公告)日：2011-03-24
申请号：US12563591
申请日：2009-09-21
申请人： Mark G. Riley , Bryan K. Glover
发明人： Mark G. Riley , Bryan K. Glover
IPC分类号： C07C5/05
CPC分类号： B01J23/58 , B01J21/04 , B01J23/44 , B01J35/0026 , B01J35/1014 , B01J35/1019 , B01J35/1047 , B01J35/1066 , B01J35/108 , C07C5/05 , C07C5/09 , C07C15/107 , C07C2521/04 , C07C2523/44 , C07C2523/58 , C07C11/02
摘要： A process and catalyst are presented for the selective hydrogenation of branched diolefins and acetylenes to olefins. The process uses a catalyst having large pores, and a minimal amount of micropores. The catalyst is designed to have minimal diffusional resistance through the large pores, and to minimize the hydrogenation of olefins to paraffins.
摘要翻译：提出了一种方法和催化剂，用于将支链二烯烃和炔烃选择性氢化成烯烃。该方法使用具有大孔的催化剂和最少量的微孔。该催化剂被设计为具有通过大孔的最小扩散阻力，并使烯烃氢化至链烷烃最小化。

46. 发明授权

US07902416B2 Fluidized bed reactor with back-mixing for dehydrogenation of light paraffins 有权
标题翻译：具有反混合的流化床反应器用于轻链烷烃的脱氢
公开(公告)号：US07902416B2
公开(公告)日：2011-03-08
申请号：US11954153
申请日：2007-12-11
申请人： Bryan K. Glover , Julie A. Zarraga , Michael A. Schultz
发明人： Bryan K. Glover , Julie A. Zarraga , Michael A. Schultz
IPC分类号： C07C5/333
CPC分类号： C07C5/324 , C07C5/325 , C07C2521/04 , C07C2521/08 , C07C2521/16 , C07C2523/26 , C07C2523/28 , C07C2523/30 , C07C2523/36 , C07C2523/42 , C07C2523/44 , C07C2523/745 , C07C2523/75 , C07C2523/755 , Y02P20/584 , C07C11/02
摘要： An improved process and system for the endothermic dehydrogenation of an alkane stream is described. The process and system of the present invention comprise a back-mixed fluidized bed reactor. The alkane stream is dehydrogenated in a single reactor stage by contacting the alkane stream with a back-mixed fluidized bed of catalyst. Deactivated catalyst is withdrawn from the back-mixed fluidized reactor and heated to produce hot regenerated catalyst. The hot regenerated catalyst is returned to the back-mixed fluidized bed reactor at a rate sufficient to maintain the back-mixed fluidized bed reactor at substantially isothermal conditions.
摘要翻译：描述了用于烷烃流的吸热脱氢的改进方法和系统。本发明的方法和系统包括反混流化床反应器。通过使烷烃流与催化剂的反混合流化床接触，在单个反应器阶段使烷烃流脱氢。将脱活催化剂从反混合流化反应器中取出并加热，生成热再生催化剂。热再生催化剂以足以将反混流化床反应器保持在基本等温条件的速率返回到反混流化床反应器。

47. 发明申请

US20100331171A1 Layered Sphere Catalysts with High Accessibility Indexes 审中-公开
公开(公告)号：US20100331171A1
公开(公告)日：2010-12-30
申请号：US12493415
申请日：2009-06-29
申请人： Gregory J. Gajda , Bryan K. Glover , Antoine Negiz , Mark G. Riley , John J. Senetar , Erik M. Holmgreen
发明人： Gregory J. Gajda , Bryan K. Glover , Antoine Negiz , Mark G. Riley , John J. Senetar , Erik M. Holmgreen
IPC分类号： B01J29/89 , B01J23/44 , B01J23/42 , B01J21/12 , B01J21/16 , B01J21/08
CPC分类号： B01J23/40 , B01J23/44 , B01J23/58 , B01J23/66 , B01J35/002 , B01J35/008 , B01J35/023 , B01J37/0205 , B01J37/0221 , B01J37/0242 , B01J37/08 , B01J37/18 , C07C7/163 , C07C7/167 , C10G45/40 , Y02P20/52 , C07C11/04
摘要： A process and catalyst for use in the selective hydrogenation of acetylene to ethylene is presented. The catalyst comprises a layered structure, wherein the catalyst has an inner core and an outer layer of active material. The catalyst further includes a metal deposited on the outer layer, and the catalyst is formed such that the catalyst has an accessibility index between 3 and 500.

48. 发明授权

US07781630B2 Integrated processes for making detergent range alkylbenzenes from C5-C6-containing feeds 有权
公开(公告)号：US07781630B2
公开(公告)日：2010-08-24
申请号：US12511567
申请日：2009-07-29
申请人： Bryan K. Glover , Stephen W. Sohn , Mark G. Riley , Dean E. Rende
发明人： Bryan K. Glover , Stephen W. Sohn , Mark G. Riley , Dean E. Rende
IPC分类号： C07C2/58 , C07C5/02 , C07C5/32
CPC分类号： C07C15/107 , C07C2/66 , C07C5/333 , C07C2521/12 , Y02P20/125
摘要： Integrated processes for making detergent range alkylbenzenes from C5-C6-containing feeds involve feed pretreatment and/or selective hydrogenation to enable acceptable quality alkylbenzene production at attractive capital and operating costs.

49. 发明授权

US07750198B2 Olefinic feedstock treatment processes 有权
标题翻译：烯烃原料处理工艺
公开(公告)号：US07750198B2
公开(公告)日：2010-07-06
申请号：US12046948
申请日：2008-03-12
申请人： Bryan K. Glover , Andrea G. Bozzano , Antoine Negiz
发明人： Bryan K. Glover , Andrea G. Bozzano , Antoine Negiz
IPC分类号： C07C7/12 , C07C7/13
CPC分类号： C07C15/107 , C07C2/66
摘要： Aromatic by-products are sorbed from mono-olefin-containing feedstocks of olefins having from about 6 to 22 carbon atoms per molecule that contain aromatic by-products having from 7 to 22 carbon atoms per molecule. A benzene-containing regenerant displaces and desorbs the aromatic by-products from the sorbent and a regeneration effluent is provided. The regeneration effluent is treated in a regeneration effluent distillation system to provide a benzene-rich stream and an aromatic by-products-containing stream. The latter is subjected to benzene-forming conditions and recycled to the regeneration effluent distillation system where benzene is recovered.
摘要翻译：芳族副产物被从每分子含有约6至22个碳原子的含单烯烃的原料中吸收，每分子含有7至22个碳原子的芳族副产物。含苯的再生剂从吸附剂中取代并解吸芳族副产物，并提供再生流出物。再生流出物在再生流出物蒸馏系统中处理以提供富含苯的流和含芳香族副产物的流。后者经受苯形成条件并再循环至回收苯的再生流出物蒸馏系统。

50. 发明申请

US20100152026A1 Layered Sphere Catalysts with High Accessibility Indexes 审中-公开
标题翻译：具有高可访问性指数的分层球体催化剂
公开(公告)号：US20100152026A1
公开(公告)日：2010-06-17
申请号：US12335643
申请日：2008-12-16
申请人： Gregory J. Gajda , Bryan K. Glover , Antoine Negiz , Mark G. Riley , John J. Senetar , Erik M. Holmgreen
发明人： Gregory J. Gajda , Bryan K. Glover , Antoine Negiz , Mark G. Riley , John J. Senetar , Erik M. Holmgreen
IPC分类号： B01J29/068 , B01J23/42 , B01J23/66 , B01J23/62 , B01J23/44 , B01J21/08 , B01J21/04 , B01J21/02 , B01J21/16 , B01J27/22
CPC分类号： B01J35/023 , B01J23/50 , B01J23/52 , B01J23/58 , B01J23/622 , B01J23/8926 , B01J35/002 , B01J35/008 , B01J37/0221 , B01J37/0242 , C07C5/09 , C07C2523/62 , C07C2523/66 , C07C2523/89 , Y02P20/52 , C07C11/04
摘要： A process and catalyst for use in the selective hydrogenation of acetylene to ethylene is presented. The catalyst comprises a layered structure, wherein the catalyst has an inner core and an outer layer of active material. The catalyst further includes a metal deposited on the outer layer, and the catalyst is formed such that the catalyst has an accessibility index between 3 and 500.
摘要翻译：提出了一种用于将乙炔选择性氢化成乙烯的方法和催化剂。催化剂包括层状结构，其中催化剂具有内核和活性材料的外层。催化剂还包括沉积在外层上的金属，并且形成催化剂使得催化剂的可接近指数在3和500之间。

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