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    • 48. 发明申请
    • LITHIUM SECONDARY BATTERY AND METHOD FOR MANUFACTURING THE SAME
    • 锂二次电池及其制造方法
    • US20130101897A1
    • 2013-04-25
    • US13636811
    • 2011-03-24
    • Atsushi FukuiTaizo SunanoMaruo Kamino
    • Atsushi FukuiTaizo SunanoMaruo Kamino
    • H01M4/62H01M4/04
    • H01M4/622C08G73/1067C08G73/1082C08L79/08H01M4/04H01M4/0404H01M4/134H01M4/1395H01M10/052Y02E60/122Y02P70/54Y10T29/49115
    • Provided is a lithium secondary battery in which negative-electrode active material particles containing silicon and/or a silicon alloy are used and which prevents the occurrence of breakage of a binder itself and peel-off of the binder at the interfaces with the negative-electrode active material and the negative-electrode current collector and has a high energy density and an excellent cycle characteristic. The lithium secondary battery includes: a negative electrode in which a negative-electrode active material layer including negative-electrode active material particles containing silicon and/or a silicon alloy and a binder is formed on a surface of electrically conductive metal foil serving as a negative-electrode current collector; a positive electrode; and a nonaqueous electrolyte, wherein the binder contains a polyimide resin including a crosslinked structure formed by imidization of a hexavalent or higher-valent carboxylic acid or an anhydride thereof with a diamine.
    • 提供一种锂二次电池,其中使用含有硅和/或硅合金的负极活性物质颗粒,并且防止粘合剂本身的破裂发生和粘合剂在与负极的界面处的剥离 活性物质和负极集电体,具有高能量密度和优异的循环特性。 锂二次电池包括:在作为负极的导电性金属箔的表面上形成有负极活性物质层的负极,负极活性物质层包含含有硅和/或硅合金的负极活性物质粒子和粘合剂 电极集电器; 正极; 和非水电解质,其中所述粘合剂含有通过将六价或更高价羧酸或其酸酐与二胺酰亚胺化而形成的交联结构的聚酰亚胺树脂。