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    • 39. 发明授权
    • Polymer/polyols having improved combustion resistance and intrinsic
viscosity, methods of making same and polyurethanes prepared therefrom
    • 具有改善的耐燃性和特性粘度的聚合物/多元醇,其制备方法和由其制备的聚氨酯
    • US4652589A
    • 1987-03-24
    • US699970
    • 1985-02-08
    • Donald W. SimrothFrank E. CritchfieldRichard C. Myerly
    • Donald W. SimrothFrank E. CritchfieldRichard C. Myerly
    • C08G18/00C08F283/00C08F283/06C08F291/08C08G18/63C08G18/14C09K3/00
    • C08F291/08C08F283/06C08G18/63C08G18/635C08G18/636Y10S524/923
    • A normally liquid, stable polymer/polyol composition which imparts improved combustion resistance to polyurethane foams prepared therefrom while retaining satisfactory foam tensile properties are formed by polymerizing in the presence of a free radical catalyst and in the essential absence of an alkyl mercaptan, (1) from about 25 to about 60 weight percent of an ethylenically unsaturated monomer or monomers, for example, a mixture of acrylonitrile and styrene in a weight ratio respectively of 25:75 to 0:100, dissolved or dispersed in (2) from about 40 to about 75 weight percent of a polyol comprising a base polyol having a hydroxyl number of less than about 150, wherein the polymer is characterized by a crosslinking coefficient of less than 55 and an intrinsic viscosity of at least 0.30.A process for treating the resulting polymer/polyol composition to reduce the product viscosity to essentially the indigenous system viscosity in polymer/polyol compositions of this type is disclosed, as is a stabilizer precursor which assists in stabilizing the resulting polymer/polyol compositions.
    • 通过在自由基催化剂的存在下和基本不存在烷基硫醇的情况下聚合形成通常液体的,稳定的聚合物/多元醇组合物,其通过在保持令人满意的泡沫拉伸性能的同时保持令人满意的泡沫拉伸性能, 约25至约60重量%的烯属不饱和单体或单体,例如丙烯腈和苯乙烯的混合物,其重量比分别为25:75至0:100,溶解或分散于(2)约40至 约75重量%的包含羟基数小于约150的基础多元醇的多元醇,其中所述聚合物的特征在于交联系数小于55,特性粘度至少为0.30。 公开了一种用于处理所得聚合物/多元醇组合物以将产品粘度降低至基本上这种类型的聚合物/多元醇组合物中的本体系粘度的方法,以及有助于稳定所得聚合物/多元醇组合物的稳定剂前体。