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    • 3. 发明授权
    • Cotelomer compounds
    • US4681686A
    • 1987-07-21
    • US753510
    • 1985-07-10
    • Norman RichardsonBrian HoltBarry Cook
    • Norman RichardsonBrian HoltBarry Cook
    • C08F220/00C02F5/00C02F5/08C02F5/10C02F5/14C07F9/53C08F2/38C08F220/04C23F11/173C25D11/24
    • C23F11/173C02F5/14C08F2/38C08F220/04C25D11/246
    • New cotelomer compounds having the formula I ##STR1## and salts thereof wherein A is a random polymeric residue comprising at least one unit of formula II ##STR2## and at least one unit of formula III, different from a unit of formula II, ##STR3## and B is hydrogen or a residue A; wherein m and n are integers such that the sum of m+n is an integer of from 3 to 100, the ratio of n:m being from 99 to 1:1 to 99, provided that the resulting telomers are water-soluble and wherein m and/or n in a residue A may be the same as or different from m and/or n in a residue B; R is hydrogen, methyl or ethyl;R.sub.1 is a residue -OX, wherein X is hydrogen, an alkali- or alkaline earth metal, ammonium or an amine residue;R.sub.2 is hydrogen, methyl or a residue --CO.sub.2 R.sub.5, wherein R.sub.5 is hydrogen or a straight- or branched chain alkyl residue having 1 to 8 carbon atoms;R.sub.3 is hydrogen, a straight- or branched chain alkyl residue having 1 to 4 carbon atoms, hydroxymethyl or a residue --CO.sub.2 R.sub.6, wherein R.sub.6 is hydrogen, a residue of formula ##STR4## a residue of formula --[CH.sub.2 --CH(R.sub.9)O].sub.z H, in which R.sub.9 is hydrogen, methyl or phenyl and z is an integer from 1 to 20, or R.sub.6 is a straight- or branched chain alkyl residue having 1 to 8 carbon atoms or by a group SO.sub.3 M in which M is hydrogen or an alkali- or alkaline earth metal atom;R.sub.4 is a residue --CO.sub.2 R.sub.6 (wherein R.sub.6 has its previous significance), a straight- or branched alkyl residue having 1 to 8 carbon atoms optionally substituted by one to three carboxylic acid groups, a phenyl residue, an acetyl residue, hydroxymethyl, an acetomethyl residue, --SO.sub.3 M, --CH.sub.2 SO.sub.3 M or --PO.sub.3 M.sub.2, in which M is hydrogen or an alkali metal or alkaline earth metal atom, a residue --CONR.sub.7 R.sub.8, wherein R.sub.7 and R.sub.8 are the same or different and each is hydrogen, a straight- or branched chain alkyl residue having 1 to 8 carbon atoms, hydroxymethyl or a residue --CH(OH)CO.sub.2 M, --C(CH.sub.3).sub.2 CH.sub.2 SO.sub.3 M or --C(CH.sub.3).sub.2 CH.sub.2 PO.sub.3 M.sub.2, wherein M has its previous significance, or --N(R.sub.10)COCH.sub.3, in which R.sub.10 is hydrogen or C.sub.1 -C.sub.4 straight or branched chain alkyl group.Compounds I are useful as corrosion and/or scale inhibitors in aqueous systems, as agents for facilitating dispersion of particulate matter in aqueous systems and as sealing smut inhibitors in processes for sealing anodically produced oxide layers on aluminium surfaces.