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1. 发明授权

US4690954A Halogenated phosphorate ethers with flame-retardant polyurethanes 失效
标题翻译：卤化磷酸酯醚与阻燃聚氨酯
公开(公告)号：US4690954A
公开(公告)日：1987-09-01
申请号：US856524
申请日：1986-04-28
申请人： David J. Wampfler , Donna J. Fielding , Chester E. Pawloski
发明人： David J. Wampfler , Donna J. Fielding , Chester E. Pawloski
IPC分类号： C08K5/521 , C08G18/14
CPC分类号： C08K5/521
摘要： A method for improving a production characteristic of flame-retardant polyurethanes. The characteristic may be selected from the group consisting of(1) processability;(2) scorch;(3) odor; and(4) flame-retardant efficiency.The method comprises incorporation into a polyurethane an amount effective to reduce combustibility of a haloether phosphorate flame-retardant under conditions sufficient to improve said characteristic. Also, the flame-retardant polyurethane composition such as prepared by said method. Preferably, the polyurethane is a foam, especially a flexible foam and most especially flexible slabstock foam.
摘要翻译：一种改善阻燃聚氨酯的生产特性的方法。特征可以选自（1）加工性; （2）焦烧; （3）气味; 和（4）阻燃效率。该方法包括在足以改善所述特性的条件下将有效降低卤代磷酸酯阻燃剂的可燃性的量掺入聚氨酯中。而且，通过所述方法制备的阻燃聚氨酯组合物。优选地，聚氨酯是泡沫，特别是柔性泡沫，最特别是柔性块状泡沫。

2. 发明授权

US4851559A (Haloneocarbyl-substituted)(aliphatic or oxyaliphatic)halogenated aliphatic or oxyaliphatic)phosphorates and process for preparing 失效
标题翻译：（卤代烃基取代的）（脂族或脂族脂族）卤代脂族或脂族脂肪族）磷酸酯和制备方法
公开(公告)号：US4851559A
公开(公告)日：1989-07-25
申请号：US895541
申请日：1986-08-11
申请人： Chester E. Pawloski , David J. Wampfler , Donna J. Fielding
发明人： Chester E. Pawloski , David J. Wampfler , Donna J. Fielding
IPC分类号： C07F9/09 , C08K5/521
CPC分类号： C07F9/091 , C08K5/521
摘要： Included are the title phosphorate compounds, and a process to prepare them comprising contacting a carbylphosphorate mono acid halide with a carbyloxide. For example, ((2-(3-bromo-2,2-bis(bromomethyl)propxy)ethyl(chloroethyl)-(ethyl))phosphorat e can be prepared with (2-(3-bromo-2,2-bis(bromomethyl)propoxy)ethyl)(ethyl)chloridophosphorate and ethylene oxide. The compounds are useful so-called flame-retardants for polyurethanes, especially flexible foams because, for example, substantially non-scorching and non-odoriferous flame-retardant flexible foams can be readily prepared with the compounds.
摘要翻译：包括标题磷酸酯化合物，以及制备它们的方法，包括使碳酰基磷酸酯单酰卤与卡毕氧化物接触。例如，（（2-（3-溴-2,2-双（溴甲基）丙氧基）乙基（氯乙基） - （乙基））磷酸酯可用（2-（3-溴-2,2-二双（溴甲基）丙氧基）乙基）（乙基）氯代磷酸酯和环氧乙烷这些化合物是所谓的聚氨酯阻燃剂，特别是柔性泡沫塑料，因为例如基本上不易燃和无气味的阻燃柔性泡沫可以容易地用化合物制备。

3. 发明授权

US4945118A (Haloneocarbyl-substituted)(aliphatic or oxyaliphatic)(halogenated aliphatic or oxyaliphatic)-phosphorates with polyurethanes 失效
标题翻译：（卤代烃基取代的）（脂族或脂族）（卤代脂族或脂族） - 磷酸酯与聚氨酯
公开(公告)号：US4945118A
公开(公告)日：1990-07-31
申请号：US347097
申请日：1989-05-03
申请人： Chester E. Pawloski , Donna J. Fielding , David J. Wampfler
发明人： Chester E. Pawloski , Donna J. Fielding , David J. Wampfler
IPC分类号： C07F9/09 , C08K5/521
CPC分类号： C07F9/091 , C08K5/521 , Y10S521/906
摘要： Included are the title phosphorate compounds, and a process to prepare them comprising contacting a carbylphosphorate mono acid halide with a carbyloxide. For example, ((2-(3-bromo-2,2-bis(bromomethyl)propoxy)ethyl(chloroethyl)-(ethyl))phosphorate can be prepared with (2-(3-bromo-2,2-bis(bromomethyl)propoxy)ethyl)(ethyl)-chloridophosphorate and ethylene oxide. The compounds are useful so-called flame-retardants for polyurethanes, especially flexible foams because, for example, substantially non-scorching and non-odoriferous flame-retardant flexible foams can be readily prepared with the compounds.
摘要翻译：包括标题磷酸酯化合物，以及制备它们的方法，包括使碳酰基磷酸酯单酰卤与卡毕氧化物接触。例如，（（2-（3-溴-2,2-双（溴甲基）丙氧基）乙基（氯乙基） - （乙基）（溴甲基）丙氧基）乙基）（乙基） - 氯代磷酸酯和环氧乙烷。这些化合物是有用的聚氨酯阻燃剂，特别是柔性泡沫，因为例如基本上不易燃和无气味的阻燃柔性泡沫可以容易地用化合物制备。

4. 发明授权

US4686241A (Haloneocarbyl-substituted)-bis(aliphatic hydrocarbyl)phosphorates with polyurethanes 失效
标题翻译：（卤代烃基取代的） - 双（脂族烃基）磷酸酯与聚氨酯
公开(公告)号：US4686241A
公开(公告)日：1987-08-11
申请号：US856523
申请日：1986-04-28
申请人： Chester E. Pawloski , David J. Wampfler , Donna J. Fielding
发明人： Chester E. Pawloski , David J. Wampfler , Donna J. Fielding
IPC分类号： C07F9/09 , C08K5/521 , C08G18/14
CPC分类号： C07F9/091 , C08K5/521
摘要： Included are the title phosphorate compounds, and a process to prepare them comprising contacting a carbylphosphorate acid halide with a carbyloxide. For example, (3-chloro-2,2-bis(bromomethyl)propyl)bis(ethyl)phosphorate can be prepared with 3,3-bis(bromomethyl)oxetane and bis(ethyl)chloridophosphorate. The compounds are useful flame retardants for polyurethanes, especially flexible foams because, for example, substantially non-scorching and non-odoriferous flame-retardant flexible foams can be readily prepared with the compounds. Also included is a method for inducing scorch in polyurethanes, which can be used to generally determine polyurethane formulations which are prone to not scorch in commercial production.
摘要翻译：包括标题磷酸酯化合物，以及制备它们的方法，包括使碳酰基磷酸酯酰卤与卡毕氧化物接触。例如，可以使用3,3-双（溴甲基）氧杂环丁烷和双（乙基）氯代磷酸酯制备（3-氯-2,2-双（溴甲基）丙基）双（乙基）磷酸酯。这些化合物是用于聚氨酯，特别是柔性泡沫的有用的阻燃剂，因为例如可以容易地用这些化合物制备基本上非焦化和无气味的阻燃柔性泡沫。还包括用于在聚氨酯中引起焦烧的方法，其可用于通常测定在商业生产中容易不起焦的聚氨酯配方。

5. 发明授权

US4734443A Polyurethanes with mono-ol/diol haloneocarbyl polyethers and their esters 失效
标题翻译：具有单醇/二醇卤代烃基聚醚及其酯的聚氨酯
公开(公告)号：US4734443A
公开(公告)日：1988-03-29
申请号：US854189
申请日：1986-04-21
申请人： Chester E. Pawloski , Sally P. Ginter , David J. Wampfler
发明人： Chester E. Pawloski , Sally P. Ginter , David J. Wampfler
IPC分类号： C08G18/28 , C08G18/38 , C08G18/50 , C08K5/103 , C08G18/00 , C08G18/14
CPC分类号： C08G18/5003 , C08G18/2885 , C08G18/3804 , C08K5/103 , Y10S521/906
摘要： Included are mondiol haloneocarbyl polyethers and their esters incorporated in polyurethane foams. The compositions have haloneocarbyl moieties, and in general, the polyethers before the incorporation in the polyurethanes contain from one to two hydroxy moieties. The polyurethane foam compositions are flame-retardant and can have little or no scorch and little or no odor.
摘要翻译：包括掺入聚氨酯泡沫中的二醇卤代烃基聚醚及其酯。组合物具有卤代烃基部分，通常在引入聚氨酯之前的聚醚包含1至2个羟基部分。聚氨酯泡沫组合物是阻燃性的，并且可以具有很少或没有焦烧和很少或没有气味。

6. 发明授权

US4885381A Phosphate-phosphites acid halides 失效
标题翻译：磷酸亚磷酸酯
公开(公告)号：US4885381A
公开(公告)日：1989-12-05
申请号：US179793
申请日：1988-04-11
申请人： Chester E. Pawloski
发明人： Chester E. Pawloski
IPC分类号： C07F9/141 , C07F9/146 , C08K5/524
CPC分类号： C08K5/524 , C07F9/1411 , C07F9/146
摘要： Included are halogenated phosphate-phosphites and their acid halides and acids. The halogenated phosphate-phosphites can be prepared by a process comprising serially contacing(A) a phosphorus trihalide with a triol;(B) a halogenating agent; and(C) an oxirane or an alcohol;under conditions sufficient to prepare the halogenated phosphate-phosphite. Steps (A) and (B) can prepare their acid halides. Use of water in step (C) can prepare their acids. For example, 3-((bis(2-chloroethoxy)phosphino)oxy)(2-bromoethyl-2-methylpropyl, 2-bromoethyl, 2-chloroethyl)phosphorate can be prepared from 2-methyl-2-(hydroxymethyl)-1,3-propanediol; phosphorus trichloride; bromine; and ethylene oxide.Also included is use of the compounds as a hyraulic fluid or flame retardant. For example, polyurethanes can be rendered less flammable with the halogenated phosphate-phosphite flame retardant.
摘要翻译：包括卤代磷酸酯 - 亚磷酸酯及其酰基卤和酸。卤代磷酸酯 - 亚磷酸酯可以通过包括（A）三卤化磷与三醇的串联方法来制备; （B）卤化剂; 和（C）环氧乙烷或醇; 在足以制备卤代磷酸酯 - 亚磷酸酯的条件下。步骤（A）和（B）可以制备它们的酰卤。在步骤（C）中使用水可以制备它们的酸。例如，可以从2-甲基-2-（羟基甲基）-1（2-甲基-2-氧代乙基）氧基）（2-溴乙基），3-丙二醇; 三氯化磷; 溴; 和环氧乙烷。还包括使用化合物作为液压油或阻燃剂。例如，使用卤代磷酸酯 - 亚磷酸酯阻燃剂，可以使聚氨酯变得不易燃。

7. 发明授权

US4739091A Neucarbyl-substituted phosphorates 失效
标题翻译：烯基取代的磷酸盐
公开(公告)号：US4739091A
公开(公告)日：1988-04-19
申请号：US843452
申请日：1986-03-24
申请人： Chester E. Pawloski
发明人： Chester E. Pawloski
IPC分类号： C07F9/09 , C08K5/521
CPC分类号： C07F9/091 , C08K5/521
摘要： Included is a process for the preparation of a ((neocarbyl)contrasting-halo-substituted)phosphorate comprising serially contacting (1) a phosphorus trihalide with a neocarbyl alcohol; (2) an oxirane; (3) a halogenating agent; and (4) an oxirane, under conditions sufficient to prepare the ((neocarbyl)contrasting-halo-substituted)phosphorate.The phosphate can be very pure.Also included is a method for improving a production characteristic of flame-retardant polyurethanes. The characteristic may be selected from the group consisting of (1) processability; (2) scorch; (3) odor; (4) flame-retardant efficiency; and (5) combinations thereof. The method comprises incorporation into a polyurethane an amount effective to reduce combustibility of the foregoing phosphorate flame retardant under conditions sufficient to improve said characteristic. Also included is the flame-retardant polyurethane composition of said method. Preferably, the polyurethane is a foam, especially a flexible foam and most especially flexible slabstock foam.
摘要翻译：包括制备（（新碳基）对比卤素取代的）磷酸盐的方法，包括使（1）三卤化磷与新碳酸氢盐连续接触; （2）环氧乙烷; （3）卤化剂; 和（4）环氧乙烷，在足以制备（（新碳基）对比卤代取代的）磷酸盐的条件下。磷酸盐可以是非常纯的。还包括改善阻燃聚氨酯的生产特性的方法。特征可以选自（1）加工性; （2）焦烧; （3）气味; （4）阻燃效率; 和（5）其组合。该方法包括在足以改善所述特性的条件下将有效降低前述磷酸酯阻燃剂的可燃性的量掺入聚氨酯中。还包括所述方法的阻燃聚氨酯组合物。优选地，聚氨酯是泡沫，特别是柔性泡沫，最特别是柔性块状泡沫。

8. 发明授权

US4607063A Novel primary hydroxyl-containing phosphono-s-triazines as reactants in the production of polyurethanes 失效
标题翻译：新型含羟基的膦酰基 - 三嗪作为聚氨酯生产中的反应物
公开(公告)号：US4607063A
公开(公告)日：1986-08-19
申请号：US764032
申请日：1985-08-09
申请人： Chester E. Pawloski , Sally P. Ginter
发明人： Chester E. Pawloski , Sally P. Ginter
IPC分类号： C07F9/6521 , C08G18/38 , C08G18/14
CPC分类号： C08G18/3889 , C07F9/65216
摘要： The invention is phosphono-s-triazines corresponding to the formula ##STR1## wherein: X is separately in each occurrence chlorine, bromine, haloalkyl or alkyl;Y is separately in each occurrence hydrogen, chlorine or bromine;R is separately in each occurrence hydrogen, hydrocarbyl, CH.sub.2 Y, CH.sub.2 OH or CH.sub.2 OC(R.sup.1).sub.3 wherein R.sup.1 is alkyl;a is an integer from 0 to 2 inclusive; andb is an integer from 1 to 3 inclusive, with the proviso that the sum of a and b equal 3, and with the further proviso that at least one R is CH.sub.2 OH or CH.sub.2 OC(R.sup.1).sub.3.
摘要翻译：本发明是对应于下式的膦酰基-s-三嗪：其中：X在每次出现时分别为氯，溴，卤代烷基或烷基; Y在每次出现时分别是氢，氯或溴; R各自独立地为氢，烃基，CH 2 Y，CH 2 OH或CH 2 OC（R 1）3，其中R 1为烷基; a是0到2的整数; b为1〜3的整数，条件是a和b之和等于3，另外条件是至少一个R为CH 2 OH或CH 2 OC（R 1）3。

9. 发明授权

US4451653A Heterocyclic substituted triazolyl phosphorous compounds 失效
标题翻译：杂环取代的三唑基磷化合物
公开(公告)号：US4451653A
公开(公告)日：1984-05-29
申请号：US440934
申请日：1982-11-12
申请人： Chester E. Pawloski
发明人： Chester E. Pawloski
IPC分类号： A01N57/08 , C07D213/77 , C07D249/12 , C07F9/6518 , C07F9/6558 , C07D237/30 , C07D241/10
CPC分类号： C07D213/77 , A01N57/08 , C07F9/65185 , C07F9/65583
摘要： Compounds are prepared which correspond to the formulae ##STR1## wherein R represents a nitrogen containing heterocyclic radical corresponding to one of the formulae ##STR2## each X independently represents chloro, fluoro, bromo, nitro, alkyl of 1 to 4 carbon atoms, amino, mono- or dialkylamino wherein each alkyl group independently contains from 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkylsulfinyl of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, cyano, trifluoromethyl, trichloromethyl, phenoxy or substituted phenoxy of the formula ##STR3## wherein each Z independently represents chloro, fluoro, bromo, nitro, cyano, alkoxy of 1 to 4 carbon atoms or alkylthio of 1 to 4 carbon atoms, with the proviso that when either n is 2 or 3, all X groups are sterically compatible with each other and all Z groups are sterically compatible with each other; Y represents oxygen or sulfur; each n can independently represent an integer of from 0 to 3, inclusive; R.sup.1 represents hydrogen, chloro, fluoro, bromo, alkyl of 1 to 4 carbon atoms, cycloalkyl of 3-6 carbon atoms, phenyl, phenylthio, alkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkylsulfinyl of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, thiocyanato, trifluoromethyl, trichloromethyl, amino, mono- and dialkylamino wherein each alkyl group independently contains from 1 to 4 carbon atoms; R.sup.2 represents methyl, ethyl, propyl or isobutyl and R.sup.3 represents methoxy, ethoxy, propoxy, ethyl, mono- or dialkylamino wherein each alkyl group independently contains from 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms or phenyl.
摘要翻译：制备符合下式的化合物：其中R表示与下式之一相对应的含氮杂环基，每个X独立地表示氯，氟，溴，硝基，1至4个碳原子的烷基，氨基，单 - 或二烷基氨基，其中每个烷基独立地含有1至4个碳原子，1至4个碳原子的烷氧基，1至4个碳原子的烷硫基，1至4个碳原子的烷基亚磺酰基 1至4个碳原子的烷基磺酰基，氰基，三氟甲基，三氯甲基，苯氧基或取代的苯氧基，其中每个Z独立地表示氯，氟，溴，硝基，氰基，1-4个碳原子的烷氧基或烷硫基具有1至4个碳原子，条件是当n为2或3时，所有X基彼此在空间上相容，并且所有Z基彼此在空间上相容; Y表示氧或硫; 每个n可以独立地表示0至3的整数，包括0和3; R 1表示氢，氯，氟，溴，1至4个碳原子的烷基，3-6个碳原子的环烷基，苯基，苯硫基，1至4个碳原子的烷氧基，1至4个碳原子的烷硫基，1至 4个碳原子，1至4个碳原子的烷基磺酰基，硫氰酸酯，三氟甲基，三氯甲基，氨基，单 - 和二烷基氨基，其中每个烷基独立地含有1至4个碳原子; R 2表示甲基，乙基，丙基或异丁基，R 3表示甲氧基，乙氧基，丙氧基，乙基，单 - 或二烷基氨基，其中各烷基独立地含有1至4个碳原子，1至4个碳原子的烷硫基或苯基。

10. 发明授权

US4418198A Substituted pyridine carbonyl amino ethyl esters of 2-methyl-2-propenoic acid 失效
标题翻译：取代的2-甲基-2-丙烯酸的吡啶羰基氨基乙酯
公开(公告)号：US4418198A
公开(公告)日：1983-11-29
申请号：US321356
申请日：1981-11-16
申请人： Chester E. Pawloski
发明人： Chester E. Pawloski
IPC分类号： A01N47/12 , A01N47/18 , A01N47/36 , C07D213/64 , C07D213/65 , C07D213/68 , C07D213/70
CPC分类号： C07D213/64 , A01N47/12 , A01N47/18 , A01N47/36 , C07D213/65 , C07D213/68 , C07D213/70
摘要： The invention is directed to the novel 2-(((substituted pyridinyl)carbonyl)amino)ethyl esters of 2-methyl-2-propenoic acid and their method of preparation. The compounds are prepared by reacting an appropriately substituted pyridinol, pyridinethiol, aminopyridine, or hydroxyalkyloxypyridine with isocyanatoethyl methacrylate in an appropriate solvent in the presence of an activating agent. These compounds may be utilized as herbicides, fungicides, or both.
摘要翻译：本发明涉及2-甲基-2-丙烯酸的新型2 - （（（取代吡啶基）羰基）氨基）乙酯及其制备方法。通过使适当取代的吡啶酚，吡啶硫醇，氨基吡啶或羟基烷氧基吡啶与甲基丙烯酸异氰酸根合乙酯在合适的溶剂中，在活化剂的存在下反应制备化合物。这些化合物可以用作除草剂，杀真菌剂或两者。

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