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    • 32. 发明授权
    • Monoazo compounds containing long-chain alkyl radicals
    • 含有长链烷基的单偶氮化合物
    • US4997920A
    • 1991-03-05
    • US405612
    • 1989-09-11
    • Stefan HariOlof WallquistJost von der Crone
    • Stefan HariOlof WallquistJost von der Crone
    • C07D239/88C07C245/06C07C245/10C07C255/65C07D235/26C07D263/58C07D265/36C07D277/82C08K5/00C08K5/23C08K5/34C08K5/35C08K5/46C09B29/01C09B29/20C09B29/33C09B67/20
    • C08K5/23C08K5/0041C09B29/0003C09B29/20C09B29/337C09B29/338
    • Compounds of the formulae I and II ##STR1## in which A is a radical of the formulae III, IV or V ##STR2## R.sub.1 and R.sub.4 are --H or --Cl, R.sub.2 and R.sub.5 are --H, halogen, --NO.sub.2, --CN, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 alkoxy, --CF.sub.3 or phenyloxy which is unsubstituted or substituted by one or two chlorine atoms and/or one or two methyl or methoxy groups, and R.sub.3 is alkyl having at least 10 C atoms, X is a radical of the formulae --NH--, --O--, ##STR3## n is the number 1 or 2, Y is the radical of the formulae --COO--, --OOC--, --CONH-- or --NHCO-- or a radical of the formulae ##STR4## in which R.sub.1 and R.sub.2 are as defined above, D is an aromatic heterocyclic 5- or 6-membered ring, in which the ring contains 1 or 2 N atoms and may additionally contain an O atom or S atom, Z is --H, --Br, --OCH.sub.3, --CN or --NO.sub.2 and X.sub.1 and X.sub.2, independently of one another, are --H, halogen, --CH.sub.3, --OCH.sub.3, --OC.sub.2 H.sub.5 or --NO.sub.2 and X.sub.3 is --H, --NHCO--C.sub.1 -C.sub.4 alkyl, benzoylamino or phenylcarboxamide which are each unsubstituted or substituted on the phenyl ring by one or two chlorine atoms and/or one or two methyl or methoxy groups or an --NHCO--C.sub.1 -C.sub.4 alkyl group, or X.sub.2 and X.sub.3 together with the carbon atom to which they are bound are an aromatic carbocyclic 6-membered ring or an aromatic heterocyclic 5- or 6-membered ring, in which the heterocyclic ring contains 1 or 2 N atoms and can additionally have an O atom or S atom, and Y.sub.1 is --H, --OCH.sub.3, --OC.sub.2 H.sub.5 or --NHCOCH.sub.3, with the proviso that X.sub.3 must not be H, if X is --O-- or --NH--, are highly suitable for the mass coloration of plastics, in particular of polyolefins.
    • 其中A是式III,IV或V的基团,其中A是式(I)的化合物,其中A是式III,IV或V的基团(III) (V)R 1和R 4是-H或-Cl,R 2和R 5是-H,卤素,-NO 2,-CN,C 1 -C 4 - 烷基,C 1 -C 4烷氧基,-CF 3或苯氧基,其未被取代或被 一个或两个氯原子和/或一个或两个甲基或甲氧基,并且R 3是具有至少10个C原子的烷基,X是式-NH-,-O-, 的基团 > + TR n是数字1或2,Y是式-COO-,-OOC-,-CONH-或-NHCO-的基团或式(IMAGE)+ TR 其中R1和R2如上定义,D是芳族杂环的5或6元环,其中环含有1或2个N原子,并且可以另外含有O原子或S原子,Z是-H, - Br,-OCH 3,-CN或-NO 2,X 1和X 2彼此独立地是-H,卤素,-CH 3,-OCH 3,-OC 2 H 5或-NO 2,X 3是-H,-NHCO-C 1 -C 4烷基, 苯甲酰氨基或苯基 甲酰胺,其各自未被取代或在苯环上被一个或两个氯原子和/或一个或两个甲基或甲氧基或-NHCO-C 1 -C 4烷基取代,或X 2和X 3与它们所在的碳原子一起 结合的是芳族碳环6元环或芳族杂环5或6元环,其中杂环含有1或2个N原子,并且可以另外具有O原子或S原子,Y 1是-H, - OCH 3,-OC 2 H 5或-NHCOCH 3,条件是如果X为-O-或-NH-,则X3不能为H,高度适用于塑料,特别是聚烯烃的大量着色。