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    • 32. 发明授权
    • Carbon fiber prepreg, and a production process thereof
    • 碳纤维预浸料及其制造方法
    • US06117551A
    • 2000-09-12
    • US125124
    • 1998-08-11
    • Hideo NagataNobuyuki OdagiriTakeshi TerashitaHajime KishiShoji Yamane
    • Hideo NagataNobuyuki OdagiriTakeshi TerashitaHajime KishiShoji Yamane
    • B29B11/16B29B15/10C08J5/24C08L63/00B32B5/16B32B9/06B32B31/20
    • C08J5/24B29B15/105C08L63/00B29K2307/00C08J2363/00C08J2477/00C08J2481/06Y10T428/24994Y10T428/254Y10T428/30Y10T428/31511Y10T428/31551
    • The present invention relates to a carbon fiber prepreg. The carbon fiber prepreg of the present invention is characterized in that a carbon fiber bundle comprising a plurality of continuous carbon filaments and having a hook drop value of 10 cm or more as the degree of fiber entanglement is impregnated with a base resin mainly composed of a thermosetting resin, and that particles of 150 .mu.m or less in particle size made of a thermoplastic resin account for 20 wt % or less based on the weight of the entire prepreg and distributed at a higher concentration in the surface zone than in the inside. The carbon fiber prepreg of the present invention is good in tackiness and less changing in tackiness with the lapse of time, and can form a composite with an excellent compression interlaminar shear strength (CILS) at high temperature after moisture absorption while maintaining good impact resistance. It also allows the production of a composite very higher than the conventional composite in the compressive strength (LCS) of a cross laminated panel. The carbon fiber prepreg of the present invention can be preferably used as a structural member in such areas as aerospace area, sporting area and civil engineering and architecture area.
    • PCT No.PCT / JP97 / 04642 Sec。 371日期:1998年8月11日 102(e)日期1998年8月11日PCT 1997年12月16日PCT公布。 第WO98 / 26912号公报 日期:1998年6月25日本发明涉及一种碳纤维预浸料。 本发明的碳纤维预浸料的特征在于,将包含多个连续碳纤丝并且具有10cm以上的钩滴值作为纤维缠结度的碳纤维束浸渍在主要由 热可塑性树脂,由热塑性树脂制成的粒径为150μm以下的粒子相对于整个预浸料坯的重量为20重量%以下,分散在表面区域的浓度高于内部。 本发明的碳纤维预浸料随着时间的推移粘合性和粘合性变化小,能够在保持良好的耐冲击性的同时,在高温下形成具有优异的压缩层间剪切强度(CILS)的复合体。 它还允许在交叉层压板的抗压强度(LCS)中生产比常规复合材料高得多的复合材料。 本发明的碳纤维预浸料可以优选用作航空航天领域,体育用地,民用建筑领域等的结构构件。
    • 35. 发明授权
    • Cellular intumescent materials
    • 蜂窝膨胀材料
    • US4324835A
    • 1982-04-13
    • US143522
    • 1980-04-24
    • Christopher V. Keen
    • Christopher V. Keen
    • C08J9/42B32B3/02B32B5/20B32B7/02
    • C08J9/42C08J2421/00C08J2427/00C08J2429/00C08J2433/00C08J2461/00C08J2467/00C08J2477/00Y10S428/921Y10T428/249954Y10T428/249958
    • A cellular intumescent material comprising a substantially open-called substrate impregnated with a flexible intumescent polymer. The open-celled nature of the substrate is retained. The substrate may be a latex or urethane-based foam, a natural rubber or a synthetic rubber. The impregnant comprises at least a binder (A) and an intumescent component (B).The binder (A) can be a polyester, a liquid polymer system, a resin, a latex or an elastomer solution.The intumescent component (B) consists of a carbonific element (e.g. starch, sugar, sorbitol or pentaerythritol, or a compound which can polymerize to a "ladder" structure) and a spumific element (e.g. an inorganic acid or a precursor therefor).On exposure to a flame the materials flame initially but form a protective char and subsequently extinguish. The char prevents further burning of the treated material.
    • 一种细胞膨胀材料,其包含浸渍有柔性膨胀聚合物的基本上开放的基底。 保留基底的开孔性质。 基材可以是胶乳或聚氨酯基泡沫,天然橡胶或合成橡胶。 浸渍剂至少包含粘合剂(A)和膨胀组分(B)。 粘合剂(A)可以是聚酯,液体聚合物体系,树脂,胶乳或弹性体溶液。 膨胀性组分(B)由碳质元素(例如淀粉,糖,山梨糖醇或季戊四醇,或可以与“梯”结构聚合的化合物)和疏水性元素(例如无机酸或其前体)组成。 在暴露于火焰中,材料最初起火,但形成保护性炭,随后熄灭。 炭防止处理过的材料的进一步燃烧。
    • 39. 发明授权
    • Textile
    • 纺织品
    • US3053609A
    • 1962-09-11
    • US79481359
    • 1959-02-24
    • DU PONT
    • MILLER RICHARD A
    • A01G9/24C08J7/04C08L63/00D04H1/54D06M20060101D06M13/372D06M13/385D06M15/37D06M15/55D06M23/00D06M23/06
    • A01G9/241C08J7/047C08J7/08C08J2323/06C08J2477/00C08L63/00D04H1/54D06M13/372D06M13/385D06M15/37D06M15/55D06M23/00D06M23/06Y02A40/268Y10S8/04Y10S8/09Y10S8/10Y10S8/21Y10T428/2915Y10T428/2967Y10T428/2969C08L2666/22
    • A composition for application to hydrophobic shaped structures to reduce the accumulation of static electricity thereon, comprises a mixture of a polyepoxide and a polyamine of the formula H[-X-CH2-CH2(OCH2 OCH2)m-O-R-O-(CH2 CH2 O)n-CH2.CH2]p-X-H where -R- is a divalent radical, -X- is a divalent radical derived from an amine, in which at least one free valency is directly attached to the nitrogen atom of the amine, m and n are whole numbers from 3 to 40 inclusive and p is an integer not greater than 10, or a polyamine of the formula H[-X1-CH2 CH2-(OCH2 CH2)q-OCH2 CH2]p -X1-H, where X1 is R1 being hydrogen or an alkyl or amino alkyl radical containing less than 8 carbon atoms in its longest chain, -Y- being a divalent aliphatic hydrocarbon radical which may contain aza linkages, q an integer from 6 to 40 inclusive and p an integer not greater than 10. The preparation of the polyamines by reacting a polyethylene glycol dihalide with an amine, e.g. methylamine, ethylamine, propylamine, butylamine, amylamine, hexylamine, dodecylamine, allylamine, monoethanolamine, 3-isopropyl-n-propylamine, 3-methoxy-n-propylamine, diethylene triamine, hexamethylene diamine, bis(3-amino propyl)-amine, bis(2-amino propyl)amine, triethylene tetramine and tetraethylene pentamine is described in Belgian Specifications 554,506 and 560,446. Specified hydrophobic shaped structures are foams, fibres, filaments, yarns or fabrics of polyamides, acrylonitrile polymers or polyesters, the compositions being preferably applied to the substrate in emulsified form and cured thereon. The examples disclose the reaction of polyamines derived from diethylene triamine and the dichloride of polyethylene glycol and methylamine and the dichloride of polyethylene glycol, with polyepoxides derived from glycerin and epichlorohydrin; alkylphenoxypolyoxyethanol, glyceryl mono oleate and glycidyl methacrylate; and 1 :3-bis[3-(2 :3-epoxy-propoxy) propyl] tetramethyldisiloxane, curing being effected in the presence of zinc fluoroborate. Specifications 578,079, 586,796, 586,881, 765,585 and 780,288 also are referred to.ALSO:A process for reducing the accumulation of static electricity on synthetic hydrophobic shaped structures, comprises applying thereto a mixture of a polyepoxide and a polyamine of the formula where -R- is a divalent radical, -X- is a divalent radical derived from an amine, in which at least one free valency is directly attached to the nitrogen atom of the amine, m and n are whole numbers from 3 to 40 inclusive and p is an integer not greater than 10, or a polyamine of the formula H[-X1-CH2CH2-(OCH2CH2) q-O-CH2CH2]p-X1-H where X1 is R1 being hydrogen or an alkyl or aminoalkyl radical containing less than 8 carbon atoms in its longest chain, -Y- being a divalent aliphatic hydrocarbon radical which may contain aza linkages, q an integer from 6 to 40 inclusive and p an integer not greater than 10. Specified hydrophobic shaped structures are fibres, filaments, yarns or fabrics of polyamides, acrylonitrile polymers and polyesters. In the examples, polyethylene terephthalate fabrics, polyacrylonitrile fabrics, polyhexamethylene adipamide fabrics and tows of polyacrylonitrile fabrics are coated with compositions containing polyamines derived from the dichloride of polyethylene glycol and diethylene triamine or methylamine, polyepoxides derived glycerin and epichlorohydrin or alkyl phenoxy polyoxyethanol, glyceryl monooleate and glycidyl methacrylate or with 1:3-bis[3-(2:3-epoxy-propoxy)propyl]-tetramethyl disiloxane, curing being effected in the presence of zinc fluoroborate. Specifications 578,079, 586,796, 586,881, 765,585 and 780,288 are referred to.