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    • 37. 发明授权
    • Aqueous dispersion composition and production thereof
    • 水分散体组合物及其制备
    • US5461102A
    • 1995-10-24
    • US88010
    • 1993-07-06
    • Toshiyuki MasudaTakanori HatanoNaotami Ando
    • Toshiyuki MasudaTakanori HatanoNaotami Ando
    • C08F2/24C08F30/08C08F275/00C08L13/02
    • C08F30/08C08F275/00
    • A monomer mixture (B) containing a vinyl monomer having a functional silyl group of the general formula (ii) is subjected to emulsion polymerization in an aqueous solution of a water-soluble resin (A) having a functional silyl group of the general formula (i) the water-soluble resin [A] is synthesized using, as a polymerization solvent, a water-soluble organic solvent containing a (poly)ethylene glycol monoalkyl ether of the general formula HO--(CH.sub.2 CH.sub.2 O).sub.n --R.sup.3 or a (poly)propylene glycol monoalkyl ether of the general formula HO--(C.sub.3 H.sub.6 O).sub.n --R.sup.4 ; ##STR1## wherein R.sup.1 and R.sup.2 each independently is a monovalent group selected from the class consisting of alkyl groups containing 1 to 10 carbon atoms, aryl groups and aralkyl groups, X is a group selected from the class consisting of halogen atoms, alkoxy groups, a hydroxy group, acyloxy groups, an aminoxy group, a phenoxy group, thioalkoxy groups and an amino group, a and b each independently is an integer of 0 to 2, R.sup.3 and R.sup.4 each is an alkyl group containing 1 to 10 carbon atoms and n is an integer of 1 to 10 and wherein, when two or more R.sup.1 and/or R.sup.2 or X groups are bound to Si, they respectively may be the same or different.
    • 将含有具有通式(ii)的官能甲硅烷基的乙烯基单体的单体混合物(B)在具有通式(II)的官能甲硅烷基的水溶性树脂(A)的水溶液中进行乳液聚合, i)水溶性树脂[A]使用含有通式HO-(CH 2 CH 2 O)n -R 3((多))乙二醇单烷基醚或(聚 )通式HO-(C 3 H 6 O)n -R 4的丙二醇单烷基醚; (i)其中R 1和R 2各自独立地是选自由含有1至10个碳原子的烷基,芳基和芳烷基组成的类中的一价基团,X是选自 由卤素原子,烷氧基,羟基,酰氧基,氨氧基,苯氧基,硫代烷氧基和氨基组成的类别,a和b各自独立地为0〜2的整数,R3和R4分别为 含有1至10个碳原子的烷基,n是1至10的整数,并且其中当两个或多个R 1和/或R 2或X基团与Si结合时,它们可以相同或不同。
    • 38. 发明授权
    • Process for preparing alkoxysilane
    • 制备烷氧基硅烷的方法
    • US5391797A
    • 1995-02-21
    • US220594
    • 1994-03-31
    • Toshifumi HiroseKatsuya OuchiHiroshi Awaji
    • Toshifumi HiroseKatsuya OuchiHiroshi Awaji
    • C07F7/18C07F7/08
    • C07F7/1832C07F7/1868C07F7/1876C07F7/1888
    • A process for preparing an alkoxysilane of the general formula:R.sup.3.sub.b SiH.sub.c (OR.sup.2).sub.4-(b+c)in which R.sup.2 represents a substituted or unsubstituted alkyl group, R.sup.3 represents a monovalent substituted or unsubstituted hydrocarbon group, b is 1, 2 or 3, and c is 0, 1, or 2, having the step of:reacting an alkoxysilane of the general formula:R.sup.1.sub.a Si(OR.sup.2).sub.4-a wherein R.sup.1 represents a monovalent substituted or unsubstituted hydrocarbon group, R.sup.2 is the same as defined above, and a is 0, 1, 2 or 3, with a polysiloxane in the presence of a catalyst containing an aluminum alkoxide, a zirconium alkoxide or a zirconium chelate to obtain the alkoxysilane, which process suppresses side reactions to provide the intended compound which is free from halogen compounds in a high yield.
    • 制备通式R3bSiHc(OR2)4-(b + c)的烷氧基​​硅烷的方法,其中R2表示取代或未取代的烷基,R3表示一价取代或未取代的烃基,b为1,2或3 并且c为0,1或2,具有如下步骤:使通式为R1aSi(OR2)4-a的烷氧基硅烷反应,其中R1表示一价取代或未取代的烃基,R2与上述定义相同, 和a为0,1,2或3,在含有烷氧基铝,锆醇盐或锆螯合物的催化剂的存在下,聚硅氧烷获得烷氧基硅烷,该方法抑制副反应以提供无定形化合物 从卤素化合物中获得高产率。
    • 40. 发明授权
    • Process for suspension polymerization
    • 悬浮聚合方法
    • US5276113A
    • 1994-01-04
    • US938515
    • 1992-09-02
    • Yoshiyuki HashiguchiMasakiti KishiTakehiko Yagyu
    • Yoshiyuki HashiguchiMasakiti KishiTakehiko Yagyu
    • B01J4/04B01J19/18C08F2/18
    • B01J4/04B01J19/1862B01J19/1881C08F2/18B01J2219/00103B01J2219/0011B01J2219/00164B01J2219/182
    • There is provided a suspension polymerization process for production of polymer particles having a substantially uniform size, which process comprises the steps of: (a) applying regular vibration to a flow of a monomer liquid which has a specific gravity smaller than that of an aqueous dispersion medium, (b) introducing the aqueous dispersion medium containing the droplets in a first reactor comprising a recycling means which discharges the aqueous dispersion medium from the bottom of the reactor and recycles it to the top of the reactor, (c) partially polymerizing the monomer liquid in the first reactor so that the specific gravity of the droplets does not exceed that of the aqueous dispersion medium while maintaining the suspended condition of the droplets, and (d) discharging the partially polymerized droplets together with the aqueous dispersion medium from a lower portion of the first reactor and introducing them in a second reactor, and (e) further polymerizing the partially polymerized droplets in the second reactor.
    • 提供了一种用于生产具有基本均匀尺寸的聚合物颗粒的悬浮聚合方法,该方法包括以下步骤:(a)对比重小于水分散体的比重的单体液体的流动施加规则的振动 介质,(b)将含有液滴的水性分散介质引入第一反应器,该第一反应器包括从反应器底部排出水分散介质并将其再循环到反应器顶部的再循环装置,(c)将单体部分聚合 液体在第一反应器中,使得液滴的比重不超过水分散介质的比重,同时保持液滴的悬浮状态,并且(d)将部分聚合的液滴与水分散介质一起从下部排出 的第一反应器并将其引入第二反应器,和(e)进一步聚合部分聚合物 在第二反应器中精馏液滴。