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    • 36. 发明授权
    • O-acyloxime photoinitiators
    • O-酰基肟光引发剂
    • US06596445B1
    • 2003-07-22
    • US09338152
    • 1999-06-23
    • Akira MatsumotoHidetaka OkaMasaki OhwaHisatoshi KuraJean-Luc BirbaumKurt Dietliker
    • Akira MatsumotoHidetaka OkaMasaki OhwaHisatoshi KuraJean-Luc BirbaumKurt Dietliker
    • C07C25164
    • C07C251/66B33Y70/00C07C251/68C07C323/47C07D295/135C07D335/18C08F2/50G03F7/0007G03F7/002G03F7/0045G03F7/031G03F7/0388
    • Oximeester compounds of the formulae I, II, III and IV wherein R1 is phenyl, C1-C20alkyl or C2-C20alkyl optionally interrupted by —O—, C2-C20alkanoyl or benzoyl, or R1 is C2-C12alkoxycarbonyl or phenoxycarbonyl; R1′ is C2-C12alkoxycarbonyl, or R1′ is phenoxycarbonyl, or R1′ is —CONR10R11 or CN; R2 is C2-C12alkanoyl, C4-C6alkenoyl, benzoyl, C2-C6alkoxycarbonyl or phenoxycarbonyl; R3, R4, R5, R6 and R7 are hydrogen, halogen, C1-C12alkyl, cyclopentyl, cyclohexyl, phenyl, benzyl, benzoyl, C2-C12alkanoyl, C2-C12alkoxycarbonyl, phenoxycarbonyl or a group OR8, SR9, SOR9, SO2R9 or NR10R11; R4′, R5′ and R6′ are hydrogen, halogen, C1-C12alkyl, cyclopentyl, cyclohexyl, phenyl, benzyl, benzoyl, C2-C12-alkanoyl, C2-C12alkoxycarbonyl, phenoxycarbonyl, or are a group OR8, SR9, SOR9, SO2R9, NR10R11; provided that at least one of R3, R4, R5, R6, R7, R′4, R′5 and R′6 is OR8, SR9 or NR10R11; R8, R9, R10 and R11 are for example hydrogen, C1-C12alkyl, phenyl; are suitable as initiators for the photopolymerization of radically polymerizable compounds.
    • 式I,II,III和IV其中R 1的肟酯化合物是苯基,任选被-O - ,C 2 -C 20烷酰基或苯甲酰基中断的C 1 -C 20烷基或C 2 -C 20烷基,或者R 1是C 2 -C 12烷氧基羰基或苯氧基羰基; R1'是C2-C12烷氧基羰基,或R1'是苯氧基羰基,或R1'是-CONR10R11或CN; R2是C2-C12烷酰基,C4-C6链烯酰基,苯甲酰基,C2-C6烷氧基羰基或苯氧基羰基; R3,R4,R5,R6和R7是氢,卤素,C1-C12烷基,环戊基,环己基,苯基,苄基,苯甲酰基,C2-C12烷酰基,C2-C12烷氧基羰基,苯氧基羰基或OR8,SR9,SOR9,SO2R9或NR10R11; R4',R5'和R6'为氢,卤素,C1-C12烷基,环戊基,环己基,苯基,苄基,苯甲酰基,C2-C12-烷酰基,C2-C12烷氧基羰基,苯氧基羰基,或为OR8,SR9,SOR9,SO2R9 ,NR10R11; 条件是R3,R4,R5,R6,R7,R'4,R'5和R'6中的至少一个是OR8,SR9或NR10R
    • 37. 发明授权
    • Organosilyl radical generators and their applications
    • 有机硅自由基发生器及其应用
    • US06489081B1
    • 2002-12-03
    • US09726684
    • 2000-11-30
    • Akira MatsumotoYoshihiko Ito
    • Akira MatsumotoYoshihiko Ito
    • C07F502
    • G03F7/029B33Y70/00C07F7/0803
    • Compounds of formula I wherein R1, R2, and R3 independently of one another are hydrogen; C1-C20alkyl which is unsubstituted or substituted by OH, C1-C4alkoxy, C1-C4alkylthio, phenylthio, F, Cl, Br, I, CN, (C1-8alkyl)O—(CO)—, (C1-C4alkyl)—(CO)O— or/and di(C1-C4alkyl)amino; or R1, R2, and R3 independently of one another are C3-C6alkenyl; phenyl which is unsubstituted or substituted by OH, C1-C4alkoxy, C1-C4alkylthio, phenylthio, F, Cl, Br, I, CN, (C1-C8alkyl)O(CO)—, (C1-C4alkyl)—(CO)O— or/— and di(C1-C4alkyl)amino; or R1 and R2 together are C2-C9alkylene, o-xylylene, 2-butenylene, C3-C9oxaalkylene or C3-C9azaalkylene; R4, R5, R6, and R7 independently of one another are sec-C3-C20alkyl, tert-C4-C20alkyl or phenyl wherein these radicals are unsubstituted or substituted by OH, C1-C4alkoxy, C1-C4alkylthio, phenylthio, F, Cl, Br, I, CN, (C1-C8alkyl)O(CO)—, (C1-C4alkyl)—(CO)O— or/and di(C1-C4alkyl)amino; or R4 and R5, and/or R6 and R7 together are C2-C9alkylene, o-xylylene, 2-butenylene, C3-C9oxaalkylene or C3-C9azaalkylene, or R4 and R6, and/or R5 and R7 together are branched C2-C9alkylene, o-xylylene, 2-butenylene, C3-C9oxaalkylene or C3-C9azaalkylene; are suitable as photoinitiators for the photopolymerization of unsaturated compounds.
    • R1,R2和R3彼此独立的式Ⅰ化合物是氢; 未被取代或被OH,C 1 -C 4烷氧基,C 1 -C 4烷硫基,苯硫基,F,Cl,Br,I,CN,(C 1-8烷基)O-(CO) - ,(C 1 -C 4烷基) - CO)O-或/和二(C 1 -C 4烷基)氨基; 或R 1,R 2和R 3彼此独立地为C 3 -C 6烯基; 苯基,未取代或被OH,C1-C4烷氧基,C1-C4烷硫基,苯硫基,F,Cl,Br,I,CN,(C1-C8烷基)O(CO) - ,(C1-C4烷基) - (CO) - 或 - 和二(C 1 -C 4烷基)氨基; 或者R 1和R 2一起是C 2 -C 9亚烷基,邻亚二甲苯基,2-亚丁烯基,C 3 -C 9亚烷基或C 3 -C 9氮杂亚烷基; R 4,R 5,R 6和R 7彼此独立地为C 1 -C 3烷基,C 4 -C 20烷基或苯基,其中这些基团未被取代或被OH,C 1 -C 4烷氧基,C 1 -C 4烷硫基,苯硫基,F,Cl, Br,I,CN,(C 1 -C 8烷基)O(CO) - ,(C 1 -C 4烷基) - (CO)O-或/和二(C 1 -C 4烷基) 或R 4和R 5,和/或R 6和R 7一起是C 2 -C 9亚烷基,邻亚二甲苯基,2-亚丁烯基,C 3 -C 9亚烷基或C 3 -C 9亚烷基,
    • 40. 发明授权
    • Disk recording/reproducing device
    • 磁盘记录/再现装置
    • US06330219B1
    • 2001-12-11
    • US09047524
    • 1998-03-25
    • Kenji UrushibaraAkira MatsumotoMakoto DoiIsamu Nakade
    • Kenji UrushibaraAkira MatsumotoMakoto DoiIsamu Nakade
    • G11B2300
    • G11B17/0282G11B17/028
    • A disk recording/reproducing device includes a power transmitting mechanism which transmits movement of a pickup while engaging with the pickup, and a disk retaining mechanism which, in response to the movement of the pickup transmitted by the power transmitting mechanism, retains a disk on a turntable or releases retention of the disk. Radially inward movement of the pickup causes the disk retaining mechanism to retain the disk on the turntable, while radially outward movement of the pickup causes the disk retaining mechanism to release retention of the disk. For accomplishing the release of the retention of the disk upon the radially outward movement of the pickup, an operation switching mechanism is provided for changing a position of the power transmitting mechanism to cause the power transmitting mechanism to engage with the pickup upon the radially outward movement of the pickup.
    • 磁盘记录/再现装置包括:电源传输机构,其在与拾取器接合的同时传送拾取器的运动;以及磁盘保持机构,其响应于由电力传输机构传送的拾取器的移动将磁盘保持在磁盘上 转盘或释放磁盘的保留。 拾取器的向内向内移动导致盘保持机构将盘保持在转台上,同时拾取器的径向向外移动使得盘保持机构释放盘的保持。 为了在拾取器的径向向外移动时实现盘的保持释放,提供了一种操作切换机构,用于改变动力传递机构的位置,以使得动力传递机构在径向向外移动时与拾取器接合 的皮卡。