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31. 发明授权

US5994479A Curable coating compositions containing blends of carbamate-functional compounds 失效
标题翻译：含有氨基甲酸酯官能化合物的混合物的可固化涂料组合物
公开(公告)号：US5994479A
公开(公告)日：1999-11-30
申请号：US997317
申请日：1997-12-23
申请人： Marvin L. Green , John D. McGee , Brian D. Bammel , Danielle A. Regulski , Walter H. Ohrbom
发明人： Marvin L. Green , John D. McGee , Brian D. Bammel , Danielle A. Regulski , Walter H. Ohrbom
IPC分类号： C08G18/40 , C08G18/80 , C09D5/02 , C09D5/03 , C09D161/20 , C09D175/00 , C09D201/02 , C08G8/28 , C08G59/14 , C08L63/00 , C08L67/04
CPC分类号： C09D161/20 , C08G18/8077 , C09D201/025 , Y10T428/31551
摘要： The present invention provides a curable coating composition comprising(a) a first component comprising at least two functional groups, at least one of which is a carbamate or urea group that is the reaction product of:(1) a hydroxyl group that is the result of a ring-opening reaction between an epoxy group and an organic acid group, and(2) cyanic acid or a carbamate or urea group;(b) a curing agent having a plurality of functional groups that are reactive with component (a), and(c) a second component having functional groups that are reactive with component (a) or component (b) or both components (a) and (b).
摘要翻译：本发明提供一种可固化涂料组合物，其包含（a）包含至少两个官能团的第一组分，其中至少一个为氨基甲酸酯或脲基，其为：（1）作为结果的羟基的反应产物的环氧基和有机酸基之间的开环反应，和（2）氰酸或氨基甲酸酯或脲基; （b）具有多个与组分（a）反应的官能团的固化剂，和（c）具有与组分（a）或组分（b）或两种组分（a）反应的官能团的第二组分）和（b）。

32. 发明授权

US5827931A Polyurethane polymer or oligomer having carbamate groups, method for its preparation, and coating composition 失效
公开(公告)号：US5827931A
公开(公告)日：1998-10-27
申请号：US950950
申请日：1997-10-15
申请人： Gregory L. Menovcik , Walter H. Ohrbom
发明人： Gregory L. Menovcik , Walter H. Ohrbom
IPC分类号： C08G18/08 , C08G18/32 , C08G18/38 , C08G18/46 , C08G18/66 , C08G18/80 , C08G71/00 , C08G71/04 , C09D175/00 , C09D175/04 , C09D201/02 , C08G18/28
CPC分类号： C09D201/025 , C08G18/0823 , C08G18/3831 , C08G18/6633 , C08G18/8077 , C09D175/04
摘要： Polyurethane polymers having pendant carbamate groups are disclosed. The polymers are prepared by: (a) reacting a mixture comprising a polyol having at least one pendant carbamate group and a polyisocyanate to form a polyurethane having pendant carbamate groups, and (b) optionally, capping the polyurethane from (b) with an active hydrogen-containing capping agent.

33. 发明授权

US5760127A Curable coating composition 失效
标题翻译：可固化涂料组合物
公开(公告)号：US5760127A
公开(公告)日：1998-06-02
申请号：US698526
申请日：1996-08-15
申请人： Brian D. Bammel , John D. McGee , Walter H. Ohrbom , Todd A. Seaver , Gregory G. Menovcik , Paul J. Harris , John W. Rehfuss
发明人： Brian D. Bammel , John D. McGee , Walter H. Ohrbom , Todd A. Seaver , Gregory G. Menovcik , Paul J. Harris , John W. Rehfuss
IPC分类号： C08G71/00 , C09D167/04 , C09D201/02 , C08J3/00 , B32B27/00 , C08K3/20 , C08L75/00
CPC分类号： C09D201/02 , C08G71/00 , C09D167/04 , C09D201/025 , Y10T428/31551
摘要： A curable coating composition is described comprising (A) a carbamate- or urea-functional compound that is the reaction product of a mixture comprising (1) a compound comprising a carbamate or urea group or a group that can be converted to carbamate or urea, and a hydroxyl functional group that is the reaction product of (a) a compound comprising a carbamate or urea group or a group that can be converted to a carbamate or urea group, and an active hydrogen group that is reactive with a lactone ring or a hydroxy carboxylic acid, and (b) a lactone or a hydroxy carboxylic acid, and (2) a compound that is reactive with hydroxyl groups on a plurality of molecules of compound (A)(1), but that is not reactive with the carbamate or urea groups on compound (A)(1), (B) a compound comprising a plurality of groups that are reactive with carbamate or urea.
摘要翻译：描述了可固化涂料组合物，其包含（A）氨基甲酸酯或脲官能化合物，其为包含（1）包含氨基甲酸酯或脲基团的化合物或可转化为氨基甲酸酯或脲的基团的混合物的反应产物，和作为（a）包含氨基甲酸酯或脲基的化合物或可以转化为氨基甲酸酯或脲基的基团的反应产物的羟基官能团以及与内酯环或羟基羧酸和（b）内酯或羟基羧酸，和（2）与多个化合物（A）（1）分子上的羟基反应但不与氨基甲酸酯反应的化合物或化合物（A）（1）上的脲基，（B）包含与氨基甲酸酯或脲反应的多个基团的化合物。

34. 发明授权

US5451656A Carbamate-functional polyester polymer or oligomer and coating composition 失效
公开(公告)号：US5451656A
公开(公告)日：1995-09-19
申请号：US361244
申请日：1994-12-21
申请人： Gregory L. Menovcik , Walter H. Ohrbom
发明人： Gregory L. Menovcik , Walter H. Ohrbom
IPC分类号： C08G12/32 , C08G63/685 , C09D167/00
CPC分类号： C08G63/6854
摘要： Polyester polymers having pendant carbamate groups are disclosed. The polymers are prepared by:(a) reacting a hydroxyalkyl cyclic carbonate with ammonia, ammonium hydroxide, or a primary amine to form a dihydric alcohol having a carbamate group appended thereto,(b) reacting the dihydric alcohol from (a) and a cyclic anhydride to form a half-ester diacid having a carbamate group appended thereto, and(c) reacting a mixture comprising the half-ester diacid from step (b) and a polyol to form a polyester having carbamate groups appended thereto.

35. 发明授权

US08686090B2 Use of urea crystals for non-polymeric coatings 有权
标题翻译：尿素晶体用于非聚合物涂层
公开(公告)号：US08686090B2
公开(公告)日：2014-04-01
申请号：US10732850
申请日：2003-12-10
申请人： Marvin L. Green , Swaminathan Ramesh , Walter H. Ohrbom
发明人： Marvin L. Green , Swaminathan Ramesh , Walter H. Ohrbom
IPC分类号： B01F17/00 , B05D3/02 , C08F283/00 , C08F283/02 , C08F283/04 , C08G6/02 , C08G8/28 , C08G12/42 , C08G18/00 , C08G18/08 , C08G18/28 , C08G18/42 , C08G18/67 , C08G18/83 , C08G63/08 , C08G63/44 , C08G63/91 , C08G65/32 , C08G67/02 , C08G69/00 , C08G69/44 , C08K5/00 , C08L51/00 , C08L61/00 , C08L61/02 , C08L63/00 , C08L67/00 , C08L67/02 , C08L69/00 , C08L71/00 , C08L75/00 , C08L77/00 , C08L79/00
CPC分类号： C09D175/02 , C08G18/2865 , C08G18/4615 , C09D201/025
摘要： The thermosetting, non-polymeric coating composition includes at least one monomeric material having a plurality of carbamate and/or urea groups, at least one crosslinker reactive with the at least one monomeric material, and a sag control agent that is a crystalline reaction product of an amine and an isocyanate.
摘要翻译：热固性非聚合物涂料组合物包括至少一种具有多个氨基甲酸酯和/或脲基团的单体材料，至少一种与至少一种单体材料反应的交联剂，以及一种下垂控制剂，其为下列物质的结晶反应产物：胺和异氰酸酯。

36. 发明申请

US20100298490A1 OLIGOMERS, METHODS OF MAKING THEM, COATING COMPOSITIONS CONTAINING THEM, AND CURED COATINGS 失效
标题翻译：低聚物，其制备方法，包含它们的涂料组合物和固化涂料
公开(公告)号：US20100298490A1
公开(公告)日：2010-11-25
申请号：US12469261
申请日：2009-05-20
申请人： Nicholas Caiozzo , Walter H. Ohrbom , David C. Cranfill
发明人： Nicholas Caiozzo , Walter H. Ohrbom , David C. Cranfill
IPC分类号： C08L75/04 , C08G18/10
CPC分类号： C08G18/3831 , C08G18/222 , C08G18/2815 , C08G18/3206 , C08G18/36 , C08G18/798 , C09D175/04 , C08L2666/16
摘要： An oligomer may be made by capping a uretdione compound of structure (I) wherein each R1 is independently selected from alkylene groups having 1 to 12 carbon atoms, arylene groups having 5 to 12 carbon atoms, and arylalkylene and alkylarylene groups having 6 to 15 carbon atoms, wherein alkylene groups, alkylene portions of arylakylene groups, and alkyl portions of alkylarylene groups may be linear, branched, or cyclic with a compound having an active hydrogen and having a carbamate group or cyclic carbonate group the reaction being carried out under conditions in which the isocyanate groups but not the uretdione group of compound (I) react to form a compound (III), the compound (III) then being reacted with a reactant having at least two active hydrogens selected from polyols, polyamines having at least two amine groups selected from primary and secondary amine groups, and aminoalcohols having at least one amine group that is a primary or secondary amine group to form a product that is an oligomer. Any cyclic carbonate groups may be converted to carbamate groups.Also disclosed is an oligomer comprising repeating monomer units of structures in which n is an integer from 1 to 4 and R1 is as previously defined.Also disclosed is a curable coating composition including at least one of the disclosed oligomers and at least one aminoplast resin crosslinker; a method of coating a substrate with the coating composition, a cured coating derived from the coating composition, and a coated substrate with the cured coating.
摘要翻译：低聚物可以通过将结构（I）的脲二酮化合物（其中每个R 1独立地选自具有1至12个碳原子的亚烷基，具有5至12个碳原子的亚芳基）和具有6至15个碳原子的芳基亚烷基和烷基亚芳基原子，其中亚烷基，亚烷基的亚烷基部分和烷基亚芳基的烷基部分可以是具有活性氢的化合物，具有氨基甲酸酯基或环状碳酸酯基的直链，支链或环状的反应，其条件是化合物（I）的异氰酸酯基团而不是脲二酮基团反应形成化合物（III），然后使化合物（III）与具有至少两个活性氢的反应物反应，所述活性氢选自多元醇，具有至少两个胺的多胺选自伯胺基和仲胺基团的基团和具有至少一个胺基团的氨基醇，其是伯胺基或仲胺基团，以形成为低聚物。任何环状碳酸酯基团可以转化为氨基甲酸酯基团。还公开了包含其中n为1至4的整数并且R 1如前所定义的结构的重复单体单元的低聚物。还公开了包含至少一种所公开的低聚物和至少一种氨基塑料树脂交联剂的可固化涂料组合物; 用涂料组合物涂布基材的方法，衍生自涂料组合物的固化涂料和具有固化涂层的涂布基材。

37. 发明申请

US20100022712A1 Coating Composition and Cured Film Formed Therefrom 审中-公开
标题翻译：涂料组合物和固化膜
公开(公告)号：US20100022712A1
公开(公告)日：2010-01-28
申请号：US12179936
申请日：2008-07-25
申请人： William H. Merritt , Nicholas Caiozzo , Sergio Balatan , Walter H. Ohrbom , Gregory G. Menovcik
发明人： William H. Merritt , Nicholas Caiozzo , Sergio Balatan , Walter H. Ohrbom , Gregory G. Menovcik
IPC分类号： C08L37/00
CPC分类号： C09D137/00 , C08L33/068 , C08L33/08 , C09D133/068 , C09D133/08 , C08L2666/02 , C08L2666/04
摘要： A coating composition comprises a first copolymer and a second copolymer. The first copolymer has at least one linear polymer strand having a weight average molecular weight of at least 1,500 Daltons and functionality X with an equivalent weight of no more than 500. The second copolymer has at least one linear polymer strand having a weight average molecular weight of at least 1,500 Daltons and functionality X′ with an equivalent weight of no more than 1,500. The coating composition is free of gloss flattening agents, yet still produces a cured film having a low gloss of less than 70 gloss units at an angle of incidence of 60°, as measured according to ASTM D 2457.
摘要翻译：涂料组合物包含第一共聚物和第二共聚物。第一共聚物具有至少一种直链聚合物链，其重均分子量为至少1,500道尔顿，官能度X为当量不大于500.第二共聚物具有至少一个线性聚合物链，其重均分子量至少1500道尔顿和功能X'，当量不超过1,500。涂料组合物没有光泽的平整剂，但仍然根据ASTM D 2457测量，仍然以60°的入射角产生具有小于70个光泽单位的低光泽度的固化膜。

38. 发明授权

US07022747B2 Method for creating microsphere polymers and particles 失效
标题翻译：制造微球聚合物和颗粒的方法
公开(公告)号：US07022747B2
公开(公告)日：2006-04-04
申请号：US10426110
申请日：2003-04-29
申请人： Thaddeus J. Lepkowski , Craig S. Schang , Walter H. Ohrbom
发明人： Thaddeus J. Lepkowski , Craig S. Schang , Walter H. Ohrbom
IPC分类号： C08F2/46
CPC分类号： C09D5/03 , C08F2/00 , Y10S204/902 , Y10T428/2982
摘要： A polymeric material is produced by atomizing into droplets a composition containing addition-polymerizable material and reacting the addition polymerizable material in the droplets to produce the particulate product. The polymeric product may be, for example, a powder coating composition.
摘要翻译：通过将包含可加成聚合材料的组合物雾化成液滴中的加成聚合材料并使该微粒产物反应来制备聚合物材料。聚合物可以是例如粉末涂料组合物。

39. 发明授权

US06992149B2 Use of carbamate-modified aminoplast resins to improve the appearance and performance of powder coatings 失效
标题翻译：使用氨基甲酸酯改性的氨基塑料树脂来改善粉末涂料的外观和性能
公开(公告)号：US06992149B2
公开(公告)日：2006-01-31
申请号：US10777301
申请日：2004-02-12
申请人： Walter H. Ohrbom , Thomas S. Richards , Timothy S. December , James A. Laugal
发明人： Walter H. Ohrbom , Thomas S. Richards , Timothy S. December , James A. Laugal
IPC分类号： C08L61/20 , C08G12/30
CPC分类号： C09D161/20 , C08G12/00 , C08G12/32 , C08G12/427 , C09D5/037
摘要： A powder coating composition comprising at least about 0.1% by weight of a reaction product of an aminoplast and a compound having one carbamate group has improved smoothness.
摘要翻译：包含至少约0.1重量％的氨基塑料和具有一个氨基甲酸酯基团的化合物的反应产物的粉末涂料组合物具有改善的平滑度。

40. 发明授权

US06812316B2 Powder coating compositions and powder slurry coating compositions containing monomeric difunctional compounds 失效
标题翻译：含有单体双官能化合物的粉末涂料组合物和粉末浆料涂料组合物
公开(公告)号：US06812316B2
公开(公告)日：2004-11-02
申请号：US10261427
申请日：2002-09-30
申请人： Walter H. Ohrbom , David J. Law , Robert D. Weise
发明人： Walter H. Ohrbom , David J. Law , Robert D. Weise
IPC分类号： C08G1881
CPC分类号： C09D133/14 , C09D5/02 , C09D5/033 , C09D201/00 , C09D201/02 , C09D201/025 , Y10S525/934
摘要： The curable coating compositions of the invention comprise a particulate component having at least one binder component (a) which is a solid at 75° F./24° C., and an additive component (b). The curable coating compositions further comprise a crosslinking component (c) reactive with the at least one binder component (a). Additive component (b) has from 12 to 72 carbon atoms, is substantially free of any heteroatoms, is not a crystalline solid at 75° F./24° C. and comprises a mixture of two or more structures selected from the group consisting of aliphatic structures for additive component (b), aromatic-containing structures for additive component (b), cycloaliphatic-containing structures for additive component (b), and mixtures thereof, wherein at least one of the two or more structures is either a cycloaliphatic-containing structure or an aromatic-containing structure. The curable coating compositions are useful as powder coating compositions and powder slurry coating compositions having improved application and/or performance properties.
摘要翻译：本发明的可固化涂料组合物包含具有至少一种在75°F / 24℃下为固体的粘合剂组分（a）和添加剂组分（b）的颗粒组分。可固化涂料组合物还包含与至少一种粘合剂组分（a）反应的交联组分（c）。添加剂组分（b）具有12至72个碳原子，基本上不含任何杂原子，在75°F / 24℃下不是结晶固体，并且包含两种或更多种选自以下的结构的混合物：用于添加剂组分（b）的脂族结构，用于添加剂组分（b）的含芳族化合物结构，用于添加剂组分（b）的含脂环族基团的结构）及其混合物，其中两种或多种结构中的至少一种是脂环族 - 含有结构或含芳香族结构。可固化涂料组合物可用作具有改进的应用和/或性能特性的粉末涂料组合物和粉末淤浆涂料组合物。

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