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31. 发明授权

US4530769A Process for separating carbon black from an aqueous suspension 失效
标题翻译：从水性悬浮液中分离炭黑的方法
公开(公告)号：US4530769A
公开(公告)日：1985-07-23
申请号：US479965
申请日：1983-03-29
申请人： Manfred Wolter , Friedrich-Wilhelm Dorn , Gero Heymer , Hans-Werner Stephan
发明人： Manfred Wolter , Friedrich-Wilhelm Dorn , Gero Heymer , Hans-Werner Stephan
IPC分类号： B01D25/12 , C09C1/48 , C10G31/09 , B01D29/10
CPC分类号： C09C1/487 , C01P2006/12
摘要： The disclosure relates to a process for the discontinuous separation of a solid consisting predominantly of carbon black from its aqueous suspension by filtration. To this end, the disclosure provides for use to be made of a tube pressure filter which is operated under a final pressure of 30 to 100 bars.
摘要翻译：本公开涉及通过过滤从其水悬浮液中主要由炭黑组成的固体的不连续分离的方法。为此，本公开提供了用于在30至100巴的最终压力下操作的管式压力过滤器的使用。

32. 发明授权

US4525333A Process for separating gallium and indium from aqueous solutions 失效
标题翻译：从水溶液中分离镓和铟的工艺
公开(公告)号：US4525333A
公开(公告)日：1985-06-25
申请号：US531156
申请日：1983-09-09
申请人： Gunther Schimmel , Gero Heymer , Werner Krause , Werner Pieper
发明人： Gunther Schimmel , Gero Heymer , Werner Krause , Werner Pieper
IPC分类号： C22B58/00 , C01G15/00 , C22B3/38
CPC分类号： C01G15/003 , C22B3/0067 , C22B3/0087 , Y02P10/234
摘要： The disclosure relates to a process for separating gallium and indium from an aqueous solution by subjecting this latter to liquid/liquid extraction with the use of certain classes of organylphosphonic acid esters and separating the resulting liquid phases from one another.
摘要翻译：本公开涉及通过使用后者使用某些种类的有机膦酸酯并将所得液相彼此分离来从水溶液中分离镓和铟的方法。

33. 发明授权

US4466948A Process for removing heavy metal ions and arsenic from wet-processed phosphoric acid 失效
标题翻译：从湿法处理的磷酸中去除重金属离子和砷的工艺
公开(公告)号：US4466948A
公开(公告)日：1984-08-21
申请号：US508272
申请日：1983-06-24
申请人： Gunther Schimmel , Reinhard Gradl , Gero Heymer
发明人： Gunther Schimmel , Reinhard Gradl , Gero Heymer
IPC分类号： C01B25/237 , C01B25/238 , C01G1/00 , C01G3/00 , C01G11/00 , C01G13/00 , C01G21/00 , C01G28/00 , C22B3/38 , C01B25/16 , B01D11/00 , B03C1/00 , C01G17/00
CPC分类号： C01G3/003 , C01B25/238 , C01G11/003 , C01G13/003 , C01G21/003 , C01G28/001 , C22B3/007 , C22B3/24 , Y02P10/234
摘要： The disclosure relates to a process for removing heavy metal ions and arsenic from wet-processed phosphoric acid, wherein the crude wet-processed phosphoric acid is treated at temperatures between 10.degree. and 100.degree. C. initially with a diorganyldithiosphosphoric acid ester and then with an adsorbent, and the phoshoric acid so purified is separated from the ester and adsorbent. More particularly, the wet-processed phosphoric acid is treated with the diorganyldithiophosphoric acid ester at temperatures higher than 50.degree. C. and with the adsorbent at temperatures lower than 50.degree. C.
摘要翻译：本公开涉及从湿法处理的磷酸中除去重金属离子和砷的方法，其中粗制湿法处理的磷酸最初用二有机基二硫代磷酸酯在10℃至100℃的温度下处理，然后用吸附剂，如此纯化的磷酸与酯和吸附剂分离。更具体地说，湿法处理的磷酸在二氧化二硫代磷酸酯的温度高于50℃下处理，吸附剂在低于50℃的温度下处理。

34. 发明授权

US4399114A Process for the dearsenification of polyphosphoric acid 失效
标题翻译：多磷酸脱砷方法
公开(公告)号：US4399114A
公开(公告)日：1983-08-16
申请号：US402941
申请日：1982-07-29
申请人： Alexander Maurer , Gero Heymer , Markus Erpenbach
发明人： Alexander Maurer , Gero Heymer , Markus Erpenbach
IPC分类号： C01B25/24 , C01B25/16
CPC分类号： C01B25/24
摘要： The disclosure relates to a process for the continuous dearsenification of polyphosphoric acid with the aid of hydrogen sulfide in a gas admission zone. To this end, the disclosure provides for the acid to be dearsenified in a gas admission zone subdivided so as to comprise at least two separate liquid matter-receiving zones, each zone being separated from the other by means of a separate gas zone; for the liquid in each of the liquid matter-receiving zones to be maintained at a level 0.1 up to 10 cm high, without admission of gas; for hydrogen sulfide which remained unreacted in the individual liquid matter-receiving zones to be collected in the respective gas zone and for it to be finely redispersed in the liquid matter-receiving zone directly upstream of the respective gas zone by allowing the hydrogen sulfide to flow through a plurality of openings into the acid, the latter being delivered from the respective liquid-matter-receiving zone into the next downstream liquid-matter-receiving zone, and introduced thereinto directly below the liquid matter level therein; for precipitated arsenic sulfide to be separated from the acid coming from the lower end of the gas admission zone, and for the filtrate obtained to be freed from gaseous hydrogen sulfide in excess.
摘要翻译：本公开涉及在气体入口区借助硫化氢连续脱砷多磷酸的方法。为此，本公开内容提供了在气体进入区域中进行脱砷的酸，其被细分为包括至少两个分离的液体物质接收区域，每个区域通过单独的气体区域与另一个区域分离; 使每个液体物质接收区域中的液体保持在0.1至10厘米高的水平，而不允许气体; 对于在各个液体物质接收区中保持未反应的硫化氢，其被收集在各个气体区中，并且通过允许硫化氢流动直接在各个气体区的上游被精细地再分散在液体物质接收区中通过多个开口进入酸，后者从相应的液体接收区输送到下一个下游液体接收区，并直接在其中引入液体物质的下方; 使沉淀的硫化砷与气体入口区的下端的酸分离，得到的过滤得到的无水硫化氢的滤液。

35. 发明授权

US4394358A Production of granular alkali metal diphosphates or triphosphates 失效
标题翻译：生产颗粒状碱金属二磷酸盐或三磷酸盐
公开(公告)号：US4394358A
公开(公告)日：1983-07-19
申请号：US303100
申请日：1981-09-17
申请人： Alexander Maurer , Renate Adrian , Herbert Panter , Gero Heymer , Dieter Nolker
发明人： Alexander Maurer , Renate Adrian , Herbert Panter , Gero Heymer , Dieter Nolker
IPC分类号： C01B25/41 , C01B25/42 , C11D3/06 , C01B25/30
CPC分类号： C01B25/418 , C01B25/425 , C11D3/062
摘要： The invention relates to a process for making granulated, partially or completely hydrated alkali metal diphosphates or triphosphates. To this end, the invention provides for alkali metal diphosphates or triphosphates which consist to an extent of at least 20% of particles with a size of less than 0.045 mm and are hydrated to an extent of less than 90%, based on the phosphates' theoretical content of water of hydration, to be intensively mixed and granulated in the presence of water and an ammonium polyphosphate, this latter being used in a proportion of about 0.5 to 50 weight %, based on the quantity of water used.
摘要翻译：本发明涉及制备颗粒状，部分或完全水合的碱金属二磷酸盐或三磷酸盐的方法。为此，本发明提供碱金属二磷酸盐或三磷酸盐，其碱度至少为20％，其尺寸小于0.045mm，并且基于磷酸盐的水合物水合至小于90％的程度，在水和多磷酸铵的存在下，水合的水的理论含量将被浓缩混合和造粒，后者基于所用的水量以约0.5至50重量％的比例使用。

36. 发明授权

US4385041A Process for making aqueous alkali metal phosphate solutions 失效
标题翻译：制备碱金属磷酸盐水溶液的方法
公开(公告)号：US4385041A
公开(公告)日：1983-05-24
申请号：US326078
申请日：1981-11-30
申请人： Klaus Jodden , Gero Heymer
发明人： Klaus Jodden , Gero Heymer
IPC分类号： C01B25/30 , C01B15/16 , C01B25/26
CPC分类号： C01B25/30
摘要： The invention relates to a process for making aqueous alkali metal phosphate solutions by subjecting aqueous alkali metal phosphite solutions to catalytic oxidation with oxygen or air. More particularly, oxygen or air in stoichiometric excess proportions is introduced into the aqueous alkali metal phosphite solution at about 30.degree. to 110.degree. C., at a pH-value of 0 to about 8, and in the presence of SiO.sub.2 or aluminum silicate containing at most 10 weight % Al.sub.2 O.sub.3, for as long as necessary to achieve conversion of the alkali metal phosphite to alkai metal phosphate. After completion of the oxidation, the aqueous solution is separated from the catalyst.
摘要翻译：本发明涉及通过使碱金属亚磷酸盐水溶液用氧气或空气进行催化氧化来制备碱金属磷酸盐水溶液的方法。更具体地说，在约30℃至110℃，pH值为0至约8的条件下，在含碱金属亚磷酸盐水溶液中的化学计量过量的氧气或空气中，在含有至多10重量％的Al 2 O 3，只要需要实现碱金属亚磷酸盐转化为磷酸金属。氧化完成后，将水溶液与催化剂分离。

37. 发明授权

US4294808A Production of anticorrosive pigments containing phosphorus 失效
标题翻译：生产含磷的防锈颜料
公开(公告)号：US4294808A
公开(公告)日：1981-10-13
申请号：US76307
申请日：1979-09-17
申请人： Horst-Dieter Wasel-Nielen , Renate Adrian , Herbert Panter , Gero Heymer , Alexander Maurer , Raban von Schenck
发明人： Horst-Dieter Wasel-Nielen , Renate Adrian , Herbert Panter , Gero Heymer , Alexander Maurer , Raban von Schenck
IPC分类号： C23C22/08 , C01B25/163 , C01B25/165 , C01B25/26 , C01B25/32 , C01B25/34 , C01B25/37 , C09D5/08 , C01B25/36
CPC分类号： C09D5/084 , C01B25/163 , C01B25/165 , C01B25/265 , C01B25/325 , C01B25/34 , C01B25/37
摘要： The invention relates to a process for making phosphorus-containing anticorrosive pigments having a size of at most 20 microns by reacting one or more compounds of magnesium, calcium, strontium, barium, zinc, aluminum, iron, chromium or manganese with an oxygen acid of phosphorus or its alkali metal or ammonium salts at temperatures within the range 10.degree. to 100.degree. C. More particularly pigments consisting to an extent of at least 90% of particles with a size between 0.05 and 8 microns are produced by introducing an aqueous suspension or solution of the reactants into a dispersing means rotating at a speed of 3000 to 10,000 rpm, reacting the reactants by intimately mixing them, and separating and drying precipitated pigment.
摘要翻译：本发明涉及一种通过使一种或多种镁，钙，锶，钡，锌，铝，铁，铬或锰的化合物与氧酸的氧酸反应制备尺寸至多为20微米的含磷防腐颜料的方法磷或其碱金属或铵盐。更具体地说，通过将水性悬浮液或水溶性悬浮液引入至少90％的尺寸为0.05至8微米的颗粒的程度，将反应物溶解在以3000至10,000rpm的速度旋转的分散装置中，通过将它们紧密混合使反应物反应，并分离和干燥沉淀的颜料。

38. 发明授权

US4294621A Production of an anticorrosive pigment on phosphate basis 失效
标题翻译：以磷酸盐为基础生产防腐颜料
公开(公告)号：US4294621A
公开(公告)日：1981-10-13
申请号：US141135
申请日：1980-04-16
申请人： Alexander Maurer , Renate Adrian , Klaus Hestermann , Gero Heymer
发明人： Alexander Maurer , Renate Adrian , Klaus Hestermann , Gero Heymer
IPC分类号： C09D5/08 , C01B25/32 , C09C1/00 , C09C1/02 , C08K3/10
CPC分类号： C01B25/322 , C01B25/325 , C09C1/02 , C01P2004/61 , C01P2006/12
摘要： The invention relates to the production of phosphorus-containing anticorrosive pigments with a particle size of at most 20 microns by reacting one or more calcium or magnesium compounds with phosphoric acid or acid alkali metal or ammonium phosphates by intimately mixing an aqueous suspension or solution of the reactants inside a dispersing means rotating at a speed of 3000 to 10,000 rpm. More particularly, fine pulverulent calcium and magnesium compounds are converted, with agitation, together with water and, if desired, a water-soluble alkanol to a homogeneous suspension or solution. The suspension or solution is intimately mixed, inside the dispersing means at 0.degree. to 40.degree. C. and in an approximately stoichiometric ratio, with the phosphoric acid or acid phosphate solution. Resulting and precipitated pigment is separated and dried under mild conditions while maintaining its content of water of crystallization. The anticorrosive pigment is comprised of a homogeneous mixture and/or mixed crystals of which 10 to 95 mol % is calcium hydrogen phosphate dihydrate, the balance being magnesium hydrogen phosphate trihydrate. An at least 55 weight % proportion consists of particles with a size of up to 5 microns with a BET-surface of at least 1 m.sup.2 /g.
摘要翻译：本发明涉及通过使一种或多种钙或镁化合物与磷酸或酸性碱金属或铵磷酸盐反应，通过将下列物质的水性悬浮液或溶液紧密混合，从而生产粒径至多为20微米的含磷防腐颜料分散装置内的反应物以3000至10,000rpm的速度旋转。更具体地，精细的粉末状钙和镁化合物在搅拌下与水一起转化，如果需要，将水溶性链烷醇转化成均匀的悬浮液或溶液。悬浮液或溶液在分散装置内在0℃至40℃下以大约化学计量比与磷酸或酸式磷酸盐溶液紧密混合。将所得沉淀的颜料分离并在温和条件下干燥，同时保持其结晶水含量。防腐颜料由均匀的混合物和/或其中10〜95摩尔％为磷酸氢钙二水合物的混合晶体组成，余量为磷酸氢二氢钙三水合物。至少55重量％的比例由尺寸高达5微米，BET表面至少为1m 2 / g的颗粒组成。

39. 发明授权

US4163760A Continuous production of organic phosphines 失效
标题翻译：连续生产有机膦
公开(公告)号：US4163760A
公开(公告)日：1979-08-07
申请号：US872250
申请日：1978-01-25
申请人： Georg Elsner , Gero Heymer , Hans-Werner Stephan
发明人： Georg Elsner , Gero Heymer , Hans-Werner Stephan
IPC分类号： C07F9/50 , C07F9/6568 , C07F9/54
CPC分类号： C07F9/5059 , C07F9/65683
摘要： Organic phosphines are produced by reacting an alkylene, cycloalkylene or aralkylene in the presence of a free radical-yielding catalyst. More specifically, a pressure reactor, which is provided in its interior with mixing elements, kept free from oxygen, and subdivided so as to comprise an upper cooling zone and a lower reaction zone, is continuously supplied from above with (a) a solution of the alkylene, cycloalkylene or aralkylene and the catalyst in an inert solvent, and (b) a stoichiometric excess of hydrogen phosphide, the said (a) and (b) reactants being supplied jointly with but separately from one another; the (a) and (b) reactants are mixed in the upper cooling zone of the reactor at about 0.degree. to 35.degree. C. and under a PH.sub.3 -pressure of about 80 to 300 bars; the resulting mixture, which travels downwardly in the reactor, is reacted in the lower reaction zone at about 90.degree. to 190.degree. C., the reactants being allowed to remain in the reactor for a period of time about 13 to 15 times longer than the half life period of the catalyst; the reaction mixture is removed through the bottom portion of the reactor and subjected to distillation so as to separate the organic phosphines.
摘要翻译：有机膦通过在产生自由基的催化剂存在下使亚烷基，亚环烷基或亚芳烷基反应来制备。更具体地，在其内部设置有保持无氧的并且被分为包括上部冷却区和下部反应区的混合元件的压力反应器从上方连续地供给（a）所述（a）和（b）反应物是由彼此共同供应的;（b）化学计量过量的磷酸氢盐，所述（a）和（b）（a）和（b）反应物在反应器的上部冷却区中在约0℃至35℃下混合，并在约80至300巴的PH3压力下混合; 在反应器中向下移动的所得混合物在下部反应区中在约90℃至190℃下反应，使反应物在反应器中保留约13至15倍的时间催化剂的半衰期; 将反应混合物通过反应器的底部除去并进行蒸馏以分离有机膦。

40. 发明授权

US3980711A Production of methylphosphine oxides 失效
标题翻译：生产甲基膦氧化物
公开(公告)号：US3980711A
公开(公告)日：1976-09-14
申请号：US549174
申请日：1975-02-12
申请人： Bernd Lippsmeier , Klaus Hestermann , Gero Heymer
发明人： Bernd Lippsmeier , Klaus Hestermann , Gero Heymer
IPC分类号： B01J31/00 , C07F9/53 , C07F9/02
CPC分类号： C07F9/53
摘要： Methylphosphine oxides of the general formula (I) ##EQU1## are produced from hydroxymethylphosphines of the general formula (II) ##EQU2## in which formulae R and R' each stand for identical or different alkyl-, cycloalkyl-, aralkyl- or aryl groups having from 1 to 18 carbon atoms, or carrying substituents being inert under the reaction conditions.The methylphosphine oxides are more particularly produced by subjecting the hydroxymethylphosphines to a rearrangement reaction with the aid of radical-yielding compounds.
摘要翻译：由通式（I）R HOCH2-P ANGLE（II）R'的羟甲基膦制备通式（I）的二甲基膦氧化物。其中式R和R'各自为代表具有1至18个碳原子的相同或不同的烷基 - ，环烷基 - ，芳烷基 - 或芳基，或在反应条件下携带取代基是惰性的。

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