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31. 发明授权

US4673728A Process for the production of copolyamide from aromatic dicarboxylic acids, adipic acid and hexamethylene diamine 失效
标题翻译：从芳族二羧酸，己二酸和六亚甲基二胺生产共聚酰胺的方法
公开(公告)号：US4673728A
公开(公告)日：1987-06-16
申请号：US830269
申请日：1986-02-18
申请人： Werner Nielinger , Hermann Brinkmeyer , Rudolf Binsack , Ludwig Bottenbruch , Heinz-Josef Fullmann
发明人： Werner Nielinger , Hermann Brinkmeyer , Rudolf Binsack , Ludwig Bottenbruch , Heinz-Josef Fullmann
IPC分类号： C08G69/00 , C08G69/26 , C08G69/28 , C08G69/30
CPC分类号： C08G69/265
摘要： A process for the production of copolyamides from aromatic dicarboxylic acids, adipic acid, and hexamethylene diamine having from 30 to 51.5% by weight of units of the hexamethylene adipic acid amide, the monomers being precondensed at at least 250.degree. C. and under a pressure of at least 35 bars and the polycondensation being conducted in a conventional manner to completion.
摘要翻译：一种由芳族二羧酸，己二酸和六亚甲基二胺生产共聚酰胺的方法，其具有己二酸己二酸酰胺的单体重量的30-51.5％，所述单体在至少250℃和压力下预缩合的至少35巴，并且缩聚以常规方式进行完成。

32. 发明授权

US4567226A Elastomeric block copolyamides 失效
标题翻译：弹性嵌段共聚酰胺
公开(公告)号：US4567226A
公开(公告)日：1986-01-28
申请号：US453539
申请日：1982-12-27
申请人： Ulrich Grigo , Karl-Heinz Kohler , Rudolf Binsack , Leo Morbitzer , Josef Merten , Ludwig Trabert , Walter Heitz
发明人： Ulrich Grigo , Karl-Heinz Kohler , Rudolf Binsack , Leo Morbitzer , Josef Merten , Ludwig Trabert , Walter Heitz
IPC分类号： C08G69/00 , C08G69/36 , C08G81/02 , C08F8/30 , C08L23/00 , C08L51/00
CPC分类号： C08G69/00 , C08G81/028 , Y10S525/94
摘要： Block copolyamides consisting of from 1 to 80% by weight of hydrogenated telechelic diene polymers having M.sub.n molecular weight of from 400 to 6000 and from 99 to 20% by weight of polyamides or polyamide-forming components.
摘要翻译：由1至80重量％的Mn分子量为400至6000和99至20重量％的聚酰胺或聚酰胺形成组分的氢化遥爪二烯聚合物组成的嵌段共聚酰胺。

33. 发明授权

US4287108A Mixtures of polypropylene and liquid saturated diorganopolysiloxanes 失效
标题翻译：聚丙烯和液体饱和二有机聚硅氧烷的混合物
公开(公告)号：US4287108A
公开(公告)日：1981-09-01
申请号：US119940
申请日：1980-02-08
申请人： Ulrich Grigo , Leo Morbitzer , Klaus-Peter Arlt , Rudolf Binsack , Josef Merten
发明人： Ulrich Grigo , Leo Morbitzer , Klaus-Peter Arlt , Rudolf Binsack , Josef Merten
IPC分类号： C08L23/00 , C08L23/12 , C08L87/00 , C08L101/00 , C08L83/04
CPC分类号： C08L23/12 , C08L83/04
摘要： A homogeneous, thermoplastic mixture comprising (A) from 85 to 99.5% by weight of isotactic polypropylene; and (B) from 15 to 0.5% by weight of a liquid, saturated diorganopolysiloxane having a viscosity of from 30,000 to 80,000 cSt at 20.degree. C.The elastic properties of moulded articles produced from the polypropylene/diorganopolysiloxane mixtures of the present invention are substantially improved by the addition of small quantities of diorganopolysiloxane while their dimensional stability under heat and their rigidity are largely preserved.
摘要翻译：一种均匀的热塑性混合物，其包含（A）85-99.5重量％的全同立构聚丙烯; 和（B）15至0.5重量％的在20℃下粘度为30,000至80,000cSt的液体饱和二有机聚硅氧烷。由本发明的聚丙烯/二有机聚硅氧烷混合物制备的模制品的弹性性质基本上通过添加少量的二有机聚硅氧烷来改善，同时它们在加热下的尺寸稳定性和它们的刚性被大大保持。

34. 发明授权

US4260690A Thermoplastic polyester moulding compositions with good toughness properties 失效
标题翻译：具有良好韧性的热塑性聚酯成型组合物
公开(公告)号：US4260690A
公开(公告)日：1981-04-07
申请号：US113369
申请日：1980-01-18
申请人： Rudolf Binsack , Dieter Rempel , Helmut Korber , Dieter Neuray
发明人： Rudolf Binsack , Dieter Rempel , Helmut Korber , Dieter Neuray
IPC分类号： C08F255/00 , C08F257/00 , C08L23/00 , C08L51/00 , C08L51/02 , C08L51/06 , C08L67/00 , C08L67/02 , C08L101/00
CPC分类号： C08L67/02
摘要： The toughness of thermoplastic polyesters can essentially be improved by addition of a new type of graft polymers which contain one grafting site for about 400 to 2000 carbon atoms, the average molecular weight M.sub.w of the graft branches being from 2000 to 40,000.
摘要翻译：热塑性聚酯的韧性基本上可以通过加入含有一个接枝位点约400至2000个碳原子的新型接枝聚合物而得到改进，接枝分枝的平均分子量为2000至40,000。

35. 发明授权

US4223106A Block copolyesters which crystallize rapidly 失效
标题翻译：封闭共聚酯快速结晶
公开(公告)号：US4223106A
公开(公告)日：1980-09-16
申请号：US730208
申请日：1976-10-06
申请人： Peter Bier , Rudolf Binsack , Dieter Rempel
发明人： Peter Bier , Rudolf Binsack , Dieter Rempel
IPC分类号： C08G63/00 , C08G63/181 , C08G63/46 , C08G63/66 , C08F8/00
CPC分类号： C08G63/00 , C08G63/66
摘要： Polyethylene terephthalate copolymers comprising (I) blocksegments having a glass transition temperature below 0.degree. C. and (II) polyethylene terephthalate segments modified with certain diols having 3 to 10 carbon atoms, have an excellent rate of crystallization and necessitate mould temperatures of below 100.degree. C.
摘要翻译：包含（I）玻璃化转变温度低于0℃的块状物的聚对苯二甲酸乙二醇酯共聚物和（II）用某些具有3-10个碳原子的二醇改性的聚对苯二甲酸乙二醇酯链段具有优异的结晶速率，并且模具温度低于100℃ C。

36. 发明授权

US4214062A Polycarbonate films of low flammability and improved stress crack resistance 失效
标题翻译：聚碳酸酯薄膜具有低可燃性和改善的抗应力开裂性能
公开(公告)号：US4214062A
公开(公告)日：1980-07-22
申请号：US875014
申请日：1978-02-03
申请人： Rudolf Binsack , Joachim Wank , Eckart Reese
发明人： Rudolf Binsack , Joachim Wank , Eckart Reese
IPC分类号： C08L69/00 , C08K5/36 , C08K5/42
CPC分类号： C08K5/42
摘要： The present invention relates to polycarbonate films, and in particular extruded films and cast films, but preferably extruded films, which are characterized in that they contain about 0.01% to 2% by weight of a NH.sub.4 salt, alkali metal salt or alkaline earth metal salt of a perhalogenoalkanesulphonic acid, preferably a perfluoroalkanesulphonic acid.
摘要翻译：本发明涉及聚碳酸酯膜，特别是挤出膜和流延膜，但优选挤出膜，其特征在于它们含有约0.01重量％至2重量％的NH 4盐，碱金属盐或碱土金属盐的全卤烷基磺酸，优选全氟烷基磺酸。

37. 发明授权

US4212963A Polybutylene terephthalates having a low carboxyl content and continuous process for the production thereof 失效
标题翻译：具有低羧基含量的聚对苯二甲酸丁二酯和用于生产的连续方法
公开(公告)号：US4212963A
公开(公告)日：1980-07-15
申请号：US968892
申请日：1978-12-13
申请人： Gunter Lehr , Rudolf Binsack
发明人： Gunter Lehr , Rudolf Binsack
IPC分类号： C08G63/00 , C08G63/78 , C08G63/18
CPC分类号： C08G63/785 , C08G63/78
摘要： Polybutylene terephthalates having a narrow molecular weight distribution, a low carboxyl group content and an intrinsic viscosity of from 0.2 to 1.4 dl/g can be continuously produced by transporting a molten reaction mixture of terephthalic acid mono- and/or bis-(hydroxybutyl) ester or low viscosity polybutylene terephthalate at 160.degree. to 300.degree. C., together with a heated inert gas, in a diphasic annular stream through an externally heated spiral reaction tube (of substantially constant pitch) having a diameter of from 3 to 100 mm and a diameter/length ratio of from 1:400 to 1:2000 by the maintenance of a pressure difference between the beginning and the end of the reaction tube, under conditions such that the absolute pressure, determined at the point of entry of the reaction mixture into the tube, is from 1 to 100 bar and the viscosity of the annular stream is from 1 to 10,000 poises (determined at the reaction temperature), and a circular stream between the surface of the melt and the wall of the tube is produced by the curvature of the tube and a stream of gas flowing at a velocity of from 20 to 300 m/sec to accelerate the transport of material between the melt and the inert gas, whereby the reaction takes place in the liquid phase and/or at the melt/gas interface.
摘要翻译：通过将对苯二甲酸单 - 和/或双 - （羟基丁基）酯的熔融反应混合物输送，可以连续制备具有窄分子量分布，低羧基含量和特性粘度为0.2-1.4dl / g的聚对苯二甲酸丁二醇酯或低粘度聚对苯二甲酸丁二醇酯在160℃至300℃下与加热的惰性气体一起通过直径为3至100mm的外部加热的螺旋反应管（基本上恒定的间距）和二价环状流通过维持反应管的开始和结束之间的压力差，在使反应混合物进入点确定的绝对压力为管子为1至100巴，环形流的粘度为1至10,000泊（在反应温度下确定），并且在熔体表面之间的圆形流 d管的壁由管的曲率和以20-300m / sec的速度流动的气流产生，以加速在熔体和惰性气体之间的材料的输送，从而发生反应在液相和/或在熔体/气体界面处。

38. 发明授权

US4152367A Branched polyaryl-sulphone/polycarbonate mixtures and their use for the production of extruded films 失效
标题翻译：分散式聚氨酯/多环芳烃混合物及其生产超滤膜的用途
公开(公告)号：US4152367A
公开(公告)日：1979-05-01
申请号：US927808
申请日：1978-07-25
申请人： Rudolf Binsack , Eckart Reese , Joachim Wank
发明人： Rudolf Binsack , Eckart Reese , Joachim Wank
IPC分类号： C08L69/00 , C08L81/00 , C08L81/06
CPC分类号： C08L81/06
摘要： The present invention is concerned with mixtures of branched polyaryl-sulphone and aromatic polycarbonates having Mw in excess of about 60,000. These mixtures are particularly suitable for the production of extruded film although the polycarbonate itself is of too high a molecular weight to be conveniently extruded by itself. These films display superior stress-cracking properties and resistance to unsaturated polyester resins compared to similar blends with lower molecular weight polycarbonates.

39. 发明授权

US4115371A Stabilization of polycondensates of polyethylene terephthalate 失效
标题翻译：聚对苯二甲酸乙二醇酯缩聚物的稳定化
公开(公告)号：US4115371A
公开(公告)日：1978-09-19
申请号：US802858
申请日：1977-06-02
申请人： Peter Bier , Rudolf Binsack
发明人： Peter Bier , Rudolf Binsack
IPC分类号： C08L67/00 , C08G63/00 , C08G63/78 , C08G63/82 , C08K3/32 , D01F6/92 , C08G63/34 , C08G63/32
CPC分类号： C08K3/32
摘要： A process for the production of high molecular weight low color polyethylene terephthalates using a particulaarly effective polycondensation catalyst is disclosed. Titanium tetrabutylate is added to the reaction mixture after the initial esterification or transesterification reaction is about 95% complete and the polycondensation is completed at temperatures between about 200 and 270.degree. C under reduced pressure. Metaphosphoric acid or its alkali or alkaline earth metal salts are added with the titanium tertrabutylate to control the color. Commonly accepted catalysts may be employed for the initial esterification or transesterification. Polymers with intrinsic viscosities in excess of 0.7 dl/g and yellowness numbers less than 6 can be produced.
摘要翻译：公开了一种使用特别有效的缩聚催化剂生产高分子量低颜色聚对苯二甲酸乙二醇酯的方法。在初始酯化反应或酯交换反应完成约95％之后，向反应混合物中加入四丁基钛，缩聚反应在约200-270℃的温度下在减压下完成。将偏磷酸或其碱金属或碱土金属盐与叔丁醇钛一起加入以控制颜色。常用的催化剂可用于初始酯化或酯交换。特性粘度超过0.7dl / g，黄度数小于6的聚合物。

40. 发明授权

US4056504A Polycarbonate molding compositions 失效
标题翻译：聚碳酸酯成型组合物
公开(公告)号：US4056504A
公开(公告)日：1977-11-01
申请号：US647228
申请日：1976-01-07
申请人： Manfred Grundmeier , Rudolf Binsack , Hugo Vernaleken
发明人： Manfred Grundmeier , Rudolf Binsack , Hugo Vernaleken
IPC分类号： C08K7/14 , C08L69/00 , C08L67/02
CPC分类号： C08K7/14 , C08L69/00
摘要： The present invention is concerned with polycarbonate molding resins with improved flow and strength properties which contain about 10 to 40 wt.% glass fibers and about 0.5 to 5 wt. % of polyalkylene glycol terephthalate or about 0.5 to 10 wt.% of polyalkylene glycol isophthalate.

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