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31. 发明授权

US4728337A Assistant combination and use thereof as wool textile finishing agent 失效
标题翻译：助剂组合使用，作为羊毛纺织整理剂
公开(公告)号：US4728337A
公开(公告)日：1988-03-01
申请号：US925027
申请日：1986-10-30
申请人： Heinz Abel , Rosemarie Topfl , Franz Gunter
发明人： Heinz Abel , Rosemarie Topfl , Franz Gunter
IPC分类号： D06M13/02 , D06M13/322 , D06M13/332 , D06M13/405 , D06M13/46 , D06M13/463 , D06M13/467 , D06P1/52 , D06P1/645 , D06P1/647 , D06P1/649 , D06P1/66 , D06P3/16 , D06P5/06 , D06M15/37
CPC分类号： D06M13/405 , D06M13/332 , D06M13/467 , D06P1/5278 , D06P1/66 , D06P5/06 , Y10S8/917
摘要： An assistant combination for use as textile finishing agent, especially in a process for aftertreating wool dyeings, which comprises(1) a diquaternary ammonium salt of formula ##STR1## wherein Q is a divalent aliphatic hydrocarbon radical of 2 to 12 carbon atoms which may be interrupted in the chain by oxygen atoms and is unsubstituted or substituted by hydroxy.R.sub.1 and R.sub.2 are each independently of the other an aliphatic radical of 6 to 24 carbon atoms,R.sub.3 to R.sub.6 are independently of the other lower alkyl, hydroxy-lower alkyl or lower alkoxy-lower alkyl,X.sub.1 and X.sub.2 are each oxygen or --NH--,Z.sub.1 and Z.sub.2 are each independently of the other C.sub.2 -C.sub.6 alkylene, andY.sup..crclbar. is an anion of a strong inorganic or organic acid, and(2) (A) a mono- or polyquaternary ammonium salt which carries at least one hydrocarbon radical of not less than 7 carbon atoms attached to the nitrogen atom, or(B) a polymeric ammonium salt, or(C) a basic non-quaternized nitrogen-containing polycondensate.
摘要翻译：用作织物整理剂的助剂组合物，特别是在羊毛染色后处理的方法中，其包括（1）式（1）的二季铵盐，其中Q是2至12个碳原子的二价脂族烃基其可以在链中被氧原子中断，并且是未取代的或被羟基取代。 R 1和R 2各自独立地为6至24个碳原子的脂族基团，R 3至R 6独立于其它低级烷基，羟基 - 低级烷基或低级烷氧基 - 低级烷基，X 1和X 2各自为氧或-NH - ，Z 1和Z 2各自独立地为C 2 -C 6亚烷基，Y（ - ）是强无机或有机酸的阴离子，和（2）（A）单或多季铵盐，其携带至少一种与氮原子连接的不少于7个碳原子的烃基，或（B）聚合铵盐，或（C）碱性非季铵化含氮缩聚物。

32. 发明授权

US4705526A Water-soluble or water-dispersible graft polymers and the preparation and use thereof 失效
标题翻译：水溶性或水分散性接枝聚合物及其制备和应用
公开(公告)号：US4705526A
公开(公告)日：1987-11-10
申请号：US876034
申请日：1986-06-19
申请人： Heinz Abel , Paul Schafer , Hans-Ulrich Berendt
发明人： Heinz Abel , Paul Schafer , Hans-Ulrich Berendt
IPC分类号： C08F283/00 , C08F283/02 , C08F299/04 , C08G63/676 , D06M13/02 , D06M13/184 , D06M13/203 , D06M13/322 , D06M13/402 , D06M13/41 , D06M15/263 , D06M101/00 , D06M101/02 , D06M101/06 , D06M101/08 , D06M101/10 , D06M101/16 , D06P1/613 , C08F283/01 , C08G63/66
CPC分类号： C08F283/02 , C08F299/04 , C08G63/676 , D06P1/613 , Y10S8/917 , Y10S8/918 , Y10S8/922 , Y10S8/924 , Y10S8/927
摘要： Water-soluble or water-dispersible graft polymers comprising i) as main chain, (1) a condensate of (A) (1) an aliphatic monoalcohol of 6 to 22 carbon atoms or (2) a fatty acid of 8 to 22 carbon atoms with (B) the reaction product of (a) an adduct of propylene adduct with at least trihydric aliphatic alcohol of 3 to 10 carbon atoms, (b) an aliphatic dicarboxylic acid of 4 to 10 carbon atoms, or an anhydride thereof, and (c) an aliphatic diol having an average molecular weight of not more than 1800 and ii) grafted ethylenically unsaturated polymerisable monomers, preferably acrylic acid or acrylamide, in the form of side chains at individual carbon atoms of said condensate.These graft polymers are particularly suitable for use as anticrease agents for dyeing, whitening, bleaching or washing textile materials, e.g. textiles containing cellulosic fibres, natural or synthetic polyamide fibres, polyacrylonitrile fibres or, in particular, for dyeing or whitening cotton or polyester fibres.
摘要翻译：包括i）作为主链的（1）（A）（1）碳原子数为6〜22的脂肪族一元醇或（2）碳原子数为8〜22的脂肪酸的缩合物的水溶性或水分散性接枝聚合物与（B）反应产物（a）丙烯加成物与至少三元碳原子数为3〜10的脂肪醇的加成物，（b）4-10个碳原子的脂肪族二羧酸或其酸酐，和 c）平均分子量不大于1800的脂肪族二醇和ii）在所述缩合物的各个碳原子处的侧链形式的接枝烯属不饱和可聚合单体，优选丙烯酸或丙烯酰胺。这些接枝聚合物特别适合用作染色，增白，漂白或洗涤织物材料的抗磨剂，例如。含有纤维素纤维，天然或合成聚酰胺纤维，聚丙烯腈纤维或特别是用于染色或增白棉或聚酯纤维的纺织品。

33. 发明授权

US4539353A Aqueous composition of polymaleic acid, surfactants and complexing agents, and its preparation and use as an assistant in the pretreatment of cellulose-containing fibre materials 失效
标题翻译：聚马来酸，表面活性剂和络合剂的水性组合物及其在纤维素纤维材料预处理中的助剂的制备和用途
公开(公告)号：US4539353A
公开(公告)日：1985-09-03
申请号：US570710
申请日：1984-01-13
申请人： Heinz Abel , Christian Guth
发明人： Heinz Abel , Christian Guth
IPC分类号： C08L33/00 , C08K5/05 , C08K5/07 , C08K5/09 , C08K5/53 , C08L33/02 , C08L35/02 , C11D3/37 , D06B7/00 , D06L1/14 , D06L3/00 , D06L3/02
CPC分类号： D06L1/14 , D06L3/00
摘要： Aqueous compositions which contain a hydrolysed polymaleic anhydride, a complexing agent and a mixture of nonionic and anionic surfactants are suitable for use as assistants in the opening up of cellulose-containing fibre materials.
摘要翻译：包含水解的聚马来酸酐，络合剂和非离子表面活性剂和阴离子表面活性剂的混合物的水性组合物适合用作开纤含纤维素纤维材料的辅助剂。

34. 发明授权

US4494952A Wetting agents and their use as mercerizing assistants 失效
标题翻译：润湿剂及其作为丝光助剂的用途
公开(公告)号：US4494952A
公开(公告)日：1985-01-22
申请号：US527600
申请日：1983-08-29
申请人： Heinz Abel , Christian Guth
发明人： Heinz Abel , Christian Guth
IPC分类号： B01F17/02 , D06M11/38 , D06M1/02 , B01F17/12
CPC分类号： D06M11/38 , Y10S516/03
摘要： A wetting agent, in particular for mercerizing cotton and cotton blend fabrics, which contains(a) sulfates of a fatty alcohol having 6 to 18 carbon atoms,(b) phosphates of a monoalcohol having 4 to 12 carbon atoms,(c) alcohols having 6 to 18 carbon atoms or condensation products thereof with paraformaldehyde,(d) a hydrotropic solubilizing agent and optionally(e) an adduct of an organopolysiloxane and ethylene oxide and/or propylene oxide and/or(f) a complexing agent.The wetting agents are distinguished by great wetting power and low foaming, not only in the course of the mercerization but also in the recovery of liquor from mercerizing washing baths.
摘要翻译：特别是用于丝光棉和棉混纺织物的润湿剂，其包含（a）具有6至18个碳原子的脂肪醇的硫酸盐，（b）具有4至12个碳原子的一元醇的磷酸酯，（c）具有 6至18个碳原子或其与多聚甲醛的缩合产物，（d）水溶助长增溶剂和任选（e）有机聚硅氧烷和环氧乙烷和/或环氧丙烷和/或（f）络合剂的加合物。润湿剂的特征在于不仅在丝光过程中而且在丝光洗涤液中回收液体时具有很大的润湿力和低泡沫性。

35. 发明授权

US4460374A Stable composition for treating textile substrates 失效
标题翻译：用于处理织物基材的稳定组合物
公开(公告)号：US4460374A
公开(公告)日：1984-07-17
申请号：US346706
申请日：1982-02-08
申请人： Heinz Abel , Carl Becker , Paul Schafer
发明人： Heinz Abel , Carl Becker , Paul Schafer
IPC分类号： D06L3/12 , D06M13/127 , D06M13/144 , D06M13/224 , D06M16/00 , D06P3/54 , D06P1/90 , D06P1/653
CPC分类号： D06L3/1264 , D06M13/127 , D06M13/144 , D06M13/224 , D06M16/00 , D06P3/54
摘要： The invention relates to a stable composition for treating textile substrates which contains at least(a) an organic solvent which is sparingly soluble to insoluble in water and in which component (b) is dissolved and component (c) is dissolved or dispersed,(b) a vehicle for component (c) which is sparingly soluble to insoluble in water, and(c) a finishing agent which is sparingly soluble to insolube in water and which is soluble or dispersible in the vehicle (b). In addition to components (a), (b) and (c), the composition of the invention may also contain(d) a solid carboxylic acid which is sparingly soluble in water, and preferably soluble in the solvent (a), and/or(e) a polar organic solvent as well as further additives or assistants.The novel composition, which preferably contains fluorescent whitening agents as finishing agents, is used in particular for whitening manmade textiles, especially made-up goods such as curtains or underwear.
摘要翻译：本发明涉及一种用于处理纺织品基材的稳定组合物，该组合物至少包含（a）微溶于不溶于水且其中组分（b）溶解并且组分（c）溶解或分散的有机溶剂）（b ）一种微溶于水的组分（c）的载体，和（c）一种在水中微溶于无纺物并且可溶或可分散于载体（b）中的整理剂。除了组分（a），（b）和（c）之外，本发明的组合物还可以含有（d）微溶于水，优选溶于溶剂（a）的固体羧酸和/ 或（e）极性有机溶剂以及其它添加剂或助剂。优选含有荧光增白剂作为整理剂的新型组合物特别用于美白人造纺织品，特别是诸如窗帘或内衣的制成品。

36. 发明授权

US4441885A Anticrease finishing composition and use thereof in the dyeing or whitening of textile material which contains polyester fibres 失效
标题翻译：抗皱整理组合物及其在含有聚酯纤维的纺织材料的染色或增白中的应用
公开(公告)号：US4441885A
公开(公告)日：1984-04-10
申请号：US370761
申请日：1982-04-22
申请人： Heinz Abel , Paul Schafer
发明人： Heinz Abel , Paul Schafer
IPC分类号： D06L3/12 , D06P1/642 , D06P3/52 , D06P1/16 , D06P1/613
CPC分类号： D06P1/6421 , D06L3/1264
摘要： The invention relates to a novel anticrease finishing composition which comprises at least(A) an O-cyanoethylated compound of the formula(1) R(O--CH.sub.2 CH.sub.2 CN).sub.n, wherein R is an n-valent aliphatic, cycloaliphatic or araliphatic radical, and n is 1 to 5, and(B) a carboxylated polypropylene oxide adduct, or salt thereof, which adduct is obtainable from(a) an aliphatic diol having an average molecular weight of at most 2600,(b) an aliphatic dicarboxylic acid, or anhydride thereof, containing 4 to 10 carbon atoms,(c) an adduct of propylene oxide and an at least trihydric aliphatic alcohol containing 3 to 10 carbon atoms, and(d) a fatty acid containing 8 to 22 carbon atoms, and optionally,(C) an aliphatic alcohol containing 5 to 18 carbon atoms, a siloxane-oxyalkylene copolymer, or a mixture thereof, and/or(D) a polar solvent.The novel composition is used in dyeing or whitening textile material which contains polyester fibres.
摘要翻译：本发明涉及一种新型抗皱整理组合物，其至少包含（A）式（1）R（O-CH 2 CH 2 CN）n的O-氰乙基化化合物，其中R为n价脂肪族，脂环族或芳脂族基团，以及 n为1〜5，（B）羧基化聚环氧丙烷加成物或其盐，所述加合物可从（a）平均分子量至多为2600的脂族二醇得到，（b）脂肪族二羧酸或含有4-10个碳原子的酸酐，（c）环氧丙烷与含有3-10个碳原子的至少三元脂肪醇的加合物，和（d）含有8-22个碳原子的脂肪酸， C）含有5至18个碳原子的脂族醇，硅氧烷 - 氧化烯共聚物或其混合物，和/或（D）极性溶剂。该新型组合物用于含有聚酯纤维的染色或增白纺织材料中。

37. 发明授权

US4426203A Stable anhydrous textile assistant 失效
标题翻译：稳定无水纺织助剂
公开(公告)号：US4426203A
公开(公告)日：1984-01-17
申请号：US335939
申请日：1981-12-30
申请人： Heinz Abel , Josef Oxe
发明人： Heinz Abel , Josef Oxe
IPC分类号： D06L1/14 , D06L3/02
CPC分类号： D06L1/14
摘要： The invention relates to a stable anhydrous textile assistant which comprises at least(A) an anionic surfactant,(B) an inorganic oxidizing agent,(C) a siloxane-oxyalkylene copolymer and, optionally,(D) a compound which combines with metal ions to form water-soluble colorless complexes, and/or(E) a polar organic solvent.The anionic surfactant (A) can also be combined with a non-ionic surfactant. The assistant mixture is used in particular for desizing cellulosic fibre materials by oxidation, preferably in combination with a bleaching process.
摘要翻译：本发明涉及一种稳定的无水纺织助剂，其至少包含（A）阴离子表面活性剂，（B）无机氧化剂，（C）硅氧烷 - 氧化烯共聚物和（D）与金属离子结合的化合物形成水溶性无色复合物，和/或（E）极性有机溶剂。阴离子表面活性剂（A）也可以与非离子表面活性剂组合。辅助混合物特别用于通过氧化来脱浆纤维素纤维材料，优选与漂白工艺组合。

38. 发明授权

US4405329A Stable concentrated fluid formulations of metal-free dyes, process for their preparation, and their use 失效
标题翻译：稳定的无金属染料的浓缩液配方，其制备方法及其用途
公开(公告)号：US4405329A
公开(公告)日：1983-09-20
申请号：US268978
申请日：1981-06-01
申请人： Heinz Abel , Paul Hugelshofer
发明人： Heinz Abel , Paul Hugelshofer
IPC分类号： C09B67/44 , C09B67/00 , C09B67/26 , C09B67/54 , C09B67/42 , C09B67/46 , D06P1/04 , D06P1/20
CPC分类号： C09B67/0092 , C09B67/0073 , C09B67/0096
摘要： Concentrated fluid formulations of textile dyes, leather dyes or paper dyes, comprising(1) metal-free dyes,(2) non-ionic compounds having a hydrotropic action, at least one of components (3) or (4), component(3) being a reaction product of a fatty acid having 8 to 22 carbon atoms and 1 to 2 mols of diethanolamine, and component(4) being a compound of the formula ##STR1## in which R is an aliphatic hydrocarbon radical having 8 to 22 carbon atoms or a cycloaliphatic, aromatic or aliphatic-aromatic hydrocarbon radical having 10 to 22 carbon atoms, R.sub.1 is hydrogen or methyl, A is --O-- or ##STR2## X is the acid radical of an inorganic, oxygen-containing acid, the acid radical of a polybasic carboxylic acid or a carboxyalkyl radical and m is a number from 1 to 50,(5) water, a water-soluble organic solvent having a boiling point of at least 80.degree. C., or a mixture of the two, and,(6) optionally conventional formulating assistants, have excellent stability over a wide temperature range and, on dilution with water or solvents, do not form any undesired multi-phase systems or precipitates.
摘要翻译：纺织染料，皮革染料或纸染料的浓缩液制剂，包含（1）无金属染料，（2）具有水溶助长作用的非离子化合物，组分（3）或（4），组分（3）中的至少一种）是具有8至22个碳原子的脂肪酸和1至2摩尔二乙醇胺的反应产物，以及组分（4），其为R为具有8至22个碳原子的脂族烃基的式原子或具有10至22个碳原子的脂环族，芳族或脂族 - 芳族烃基，R 1是氢或甲基，A是-O-或X是无机，含氧酸的酸基，酸多元羧酸或羧烷基自由基，m为1〜50的数，（5）水，沸点为80℃以上的水溶性有机溶剂，或两者的混合物，和（6）任选的常规配方助剂在宽温度范围内具有优异的稳定性，在用水或溶剂稀释时，不要形成任何不需要的多相体系或沉淀物。

39. 发明授权

US4322415A Stable concentrated liquid preparations of metal complex dyes 失效
标题翻译：稳定的浓缩液体制剂的金属络合染料
公开(公告)号：US4322415A
公开(公告)日：1982-03-30
申请号：US159256
申请日：1980-06-13
申请人： Heinz Abel , Paul Hugelshofer , Arthur Buhler
发明人： Heinz Abel , Paul Hugelshofer , Arthur Buhler
IPC分类号： C09B67/42 , C09B67/00 , C09B67/26 , C09B67/44 , C09B67/46 , D06P1/10 , D06P1/647 , D06P1/90
CPC分类号： C09B67/0092 , C09B67/0073 , C09B67/0084
摘要： Stable concentrated liquid preparations of metal complex dyes are provided. These preparations contain (1) a metal complex dye, (2) a non-ionic compound having a hydrotropic action and at least one of components (3) or (4), component (3) being a reaction product of a fatty acid having 8 to 22 carbon atoms and 1 to 2 mols of diethanolamine and component (4) being a compound of the formula ##STR1## in which R is an aliphatic hydrocarbon radical having 8 to 22 carbon atoms or a cycloaliphatic, aromatic or aliphatic-aromatic hydrocarbon radical having 10 to 22 carbon atoms, R.sub.1 is hydrogen or methyl, A is --O-- or ##STR2## X is the acid radical of an inorganic, oxygen-containing acid, the acid radical of a polybasic carboxylic acid or a carboxyalkyl radical and m is a number from 1 to 50, and (5) water, a water-soluble organic solvent having a boiling point of at least 80.degree. C. or a mixture of the two and (6) optionally conventional formulating agents. The preparations have a good stability on storage over a broad temperature range and can be diluted with water and/or organic solvents without precipitating the dye or producing other inhomogeneities. The preparations are useful for preparing padding liquors, dye baths printing pastes and spray solutions.
摘要翻译：提供了稳定的金属络合染料的浓缩液体制剂。这些制剂包含（1）金属络合染料，（2）具有水溶助角剂作用的非离子化合物和组分（3）或（4）中的至少一种，组分（3）是具有 8至22个碳原子和1至2摩尔二乙醇胺，组分（4）为下式化合物，其中R为具有8至22个碳原子的脂族烃基或脂环族芳族或脂族 - 芳烃具有10至22个碳原子的基团，R 1是氢或甲基，A是-O-或X是无机，含氧酸的酸根，多元羧酸或羧基烷基的酸基， m是1至50的数，和（5）水，沸点至少为80℃的水溶性有机溶剂或两种和（6）任选的常规配制剂的混合物。制剂在宽温度范围内储存时具有良好的稳定性，并且可以用水和/或有机溶剂稀释，而不会沉淀染料或产生其它不均匀性。该制剂可用于制备填充液，染浴浴印刷浆液和喷雾溶液。

40. 发明授权

US4252534A Dyeing assistants and their use in dyeing synthetic fibre material 失效
标题翻译：染色助剂及其在染色合成纤维材料中的应用
公开(公告)号：US4252534A
公开(公告)日：1981-02-24
申请号：US83066
申请日：1979-10-09
申请人： Heinz Abel , Karlheinz Keller
发明人： Heinz Abel , Karlheinz Keller
IPC分类号： D06P1/60 , D06P1/651 , D06P3/24 , D06P3/52 , D06P3/54 , D06P3/76 , D06P3/82 , C09B67/00 , D06P1/64
CPC分类号： D06P3/242 , D06P1/60 , D06P1/65118 , D06P1/65162 , D06P3/522 , D06P3/54 , D06P3/76 , D06P3/8214 , D06P3/8238 , Y10S8/907 , Y10S8/908 , Y10S8/922 , Y10S8/925 , Y10S8/927
摘要： A dyeing assistat containing at least(a) an alkylbenzene or tetrahydronaphthalene (tetralin) or a mixture thereof,(b) an anionic surfactant,(c) a non-aromatic and water-immiscible solvent and optionally also(d) a polar solvent and/or(e) a non-ionic surfactant; this dyeing assistant can be used to promote the migration of the dyes and thus to improve the levelness and dye yield when dyeing synthetic fibre material, preferably polyester, in particular in the temperature range from 80.degree. to 130.degree. C.
摘要翻译：包含至少（a）烷基苯或四氢化萘（tetralin）或其混合物的染色助剂，（b）阴离子表面活性剂，（c）非芳香族和水不混溶性溶剂以及任选地还可以（d）极性溶剂和 /或（e）非离子表面活性剂; 这种染色助剂可用于促进染料的迁移，从而提高染色合成纤维材料（优选聚酯）时的水平度和染色产率，特别是在80至130℃的温度范围内。

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