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    • 2. 发明授权
    • Dyeing assistant preparations and their use for dyeing wool
    • 染色助剂及其用于染色羊毛的用途
    • US5914445A
    • 1999-06-22
    • US935429
    • 1997-09-23
    • Jorg BinzBruno SaladinMartin Jollenbeck
    • Jorg BinzBruno SaladinMartin Jollenbeck
    • D06P1/607D06P1/613D06P1/642D06P1/645D06P1/649D06P1/651D06P1/92D06P3/14D06P3/16D06P1/38
    • D06P1/65131D06P1/6073D06P1/6133D06P1/6428D06P1/6495D06P1/90D06P3/14D06P3/148Y10S8/917
    • The present invention relates to novel dyeing assistant preparations comprising, as component (a), at least one amine oxide of the formula ##STR1## in which R is an aliphatic radical having 8 to 24 carbon atoms andR.sub.1 is an aliphatic radical which is unsubstituted or substituted by hydroxyl and has 1 to 24 carbon atoms, preferably 1 to 6 carbon atoms,as component (b), at least one compound of the formulaR.sub.2 --U--(R.sub.3 --O).sub.m --W (2),in whichR.sub.2 is an aliphatic radical having 8 to 24 carbon atoms,R.sub.3 is alkylene having 2 to 4 carbon atoms,U is --O-- or ##STR2## in which Z is a direct bond, (R.sub.3 --O)).sub.r or C.sub.1 -C.sub.6 alkylene andW.sub.1 is hydrogen or C.sub.1 -C.sub.6 alkyl which is unsubstituted or substituted by hydroxyl, carboxyl, isocyanato, phenyl, benzyloxymethylene or phenethyloxymethylene, m and r independently of one another are a number from 2 to 25,(R.sub.3 --O).sub.m is m identical or different radicals (R.sub.3 --O) and(R.sub.3 --O).sub.r is r identical or different radicals (R.sub.3 --O), andW is hydrogen or C.sub.1 -C.sub.6 alkyl which is unsubstituted or substituted by hydroxyl, carboxyl, isocyanato, phenyl, benzyloxymethylene or phenethyloxymethylene, and, as component (c), an organic solvent, and to their use as dyeing assistants for dyeing wool.
    • 本发明涉及包含作为组分(a)的至少一种下式的氧化胺的新型染色助剂,其中R是具有8至24个碳原子的脂族基团,R 1是未被取代或被 羟基并且具有1至24个碳原子,优选1至6个碳原子,作为组分(b),至少一种式R 2 -U-(R 3 -O)m W(2)的化合物,其中R 2是具有 8至24个碳原子,R 3是具有2至4个碳原子的亚烷基,U是-O-或其中Z是直接键,(R 3 -O))r或C 1 -C 6亚烷基,并且W 1是氢或C 1 -C 6烷基, 羟基,羧基,异氰酸酯基,苯基,苄氧基亚甲基或苯乙氧基亚甲基,m和r彼此独立地为2〜25,(R3-O)m为相同或不同的基团(R3-O)和 (R3-O)r是相同或不同的基团(R3-O),W是氢或未被取代或被氢取代的C1-C6烷基 甲醛,羧基,异氰酸酯基,苯基,苄氧基亚甲基或苯乙氧基亚甲基,和作为组分(c)的有机溶剂,以及它们用作染色羊毛的染色助剂。
    • 4. 发明授权
    • Process for trichromatic dyeing or printing
    • 三色染色或印刷方法
    • US5630851A
    • 1997-05-20
    • US609217
    • 1996-03-01
    • Guido JordineJean-Marie Adam
    • Guido JordineJean-Marie Adam
    • C09B29/01C09B29/30C09B67/22D06P3/16D06P3/24
    • C09B67/0051C09B29/0007C09B29/30D06P3/16D06P3/241Y10S8/917Y10S8/924
    • A process for dyeing or printing polyamide material by the trichromatic technique using a dye mixture which contains least two yellow- or orange-dyeing dyes of formula (1) ##STR1## wherein R.sub.1 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy or halogen, and X is hydrogen or C.sub.1 -C.sub.4 alkyl; together with at least one red-dyeing dye of formulae (2) and (3) ##STR2## wherein R.sub.2 is C.sub.1 -C.sub.6 alkyl, phenyl or cyclohexyl and R.sub.3 is C.sub.1 -C.sub.6 alkyl, or wherein R.sub.2 and R.sub.3, together with the linking nitrogen atom, form an azepinyl ring, and R.sub.4 is hydrogen, C.sub.2 -C.sub.4 alkanoylamino or halogen; and together with at least one of the blue-dyeing dyes of formulae (4) and (5) ##STR3## wherein R.sub.5 is hydrogen or C.sub.1 -C.sub.4 alkyl, R.sub.6 is C.sub.1 -C.sub.4 alkyl or amino, R.sub.7 is hydrogen or methyl, and R.sub.8 is a C.sub.2-4 hydroxyalkylsulfamoyl radical, is disclosed.
    • 一种通过三色技术使用含有至少两种式(1)的黄色或橙色染色染料(1)的染料混合物染色或印刷聚酰胺材料的方法,其中R1是氢,C1-C4烷基,C1-C4烷氧基 或卤素,X为氢或C 1 -C 4烷基; 连同至少一种式(2)和(3)的染色染料,烷基,苯基或环己基,R 3是C 1 -C 6烷基,或其中R 2和R 3与连接氮原子一起形成吖庚因环,R 4 是氢,C 2 -C 4烷酰基氨基或卤素; 并且与至少一种式(4)和(5)的染色染料中的至少一种(5)其中R 5是氢或C 1 -C 4烷基,R 6是C 1 -C 4烷基或氨基, R7是氢或甲基,R8是C2-4羟烷基氨磺酰基。
    • 5. 发明授权
    • Low-temperature dyeing additive for protein fiber products and dyeing
method using the same
    • 蛋白质纤维制品的低温染色添加剂和使用其的染色方法
    • US5571291A
    • 1996-11-05
    • US481316
    • 1995-07-05
    • Sachizumi Koike
    • Sachizumi Koike
    • D06P1/642D06P1/62D06P1/667D06P1/673D06P1/92D06P3/04D06P3/06D06P3/14D06P3/16D06P5/00D06P1/90
    • D06P3/14D06P1/667D06P1/67341D06P1/6735D06P1/67358D06P1/90D06P3/06D06P3/16Y10S8/917
    • A low-temperature dyeing additive for protein fiber products contains one or more kinds of solvents which are freely miscible with water and having a donor number within the range of 24 to 50 and an acceptor number within the range of 10 to 24 in the presence or absence of a surfactant, in an amount of 0.025 to 40 g per liter of water, has a pH of 3.5 to 9.5. If necessary, it contains tributoxyethyl phosphate in an amount of 0.025 to 4.0 g per liter of water, and/or contains one or more kinds of anions having an enthalpy of hydration (-.DELTA.H.sub.KJ.multidot.mol.sup.-1) of 200 to 290 in an amount of 0.05 to 40 g per liter of water. This low-temperature dyeing additive for protein fiber products serves to relax the higher-order structures of the protein fibers before dyeing or during dyeing, to thereby swell the fibers, thus rendering the fibers readily dyeable without detriment to the properties thereof.
    • PCT No.PCT / JP94 / 01259 Sec。 371日期:1995年7月5日 102(e)日期1995年7月5日PCT提交1994年7月29日PCT公布。 公开号WO95 / 12707 日期1995年5月11日蛋白质纤维制品的低温染色添加剂含有与水自由混溶并且供体数在24〜50范围内且受体数在10〜24范围内的一种或多种溶剂 在存在或不存在表面活性剂的情况下,每升水为0.025〜40g,pH为3.5〜9.5。 如果需要,它含有0.025至4.0g / l水的三丁氧基乙基磷酸酯,和/或含有一种或多种具有水合焓(〜DELTA HKJxmol-1)的阴离子的量为200至290, 每升水0.05至40克。 这种用于蛋白质纤维产品的低温染色添加剂用于在染色之前或染色期间松弛蛋白质纤维的高级结构,从而使纤维溶胀,从而使纤维易于染色,而不损害其性质。