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1. 发明授权

US4705525A Water-soluble or water-dispersible graft polymers, process for their preparation and the use thereof 失效
标题翻译：水溶性或水分散性接枝聚合物，其制备方法及其用途
公开(公告)号：US4705525A
公开(公告)日：1987-11-10
申请号：US876033
申请日：1986-06-19
申请人： Heinz Abel , Paul Schafer , Hans-Ulrich Berendt
发明人： Heinz Abel , Paul Schafer , Hans-Ulrich Berendt
IPC分类号： C08F283/00 , C08F283/06 , C11D3/37 , D06L1/14 , D06P1/613
CPC分类号： D06L1/14 , C08F283/06 , C11D3/3788 , D06P1/613 , Y10S8/917 , Y10S8/918 , Y10S8/922 , Y10S8/924 , Y10S8/927
摘要： Water-soluble or water-dispersible graft polymers which comprise (a) as main chain, a polyalkylene glycol, in particular polyethylene glycol, which is esterified at the two terminal hydroxyl groups with a long chain fatty acid of 8 to 26, preferably 10 to 22, carbon atoms, and (b) grafted ethylenically unsaturated monomers, preferably acrylic acid or acrylamide, in the form of side chains at individual carbon atoms of the polyalkylene glycol chain.These graft polymers are particularly suitable for use as anticrease agents for dyeing, whitening, bleaching or washing textile materials, e.g. textiles containing cellulosic fibres, natural or synthetic polyamide fibres, polyacrylonitrile fibres or, in particular, for dyeing or whitening cotton or polyester fibres.
摘要翻译：水溶性或水分散性接枝聚合物，其包含（a）主链，聚亚烷基二醇，特别是聚乙二醇，其在两末端羟基上被酯化，长链脂肪酸为8至26，优选10至 22，碳原子，和（b）接枝的烯属不饱和单体，优选丙烯酸或丙烯酰胺，以聚亚烷基二醇链的单个碳原子上的侧链形式。这些接枝聚合物特别适合用作染色，增白，漂白或洗涤织物材料的抗磨剂，例如。含有纤维素纤维，天然或合成聚酰胺纤维，聚丙烯腈纤维或特别是用于染色或增白棉或聚酯纤维的纺织品。

2. 发明授权

US4268686A Propylene oxide reaction products 失效
标题翻译：环氧丙烷反应产物
公开(公告)号：US4268686A
公开(公告)日：1981-05-19
申请号：US136614
申请日：1980-04-02
申请人： Paul Schafer , Heinz Abel , Fritz Mayer
发明人： Paul Schafer , Heinz Abel , Fritz Mayer
IPC分类号： C07C69/003 , C07C69/593 , C07C69/76 , C08G63/00 , C08G63/02 , C08G63/12 , C08G63/48 , C08G63/52 , C08G63/685 , C08G65/26 , C08G65/32 , D06M13/02 , D06M13/184 , D06M15/507 , D06M15/53 , D06P1/44 , D06P1/60 , D06P1/613 , D06P3/84 , D06P5/04 , C07C69/60 , C07C69/80
CPC分类号： D06P1/60 , C08G65/2615 , Y10S8/922 , Y10S8/924
摘要： Propylene oxide reaction products, and the salts or quaternization products thereof are provided which are obtained from(a) an at least trihydric aliphatic alcohol of 3 to 10 carbon atoms,(b) 1,2-propylene oxide,(c) an aliphatic dicarboxylic acid of 2 to 10 carbon atoms, an aromatic dicarboxylic acid of 8 to 12 carbon atoms or the anhydrides thereof,and at least one of the following components:(d) an aliphatic diol with a molecular weight of at most 2000,(e) a fatty alcohol containing 12 to 22 carbon atoms,(f) a fatty acid containing 12 to 22 carbon atoms, and(g) an aliphatic monoamine or diamine containing 2 to 12 carbon atoms,of which component (g) is used only at the conclusion and only if component (c) is ethylenically unsaturated.The inventive products are suitable for widely varying uses in textile finishing. In particular they are used as printing and dyeing assistants, for example, to improve the fastness properties of dyeings, to prevent the bleeding of non-dyed or non-printed areas during the washing-off process of these dyeings or prints, or to prevent the deposition of oligomers on the textile material during the high temperature dyeing of polyester fibres.
摘要翻译：提供了环氧丙烷反应产物及其盐或季铵化产物，其由（a）至少三元碳原子数为3〜10的脂肪族醇，（b）1,2-环氧丙烷，（c）脂肪族二羧酸 2至10个碳原子的酸，8-12个碳原子的芳族二羧酸或其酸酐，和至少一种以下组分：（d）分子量至多为2000的脂族二醇，（e）含有12-22个碳原子的脂肪醇，（f）含有12-22个碳原子的脂肪酸，和（g）含有2至12个碳原子的脂族单胺或二胺，其中组分（g）仅在结论并且仅当组分（c）是烯属不饱和的时）。本发明的产品适用于纺织品整理中广泛使用的用途。特别是它们可用作印染助剂，例如提高染色的牢度性能，以防止在这些染色或印花的洗涤过程中非染色或非印刷区域的渗色，或防止染色在聚酯纤维的高温染色期间，低聚物沉积在纺织材料上。

3. 发明授权

US4615837A Propylene oxide polyadducts containing carboxyl groups and their salts useful as dyeing assistants for dyeing wool fibers 失效
标题翻译：含有羧基的环氧丙烷加成物及其盐可用作染色羊毛纤维的染色助剂
公开(公告)号：US4615837A
公开(公告)日：1986-10-07
申请号：US321850
申请日：1981-11-16
申请人： Heinz Abel , Paul Schafer
发明人： Heinz Abel , Paul Schafer
IPC分类号： C08G63/00 , C08G63/46 , C08G63/668 , C09D167/00 , D06P1/613 , D06P1/647 , D06P3/14 , C09B67/00 , C09F5/08
CPC分类号： D06P1/613 , C08G63/668 , C09D167/00 , Y10S8/917
摘要： A propylene oxide polyadduct containing carboxyl groups, or a salt thereof, obtained from(a) an adduct of propylene oxide and an aliphatic alcohol having 3 to 10 carbon atoms which is at least trihydric,(b) an aliphatic dicarboxylic acid or the anhydride thereof having 2 to 10 carbon atoms or a mono- or di-lower alkylester of said dicarboxylic acids,(c) an aliphatic diol having an average molecular weight of at most 2,000,(d) a fatty acid having 8 to 22 carbon atoms and(e) an aromatic dicarboxylic acid or the anhydride thereof having 8 to 12 carbon atoms; it is in particular useful as dyeing assistant for the dyeing of fibrous material made of or containing wool with anionic dyes.
摘要翻译：由（a）环氧丙烷与3〜10个碳原子的脂肪族醇的加合物（a）至少三元得到的含有羧基的环氧丙烷聚合物或其盐，（b）脂肪族二羧酸或其酸酐具有2至10个碳原子或所述二羧酸的单 - 或二 - 低级烷基酯，（c）平均分子量至多为2,000的脂族二醇，（d）具有8至22个碳原子的脂肪酸和（ e）芳族二羧酸或其具有8至12个碳原子的酸酐; 它特别适用于用阴离子染料染色由羊毛制成或含有羊毛的纤维材料的染色助剂。

4. 发明授权

US4453946A Dyeing assistant and use thereof in dyeing synthetic fibre material 失效
标题翻译：染色助剂及其在染色合成纤维材料中的应用
公开(公告)号：US4453946A
公开(公告)日：1984-06-12
申请号：US370762
申请日：1982-04-22
申请人： Heinz Abel , Paul Schafer , Hans-Ulrich Berendt
发明人： Heinz Abel , Paul Schafer , Hans-Ulrich Berendt
IPC分类号： D06L3/12 , D06P1/642 , D06P1/667
CPC分类号： D06P1/6421 , D06L3/1264
摘要： The invention relates to a dyeing assistant comprising at least(A) an O-cyanoethylated compound of the formulaR(O--CH.sub.2 CH.sub.2 CN).sub.n, (1)wherein R is an n-valent aliphatic, cycloaliphatic or araliphatic radical, and n is 1 to 5,(B) an anionic surfactant(C) a non-ionic surfactant and optionally at least one of the following components(D) an aliphatic alcohol containing 5 to 18 carbon atoms, a siloxane-oxyalkylene copolymer or a mixture thereof, and(E) a polar solvent.This assistant is used in particular for dyeing synthetic fibre material, preferably polyester fibres, to improve levelness and crockfastness and to increase the dye yield.
摘要翻译：本发明涉及一种染色助剂，其至少包含（A）式R（O-CH 2 CH 2 CN）n的O-氰乙基化化合物，（1）其中R是n价脂肪族，脂环族或芳脂族基，n为1 至（5），（B）阴离子表面活性剂（C）非离子表面活性剂和任选的至少一种以下组分（D）含有5至18个碳原子的脂族醇，硅氧烷 - 氧化烯共聚物或其混合物，和（E）极性溶剂。该助剂特别用于染色合成纤维材料，优选聚酯纤维，以提高水平度和耐克度，并提高染色产率。

5. 发明授权

US4343620A Propylene oxide polyadducts containing carboxyl groups and their salts 失效
标题翻译：含有羧基的环氧丙烷加成物及其盐
公开(公告)号：US4343620A
公开(公告)日：1982-08-10
申请号：US219202
申请日：1980-12-22
申请人： Heinz Abel , Paul Schafer
发明人： Heinz Abel , Paul Schafer
IPC分类号： C08G63/00 , C08G63/46 , C08G63/668 , C09D167/00 , D06P1/613 , D06P1/647 , D06P3/14 , C09B67/00
CPC分类号： D06P1/613 , C08G63/668 , C09D167/00 , Y10S8/917
摘要： A propylene oxide polyadduct containing carboxyl groups, or a salt thereof, obtained from(a) an adduct of propylene oxide and an aliphatic alcohol having 3 to 10 carbon atoms which is at least trihydric,(b) an aliphatic dicarboxylic acid or the anhydride thereof having 2 to 10 carbon atoms or a mono- or di-lower alkylester of said dicarboxylic acids,(c) an aliphatic diol having an average molecular weight of at most 2,000,(d) a fatty acid having 8 to 22 carbon atoms and(e) an aromatic dicarboxylic acid or the anhydride thereof having 8 to 12 carbon atoms; it is in particular useful as dyeing assistant for the dyeing of fibrous material made of or containing wool with anionic dyes.
摘要翻译：由（a）环氧丙烷与3〜10个碳原子的脂肪族醇的加合物（a）至少三元得到的含有羧基的环氧丙烷聚合物或其盐，（b）脂肪族二羧酸或其酸酐具有2至10个碳原子或所述二羧酸的单 - 或二 - 低级烷基酯，（c）平均分子量至多为2,000的脂族二醇，（d）具有8至22个碳原子的脂肪酸和（ e）芳族二羧酸或其具有8至12个碳原子的酸酐; 它特别适用于用阴离子染料染色由羊毛制成或含有羊毛的纤维材料的染色助剂。

6. 发明授权

US4705526A Water-soluble or water-dispersible graft polymers and the preparation and use thereof 失效
标题翻译：水溶性或水分散性接枝聚合物及其制备和应用
公开(公告)号：US4705526A
公开(公告)日：1987-11-10
申请号：US876034
申请日：1986-06-19
申请人： Heinz Abel , Paul Schafer , Hans-Ulrich Berendt
发明人： Heinz Abel , Paul Schafer , Hans-Ulrich Berendt
IPC分类号： C08F283/00 , C08F283/02 , C08F299/04 , C08G63/676 , D06M13/02 , D06M13/184 , D06M13/203 , D06M13/322 , D06M13/402 , D06M13/41 , D06M15/263 , D06M101/00 , D06M101/02 , D06M101/06 , D06M101/08 , D06M101/10 , D06M101/16 , D06P1/613 , C08F283/01 , C08G63/66
CPC分类号： C08F283/02 , C08F299/04 , C08G63/676 , D06P1/613 , Y10S8/917 , Y10S8/918 , Y10S8/922 , Y10S8/924 , Y10S8/927
摘要： Water-soluble or water-dispersible graft polymers comprising i) as main chain, (1) a condensate of (A) (1) an aliphatic monoalcohol of 6 to 22 carbon atoms or (2) a fatty acid of 8 to 22 carbon atoms with (B) the reaction product of (a) an adduct of propylene adduct with at least trihydric aliphatic alcohol of 3 to 10 carbon atoms, (b) an aliphatic dicarboxylic acid of 4 to 10 carbon atoms, or an anhydride thereof, and (c) an aliphatic diol having an average molecular weight of not more than 1800 and ii) grafted ethylenically unsaturated polymerisable monomers, preferably acrylic acid or acrylamide, in the form of side chains at individual carbon atoms of said condensate.These graft polymers are particularly suitable for use as anticrease agents for dyeing, whitening, bleaching or washing textile materials, e.g. textiles containing cellulosic fibres, natural or synthetic polyamide fibres, polyacrylonitrile fibres or, in particular, for dyeing or whitening cotton or polyester fibres.
摘要翻译：包括i）作为主链的（1）（A）（1）碳原子数为6〜22的脂肪族一元醇或（2）碳原子数为8〜22的脂肪酸的缩合物的水溶性或水分散性接枝聚合物与（B）反应产物（a）丙烯加成物与至少三元碳原子数为3〜10的脂肪醇的加成物，（b）4-10个碳原子的脂肪族二羧酸或其酸酐，和 c）平均分子量不大于1800的脂肪族二醇和ii）在所述缩合物的各个碳原子处的侧链形式的接枝烯属不饱和可聚合单体，优选丙烯酸或丙烯酰胺。这些接枝聚合物特别适合用作染色，增白，漂白或洗涤织物材料的抗磨剂，例如。含有纤维素纤维，天然或合成聚酰胺纤维，聚丙烯腈纤维或特别是用于染色或增白棉或聚酯纤维的纺织品。

7. 发明授权

US4460374A Stable composition for treating textile substrates 失效
标题翻译：用于处理织物基材的稳定组合物
公开(公告)号：US4460374A
公开(公告)日：1984-07-17
申请号：US346706
申请日：1982-02-08
申请人： Heinz Abel , Carl Becker , Paul Schafer
发明人： Heinz Abel , Carl Becker , Paul Schafer
IPC分类号： D06L3/12 , D06M13/127 , D06M13/144 , D06M13/224 , D06M16/00 , D06P3/54 , D06P1/90 , D06P1/653
CPC分类号： D06L3/1264 , D06M13/127 , D06M13/144 , D06M13/224 , D06M16/00 , D06P3/54
摘要： The invention relates to a stable composition for treating textile substrates which contains at least(a) an organic solvent which is sparingly soluble to insoluble in water and in which component (b) is dissolved and component (c) is dissolved or dispersed,(b) a vehicle for component (c) which is sparingly soluble to insoluble in water, and(c) a finishing agent which is sparingly soluble to insolube in water and which is soluble or dispersible in the vehicle (b). In addition to components (a), (b) and (c), the composition of the invention may also contain(d) a solid carboxylic acid which is sparingly soluble in water, and preferably soluble in the solvent (a), and/or(e) a polar organic solvent as well as further additives or assistants.The novel composition, which preferably contains fluorescent whitening agents as finishing agents, is used in particular for whitening manmade textiles, especially made-up goods such as curtains or underwear.
摘要翻译：本发明涉及一种用于处理纺织品基材的稳定组合物，该组合物至少包含（a）微溶于不溶于水且其中组分（b）溶解并且组分（c）溶解或分散的有机溶剂）（b ）一种微溶于水的组分（c）的载体，和（c）一种在水中微溶于无纺物并且可溶或可分散于载体（b）中的整理剂。除了组分（a），（b）和（c）之外，本发明的组合物还可以含有（d）微溶于水，优选溶于溶剂（a）的固体羧酸和/ 或（e）极性有机溶剂以及其它添加剂或助剂。优选含有荧光增白剂作为整理剂的新型组合物特别用于美白人造纺织品，特别是诸如窗帘或内衣的制成品。

8. 发明授权

US4441885A Anticrease finishing composition and use thereof in the dyeing or whitening of textile material which contains polyester fibres 失效
标题翻译：抗皱整理组合物及其在含有聚酯纤维的纺织材料的染色或增白中的应用
公开(公告)号：US4441885A
公开(公告)日：1984-04-10
申请号：US370761
申请日：1982-04-22
申请人： Heinz Abel , Paul Schafer
发明人： Heinz Abel , Paul Schafer
IPC分类号： D06L3/12 , D06P1/642 , D06P3/52 , D06P1/16 , D06P1/613
CPC分类号： D06P1/6421 , D06L3/1264
摘要： The invention relates to a novel anticrease finishing composition which comprises at least(A) an O-cyanoethylated compound of the formula(1) R(O--CH.sub.2 CH.sub.2 CN).sub.n, wherein R is an n-valent aliphatic, cycloaliphatic or araliphatic radical, and n is 1 to 5, and(B) a carboxylated polypropylene oxide adduct, or salt thereof, which adduct is obtainable from(a) an aliphatic diol having an average molecular weight of at most 2600,(b) an aliphatic dicarboxylic acid, or anhydride thereof, containing 4 to 10 carbon atoms,(c) an adduct of propylene oxide and an at least trihydric aliphatic alcohol containing 3 to 10 carbon atoms, and(d) a fatty acid containing 8 to 22 carbon atoms, and optionally,(C) an aliphatic alcohol containing 5 to 18 carbon atoms, a siloxane-oxyalkylene copolymer, or a mixture thereof, and/or(D) a polar solvent.The novel composition is used in dyeing or whitening textile material which contains polyester fibres.
摘要翻译：本发明涉及一种新型抗皱整理组合物，其至少包含（A）式（1）R（O-CH 2 CH 2 CN）n的O-氰乙基化化合物，其中R为n价脂肪族，脂环族或芳脂族基团，以及 n为1〜5，（B）羧基化聚环氧丙烷加成物或其盐，所述加合物可从（a）平均分子量至多为2600的脂族二醇得到，（b）脂肪族二羧酸或含有4-10个碳原子的酸酐，（c）环氧丙烷与含有3-10个碳原子的至少三元脂肪醇的加合物，和（d）含有8-22个碳原子的脂肪酸， C）含有5至18个碳原子的脂族醇，硅氧烷 - 氧化烯共聚物或其混合物，和/或（D）极性溶剂。该新型组合物用于含有聚酯纤维的染色或增白纺织材料中。

9. 发明授权

US4612352A Water-soluble or water-dispersible graft polymers, their preparation and their use 失效
标题翻译：水溶性或水分散性接枝聚合物，其制备及其用途
公开(公告)号：US4612352A
公开(公告)日：1986-09-16
申请号：US673212
申请日：1984-11-19
申请人： Paul Schafer , Heinz Abel , Christian Guth , Albert Stehlin
发明人： Paul Schafer , Heinz Abel , Christian Guth , Albert Stehlin
IPC分类号： C08F283/00 , C08F2/22 , C08F283/06 , C08L51/00 , C08L51/02 , C08L51/08 , C08L77/00 , C11D3/37 , D06P1/60 , D06P1/613 , D21C3/28 , D21H17/53 , C08G65/32 , C08L71/02
CPC分类号： C11D3/3788 , C08F283/06 , D06P1/60 , D21C3/28 , D21H17/53
摘要： Water-soluble or water-dispersible graft polymers comprising at least 20% by weight, based on said graft polymer, of a hydrophilic graft constituent bonded to a carbon atom and at least one hydrophobic radical which is bonded to the graft constituent via a polyglycol ether chain, the polyglycol ether chain containing 2 to 200 ##STR1## groups. These graft polymers can be used individually, as mixtures or in combination with other active substances as, for example, antifoams, antistatic agents, builders, emulsifiers, padding assistants, wetting agents, paper deaerators, sludge dewatering assistants, textile assistants, greying inhibitors or detergents.
摘要翻译：包含至少20重量％的基于所述接枝聚合物的粘结到碳原子的亲水接枝组分和至少一个通过聚乙二醇醚键合到接枝组分上的疏水基团的水溶性或水分散性接枝聚合物链，聚乙二醇醚链包含2至200个基团。这些接枝聚合物可以单独使用，作为混合物或与其它活性物质组合使用，例如消泡剂，抗静电剂，助洗剂，乳化剂，填充助剂，润湿剂，纸张脱气剂，污泥脱水助剂，纺织助剂，变灰抑制剂或洗涤剂

10. 发明授权

US4430261A Propylene oxide reaction products and process for their manufacture 失效
标题翻译：环氧丙烷反应产物及其制备方法
公开(公告)号：US4430261A
公开(公告)日：1984-02-07
申请号：US245420
申请日：1981-03-19
申请人： Paul Schafer , Heinz Abel , Fritz Mayer
发明人： Paul Schafer , Heinz Abel , Fritz Mayer
IPC分类号： C07C69/003 , C07C69/593 , C07C69/76 , C08G63/00 , C08G63/02 , C08G63/12 , C08G63/48 , C08G63/52 , C08G63/685 , C08G65/26 , C08G65/32 , D06M13/02 , D06M13/184 , D06M15/507 , D06M15/53 , D06P1/44 , D06P1/60 , D06P1/613 , D06P3/84 , D06P5/04 , C09F5/00
CPC分类号： D06P1/60 , C08G65/2615 , Y10S8/922 , Y10S8/924
摘要： Propylene oxide reaction products, and the salts or quaternization products thereof are provided which are obtained from(a) an at least trihydric aliphatic alcohol of 3 to 10 carbon atoms,(b) 1,2-propylene oxide,(c) an aliphatic dicarboxylic acid of 2 to 10 carbon atoms, an aromatic dicarboxylic acid of 8 to 12 carbon atoms or the anhydrides thereof, and at least one of the following components:(d) an aliphatic diol with a molecular weight of at most 2000,(e) a fatty alcohol containing 12 to 22 carbon atoms,(f) a fatty acid containing 12 to 22 carbon atoms, and(g) an aliphatic monoamine or diamine containing 2 to 12 carbon atoms,of which component (g) is used only at the conclusion and only if component (c) is ethylenically unsaturated.The inventive products are suitable for widely varying uses in textile finishing. In particular they are used as printing and dyeing assistants, for example, to improve the fastness properties of dyeings, to prevent the bleeding of non-dyed or non-printed areas during the washing-off process of these dyeings or prints, or to prevent the deposition of oligomers on the textile material during the high temperature dyeing of polyester fibres.
摘要翻译：提供了环氧丙烷反应产物及其盐或季铵化产物，其由（a）至少三元碳原子数为3〜10的脂肪族醇，（b）1,2-环氧丙烷，（c）脂肪族二羧酸 2至10个碳原子的酸，8-12个碳原子的芳族二羧酸或其酸酐，和至少一种以下组分：（d）分子量至多为2000的脂族二醇，（e）含有12-22个碳原子的脂肪醇，（f）含有12-22个碳原子的脂肪酸，和（g）含有2至12个碳原子的脂族单胺或二胺，其中组分（g）仅在结论并且仅当组分（c）是烯属不饱和的时）。本发明的产品适用于纺织品整理中广泛使用的用途。特别是它们可用作印染助剂，例如提高染色的牢度性能，以防止在这些染色或印花的洗涤过程中非染色或非印刷区域的渗色，或防止染色在聚酯纤维的高温染色期间，低聚物沉积在纺织材料上。

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