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31. 发明申请

US20080200627A1 METHOD FOR PRODUCING MELT-PROCESSABLE FLUORORESIN 有权
标题翻译：生产熔融加工氟菊酯的方法
公开(公告)号：US20080200627A1
公开(公告)日：2008-08-21
申请号：US12104788
申请日：2008-04-17
申请人： Atsushi FUNAKI , Hiroki Kamiya
发明人： Atsushi FUNAKI , Hiroki Kamiya
IPC分类号： C08F2/30
CPC分类号： C08F2/26 , C08F14/18 , C08F14/26 , C08F214/18 , C08F2/22
摘要： To provide a method for producing a melt-processable fluororesin, which is capable of increasing the molecular weight of the fluororesin and preventing coloration of the fluororesin, by using a specific fluorinated emulsifier other than ammonium perfluorooctanoate.A method for producing a melt-processable fluororesin which is characterized in that a fluorinated monomer is emulsion-polymerized in an aqueous medium containing a fluorinated emulsifier of a formula (1)XCF2CF2(O)mCF2CF2OCF2COOA wherein X is a hydrogen atom or a fluorine atom, A is a hydrogen atom, an alkali metal or NH4, and m is an integer of 0 or 1.
摘要翻译：为了提供通过使用除全氟辛酸铵以外的特定氟化乳化剂，能够提高氟树脂的分子量并防止氟树脂着色的可熔融加工性氟树脂的制造方法。一种可熔融加工的氟树脂的制造方法，其特征在于，在含有式（1）的氟化乳化剂的水性介质中将氟化单体进行乳液聚合，得到式（1）XCF 2 CF 2的氟化乳化剂，（O）m CF 2 CO 2其中X是氢原子或一个或多个氟原子，A为氢原子，碱金属或NH 4，m为0或1的整数。

32. 发明申请

US20080102285A1 MULTILAYER LAMINATE OF FLUORORESIN 有权
标题翻译：多层层状荧光素
公开(公告)号：US20080102285A1
公开(公告)日：2008-05-01
申请号：US11955979
申请日：2007-12-13
申请人： Shigeru AIDA , Toshiyuki Chisaka , Atsushi Funaki , Hiroki Kamiya
发明人： Shigeru AIDA , Toshiyuki Chisaka , Atsushi Funaki , Hiroki Kamiya
IPC分类号： B32B27/08
CPC分类号： B32B27/28 , Y10T428/3154 , Y10T428/31551 , Y10T428/31786 , Y10T428/31855 , Y10T428/31935 , Y10T428/31938
摘要： A multilayer laminate containing a laminate (I)/(II) formed by directly bonding by means of thermal lamination or the like, a layer (I) made of a fluororesin (A) with a functional group (a) and a layer (II) made of a thermoplastic resin (B) with a functional group (b) capable of forming a chemical bond by reacting with the functional group (a) of the fluororesin, wherein the fluororesin (A) has a low melting point of from 120 to 230° C. The laminate may, for example, be a multiplayer laminate containing a layer obtained by directly laminating a layer (I) made of a fluororesin (A) containing an acid anhydride residue (for example, a tetrafluoroethylene/ethylene/hexafluoropropylene/(perfluorobutyl)ethylene)/itaconic anhydride copolymer) and a layer (II) made of an amine-modified thermoplastic resin (B) (for example, a polyurethane modified with a silane coupling agent containing an amino group). The laminate is excellent in interlayer adhesion and productivity.
摘要翻译：包含通过热层压等直接接合形成的层叠体（I）/（II）的多层层叠体，由具有官能团（a）的氟树脂（A）和层（II）构成的层（I））由与氟树脂的官能团（a）反应能够形成化学键的官能团（b）的热塑性树脂（B）制成，其中氟树脂（A）的熔点低于120℃ 层压体可以是例如包含通过直接层压由含有酸酐残基（例如四氟乙烯/乙烯/六氟丙烯）的氟树脂（A）制成的层（I）而获得的层的多层叠层叠体，（全氟丁基）乙烯）/衣康酸酐共聚物）和由胺改性热塑性树脂（B）制成的层（II）（例如，用含有氨基的硅烷偶联剂改性的聚氨酯）。该层叠体的层间粘合性和生产率优异。

33. 发明申请

US20070246255A1 LAMINATE FOR PRINTED WIRING BOARD 有权
标题翻译：印刷线路板层压板
公开(公告)号：US20070246255A1
公开(公告)日：2007-10-25
申请号：US11760809
申请日：2007-06-11
申请人： Tsuyoshi Iwasa , Atsushi Funaki , Yoshiaki Higuchi
发明人： Tsuyoshi Iwasa , Atsushi Funaki , Yoshiaki Higuchi
IPC分类号： H05K1/11 , H01R12/04
CPC分类号： B32B15/08 , B32B15/20 , B32B27/304 , B32B27/322 , B32B2255/06 , B32B2255/205 , B32B2307/202 , B32B2307/206 , B32B2307/306 , B32B2457/08 , H05K1/034 , H05K2201/015 , Y10T428/264 , Y10T428/265 , Y10T428/3154 , Y10T428/31544 , Y10T428/31721
摘要： A laminate for a printed wiring board having a laminate structure comprising an electrical insulator layer (A) and an electrical conductor layer (B) bonded directly to each other, wherein the electrical insulator layer (A) is formed of a fluorocopolymer comprising repeating units (a) based on tetrafluoroethylene and/or chlorotrifluoroethylene, repeating units (b) based on a fluoromonomer excluding tetrafluoroethylene and chlorotrifluoroethylene, and repeating units (c) based on a monomer having an acid anhydride residue and a polymerizable unsaturated bond in amounts of (a) being from 50 to 99.89 mol %, (b) being from 0.1 to 49.99 mol % and (c) being from 0.01 to 5 mol %, based on ((a)+(b)+(c)), and the electrical conductor layer (B) has a surface roughness of at most 10 μm on the side being in contact with the electrical insulator layer (A) The laminate for a printed wiring board is excellent in signal response in a high frequency region.
摘要翻译：一种用于印刷线路板的叠层，其具有包括彼此直接结合的电绝缘体层（A）和电导体层（B）的叠层结构，其中所述电绝缘体层（A）由包含重复单元的含氟共聚物 a）基于四氟乙烯和/或氯三氟乙烯，基于除四氟乙烯和氯三氟乙烯之外的含氟单体的重复单元（b）和基于具有酸酐残基和可聚合不饱和键的单体的重复单元（c），其量为（a）（a）+（b）+（c））为50〜99.89摩尔％，（b）为0.1〜49.99摩尔％，（c）为0.01〜5摩尔％层（B）在与电绝缘体层（A）接触的一侧具有至多10μm的表面粗糙度。印刷电路板用层叠体在高频区域的信号响应优异。

34. 发明授权

US07205367B2 Fluorocopolymer 有权
标题翻译：含氟共聚物
公开(公告)号：US07205367B2
公开(公告)日：2007-04-17
申请号：US11023486
申请日：2004-12-29
申请人： Atsushi Funaki , Naoko Sumi , Eiichi Nishi
发明人： Atsushi Funaki , Naoko Sumi , Eiichi Nishi
IPC分类号： C08F214/24 , C08F214/26 , B29C47/20
CPC分类号： B32B27/08 , B32B1/08 , B32B27/28 , B32B27/322 , B32B27/34 , B32B2307/306 , B32B2307/712 , B32B2377/00 , B32B2597/00 , C08F214/18 , C08F214/26 , Y10T428/1321 , Y10T428/139 , Y10T428/1393 , Y10T428/3154 , Y10T428/31544
摘要： A fluorocopolymer which comprises (a) polymerized units based on tetrafluoroethylene and/or chlorotrifluoroethylene, (b) polymerized units based on a fluorinated monomer (excluding tetrafluoroethylene and chlorotrifluoroethylene) and (c) polymerized units based on at least one member selected from the group consisting of itaconic acid, itaconic anhydride, citraconic acid and citraconic anhydride, wherein (a) is from 50 to 99.8 mol %, (b) is from 0.1 to 49.99 mol %, and (c) is from 0.01 to 5 mol %, based on ((a)+(b)+(c)), and which has a volume flow rate of from 0.1 to 1000 mm3/sec.
摘要翻译：一种含氟共聚物，其包含（a）基于四氟乙烯和/或氯三氟乙烯的聚合单元，（b）基于氟化单体的聚合单元（不包括四氟乙烯和氯三氟乙烯）和（c）基于选自以下的至少一种的聚合单元：的衣康酸，衣康酸酐，柠康酸和柠康酸酐，其中（a）为50〜99.8摩尔％，（b）为0.1〜49.99摩尔％，（c）为0.01〜5摩尔％，基于（（a）+（b）+（c）），体积流量为0.1〜1000mm 3 / sec。

35. 发明申请

US20070036927A1 Laminate tube 审中-公开
标题翻译：层压管
公开(公告)号：US20070036927A1
公开(公告)日：2007-02-15
申请号：US11580975
申请日：2006-10-16
申请人： Atsushi Funaki , Tsuyoshi Iwasa
发明人： Atsushi Funaki , Tsuyoshi Iwasa
IPC分类号： F16L11/04
CPC分类号： B32B27/40 , B32B1/08 , B32B27/08 , B32B27/28 , B32B27/322 , B32B27/36 , B32B2250/02 , B32B2250/24 , B32B2307/412 , B32B2307/554 , B32B2307/712 , B32B2307/714 , B32B2307/7242 , B32B2307/7265 , B32B2535/00 , B32B2597/00 , F16L11/04 , F16L2011/047 , Y10T428/1393
摘要： A laminate tube which comprises a layer made of a fluorocopolymer containing repeating units based on at least one fluoromonomer selected from the group consisting of tetrafluoroethylene and chlorotrifluoroethylene and repeating units based on at least one functional monomer selected from the group consisting of an acid anhydride having a polymerizable unsaturated bond and a dicarboxylic acid having a polymerizable unsaturated bond, and a layer made of a non-fluororesin directly laminated, and has a haze of from 0.1 to 30%. The laminate tube is excellent in transparency, excellent in interlaminar adhesion and anti-elution properties, excellent in liquid and gas barrier properties and applicable to transportation of a liquid such as a beverage and a coating composition.
摘要翻译：一种层压管，其包含由含氟共聚物制成的层，所述含氟共聚物包含基于至少一种选自四氟乙烯和氯三氟乙烯的含氟单体的重复单元和基于至少一种选自以下的官能单体的重复单元：酸酐，其具有聚合性不饱和键和具有聚合性不饱和键的二羧酸，以及由非氟树脂直接层压制成的层，雾度为0.1〜30％。层叠管的透明性优异，层间粘合性和抗洗脱性优异，液体和气体阻隔性优异，适用于饮料和涂料组合物等液体的输送。

36. 发明授权

US07112640B2 Fluorocopolymer and its applications 有权
标题翻译：含氟共聚物及其应用
公开(公告)号：US07112640B2
公开(公告)日：2006-09-26
申请号：US11224969
申请日：2005-09-14
申请人： Atsushi Funaki , Hiroki Kamiya , Shigeru Aida , Toshiyuki Chisaka
发明人： Atsushi Funaki , Hiroki Kamiya , Shigeru Aida , Toshiyuki Chisaka
IPC分类号： C08F214/28 , C08F214/18 , C08F222/06 , C08J7/04 , G03C1/492
CPC分类号： B32B27/322 , B32B27/08 , B32B2250/24 , B32B2255/10 , B32B2255/26 , B32B2274/00 , B32B2307/306 , B32B2307/54 , B32B2307/712 , B32B2307/714 , B32B2307/7265 , B32B2605/00 , C08F214/24 , C08F214/26 , Y10T428/31507 , Y10T428/3154 , Y10T428/31721 , Y10T428/31725 , Y10T428/31786 , Y10T428/31855 , Y10T428/31935 , Y10T428/31938
摘要： A fluorocopolymer which comprises repeating units (a) based on tetrafluoroethylene and/or chlorotrifluoroethylene, repeating units (b) based on a cyclic hydrocarbon monomer having a dicarboxylic anhydride group and an endocyclic polymerizable unsaturated group, and repeating units (c) based on other monomer, wherein the repeating units (a) are from 50 to 99.89 mol %, the repeating units (b) are from 0.01 to 5 mol % and the repeating units (c) are from 0.1 to 49.99 mol %, based on the total molar amount of the repeating units (a), (b) and (c), and which has a volume flow rate of from 0.1 to 1,000 mm3/sec., and a laminate and coated product thereof. The fluorocopolymer is excellent in adhesion, heat resistance, weather resistance, stress cracking resistance and fuel barrier properties. The laminate is excellent in interlaminar bonding and fuel barrier properties. The coated product is excellent in heat resistance, chemical resistance, corrosion resistance, oil resistance, weather resistance, abrasion resistance and lubricating properties.
摘要翻译：包含基于四氟乙烯和/或三氟氯乙烯的重复单元（a）的含氟共聚物，基于具有二羧酸酐基和环内可聚合不饱和基团的环状烃单体的重复单元（b）和基于其它单体的重复单元（c），其中重复单元（a）为50〜99.89摩尔％，重复单元（b）为0.01〜5摩尔％，重复单元（c）为0.1〜49.99摩尔％的重复单元（a），（b）和（c），并且其体积流动速率为0.1至1,000mm 3 / sec，以及其层压体和涂布产品。含氟共聚物的粘合性，耐热性，耐候性，耐应力开裂性和燃料阻隔性优异。层压板具有优异的层间结合和燃料阻隔性能。涂布产品的耐热性，耐化学性，耐腐蚀性，耐油性，耐候性，耐磨性和润滑性优异。

37. 发明授权

US06855787B2 Multi-layer hose 有权
标题翻译：多层软管
公开(公告)号：US06855787B2
公开(公告)日：2005-02-15
申请号：US10617663
申请日：2003-07-14
申请人： Atsushi Funaki , Naoko Sumi , Eiichi Nishi , Noriyuki Isobe , Tomoharu Nishioka , Koji Nakamura
发明人： Atsushi Funaki , Naoko Sumi , Eiichi Nishi , Noriyuki Isobe , Tomoharu Nishioka , Koji Nakamura
IPC分类号： B60K15/01 , B32B1/08 , B32B27/28 , B32B27/30 , B32B27/34 , C08F259/08 , C08L51/00 , F16L11/04 , F16L11/11 , F16L11/127 , F16L11/15 , C08F214/18 , B29D22/00
CPC分类号： B32B1/08 , B32B27/08 , B32B27/28 , B32B27/34 , B32B2270/00 , B32B2323/043 , B32B2323/046 , B32B2367/00 , B32B2398/20 , B32B2597/00 , C08F259/08 , C08L51/003 , F16L11/127 , F16L11/15 , Y10T428/1317 , Y10T428/139 , Y10T428/1393 , C08L2666/02
摘要： A multi-layer hose having a multi-layer structure comprising an inner layer (I) made of a fluorocopolymer and an outer layer (II) made of a polyamide resin, wherein the fluorocopolymer constituting the inner layer (I) is a fluorocopolymer which comprises polymerized units (a) based on tetrafluoroethylene, polymerized units (b) based on ethylene and polymerized units (c) based on itaconic anhydride and/or citraconic anhydride, wherein the molar ratio of (a)/(b) is from 20/80 to 80/20 and the molar ratio of (c)/((a)+(b)) is from 1/10,000 to 5/100 and which has a volume flow rate of from 1 to 1,000 mm3/sec., and the polyamide resin constituting the outer layer (II) is polyamide 11 and/or polyamide 12, which satisfies a condition of (terminal amino group concentration)/(terminal carboxyl group concentration)>1.
摘要翻译：一种具有多层结构的多层软管，包括由含氟共聚物制成的内层（I）和由聚酰胺树脂制成的外层（II），其中构成内层（I）的含氟共聚物是含氟共聚物，其包含基于四氟乙烯的聚合单元（a），基于乙烯的聚合单元（b）和基于衣康酸酐和/或柠康酸酐的聚合单元（c），其中（a）/（b）的摩尔比为20/80 至80/20，（c）/（（a）+（b））的摩尔比为1 / 10,000〜5/100，体积流量为1〜1000mm 3 / sec。构成外层（II）的聚酰胺树脂是满足（末端氨基浓度）/（末端羧基浓度）> 1的条件的聚酰胺11和/或聚酰胺12。

38. 发明授权

US06528600B2 Method for producing a tetrafluoroethylene/perfluoro(alkyl vinyl ether) type copolymer 有权
标题翻译：制备四氟乙烯/全氟（烷基乙烯基醚）型共聚物的方法
公开(公告)号：US06528600B2
公开(公告)日：2003-03-04
申请号：US09910831
申请日：2001-07-24
申请人： Atsushi Funaki , Naoko Sumi
发明人： Atsushi Funaki , Naoko Sumi
IPC分类号： C08F242
CPC分类号： C08F214/262 , C08F14/26 , C08F2438/01 , C08F2/04 , C08F2/38
摘要： A method for producing a tetrafluoroethylene/perfluoro (alkyl vinyl ether) type copolymer (PFA), which comprises carrying out the polymerization in a polymerization medium (such as CHFClCF2CF2Cl) in the presence of a chain transfer agent of a C1 or 2 hydrofluorocarbon (such as CH3CF2H) by means of a polymerization initiator (such as (FCF2CF2CF2COO)2). PFA obtained by this method has a small amount of unstable terminal groups contained in its molecule and is excellent in thermal stability and cracking resistance against a liquid reagent. Further, the amount of elution of fluorine ions is little even when it is applied to a component of e.g. an equipment for the production of semiconductors.
摘要翻译：一种四氟乙烯/全氟（烷基乙烯基醚）型共聚物（PFA）的制造方法，其包括在C1或2氢氟烃的链转移剂（例如CHFClCF 2 CF 2 Cl）的存在下在聚合介质（如CHFClCF 2 CF 2 Cl）中进行聚合作为CH 3 CF 2 H）通过聚合引发剂（如（FCF 2 CF 2 CF 2 COO）2））。通过该方法获得的PFA在其分子中含有少量不稳定的末端基团，并且对液体试剂的热稳定性和耐龟裂性优异。另外，氟离子的洗脱量即使施加于例如乙烯的成分也很少。半导体生产设备。

39. 发明授权

US06461719B1 Agricultural covering material 失效
标题翻译：农业覆盖材料
公开(公告)号：US06461719B1
公开(公告)日：2002-10-08
申请号：US09720240
申请日：2000-12-22
申请人： Naomi Ichikuni , Toru Ishida , Seitoku Kaya , Atsushi Funaki , Teruo Takakura
发明人： Naomi Ichikuni , Toru Ishida , Seitoku Kaya , Atsushi Funaki , Teruo Takakura
IPC分类号： B32B310
CPC分类号： C08L27/18 , C08L2205/02 , Y10T428/24 , Y10T428/24355 , Y10T428/24405 , C08L2666/04
摘要： An agricultural covering material made of a fluorine-containing polymer film having a dynamic viscoelastic modulus of from 1 to 70 kg/mm2, a tensile strength of from 1.5 to 5.0 kg/mm2, a specific gravity of from 1.0 to 2.0 and a contact angle with water of at most 106°.
摘要翻译：由动态粘弹性模量为1〜70kg / mm 2，拉伸强度为1.5〜5.0kg / mm 2，比重为1.0〜2.0的含氟聚合物膜制成的农业覆盖材料和接触角水最多为106°。

40. 发明授权

US5494984A Method for producing a fluorinated polymer 失效
标题翻译：氟化聚合物的制造方法
公开(公告)号：US5494984A
公开(公告)日：1996-02-27
申请号：US325437
申请日：1994-11-09
申请人： Atsushi Funaki , Teruo Takakura , Kazuo Kato , Kazuo Hamazaki , Haruhisa Miyake
发明人： Atsushi Funaki , Teruo Takakura , Kazuo Kato , Kazuo Hamazaki , Haruhisa Miyake
IPC分类号： C08F2/06 , C08F2/18 , C08F2/38 , C08F14/18
CPC分类号： C08F14/18
摘要： A method for producing a fluorinated polymer containing fluoroolefin units as the main constituting units, wherein CF.sub.3 (CF.sub.2).sub.n CH.sub.2 CH.sub.3 or CF.sub.3 (CF.sub.2).sub.n H, wherein n is an integer of from 1 to 8), the is used as the polymerization medium, and CF.sub.2 ClCF.sub.2 CHClF and/or CF.sub.3 CF.sub.2 CHCl.sub.2 as a chain transfer agent.Using the polymerization medium which is less likely to bring about an environmental destruction, it is possible to obtain a fluorinated polymer excellent in the heat resistance, solvent resistance, chemical resistance, etc. Further, the above chain transfer agent has good compatibility with the polymerization medium which scarcely brings about the environmental destruction, whereby it is possible to efficiently produce a fluorinated polymer excellent in the heat resistance and solvent resistance. This chain transfer agent has affinity to the resulting polymer and to the polymerization medium and has excellent handling efficiency for post treatment such as granulation or drying.
摘要翻译： PCT No.PCT / JP94 / 00420 Sec。 371日期：1994年11月9日 102（e）日期1994年11月9日PCT 1994年3月16日PCT公布。 WO94 / 21696 PCT公开号日本特开2002-1949号公报。一种含有氟代烯烃单元作为主要构成单元的含氟聚合物的制造方法，其中，CF 3（CF 2）n CH 2 CH 3或CF 3（CF 2）n H，其中n为1〜8的整数）用作聚合介质，CF2ClCF2CHClF和/或CF3CF2CHCl2作为链转移剂。使用不太可能引起环境破坏的聚合介质，可以获得耐热性，耐溶剂性，耐化学性等优异的氟化聚合物。此外，上述链转移剂与聚合物具有良好的相容性介质几乎不会导致环境破坏，从而可以有效地制备耐热性和耐溶剂性优异的氟化聚合物。该链转移剂对所得聚合物和聚合介质具有亲和性，并且对于后处理如造粒或干燥具有优异的处理效率。

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