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1. 发明授权

US07462396B2 Multilayer laminate of fluororesin 有权
标题翻译：氟树脂多层层压板
公开(公告)号：US07462396B2
公开(公告)日：2008-12-09
申请号：US11955979
申请日：2007-12-13
申请人： Shigeru Aida , Toshiyuki Chisaka , Atsushi Funaki , Hiroki Kamiya
发明人： Shigeru Aida , Toshiyuki Chisaka , Atsushi Funaki , Hiroki Kamiya
IPC分类号： B32B27/08 , B32B27/28 , B32B27/32 , B32B27/36 , B32B27/40
CPC分类号： B32B27/28 , Y10T428/3154 , Y10T428/31551 , Y10T428/31786 , Y10T428/31855 , Y10T428/31935 , Y10T428/31938
摘要： A multilayer laminate containing a laminate (I)/(II) that is formed by directly bonding a layer (I) made of a fluororesin (A) having a functional group (a), said fluororesin (A) being an ethylene/tetrafluoroethylene/hexafluoropropylene/CH2═CH—Rf, wherein Rf copolymer is a C2-6 perfluoroalkyl group, and in the copolymer, the molar ratio of repeating units based on ethylene/repeating units based on tetrafluoroethylene/repeating units based on hexafluoropropylene/repeating units based on CH2═ CH—Rf ranges from 40/47/10/3 to 46.9/46.9/6/0.2 and a layer (II) made of a thermoplastic resin (B) having a functional group (b) that is capable of forming a chemical bond by reacting with the functional group (a) of the fluororesin, wherein the fluororesin (A) has a melting point ranging from 120 to 230° C.
摘要翻译：包含通过直接粘合由具有官能团（a）的氟树脂（A）制成的层（I）形成的层压体（I）/（II）的多层层压体，所述氟树脂（A）是乙烯/四氟乙烯/ 六氟丙烯/ CH2-CH-Rf，其中Rf共聚物是C2-6全氟烷基，在共聚物中，基于乙烯的重复单元/基于四氟乙烯/基于六氟丙烯的重复单元/基于重复单元的重复单元的摩尔比基于 CH 2 -CH-Rf为40/47/10/3至46.9 / 46.9 / 6 / 0.2，由具有能形成化学物质的官能团（b）的热塑性树脂（B）制成的层（II）通过与氟树脂的官能团（a）反应，其中氟树脂（A）的熔点为120-230℃。

2. 发明申请

US20060093827A1 Fluorocopolymer and its applications 有权
公开(公告)号：US20060093827A1
公开(公告)日：2006-05-04
申请号：US11224969
申请日：2005-09-14
申请人： Atsushi Funaki , Hiroki Kamiya , Shigeru Aida , Toshiyuki Chisaka
发明人： Atsushi Funaki , Hiroki Kamiya , Shigeru Aida , Toshiyuki Chisaka
IPC分类号： B32B27/30 , C08F214/18 , B32B27/36 , B32B27/34 , B32B27/32
CPC分类号： B32B27/322 , B32B27/08 , B32B2250/24 , B32B2255/10 , B32B2255/26 , B32B2274/00 , B32B2307/306 , B32B2307/54 , B32B2307/712 , B32B2307/714 , B32B2307/7265 , B32B2605/00 , C08F214/24 , C08F214/26 , Y10T428/31507 , Y10T428/3154 , Y10T428/31721 , Y10T428/31725 , Y10T428/31786 , Y10T428/31855 , Y10T428/31935 , Y10T428/31938
摘要： A fluorocopolymer which comprises repeating units (a) based on tetrafluoroethylene and/or chlorotrifluoroethylene, repeating units (b) based on a cyclic hydrocarbon monomer having a dicarboxylic anhydride group and an endocyclic polymerizable unsaturated group, and repeating units (c) based on other monomer, wherein the repeating units (a) are from 50 to 99.89 mol %, the repeating units (b) are from 0.01 to 5 mol % and the repeating units (c) are from 0.1 to 49.99 mol %, based on the total molar amount of the repeating units (a), (b) and (c), and which has a volume flow rate of from 0.1 to 1,000 mm3/sec., and a laminate and coated product thereof. The fluorocopolymer is excellent in adhesion, heat resistance, weather resistance, stress cracking resistance and fuel barrier properties. The laminate is excellent in interlaminar bonding and fuel barrier properties. The coated product is excellent in heat resistance, chemical resistance, corrosion resistance, oil resistance, weather resistance, abrasion resistance and lubricating properties.

3. 发明申请

US20080102285A1 MULTILAYER LAMINATE OF FLUORORESIN 有权
标题翻译：多层层状荧光素
公开(公告)号：US20080102285A1
公开(公告)日：2008-05-01
申请号：US11955979
申请日：2007-12-13
申请人： Shigeru AIDA , Toshiyuki Chisaka , Atsushi Funaki , Hiroki Kamiya
发明人： Shigeru AIDA , Toshiyuki Chisaka , Atsushi Funaki , Hiroki Kamiya
IPC分类号： B32B27/08
CPC分类号： B32B27/28 , Y10T428/3154 , Y10T428/31551 , Y10T428/31786 , Y10T428/31855 , Y10T428/31935 , Y10T428/31938
摘要： A multilayer laminate containing a laminate (I)/(II) formed by directly bonding by means of thermal lamination or the like, a layer (I) made of a fluororesin (A) with a functional group (a) and a layer (II) made of a thermoplastic resin (B) with a functional group (b) capable of forming a chemical bond by reacting with the functional group (a) of the fluororesin, wherein the fluororesin (A) has a low melting point of from 120 to 230° C. The laminate may, for example, be a multiplayer laminate containing a layer obtained by directly laminating a layer (I) made of a fluororesin (A) containing an acid anhydride residue (for example, a tetrafluoroethylene/ethylene/hexafluoropropylene/(perfluorobutyl)ethylene)/itaconic anhydride copolymer) and a layer (II) made of an amine-modified thermoplastic resin (B) (for example, a polyurethane modified with a silane coupling agent containing an amino group). The laminate is excellent in interlayer adhesion and productivity.
摘要翻译：包含通过热层压等直接接合形成的层叠体（I）/（II）的多层层叠体，由具有官能团（a）的氟树脂（A）和层（II）构成的层（I））由与氟树脂的官能团（a）反应能够形成化学键的官能团（b）的热塑性树脂（B）制成，其中氟树脂（A）的熔点低于120℃ 层压体可以是例如包含通过直接层压由含有酸酐残基（例如四氟乙烯/乙烯/六氟丙烯）的氟树脂（A）制成的层（I）而获得的层的多层叠层叠体，（全氟丁基）乙烯）/衣康酸酐共聚物）和由胺改性热塑性树脂（B）制成的层（II）（例如，用含有氨基的硅烷偶联剂改性的聚氨酯）。该层叠体的层间粘合性和生产率优异。

4. 发明授权

US07112640B2 Fluorocopolymer and its applications 有权
标题翻译：含氟共聚物及其应用
公开(公告)号：US07112640B2
公开(公告)日：2006-09-26
申请号：US11224969
申请日：2005-09-14
申请人： Atsushi Funaki , Hiroki Kamiya , Shigeru Aida , Toshiyuki Chisaka
发明人： Atsushi Funaki , Hiroki Kamiya , Shigeru Aida , Toshiyuki Chisaka
IPC分类号： C08F214/28 , C08F214/18 , C08F222/06 , C08J7/04 , G03C1/492
CPC分类号： B32B27/322 , B32B27/08 , B32B2250/24 , B32B2255/10 , B32B2255/26 , B32B2274/00 , B32B2307/306 , B32B2307/54 , B32B2307/712 , B32B2307/714 , B32B2307/7265 , B32B2605/00 , C08F214/24 , C08F214/26 , Y10T428/31507 , Y10T428/3154 , Y10T428/31721 , Y10T428/31725 , Y10T428/31786 , Y10T428/31855 , Y10T428/31935 , Y10T428/31938
摘要： A fluorocopolymer which comprises repeating units (a) based on tetrafluoroethylene and/or chlorotrifluoroethylene, repeating units (b) based on a cyclic hydrocarbon monomer having a dicarboxylic anhydride group and an endocyclic polymerizable unsaturated group, and repeating units (c) based on other monomer, wherein the repeating units (a) are from 50 to 99.89 mol %, the repeating units (b) are from 0.01 to 5 mol % and the repeating units (c) are from 0.1 to 49.99 mol %, based on the total molar amount of the repeating units (a), (b) and (c), and which has a volume flow rate of from 0.1 to 1,000 mm3/sec., and a laminate and coated product thereof. The fluorocopolymer is excellent in adhesion, heat resistance, weather resistance, stress cracking resistance and fuel barrier properties. The laminate is excellent in interlaminar bonding and fuel barrier properties. The coated product is excellent in heat resistance, chemical resistance, corrosion resistance, oil resistance, weather resistance, abrasion resistance and lubricating properties.
摘要翻译：包含基于四氟乙烯和/或三氟氯乙烯的重复单元（a）的含氟共聚物，基于具有二羧酸酐基和环内可聚合不饱和基团的环状烃单体的重复单元（b）和基于其它单体的重复单元（c），其中重复单元（a）为50〜99.89摩尔％，重复单元（b）为0.01〜5摩尔％，重复单元（c）为0.1〜49.99摩尔％的重复单元（a），（b）和（c），并且其体积流动速率为0.1至1,000mm 3 / sec，以及其层压体和涂布产品。含氟共聚物的粘合性，耐热性，耐候性，耐应力开裂性和燃料阻隔性优异。层压板具有优异的层间结合和燃料阻隔性能。涂布产品的耐热性，耐化学性，耐腐蚀性，耐油性，耐候性，耐磨性和润滑性优异。

5. 发明申请

US20060233992A1 Laminate hose made of fluorocopolymer 有权
标题翻译：由含氟共聚物制成的层压软管
公开(公告)号：US20060233992A1
公开(公告)日：2006-10-19
申请号：US11391311
申请日：2006-03-29
申请人： Atsushi Funaki , Toshiyuki Chisaka , Hiroki Kamiya
发明人： Atsushi Funaki , Toshiyuki Chisaka , Hiroki Kamiya
IPC分类号： B32B1/08
CPC分类号： F16L11/045 , B32B1/08 , B32B27/08 , B32B27/322 , B32B27/325 , B32B27/34 , B32B2250/24 , B32B2307/306 , B32B2307/546 , B32B2307/712 , B32B2307/714 , B32B2307/7265 , B32B2597/00 , B32B2605/00 , C08F214/18 , C08F214/245 , C08F214/265 , F16L2011/047 , Y10T428/1352 , Y10T428/139 , Y10T428/1393 , Y10T428/3154 , Y10T428/31743
摘要： A laminate hose comprising a laminate of a fluorocopolymer and a polyamide, wherein the fluorocopolymer comprises repeating units (a) based on tetrafluoroethylene and/or chlorotrifluoroethylene, repeating units (b) based on a cyclic hydrocarbon monomer having a dicarboxylic anhydride group and having a polymerizable unsaturated group in the ring, and repeating units (c) based on another fluoromonomer (excluding tetrfluoroethylene and chlorofluoroethylene) with contents of the repeating units (a) of from 50 to 99.89 mol %, the repeating units (b) of from 0.01 to 5 mol % and the repeating units (c) of from 0.1 to 49.99 mol % based on the total number of mols of the repeating units (a), (b) and (c), and has a flow coefficient of from 0.1 to 1,000 mm3/sec.
摘要翻译：一种包含含氟共聚物和聚酰胺的层压体的层压软管，其中所述含氟共聚物包含基于四氟乙烯和/或氯三氟乙烯的重复单元（a），基于具有二羧酸酐基团的环状烃单体的重复单元（b）不饱和基团，以及重复单元（b）为0.05〜99.89摩尔％，重复单元（b）为0.01〜5的重复单元（c），基于另外的含氟单体（不包括四氟乙烯和氯氟乙烯）摩尔％，重复单元（c）为重复单元（a），（b）和（c）的总摩尔数为0.1〜49.99摩尔％，流动系数为0.1〜1000毫米 ³

6. 发明授权

US07662454B2 Laminate hose made of fluorocopolymer 有权
标题翻译：由含氟共聚物制成的层压软管
公开(公告)号：US07662454B2
公开(公告)日：2010-02-16
申请号：US11391311
申请日：2006-03-29
申请人： Atsushi Funaki , Toshiyuki Chisaka , Hiroki Kamiya
发明人： Atsushi Funaki , Toshiyuki Chisaka , Hiroki Kamiya
IPC分类号： B32B1/06 , B32B27/06 , B32B27/18 , B32B27/30
CPC分类号： F16L11/045 , B32B1/08 , B32B27/08 , B32B27/322 , B32B27/325 , B32B27/34 , B32B2250/24 , B32B2307/306 , B32B2307/546 , B32B2307/712 , B32B2307/714 , B32B2307/7265 , B32B2597/00 , B32B2605/00 , C08F214/18 , C08F214/245 , C08F214/265 , F16L2011/047 , Y10T428/1352 , Y10T428/139 , Y10T428/1393 , Y10T428/3154 , Y10T428/31743
摘要： A laminate hose comprising a laminate of a fluorocopolymer and a polyamide, wherein the fluorocopolymer comprises repeating units (a) based on tetrafluoroethylene and/or chlorotrifluoroethylene, repeating units (b) based on a cyclic hydrocarbon monomer having a dicarboxylic anhydride group and having a polymerizable unsaturated group in the ring, and repeating units (c) based on another fluoromonomer (excluding tetrfluoroethylene and chlorofluoroethylene) with contents of the repeating units (a) of from 50 to 99.89 mol %, the repeating units (b) of from 0.01 to 5 mol % and the repeating units (c) of from 0.1 to 49.99 mol % based on the total number of mols of the repeating units (a), (b) and (c), and has a flow coefficient of from 0.1 to 1,000 mm3/sec.
摘要翻译：一种包含含氟共聚物和聚酰胺的层压体的层压软管，其中所述含氟共聚物包含基于四氟乙烯和/或氯三氟乙烯的重复单元（a），基于具有二羧酸酐基团的环状烃单体的重复单元（b）不饱和基团，以及重复单元（b）为0.05〜99.89摩尔％，重复单元（b）为0.01〜5的重复单元（c），基于另外的含氟单体（不包括四氟乙烯和氯氟乙烯）摩尔％，重复单元（c）为重复单元（a），（b）和（c）的总摩尔数为0.1〜49.99摩尔％，流动系数为0.1〜1000毫米3 /秒。

7. 发明申请

US20060205903A1 Fluoropolymer and film made of it 有权
标题翻译：含氟聚合物及其制成的薄膜
公开(公告)号：US20060205903A1
公开(公告)日：2006-09-14
申请号：US11430054
申请日：2006-05-09
申请人： Shigeru Aida , Atsushi Funaki
发明人： Shigeru Aida , Atsushi Funaki
IPC分类号： C08F16/24
CPC分类号： C08F214/265 , C08F214/18 , C08F214/26 , C08J5/18 , C08J2327/12
摘要： (OBJECT) To provide a fluorocopolymer excellent in transparency and excellent in mechanical strength at room temperature and at high temperature, and a film made of it. (MEANS TO ACHIEVE THE OBJECT) A fluorocopolymer comprising polymerized units based on ethylene, polymerized units based on tetrafluoroethylene, polymerized units based on hexafluoropropylene and polymerized units based on a perfluoro(alkyl vinyl ether), characterized in that the molar ratio of polymerized units based on ethylene/polymerized units based on tetrafluoroethylene is from 10/90 to 60/40, the content of the polymerized units based on hexafluoropropylene is from 0.1 to 1.0 mol % based on the total polymerized units, and the content of the polymerized units based on a perfluoro(alkyl vinyl ether) is from 0.1 to 1.0 mol % based on the total polymerized units.
摘要翻译：（OBJECT）为了提供透明性优异且在室温和高温下的机械强度优异的含氟共聚物及其制成的膜。（意图实现对象）含有基于乙烯的聚合单元，基于四氟乙烯的聚合单元，基于六氟丙烯的聚合单元和基于全氟（烷基乙烯基醚）的聚合单元的含氟共聚物，其特征在于，基于聚合单元的聚合单元的摩尔比对于基于四氟乙烯的乙烯/聚合单元为10/90〜60/40，基于六氟丙烯的聚合单元的含量相对于总聚合单元为0.1〜1.0摩尔％，聚合单元的含量基于全氟（烷基乙烯基醚）相对于总聚合单元为0.1〜1.0摩尔％。

8. 发明授权

US07019079B2 Tetrafluoroethylene/ethylene copolymer composition 有权
标题翻译：四氟乙烯/乙烯共聚物组成
公开(公告)号：US07019079B2
公开(公告)日：2006-03-28
申请号：US10676122
申请日：2003-10-02
申请人： Naoko Sumi , Shigeru Aida , Atsushi Funaki , Masahide Yodogawa , Tsuyoshi Iwasa
发明人： Naoko Sumi , Shigeru Aida , Atsushi Funaki , Masahide Yodogawa , Tsuyoshi Iwasa
IPC分类号： C08L214/26 , C08L23/00 , C08L23/04 , C08L27/12
CPC分类号： C08L27/18 , C08K3/041 , C08L2205/025
摘要： A tetrafluoroethylene/ethylene copolymer composition comprising a tetrafluoroethylene/ethylene copolymer (A) and a thermoplastic fluoropolymer (B) having a crystallization temperature higher than the crystallization temperature of said tetrafluoroethylene/ethylene copolymer (A) in a mass ratio of (A)/(B)=from 99.8/0.2 to 1/99. The composition is excellent in melt processability, and its formed product is excellent in mechanical properties and fuel barrier properties.
摘要翻译：包含结晶温度高于所述四氟乙烯/乙烯共聚物（A）的结晶温度的四氟乙烯/乙烯共聚物（A）和热塑性含氟聚合物（B）的四氟乙烯/乙烯共聚物组合物的质量比为（A）/（ B）= 99.8 / 0.2〜1/99。该组合物的熔融加工性优异，其成型体的机械性能和燃料阻隔性优异。

9. 发明授权

US07402640B2 Fluoropolymer and film made of it 有权
标题翻译：含氟聚合物及其制成的薄膜
公开(公告)号：US07402640B2
公开(公告)日：2008-07-22
申请号：US11430054
申请日：2006-05-09
申请人： Shigeru Aida , Atsushi Funaki
发明人： Shigeru Aida , Atsushi Funaki
IPC分类号： C08F16/24
CPC分类号： C08F214/265 , C08F214/18 , C08F214/26 , C08J5/18 , C08J2327/12
摘要： A fluorocopolymer and film thereof exhibiting excellent transparency and mechanical strength at ambient and elevated temperatures, wherein the fluorocopolymer includes polymerized units based on ethylene (E), tetrafluoroethylene (TFE), hexafluoropropylene (HFP) and perfluoro(alkyl vinyl ether) (PFAV), wherein the molar ratio of polymerized units based on E/TFE is from 10/90 to 60/40, the content of polymerized units based on HFP is from 0.2 to 0.9 mol % based on the total number of polymerized units, and the content of polymerized units based on PFAV is from 0.1 to 1.0 mol % based on the total number of polymerized units.
摘要翻译：含氟共聚物及其膜在环境温度和高温下表现出优异的透明性和机械强度，其中含氟共聚物包括基于乙烯（E），四氟乙烯（TFE），六氟丙烯（HFP）和全氟（烷基乙烯基醚）（PFAV）的聚合单元，其中基于E / TFE的聚合单元的摩尔比为10/90〜60/40，基于HFP的聚合单元的含量相对于聚合单元的总数为0.2〜0.9摩尔％基于PFAV的聚合单元相对于聚合单元的总数为0.1〜1.0摩尔％。

10. 发明授权

US06753393B2 Fluorocopolymer 有权
标题翻译：含氟共聚物
公开(公告)号：US06753393B2
公开(公告)日：2004-06-22
申请号：US10356536
申请日：2003-02-03
申请人： Atsushi Funaki , Tatsuya Miyajima , Naoko Sumi , Eiichi Nishi , Hiroki Kamiya
发明人： Atsushi Funaki , Tatsuya Miyajima , Naoko Sumi , Eiichi Nishi , Hiroki Kamiya
IPC分类号： C08F11418
CPC分类号： C08F214/265
摘要： A fluorocopolymer which comprises (A) polymerized units based on tetrafluoroethylene, (B) polymerized units based on ethylene and (C) polymerized units based on a compound represented by CH2═CX(CF2)2Y (wherein each of X and Y which are independent of each other, is a hydrogen atom or a fluorine atom), wherein the molar ratio of (A)/(B) is from 20/80 to 80/20, and the molar ratio of (C)/((A)+(B)) is from 1/1000 to 15/100, and which has a volume flow rate of from 1 to 1000 mm3/sec. The fluorocopolymer has a low fuel permeability coefficient and is excellent in the fuel barrier properties.
摘要翻译：一种含氟共聚物，其包含（A）基于四氟乙烯的聚合单元，（B）基于乙烯的聚合单元和（C）基于由CH 2 = CX（CF 2）2 Y表示的化合物的聚合单元（其中X和Y各自独立地（A）/（B）的摩尔比为20/80〜80/20，摩尔比（C）/（（A）+ （B））为1/1000〜15/100，体积流量为1〜1000mm 3 / sec。含氟共聚物的燃料渗透系数低，燃料阻隔性优异。

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