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21. 发明授权

US5498587A Hydrogenation catalyst, a process for its preparation, and use thereof 失效
标题翻译：氢化催化剂，其制备方法及其用途
公开(公告)号：US5498587A
公开(公告)日：1996-03-12
申请号：US217151
申请日：1994-03-24
申请人： Gregor Deckers , Gerhard Diekhaus , Bernd Dorsch , Carl D. Frohning , Gerhardt Horn , Horst B. Horrig
发明人： Gregor Deckers , Gerhard Diekhaus , Bernd Dorsch , Carl D. Frohning , Gerhardt Horn , Horst B. Horrig
IPC分类号： B01J21/16 , B01J23/755 , B01J23/78 , B01J32/00 , B01J35/10 , B01J37/18 , C07B61/00 , C07C29/141 , C07C31/10 , C07C31/12 , C09K3/00 , B01J21/10 , B01J23/04
CPC分类号： B01J35/10 , B01J23/755 , B01J23/78 , C07C29/141 , C07C31/10 , C07C31/12 , B01J35/0053 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/108
摘要： A hydrogenation catalyst comprising 25 to 50% by weight of nickel (metallic) 10 to 35% by weight of nickel oxide 4 to 12% by weight of magnesium oxide 1 to 5% by weight of sodium oxide the remainder being a water-insoluble support material,wherein the total of nickel and nickel oxide is 40% to 70% by weight, and the catalyst has a surface area, determined by BET, of 80 to 200 m.sup.2 /g and a total pore volume of 0.35 to 0.6 ml/g. The total pore volume is made up of 30% to 60% by volume from pores having pore radii of .ltoreq.40 .ANG., 4% to 10% by volume from pores having pore radii of >40 to 300 .ANG., and 30% to 60% by volume from pores having pore radii of >300 to 5000 .ANG..A process for preparing the hydrogenation catalyst which comprises preparing, in a precipitation step, a green catalyst from a nickel salt, a magnesium salt, sodium carbonate, and the support material, separating off the mother liquor and partially washing the precipitate, slurrying the green catalyst in alkali solution, separating it from the liquid phase, drying it, and contacting the dried green catalyst with hydrogen until 48% to 86% by weight of the total nickel content is present in metallic form.The hydrogenation catalyst of the invention is particularly suitable for the hydrogenation of propanal, n-butanal, and i-butanal, especially at temperatures between 100.degree. and 160.degree. C.
摘要翻译：一种氢化催化剂，其包含25-50％重量的镍（金属），10-35％（重量）的氧化镍，4至12％（重量）的氧化镁，1至5％（重量）的氧化钠，其余为不溶于水的载体材料，其中镍和氧化镍的总量为40重量％至70重量％，并且催化剂具有由BET测定的表面积为80至200m 2 / g，总孔体积为0.35至0.6ml / g 。总孔体积由孔径为40μm〜40μm的孔径为4〜10体积％的孔径为30〜60体积％，孔径为40〜300埃的孔径为30〜 60％体积的孔径为> 300至5000的孔。一种制备氢化催化剂的方法，包括在沉淀步骤中，从镍盐，镁盐，碳酸钠和载体材料中制备绿色催化剂，分离母液并部分洗涤沉淀物，将绿色碱性溶液中的催化剂，将其与液相分离，干燥，并将干燥的生坯催化剂与氢气接触，直到总镍含量的48重量％至86重量％以金属形式存在。本发明的氢化催化剂特别适用于丙醛，正丁醛和异丁醛的加氢，特别是在100至160℃的温度下。

22. 发明授权

US5493064A Noble metal large pore zeolyte catalyst for methanol-ethanol coupling 失效
标题翻译：贵金属大孔沸石溶剂甲醇 - 乙醇偶联催化剂
公开(公告)号：US5493064A
公开(公告)日：1996-02-20
申请号：US354984
申请日：1994-12-13
申请人： Thomas H. Vanderspurt , Jar-Lin Kao
发明人： Thomas H. Vanderspurt , Jar-Lin Kao
IPC分类号： C07C29/34 , C07C31/10 , C07C31/12
CPC分类号： C07C29/34 , Y02P20/582
摘要： The present invention discloses an alcohol coupling process in which a vaporized mixture of starting alcohols, preferably methanol and ethanol, is reacted with syngas in the presence of a large pore L zeolite, Y zeolite or large port mordenite, to form at least one alcohol coupling product having a greater number of carbon atoms than all of the starting alcohols. The large pore zeolite preferably has a substantial absence of strongly acidic catalytic sites and the reaction preferably produces the product alcohol in the substantial absence of C.sub.6+ oxygenates.
摘要翻译：本发明公开了一种醇耦合方法，其中起始醇，优选甲醇和乙醇的蒸发混合物在大孔L沸石，Y沸石或大口径丝光沸石存在下与合成气反应，以形成至少一种醇偶联产物具有比所有起始醇更多的碳原子数。大孔沸石优选基本上不存在强酸性催化位点，反应优选在基本上没有C6 +含氧化合物的情况下产生产物醇。

23. 发明授权

US5401889A Preparation of tertiary butyl alcohol by catalytic decomposition of tertiary butyl hydroperoxide 失效
标题翻译：通过叔丁基过氧化氢的催化分解制备叔丁醇
公开(公告)号：US5401889A
公开(公告)日：1995-03-28
申请号：US150916
申请日：1993-11-12
申请人： John R. Sanderson , Mark A. Mueller , Yu-Hwa E. Sheu
发明人： John R. Sanderson , Mark A. Mueller , Yu-Hwa E. Sheu
IPC分类号： B01J23/52 , C07B61/00 , C07C27/00 , C07C29/132 , C07C31/12 , C07C29/00 , C07C29/88
CPC分类号： C07C29/132
摘要： A method for preparing tertiary butyl alcohol wherein a feedstock comprising a solution of tertiary butyl hydroperoxide in a cosolvent mixture of tertiary butyl alcohol with isobutane is charged to a hydroperoxide decomposition reaction zone containing a catalytically effective amount of a hydroperoxide decomposition catalyst and is brought into contact with the catalyst in liquid phase with agitation under hydroperoxide decomposition reaction conditions to convert the tertiary butyl hydroperoxide to decomposition products, principally tertiary butyl alcohol.
摘要翻译：制备叔丁醇的方法，其中在叔丁醇与异丁烷的共溶剂混合物中包含叔丁基过氧化氢溶液的原料加入含有催化有效量的氢过氧化物分解催化剂的氢过氧化物分解反应区，并与之接触催化剂在液相中在氢过氧化物分解反应条件下搅拌，将叔丁基氢过氧化物转化成分解产物，主要是叔丁醇。

24. 发明授权

US5395988A Metal-ligand catalyzed decomposition of organic hydroperoxides 失效
标题翻译：金属 - 配体催化分解有机氢过氧化物
公开(公告)号：US5395988A
公开(公告)日：1995-03-07
申请号：US223090
申请日：1994-04-04
申请人： Manoj V. Bhinde , James E. Lyons , Paul E. Ellis, Jr.
发明人： Manoj V. Bhinde , James E. Lyons , Paul E. Ellis, Jr.
IPC分类号： A62D3/00 , A62D3/37 , A62D101/28 , C07C29/132 , C07C31/12 , C07C35/08 , C07C45/53 , C07C407/00 , C07C29/00 , C07C33/22 , C07C35/14
CPC分类号： A62D3/37 , C07C29/132 , C07C31/12 , C07C35/08 , C07C407/003 , C07C45/53 , A62D2101/28 , C07C2101/14
摘要： Organic hydroperoxides are decomposed by drying a reaction mixture containing the organic hydroperoxide and an organic solvent and contacting the dried reaction mixture with a metal organic ligand catalyst under hydroperoxide decomposition conditions. An organic co-solvent for the hydroperoxide may also be used.
摘要翻译：通过干燥含有机氢过氧化物和有机溶剂的反应混合物分解有机氢过氧化物，并在氢过氧化物分解条件下使干燥的反应混合物与金属有机配体催化剂接触。也可以使用氢过氧化物的有机助溶剂。

25. 发明授权

US5360520A Separation of 2-butanol from t-amyl alcohol by extractive distillation 失效
标题翻译：通过萃取蒸馏从叔戊醇中分离出2-丁醇
公开(公告)号：US5360520A
公开(公告)日：1994-11-01
申请号：US181785
申请日：1994-01-18
申请人： Lloyd Berg
发明人： Lloyd Berg
IPC分类号： C07C29/84 , C07C31/12 , B01D3/40
CPC分类号： C07C31/12 , C07C29/84
摘要： 2-Butanol is difficult to separate from t-amyl alcohol by conventional distillation or rectification because of the proximity of their boiling points. 2-Butanol can be readily separated from t-amyl alcohol by extractive distillation. Effective agents are methyl caproate, adiponitrile and cyclopentanone.
摘要翻译：由于其沸点接近，常规的蒸馏或精馏，2-丁醇难以与叔戊醇分离。 2-丁醇可以通过萃取蒸馏容易地从叔戊醇中分离出来。有效剂是己酸甲酯，己二腈和环戊酮。

26. 发明授权

US5359130A Use of supported palladium/platinum catalysts in the preparation of tertiary butyl alcohol from tertiary butyl hydroperoxide 失效
标题翻译：在叔丁基过氧化氢制备叔丁醇中使用负载型钯/铂催化剂
公开(公告)号：US5359130A
公开(公告)日：1994-10-25
申请号：US150915
申请日：1993-11-12
申请人： John R. Sanderson , Roger G. Duranleau , John F. Knifton
发明人： John R. Sanderson , Roger G. Duranleau , John F. Knifton
IPC分类号： B01J23/44 , C07B61/00 , C07C27/00 , C07C29/132 , C07C29/88 , C07C31/12
CPC分类号： C07C29/88 , C07C29/132 , C07C31/12
摘要： A method for preparing tertiary butyl alcohol wherein a feedstock comprising a solvent solution of tertiary butyl hydroperoxide in tertiary butyl alcohol or a mixture of tertiary butyl alcohol with isobutane is charged to a hydroperoxide decomposition reaction zone containing a catalytically effective amount of a hydroperoxide decomposition catalyst consisting essentially of alumina having palladium and platinum deposited thereon and is brought into contact with the catalyst in liquid phase under hydroperoxide decomposition reaction conditions to convert the tertiary butyl hydroperoxide to decomposition products, principally tertiary butyl alcohol.
摘要翻译：一种制备叔丁醇的方法，其中将叔丁基过氧化氢在叔丁醇中的溶剂溶液或叔丁醇与异丁烷的混合物的原料装入含有催化有效量的氢过氧化物分解催化剂的氢过氧化物分解反应区，基本上是在其上沉积有钯和铂的氧化铝，并在氢过氧化物分解反应条件下与液相中的催化剂接触，将叔丁基氢过氧化物转化成分解产物，主要是叔丁醇。

27. 发明授权

US5043486A Aquathermolytic cleavage of ethers 失效
标题翻译：醚水解裂解
公开(公告)号：US5043486A
公开(公告)日：1991-08-27
申请号：US572485
申请日：1990-08-23
申请人： Michael Siskin , Glen B. Brons , Ramzi Y. Saleh , Stephen N. Vaughn
发明人： Michael Siskin , Glen B. Brons , Ramzi Y. Saleh , Stephen N. Vaughn
IPC分类号： C07C29/10 , C07C31/02 , C07C31/10 , C07C31/12
CPC分类号： C07C29/10
摘要： The present invention provides for a simplified process for converting ethers into their corresponding alcohols comprising forming an aqueous mixture of the ether and at least about 50% by weight water and heating the mixture under autogeneous pressure at a temperature of from about 250.degree. to 450.degree. C., more preferably from about 250.degree. C. up to the critical temperature of water which is about 374.degree. C. Heating is continued for a period of time sufficient to convert at least about 20% by weight of the ether, usually from about 5 up to about 120 minutes, depending on temperature and the amount of water present, and the identity of the starting ether feedstock.The process may be characterized as an aquathermolysis reaction wherein the reaction proceeds in water primarily through ionic routes rather than through free radical routes. Accordingly, relatively high conversion rates and good yields of alcohol and other reaction by-products may be obtained without the necessity of using a catalyst in the process.
摘要翻译：本发明提供了将醚转化成其相应的醇的简化方法，包括形成醚的水性混合物和至少约50重量％的水，并在约250-450℃的温度下在自主压力下加热混合物更优选约250℃至约374℃的水的临界温度。继续加热足够的时间以使至少约20重量％的乙醚转化成通常为约 5至约120分钟，这取决于温度和存在的水的量以及起始醚原料的特性。该方法可以表征为水解溶解反应，其中反应在水中主要通过离子路线而不是通过自由基途径进行。因此，可以获得醇和其它反应副产物的相对高的转化率和良好的产率，而不需要在该方法中使用催化剂。

28. 发明授权

US5023389A Process for preparing normally liquid oxygenate and hydrocarbonaceous products from a hydrocarbon feed containing linear- and branched olefins 失效
标题翻译：从含有直链和支链烯烃的烃进料制备正常液态含氧化合物和烃类产物的方法
公开(公告)号：US5023389A
公开(公告)日：1991-06-11
申请号：US308489
申请日：1989-02-10
申请人： Pierre Grandvallet , Andras G. T. G. Kortbeek , Johannes P. Van Den Berg , Karl-Heinz Robschlager
发明人： Pierre Grandvallet , Andras G. T. G. Kortbeek , Johannes P. Van Den Berg , Karl-Heinz Robschlager
IPC分类号： B01J29/04 , B01J23/12 , B01J29/24 , B01J29/26 , B01J29/87 , C07B61/00 , C07C1/00 , C07C2/12 , C07C2/58 , C07C5/27 , C07C5/32 , C07C5/393 , C07C5/41 , C07C11/02 , C07C27/00 , C07C29/04 , C07C31/12 , C07C41/00 , C07C41/06 , C07C43/04 , C07C67/00 , C10G50/00 , C10L1/06
CPC分类号： C07C41/06 , C07C11/02 , C10G50/00 , C10L1/06
摘要： The invention relates to a process for preparing normally liquid hydrocarbon products such as middle distillates and methyl-t-butylether from a hydrocarbon feed containing linear and branched olefins (e.g. propane and butenes in light ends) comprising at least the following steps:i) selectively converting branched olefins in the feed in the presence of a catalyst into a normally liquid hydrocarbonaceous product (e.g. MTBE);ii) separating linear olefins from product obtained in step (i), andiii) catalytically oligomerizing linear olefins obtained from step (ii) into liquid hydrocarbons such as middle distillates.

29. 发明授权

US4880937A Method of producing alcohol compounds 失效
标题翻译：醇化合物的制备方法
公开(公告)号：US4880937A
公开(公告)日：1989-11-14
申请号：US157246
申请日：1988-02-18
申请人： Hajime Matsushita , Makoto Shibagaki , Kyoko Takahashi
发明人： Hajime Matsushita , Makoto Shibagaki , Kyoko Takahashi
IPC分类号： C07C33/22 , B01J21/06 , B01J23/14 , C07B31/00 , C07B41/02 , C07B61/00 , C07C27/00 , C07C29/147 , C07C29/149 , C07C31/12 , C07C31/125 , C07C31/135 , C07C67/00 , C07C67/03
CPC分类号： C07C29/149 , B01J21/063 , B01J21/066 , B01J23/14 , C07C2101/14
摘要： An alcohol compound is produced by reducing a carboxylic acid or an ester thereof with an alcohol in the presence of a solid catalyst. The catalyst includes a hydrous metal oxide belonging to Group IV of the Periodic Table.

30. 发明授权

US4803305A Isobutane oxidation in the presence of a soluble iron complex as catalyst 失效
标题翻译：在可溶性铁络合物作为催化剂存在下，异丁烷氧化
公开(公告)号：US4803305A
公开(公告)日：1989-02-07
申请号：US125965
申请日：1987-11-27
申请人： John R. Sanderson , Edward T. Marquis , Jiang-Jen Lin
发明人： John R. Sanderson , Edward T. Marquis , Jiang-Jen Lin
IPC分类号： B01J31/04 , B01J31/22 , C07C29/50 , C07C45/33 , C07C409/04 , C07C179/025 , C07C31/12
CPC分类号： C07C409/04 , B01J31/2226 , C07C29/50 , C07C407/00 , C07C45/33 , B01J2231/70 , B01J2531/0216 , B01J2531/842 , Y02P20/52
摘要： The oxidation of isobutane in the presence of a novel, soluble catalyst of the formula Fe.sub.3 O(Pivalate).sub.6 (MeOH).sub.3 Cl is disclosed. Tertiary-Butyl alcohol, tertiary-butyl hydroperoxide, and acetone are produced. A significant increase in isobutane conversion is obtained without a large decrease in selectivity to tertiary-butyl alcohol and tertiary-butyl hydroperoxide using a small amount of catalyst. Tertiary-butyl alcohol is useful as a gasoline additive and tertiary-butyl hydroperoxide is used for the production of propylene oxide. Acetone has a variety of uses as well.
摘要翻译：公开了在式Fe 3 O（新戊酸酯）6（MeOH）3Cl）的新型可溶性催化剂存在下异丁烷的氧化。制备叔丁醇，叔丁基过氧化氢和丙酮。在使用少量催化剂的叔丁醇和叔丁基过氧化氢的选择性没有大的降低的情况下，异丁烷转化率显着增加。叔丁醇可用作汽油添加剂，叔丁基过氧化氢用于生产环氧丙烷。丙酮也有各种用途。

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