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1. 发明授权

US08859821B2 Polyketone plasticizers 有权
标题翻译：聚酮增塑剂
公开(公告)号：US08859821B2
公开(公告)日：2014-10-14
申请号：US13345014
申请日：2012-01-06
申请人： Allen D. Godwin , Kenneth J. Buturla , Karla S. Colle , Gabor Kiss , Kirk C. Nadler , Abhimanyu O. Patil , Edris Eileen Pike , Ramzi Y. Saleh , Jon E. Stanat , Manika Varma-Nair , Stephen Zushma
发明人： Allen D. Godwin , Kenneth J. Buturla , Karla S. Colle , Gabor Kiss , Kirk C. Nadler , Abhimanyu O. Patil , Edris Eileen Pike , Ramzi Y. Saleh , Jon E. Stanat , Manika Varma-Nair , Stephen Zushma
IPC分类号： C07C45/00 , C07C45/27 , C08L101/00 , C08G67/00 , C08G67/02 , C08L73/00
CPC分类号： C08G67/02 , C08L73/00 , C08L101/00 , C08L2666/14
摘要： The invention relates to polyketone compounds and the at least partially hydrogenated products thereof, the use of said polyketone compounds and/or the at least partially hydrogenated products thereof as plasticizers, processes of making polyketone compounds and the at least partially hydrogenated products thereof, compositions comprising the polyketone compounds and/or the at least partially hydrogenated products thereof, and to articles formed from products of the invention.
摘要翻译：本发明涉及聚酮化合物及其至少部分氢化的产物，所述聚酮化合物和/或其至少部分氢化产物作为增塑剂的用途，制备聚酮化合物的方法及其至少部分氢化的产物，包含聚酮化合物和/或其至少部分氢化的产物，以及由本发明的产物形成的制品。

2. 发明申请

US20080242895A1 Polyketone Plasticizers 失效
标题翻译：聚酮增塑剂
公开(公告)号：US20080242895A1
公开(公告)日：2008-10-02
申请号：US12058397
申请日：2008-03-28
申请人： Allen D. Godwin , Kenneth J. Buturla , Karla S. Colle , Gabor Kiss , Kirk C. Nadler , Abhimanyu O. Patil , Edris Eileen Pike , Ramzi Y. Saleh , Jon E. Stanat , Manika Varma-Nair , Stephen Zushma
发明人： Allen D. Godwin , Kenneth J. Buturla , Karla S. Colle , Gabor Kiss , Kirk C. Nadler , Abhimanyu O. Patil , Edris Eileen Pike , Ramzi Y. Saleh , Jon E. Stanat , Manika Varma-Nair , Stephen Zushma
IPC分类号： C07C45/27
CPC分类号： C08G67/02 , C08L73/00 , C08L101/00 , C08L2666/14
摘要： The invention relates to polyketone compounds and the at least partially hydrogenated products thereof, the use of said polyketone compounds and/or the at least partially hydrogenated products thereof as plasticizers, processes of making polyketone compounds and the at least partially hydrogenated products thereof, compositions comprising the polyketone compounds and/or the at least partially hydrogenated products thereof, and to articles formed from products of the invention.
摘要翻译：本发明涉及聚酮化合物及其至少部分氢化的产物，所述聚酮化合物和/或其至少部分氢化产物作为增塑剂的用途，制备聚酮化合物的方法及其至少部分氢化的产物，包含聚酮化合物和/或其至少部分氢化的产物，以及由本发明的产物形成的制品。

3. 发明授权

US5453561A Reactive separation process 失效
标题翻译：反应分离过程
公开(公告)号：US5453561A
公开(公告)日：1995-09-26
申请号：US187673
申请日：1994-01-27
申请人： Ramzi Y. Saleh , Michael Siskin , Glen B. Brons , Stephen N. Vaughn , Richard H. Schlosberg
发明人： Ramzi Y. Saleh , Michael Siskin , Glen B. Brons , Stephen N. Vaughn , Richard H. Schlosberg
IPC分类号： B01D17/025 , C07C7/148 , C07C11/02 , C07C29/10 , C10G50/00 , C07C7/00
CPC分类号： C07C29/10 , C07C7/148
摘要： The invention concerns a method for reactive separation of mixtures containing hydrocarbons and oxygenated hydrocarbons, by contacting a mixture of hydrocarbons such as C.sub.2 to C.sub.26 hydrocarbons and mixtures thereof and oxygenated hydrocarbons, such as C.sub.2 to C.sub.40 oxygenated hydrocarbons and mixtures thereof to form a mixture of hydrocarbons and lower molecular weight oxygenated hydrocarbons and heating the mixture in water at temperature typically from about and pressure sufficient to cleave the oxygenated hydrocarbons to lower molecular weight products to form a liquid layer containing water soluble reaction products and an organic layer containing primarily hydrocarbons.
摘要翻译：本发明涉及通过使烃类混合物例如C 2至C 26烃及其混合物和含氧烃如C2至C40含氧烃及其混合物的混合物与烃和氧化烃的混合物进行反应分离的方法，以形成混合物碳氢化合物和较低分子量的氧化烃，并将混合物在水中加热，其温度通常为足以将氧化烃切割成较低分子量产物的温度，形成含有水溶性反应产物和主要含有烃的有机层的液体层。

4. 发明授权

US5169824A Catalyst comprising amorphous NiO on silica/alumina support 失效
标题翻译：包含在二氧化硅/氧化铝载体上的无定形NiO的催化剂
公开(公告)号：US5169824A
公开(公告)日：1992-12-08
申请号：US644998
申请日：1991-01-22
申请人： Ramzi Y. Saleh , Stuart L. Soled , Nicholas C. Dispenziere
发明人： Ramzi Y. Saleh , Stuart L. Soled , Nicholas C. Dispenziere
IPC分类号： B01J23/755 , B01J37/02 , B01J37/03
CPC分类号： B01J37/0217 , B01J23/755 , B01J37/031
摘要： The present invention provides for a catalyst composition which is effective for use in the production of dimer products and higher olefin products from lower olefins such as propylene and butene in high yields and with an average degree of branching in the dimer products of less than about 1.6 methyl groups per molecule, generally in the range of from about 1.0 to 1.4 methyl groups per molecule. The present invention also provides a process for producing such dimer and higher olefin products using the catalyst composition of this invention. The catalyst of the invention comprises an amorphous nickel oxide (NiO) present as a disperse substantial monolayer on the surfaces of a silica (SiO.sub.2) support, which support also contains minor amounts of an oxide of aluminum, gallium or indium such that the ratio of NiO to metal oxide present in the catalyst is within the range of from about 4:1 to about 100:1. The catalyst may be prepared by precipitating a water insoluble nickel salt onto the surfaces of a silica support which has been impregnated with the metal oxide or onto a silica-alumina support which has been dealuminized such that the resulting nickel oxide/alumina ratio will fall within the ranges set forth above. The catalyst may then be activated by calcination in the presence of oxygen at a temperature within the range of from about 500.degree. to 700.degree. C.
摘要翻译：本发明提供了一种催化剂组合物，其有效用于以高产率从低级烯烃如丙烯和丁烯生产二烯体产物和高级烯烃产物，并且二聚体产物中的平均支化度小于约1.6 每个分子的甲基基团，通常在每分子约1.0至1.4个甲基的范围内。本发明还提供了使用本发明的催化剂组合物生产这种二聚物和较高级烯烃产物的方法。本发明的催化剂包括在二氧化硅（SiO 2）载体的表面上作为分散实质单层存在的无定形氧化镍（NiO），该载体还含有少量的铝，镓或铟的氧化物，存在于催化剂中的NiO与金属氧化物在约4:1至约100:1的范围内。催化剂可以通过将水不溶性镍盐沉淀到已经浸渍有金属氧化物的二氧化硅载体的表面上或已经脱铝的二氧化硅 - 氧化铝载体上，使得所得到的氧化镍/氧化铝比落入上述范围。催化剂然后可以在氧的存在下在约500-700℃的温度下煅烧来活化。

5. 发明授权

US5043486A Aquathermolytic cleavage of ethers 失效
标题翻译：醚水解裂解
公开(公告)号：US5043486A
公开(公告)日：1991-08-27
申请号：US572485
申请日：1990-08-23
申请人： Michael Siskin , Glen B. Brons , Ramzi Y. Saleh , Stephen N. Vaughn
发明人： Michael Siskin , Glen B. Brons , Ramzi Y. Saleh , Stephen N. Vaughn
IPC分类号： C07C29/10 , C07C31/02 , C07C31/10 , C07C31/12
CPC分类号： C07C29/10
摘要： The present invention provides for a simplified process for converting ethers into their corresponding alcohols comprising forming an aqueous mixture of the ether and at least about 50% by weight water and heating the mixture under autogeneous pressure at a temperature of from about 250.degree. to 450.degree. C., more preferably from about 250.degree. C. up to the critical temperature of water which is about 374.degree. C. Heating is continued for a period of time sufficient to convert at least about 20% by weight of the ether, usually from about 5 up to about 120 minutes, depending on temperature and the amount of water present, and the identity of the starting ether feedstock.The process may be characterized as an aquathermolysis reaction wherein the reaction proceeds in water primarily through ionic routes rather than through free radical routes. Accordingly, relatively high conversion rates and good yields of alcohol and other reaction by-products may be obtained without the necessity of using a catalyst in the process.
摘要翻译：本发明提供了将醚转化成其相应的醇的简化方法，包括形成醚的水性混合物和至少约50重量％的水，并在约250-450℃的温度下在自主压力下加热混合物更优选约250℃至约374℃的水的临界温度。继续加热足够的时间以使至少约20重量％的乙醚转化成通常为约 5至约120分钟，这取决于温度和存在的水的量以及起始醚原料的特性。该方法可以表征为水解溶解反应，其中反应在水中主要通过离子路线而不是通过自由基途径进行。因此，可以获得醇和其它反应副产物的相对高的转化率和良好的产率，而不需要在该方法中使用催化剂。

6. 发明申请

US20120108726A1 Polyketone Plasticizers 有权
标题翻译：聚酮增塑剂
公开(公告)号：US20120108726A1
公开(公告)日：2012-05-03
申请号：US13345014
申请日：2012-01-06
申请人： Allen D Godwin , Kenneth J. Buturla , Karla S. Colle , Gabor Kiss , Kirk C. Nadler , Abhimanyu O. Patil , Edris Eileen Pike , Ramzi Y. Saleh , Jon E. Stanat , Manika Varma-Nair , Stephen Zushma
发明人： Allen D Godwin , Kenneth J. Buturla , Karla S. Colle , Gabor Kiss , Kirk C. Nadler , Abhimanyu O. Patil , Edris Eileen Pike , Ramzi Y. Saleh , Jon E. Stanat , Manika Varma-Nair , Stephen Zushma
IPC分类号： C07C49/12 , C07C45/49 , C08K5/07 , C07C49/17 , C09K3/00
CPC分类号： C08G67/02 , C08L73/00 , C08L101/00 , C08L2666/14
摘要： The invention relates to polyketone compounds and the at least partially hydrogenated products thereof, the use of said polyketone compounds and/or the at least partially hydrogenated products thereof as plasticizers, processes of making polyketone compounds and the at least partially hydrogenated products thereof, compositions comprising the polyketone compounds and/or the at least partially hydrogenated products thereof, and to articles formed from products of the invention.
摘要翻译：本发明涉及聚酮化合物及其至少部分氢化的产物，所述聚酮化合物和/或其至少部分氢化产物作为增塑剂的用途，制备聚酮化合物的方法及其至少部分氢化的产物，包含聚酮化合物和/或其至少部分氢化的产物，以及由本发明的产物形成的制品。

7. 发明申请

US20090182183A1 PROPYLENE OLIGOMERIZATION PROCESS 有权
标题翻译：丙烯低聚过程
公开(公告)号：US20090182183A1
公开(公告)日：2009-07-16
申请号：US12014406
申请日：2008-01-15
申请人： Michael J. Keenan , Ramzi Y. Saleh , James C. Vartuli , Robert C. Lemon , Jean W. Beeckman , Christopher C. Boyer , Mitchell E. Loescher
发明人： Michael J. Keenan , Ramzi Y. Saleh , James C. Vartuli , Robert C. Lemon , Jean W. Beeckman , Christopher C. Boyer , Mitchell E. Loescher
IPC分类号： C07C2/24
CPC分类号： C07C2/10 , C07C2521/06 , C07C2523/30 , Y02P20/52
摘要： A process for the oligomerization of propylene is disclosed wherein a tungstated zirconia catalyst prepared as a distillation structure is used in a reaction distillation zone under conditions of temperature and pressure to concurrently react the propylene to produce oligomers thereof and separate the oligomer products from unreacted propylene by fractional distillation in a distillation column reactor. Compared to the prior art tubular or plug flow reactors, lower temperatures and pressures are used to produce higher conversions and selectivities to preferred isomeric forms useful for preparing neo acids.
摘要翻译：公开了一种用于丙烯低聚的方法，其中在反应蒸馏区中在温度和压力条件下使用制备为蒸馏结构的钨酸氧化锆催化剂，以同时使丙烯反应生成其低聚物，并将低聚物产物与未反应的丙烯分离在蒸馏塔反应器中进行分馏。与现有技术的管状或活塞式流动反应器相比，使用较低的温度和压力来产生较高的转化率和选择性，以用于制备新酸的优选异构形式。

8. 发明授权

US5565603A Process for manufacturing dialkyl carbonate from urea and alcohol 失效
标题翻译：由尿素和醇制造碳酸二烷基酯的方法
公开(公告)号：US5565603A
公开(公告)日：1996-10-15
申请号：US170468
申请日：1993-12-20
申请人： Ramzi Y. Saleh , Robert C. Michaelson , Elena N. Suciu , Barbara Kuhlmann
发明人： Ramzi Y. Saleh , Robert C. Michaelson , Elena N. Suciu , Barbara Kuhlmann
IPC分类号： B01J3/04 , B01J19/18 , B01J31/12 , C07C68/00 , C07C69/96
CPC分类号： B01J31/122 , B01J19/1881 , B01J3/04 , C07C68/00 , B01J2219/00101 , B01J2219/00155 , B01J2219/00162
摘要： A process for making a dialkyl carbonate which comprises reacting urea with a first alcohol in a carbamate reactor at a temperature and pressure sufficient to convert said urea to an alkyl carbamate; and reacting the alkyl carbamate with a second alcohol in the presence of a dialkyl isocyanato alkoxy tin catalyst or derivatives in a carbonate reactor at a temperature and pressure sufficient to convert the alkyl carbamate to a dialkyl carbonate, wherein the molar ratio of alkyl carbamate to second alcohol is in the range between about 2:1 to about 10:1 and wherein dialkyl carbonate is present within the carbonate reactor in an amount between about 1 to about 3 weight %, based on total alkyl carbamate and second alcohol content, and wherein the second alcohol is either the same as or different from the first alcohol or a mixture of alcohols.
摘要翻译：一种制备碳酸二烷基酯的方法，其包括使氨基甲酸酯反应器中的脲与第一醇在足以将所述脲转化为氨基甲酸烷基酯的温度和压力下反应; 和在碳酸酯反应器中的二烷基异氰酸酯基烷氧基锡催化剂或其衍生物的存在下，使烷基氨基甲酸酯与第二种醇反应，其温度和压力足以将氨基甲酸烷基酯转化为碳酸二烷基酯，其中氨基甲酸烷基酯与第二醇在约2:1至约10:1之间的范围内，其中碳酸二烷基酯在碳酸酯反应器内以基于总烷基氨基甲酸酯和第二醇含量为约1至约3重量％的量存在，并且其中第二醇与第一种醇或醇的混合物相同或不同。

9. 发明授权

US5561094A Dialkyl isocyanato tin alcoholate catalysts and dimers thereof 失效
标题翻译：二烷基异氰酸锡锡醇盐催化剂及其二聚体
公开(公告)号：US5561094A
公开(公告)日：1996-10-01
申请号：US429057
申请日：1995-04-26
申请人： Ramzi Y. Saleh , Robert C. Michaelson , Elena N. Suciu , Barbara Kuhlmann
发明人： Ramzi Y. Saleh , Robert C. Michaelson , Elena N. Suciu , Barbara Kuhlmann
IPC分类号： B01J3/04 , B01J19/18 , B01J31/12 , C07C68/00 , B01J31/18
CPC分类号： B01J31/122 , B01J19/1881 , B01J3/04 , C07C68/00 , B01J2219/00101 , B01J2219/00155 , B01J2219/00162
摘要： A process for making a dialkyl carbonate which comprises reacting urea with a first alcohol in a carbamate reactor at a temperature and pressure sufficient to convert said urea to an alkyl carbamate; and reacting the alkyl carbamate with a second alcohol in the presence of a dialkyl isocyanato alkoxy tin catalyst or derivatives in a carbonate reactor at a temperature and pressure sufficient to convert the alkyl carbamate to a dialkyl carbonate, wherein the molar ratio of alkyl carbamate to second alcohol is in the range between about 2:1 to about 10:1 and wherein dialkyl carbonate is present within the carbonate reactor in an amount between about 1 to about 3 weight %, based on total alkyl carbamate and second alcohol content, and wherein the second alcohol is either the same as or different from the first alcohol or a mixture of alcohols.
摘要翻译：一种制备碳酸二烷基酯的方法，其包括使氨基甲酸酯反应器中的脲与第一醇在足以将所述脲转化为氨基甲酸烷基酯的温度和压力下反应; 和在碳酸酯反应器中的二烷基异氰酸酯基烷氧基锡催化剂或其衍生物的存在下，使烷基氨基甲酸酯与第二种醇反应，其温度和压力足以将氨基甲酸烷基酯转化为碳酸二烷基酯，其中氨基甲酸烷基酯与第二醇在约2:1至约10:1之间的范围内，其中碳酸二烷基酯在碳酸酯反应器内以基于总烷基氨基甲酸酯和第二醇含量为约1至约3重量％的量存在，并且其中第二醇与第一种醇或醇的混合物相同或不同。

10. 发明授权

US5326791A Process for separation of hydrolyzable from non-hydrolyzable waste plastics for recovery of starting materials and other conversion processes, respectively 失效
标题翻译：分离可水解与不可水解废塑料的回收原料和其他转化方法的方法
公开(公告)号：US5326791A
公开(公告)日：1994-07-05
申请号：US812176
申请日：1991-12-20
申请人： Ramzi Y. Saleh , William E. Wellman
发明人： Ramzi Y. Saleh , William E. Wellman
IPC分类号： C08F6/00 , C08F6/06 , C08F8/12 , C08G85/00 , C08J11/00 , C08J11/14
CPC分类号： C08J11/14 , C08J2367/02 , Y02W30/704
摘要： The present invention relates to a process for reactively separating hydrolyzable polymers, such as PET, in mixtures of the polymer and certain non-hydrolyzable polymers, specifically polyolefins by converting the hydrolyzable polymers to their corresponding water soluble components (e.g., PET to ethylene glycol and terephthalic acid) in the presence of liquid water at temperatures from about 200.degree. C. up to the critical temperature of water and autogenous pressure. The process has utility in recycling and waste material separation processes.
摘要翻译：本发明涉及通过将可水解聚合物转化成其相应的水溶性组分（例如，PET至乙二醇和/或其衍生物）的聚合物和某些不可水解的聚合物，特别是聚烯烃的混合物，将可水解聚合物如PET，对苯二甲酸）在液态水存在下，在约200℃至临界温度和自生压力的温度下进行。该方法在回收和废料分离过程中具有实用价值。

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