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1. 发明授权

US5770728A Alkane oxidation with porphyrins and metal complexes thereof having haloalkyl side chains 失效
标题翻译：卟啉及其具有卤代烷基侧链的金属络合物的烷烃氧化
公开(公告)号：US5770728A
公开(公告)日：1998-06-23
申请号：US769814
申请日：1996-12-19
申请人： Tilak Wijesekera , James E. Lyons , Paul E. Ellis, Jr. , Manoj V. Bhinde
发明人： Tilak Wijesekera , James E. Lyons , Paul E. Ellis, Jr. , Manoj V. Bhinde
IPC分类号： B01J31/18 , C07C29/132 , C07C29/50 , C07C45/33 , C07C45/36 , C07C45/53 , C07D487/22 , C07D519/00 , C07F15/02 , C07C45/32
CPC分类号： C07F15/025 , B01J31/1815 , C07C29/132 , C07C29/50 , C07C45/33 , C07C45/36 , C07C45/53 , C07D487/22 , C07D519/00 , C12C11/02 , B01J2531/025 , B01J2531/842 , C07C2101/14 , C07C2101/16
摘要： Transition metal complexes of meso-haloalkylporphyrins, wherein the haloalkyl groups contain 2 to 8 carbon atoms have been found to be highly effective catalysts for oxidation of alkanes and for the decomposition of hydroperoxides.
摘要翻译：已经发现，其中卤代烷基含有2至8个碳原子的内消旋烷基卟啉的过渡金属络合物是用于烷烃氧化和氢过氧化物分解的高效催化剂。

2. 发明授权

US5672778A Process for increased yields of oxygenated products in two-step oxidation of hydrocarbons 失效
标题翻译：在两步氧化烃中增加氧化产物产率的方法
公开(公告)号：US5672778A
公开(公告)日：1997-09-30
申请号：US703423
申请日：1996-08-26
申请人： James E. Lyons , Paul E. Ellis, Jr. , Manoj V. Bhinde
发明人： James E. Lyons , Paul E. Ellis, Jr. , Manoj V. Bhinde
IPC分类号： A62D3/00 , A62D3/37 , A62D101/28 , B01J31/22 , C07B61/00 , C07C27/00 , C07C29/132 , C07C31/12 , C07C35/08 , C07C45/53 , C07C407/00 , C07C29/48 , C07C27/10 , C07C31/02
CPC分类号： C07C45/53 , A62D3/37 , C07C29/132 , C07C31/12 , C07C35/08 , C07C407/003 , A62D2101/28 , C07C2101/14
摘要： The invention comprises a method for the catalytic conversion of alkanes and alkylhydroperoxides to oxygenates, particularly alcohols, comprising the oxidation of alkanes to yield alkylhydroperoxides, alcohols, other reaction products and unreacted alkane, and the decomposition of said alkylhydroperoxides to form alcohols and oxygen. Decomposition of the alkylhydroperoxide in the presence of unreacted alkane increases the yield of alcohol. The process further comprises drying of the reaction mixture comprising alkylhydroperoxide. Suitable catalysts for the process of the invention comprise metal containing catalysts, including metal organic ligand catalysts such as unsubstituted and substituted metal complexes of porphyrins, phthalocyanines and acetylacetonates.
摘要翻译：本发明包括将烷烃和烷基氢过氧化物催化转化为含氧化合物，特别是醇的方法，其包括烷烃的氧化以产生烷基氢过氧化物，醇，其它反应产物和未反应的烷烃，以及所述烷基氢过氧化物分解形成醇和氧。在未反应的烷烃存在下分解烷基氢过氧化物可提高醇的产率。该方法还包括干燥包含烷基过氧化氢的反应混合物。用于本发明方法的合适的催化剂包括含金属的催化剂，包括金属有机配体催化剂，例如卟啉，酞菁和乙酰丙酮化合物的未取代和取代的金属络合物。

3. 发明授权

US5608054A Porphyrins and metal complexes thereof having haloalkyl side chains 失效
标题翻译：卟啉及其具有卤代烷基侧链的金属络合物
公开(公告)号：US5608054A
公开(公告)日：1997-03-04
申请号：US405684
申请日：1995-03-17
申请人： Tilak Wijesekera , James E. Lyons , Paul E. Ellis, Jr. , Manoj V. Bhinde
发明人： Tilak Wijesekera , James E. Lyons , Paul E. Ellis, Jr. , Manoj V. Bhinde
IPC分类号： B01J31/18 , C07C29/132 , C07C29/50 , C07C45/33 , C07C45/36 , C07C45/53 , C07D487/22 , C07D519/00 , C07F15/02
CPC分类号： C07F15/025 , B01J31/1815 , C07C29/132 , C07C29/50 , C07C45/33 , C07C45/36 , C07C45/53 , C07D487/22 , C07D519/00 , C12C11/02 , B01J2531/025 , B01J2531/842 , C07C2101/14 , C07C2101/16
摘要： Transition metal complexes of meso-haloalkylporphyrins, wherein the haloalkyl groups contain 2 to 8 carbon atoms have been found to be highly effective catalysts for oxidation of alkanes and for the decomposition of hydroperoxides.
摘要翻译：已经发现，其中卤代烷基含有2至8个碳原子的内消旋烷基卟啉的过渡金属络合物是用于烷烃氧化和氢过氧化物分解的高效催化剂。

4. 发明授权

US5550301A Dried catalytic systems for decomposition of organic hydroperoxides 失效
标题翻译：用于分解有机氢过氧化物的干燥催化体系
公开(公告)号：US5550301A
公开(公告)日：1996-08-27
申请号：US398024
申请日：1995-03-03
申请人： Manoj V. Bhinde , James E. Lyons , Paul E. Ellis, Jr.
发明人： Manoj V. Bhinde , James E. Lyons , Paul E. Ellis, Jr.
IPC分类号： A62D3/00 , A62D3/37 , A62D101/28 , B01J31/22 , C07B61/00 , C07C27/00 , C07C29/132 , C07C31/12 , C07C35/08 , C07C45/53 , C07C407/00 , C07C29/00 , C07C33/22 , C07C35/14
CPC分类号： C07C45/53 , A62D3/37 , C07C29/132 , C07C31/12 , C07C35/08 , C07C407/003 , A62D2101/28 , C07C2101/14
摘要： Organic hydroperoxides are decomposed by drying a reaction mixture containing the organic hydroperoxide and an organic solvent such that said dried reaction mixture comprises approximately 1 weight percent or less of water and contacting the dried reaction mixture with a metal organic ligand catalyst under hydroperoxide decomposition conditions. An organic co-solvent for the hydroperoxide may also be used. Particularly effective catalysts are cobalt acetylacetonates and ruthenium acetylacetonates and combinations thereof.
摘要翻译：通过干燥含有机氢过氧化物和有机溶剂的反应混合物来分解有机氢过氧化物，使得所述干燥的反应混合物包含约1重量％或更少的水，并在氢过氧化物分解条件下使干燥的反应混合物与金属有机配体催化剂接触。也可以使用氢过氧化物的有机助溶剂。特别有效的催化剂是乙酰丙酮钴和乙酰丙酮钌及其组合。

5. 发明授权

US5395988A Metal-ligand catalyzed decomposition of organic hydroperoxides 失效
标题翻译：金属 - 配体催化分解有机氢过氧化物
公开(公告)号：US5395988A
公开(公告)日：1995-03-07
申请号：US223090
申请日：1994-04-04
申请人： Manoj V. Bhinde , James E. Lyons , Paul E. Ellis, Jr.
发明人： Manoj V. Bhinde , James E. Lyons , Paul E. Ellis, Jr.
IPC分类号： A62D3/00 , A62D3/37 , A62D101/28 , C07C29/132 , C07C31/12 , C07C35/08 , C07C45/53 , C07C407/00 , C07C29/00 , C07C33/22 , C07C35/14
CPC分类号： A62D3/37 , C07C29/132 , C07C31/12 , C07C35/08 , C07C407/003 , C07C45/53 , A62D2101/28 , C07C2101/14
摘要： Organic hydroperoxides are decomposed by drying a reaction mixture containing the organic hydroperoxide and an organic solvent and contacting the dried reaction mixture with a metal organic ligand catalyst under hydroperoxide decomposition conditions. An organic co-solvent for the hydroperoxide may also be used.
摘要翻译：通过干燥含有机氢过氧化物和有机溶剂的反应混合物分解有机氢过氧化物，并在氢过氧化物分解条件下使干燥的反应混合物与金属有机配体催化剂接触。也可以使用氢过氧化物的有机助溶剂。

6. 发明授权

US5767272A Method of preparing meso-haloalkylporphyrins 失效
标题翻译：制备内消旋烷基卟啉的方法
公开(公告)号：US5767272A
公开(公告)日：1998-06-16
申请号：US769974
申请日：1996-12-19
申请人： Tilak Wijesekera , James E. Lyons , Paul E. Ellis, Jr. , Manoj V. Bhinde
发明人： Tilak Wijesekera , James E. Lyons , Paul E. Ellis, Jr. , Manoj V. Bhinde
IPC分类号： B01J31/18 , C07C29/132 , C07C29/50 , C07C45/33 , C07C45/36 , C07C45/53 , C07D487/22 , C07D519/00 , C07F15/02
CPC分类号： C07F15/025 , B01J31/1815 , C07C29/132 , C07C29/50 , C07C45/33 , C07C45/36 , C07C45/53 , C07D487/22 , C07D519/00 , C12C11/02 , B01J2531/025 , B01J2531/842 , C07C2101/14 , C07C2101/16
摘要： Transition metal complexes of meso-haloalkylporphyrins, wherein the haloalkyl groups contain 2 to 8 carbon atoms have been found to be highly effective catalysts for oxidation of alkanes and for the decomposition of hydroperoxides. Also disclosed is a process for the preparation of meso-halocarbyl-porphyrins which comprises contacting a halocarbyl dipyrromethane with a halocarbyl-substituted aldehyde in the presence of an acid granular solid catalyst. Also disclosed is a process for the preparation of meso-halocarbyl-porphyrins which comprises contacting a halocarbyl dipyrromethane with a halocarbyl-substituted aldehyde in the presence of an acid granular solic catalyst.
摘要翻译：已经发现，其中卤代烷基含有2至8个碳原子的内消旋烷基卟啉的过渡金属络合物是用于烷烃氧化和氢过氧化物分解的高效催化剂。还公开了一种制备内消旋咔咔卟啉的方法，其包括在酸性颗粒状固体催化剂存在下使卤代烃基二吡咯烷与卤代烃基取代的醛接触。还公开了制备内消旋咔咔卟啉的方法，其包括在酸性颗粒状催化剂存在下使卤代烃基二吡咯烷与卤代烃基取代的醛接触。

7. 发明授权

US5723697A Catalytic oxidation of light alkanes in presence of a base 失效
标题翻译：在碱存在下催化氧化轻链烷烃
公开(公告)号：US5723697A
公开(公告)日：1998-03-03
申请号：US580918
申请日：1995-12-29
申请人： Manoj V. Bhinde , Thomas W. Bierl
发明人： Manoj V. Bhinde , Thomas W. Bierl
IPC分类号： B01J31/22 , C07B61/00 , C07C29/50 , C07C31/04 , C07C31/08 , C07C31/10 , C07C31/12 , C07C31/125
CPC分类号： C07C29/50
摘要： The presence of a base in the reaction mixture in a metal-ligand catalyzed partial oxidation of alkanes results in sustained catalyst activity, and in greater percent conversion as compared with oxidation in the absence of base, while maintaining satisfactory selectivity for the desired oxidation, for example the oxidation of isobutane to isobutanol.
摘要翻译：在金属 - 配体催化的烷烃部分氧化中，反应混合物中碱的存在导致持续的催化剂活性，并且在不存在碱的情况下与氧化相比转化率更高百分比，同时保持对所需氧化的令人满意的选择性，例如异丁烷氧化成异丁醇。

8. 发明授权

US5494569A Hydrocracking using solid superacid catalysts comprising platinum metal 失效
标题翻译：使用包含铂金属的固体超强酸催化剂进行加氢裂化
公开(公告)号：US5494569A
公开(公告)日：1996-02-27
申请号：US184159
申请日：1994-01-21
申请人： Benjamin S. Umansky , Manoj V. Bhinde , Chao-Yang Hsu
发明人： Benjamin S. Umansky , Manoj V. Bhinde , Chao-Yang Hsu
IPC分类号： B01J27/053 , C10G47/14
CPC分类号： B01J27/053
摘要： A hydrocracking process is provided which process utilizes a sulfated solid catalyst comprising (1) oxide or hydroxide of Group III or Group IV element, e.g. zirconium, and (2) a first metal comprising a metal or combination of metals selected from the group consisting of platinum, palladium, nickel, platinum and rhenium, and platinum and tin. The catalyst may further comprise (3) a second metal selected from the group consisting of Group VIII elements, e.g. iron. One embodiment of the invention further comprises (4) a third metal selected from the group consisting of Group V, VI and VII elements, e.g. manganese.
摘要翻译：提供加氢裂化方法，该方法利用硫酸化固体催化剂，其包含（1）III族或IV族元素的氧化物或氢氧化物，例如锆，和（2）包含选自铂，钯，镍，铂和铼的金属或金属组合的第一金属以及铂和锡。催化剂还可以包含（3）选自VIII族元素的第二种金属，例如。铁。本发明的一个实施方案还包括（4）选自第V，VI和VII族元素的第三种金属，例如。锰。

9. 发明授权

US5629257A Solid superacid catalysts comprising platinum metal 失效
标题翻译：包含铂金属的固体超强酸催化剂
公开(公告)号：US5629257A
公开(公告)日：1997-05-13
申请号：US184425
申请日：1994-01-21
申请人： Benjamin S. Umansky , Manoj V. Bhinde , Chao-Yang Hsu , Chen-Shi Huang
发明人： Benjamin S. Umansky , Manoj V. Bhinde , Chao-Yang Hsu , Chen-Shi Huang
IPC分类号： B01J27/053 , B01J27/02
CPC分类号： B01J27/053
摘要： A sulfated solid catalyst is provided which comprises (1) oxide or hydroxide of Group III or Group IV element, e.g. zirconium, and (2) a first metal comprising a metal or combination of metals selected from the group consisting of platinum, palladium, nickel, platinum and rhenium, and platinum and tin. The catalyst may further comprise (3) a second metal selected from the group consisting of Group VIII elements, e.g. iron. One embodiment of the invention further comprises (4) a third metal selected from the group consisting of Group V, VI and VII elements, e.g. manganese. The catalyst of the invention is useful for the isomerization of normal alkanes having 4 to 40 carbon atoms per molecule, for the naphtha upgrading of a hydrocarbon feedstock and for the hydrocracking of a hydrocarbon feedstock.
摘要翻译：提供硫酸化固体催化剂，其包含（1）III族或IV族元素的氧化物或氢氧化物，例如锆，和（2）包含选自铂，钯，镍，铂和铼的金属或金属组合的第一金属，以及铂和锡。催化剂还可以包含（3）选自VIII族元素的第二种金属，例如。铁。本发明的一个实施方案还包括（4）选自第V，VI和VII族元素的第三种金属，例如。锰。本发明的催化剂可用于每分子具有4至40个碳原子的正构烷烃异构化，用于烃原料的石脑油升级和烃原料的加氢裂化。

10. 发明授权

US5516964A Hydrocarbon isomerization using solid superacid catalysts comprising platinum metal 失效
标题翻译：使用包含铂金属的固体超强酸催化剂进行烃异构化
公开(公告)号：US5516964A
公开(公告)日：1996-05-14
申请号：US184154
申请日：1994-01-21
申请人： Benjamin S. Umansky , Manoj V. Bhinde , Chao-Yang Hsu
发明人： Benjamin S. Umansky , Manoj V. Bhinde , Chao-Yang Hsu
IPC分类号： B01J27/053 , C07C5/27 , C10G45/62 , C10G35/085
CPC分类号： C10G45/62 , B01J27/053 , C07C5/2791 , C07C2521/06 , C07C2523/89 , C07C2527/053
摘要： An isomerization process is provided which process utilizes a sulfated solid catalyst comprising (1) oxide or hydroxide of Group III or Group IV element, e.g. zirconium, and (2) a first metal comprising a metal or combination of metals selected from the group consisting of platinum, palladium, nickel, platinum and rhenium, and platinum and tin. The sulfated support is calcined prior to incorporation of the first metal and subsequent to said incorporation. The catalyst may further comprise (3) a second metal selected from the group consisting of Group VIII elements, e.g. iron. One embodiment of the invention further comprises (4) a third metal selected from the group consisting of Group V, VI and VII elements, e.g. manganese. Said second and third metals are added prior to the first calcination.
摘要翻译：提供异构化方法，该方法利用硫酸化固体催化剂，其包含（1）III族或IV族元素的氧化物或氢氧化物，例如锆，和（2）包含选自铂，钯，镍，铂和铼的金属或金属组合的第一金属以及铂和锡。硫酸化载体在引入第一种金属之前并在所述掺入之后被煅烧。催化剂还可以包含（3）选自VIII族元素的第二种金属，例如。铁。本发明的一个实施方案还包括（4）选自第V，VI和VII族元素的第三种金属，例如。锰。在第一次煅烧之前加入所述第二和第三种金属。

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