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1. 发明授权

US09714386B2 Production of xylenes from syngas 有权
公开(公告)号：US09714386B2
公开(公告)日：2017-07-25
申请号：US14753692
申请日：2015-06-29
申请人： ExxonMobil Chemical Patents Inc.
发明人： Paul F. Keusenkothen , Juan D. Henao
IPC分类号： C10G2/00 , B01J35/00 , B01J29/48 , B01J29/42 , B01J29/40 , B01J29/076 , B01J29/064 , B01J23/12 , B01J23/10 , B01J23/06 , B01J21/06 , C10G29/20 , C10G29/22 , C10G45/58 , C07C1/04 , C07C2/86 , C07C5/27 , C07C6/12
CPC分类号： C10G2/334 , B01J21/066 , B01J23/06 , B01J23/10 , B01J23/12 , B01J29/064 , B01J29/076 , B01J29/405 , B01J29/42 , B01J29/48 , B01J35/0006 , C07C1/0425 , C07C1/0485 , C07C2/864 , C07C5/2732 , C07C6/126 , C07C2529/40 , C10G2/331 , C10G29/205 , C10G29/22 , C10G45/58 , C10G2400/30 , Y02P20/52 , C07C15/08 , C07C15/02
摘要： This disclosure relates to the production of xylenes from syngas, in which the syngas is converted to an aromatic product by reaction with an isosynthesis catalyst and an aromatization catalyst. The isosynthesis catalyst and aromatization catalyst may be different catalysts or combined into a single catalyst. The aromatic product is then subjected to one of more of (i) xylene isomerization, (ii) transalkylation with at least one C9+ aromatic hydrocarbon, and (iii) alkylation with methanol and/or carbon monoxide and hydrogen to increase its p-xylene content.

2. 发明授权

US09517451B2 Preparation of propane oxidation catalysts 有权
标题翻译：丙烷氧化催化剂的制备
公开(公告)号：US09517451B2
公开(公告)日：2016-12-13
申请号：US14430600
申请日：2013-09-05
申请人： Rohm and Haas Company
发明人： Leonard E. Bogan, Jr.
IPC分类号： B01J21/00 , B01J23/00 , B01J23/06 , B01J23/08 , B01J23/12 , B01J23/14 , B01J23/16 , B01J23/48 , B01J23/70 , B01J23/76 , B01J37/00 , B01J37/08 , B01J37/12 , B01J27/057 , B01J23/28 , B01J35/00 , C07C51/215
CPC分类号： B01J27/0576 , B01J23/28 , B01J35/002 , B01J37/0045 , B01J37/08 , B01J37/086 , B01J2523/00 , C07C51/215 , B01J2523/55 , B01J2523/56 , B01J2523/64 , B01J2523/68 , C07C57/04
摘要： A process for preparing a propane oxidation catalyst, the process comprising pre-calcining the catalyst precursor in an oxygen-containing gas at a temperature of less than 330° C. until the weight of the precursor stabilizes to obtain a pre-calcined precursor; then calcining the pre-calcined precursor to obtain the catalyst.
摘要翻译：一种制备丙烷氧化催化剂的方法，该方法包括在低于330℃的温度下在含氧气体中预煅烧催化剂前体，直到前体的重量稳定得到预煅烧的前体; 然后煅烧预煅烧的前体以获得催化剂。

3. 发明申请

US20120328505A1 Nanostructured Transition Metal Oxides Useful for Water Oxidation Catalysis 有权
标题翻译：用于水氧化催化的纳米结构过渡金属氧化物
公开(公告)号：US20120328505A1
公开(公告)日：2012-12-27
申请号：US13575829
申请日：2011-01-27
申请人： Heinz M. Frei , Feng Jiao
发明人： Heinz M. Frei , Feng Jiao
IPC分类号： B01J35/02 , B01J23/75 , C01B13/02 , B01J23/12 , B01J23/30 , B01J21/08 , B01J23/34 , B01J23/745
CPC分类号： A61K33/26 , B01J29/0333 , B01J29/0341 , B01J35/0013 , B01J35/002 , B01J35/004 , B01J37/08 , B01J2229/18 , B82Y30/00 , C01B13/0207 , C01G45/02 , C01G51/04 , C01G53/04 , C01P2004/04 , C01P2004/16 , C01P2004/32 , C01P2004/64
摘要： The present invention provides for a composition comprising a nanostructured transition metal oxide capable of oxidizing two H2O molecules to obtain four protons. In some embodiments of the invention, the composition further comprises a porous matrix wherein the nanocluster of the transition metal oxide is embedded on and/or in the porous matrix.
摘要翻译：本发明提供一种包含能够氧化两个H 2 O分子以获得四个质子的纳米结构过渡金属氧化物的组合物。在本发明的一些实施方案中，组合物还包含多孔基质，其中过渡金属氧化物的纳米团簇嵌入在多孔基体上和/或多孔基质中。

4. 发明授权

US07402612B2 Stabilized transition alumina catalyst support from boehmite and catalysts made therefrom 有权
标题翻译：来自勃姆石的稳定的过渡型氧化铝催化剂载体和由其制备的催化剂
公开(公告)号：US07402612B2
公开(公告)日：2008-07-22
申请号：US10687140
申请日：2003-10-16
申请人： Yaming Jin , Rafael L. Espinoza , Nithya Srinivasan , Olga P. Ionkina
发明人： Yaming Jin , Rafael L. Espinoza , Nithya Srinivasan , Olga P. Ionkina
IPC分类号： C01F7/02 , B01J23/02 , B01J23/04 , B01J23/06 , B01J23/08 , B01J23/10 , B01J23/12 , B01J23/14 , B01J23/16 , B01J23/18 , B01J23/20 , B01J23/22 , B01J23/24 , B01J23/26 , B01J23/28 , B01J23/30 , B01J23/31 , B01J23/32 , B01J23/34 , B01J23/36 , B01J23/38 , B01J23/40 , B01J23/42 , B01J23/44 , B01J23/46 , B01J23/48 , B01J23/50 , B01J23/52 , B01J23/54 , B01J23/56 , B01J23/58 , B01J23/63 , B01J23/66 , B01J23/68 , B01J23/70 , B01J23/72 , B01J23/74 , B01J23/755 , B01J23/76 , B01J23/78 , B01J23/80 , B01J23/825 , B01J23/83 , B01J23/835 , B01J23/84 , B01J23/843 , B01J23/89
CPC分类号： C10G2/332 , B01J21/04 , B01J21/06 , B01J21/066 , B01J23/02 , B01J23/06 , B01J23/08 , B01J23/10 , B01J23/26 , B01J23/34 , B01J23/462 , B01J23/70 , B01J23/74 , B01J23/75 , B01J23/8913 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J37/0207 , B01J37/10 , C01F7/021 , C01F7/448 , C01P2002/72 , C01P2004/04 , C01P2006/13 , C01P2006/14 , C01P2006/16 , C01P2006/37 , C10G2/333
摘要： This invention relates to methods for making a stabilized transition alumina of enhanced hydrothermal stability, which include the introduction of at least one structural stabilizer; a steaming step before or after the introduction step, wherein steaming is effective in transforming a transition alumina at least partially to boehmite and/or pseudoboehmite; and a calcining step to create a stabilized transition alumina. The combination of the structural stabilizer and the steaming step is believed to impart high hydrothermal stability to the alumina crystal lattice. Particularly preferred structural stabilizers include boron, cobalt, and zirconium. The stabilized transition alumina is useful as a catalyst support for high water partial pressure environments, and is particularly useful for making a catalyst having improved hydrothermal stability. The invention more specifically discloses Fischer-Tropsch catalysts and processes for the production of hydrocarbons from synthesis gas.
摘要翻译：本发明涉及制备具有增强的水热稳定性的稳定的转变氧化铝的方法，其包括引入至少一种结构稳定剂; 在引入步骤之前或之后的蒸汽步骤，其中蒸汽有效地将过渡氧化铝至少部分转化为勃姆石和/或假勃姆石; 和煅烧步骤以产生稳定的过渡氧化铝。认为结构稳定剂和蒸汽步骤的组合被赋予氧化铝晶格高的水热稳定性。特别优选的结构稳定剂包括硼，钴和锆。稳定的过渡氧化铝可用作高水分分压环境的催化剂载体，并且特别可用于制备具有改善的水热稳定性的催化剂。本发明更具体地公开了费 - 托催化剂和从合成气生产烃的方法。

5. 发明授权

US4937374A Process for preparing methyl 3-methoxy-2-(2-phenoxyphenyl)propenoalis 失效
标题翻译：制备3-甲氧基-2-（2-苯氧基苯基）丙烯酸甲酯的方法
公开(公告)号：US4937374A
公开(公告)日：1990-06-26
申请号：US242679
申请日：1988-09-09
申请人： Kevin Beautement , John M. Clough , Christopher R. A. Godfrey
发明人： Kevin Beautement , John M. Clough , Christopher R. A. Godfrey
IPC分类号： B01J23/06 , A01N37/38 , A01N37/40 , A01N41/04 , A01N41/06 , A01N41/10 , A01N43/10 , A01N43/20 , A01N43/36 , A01N43/40 , A01N43/42 , A01N43/54 , A01N43/58 , A01N43/60 , A01N43/653 , A01N43/66 , A01N43/74 , A01N43/90 , A01N47/20 , A01N57/24 , B01J23/10 , B01J23/12 , B01J23/20 , B01J23/24 , B01J23/32 , B01J23/38 , B01J23/72 , B01J27/10 , C07B61/00 , C07C45/59 , C07C67/00 , C07C67/31 , C07C69/734 , C07C201/00 , C07C201/12 , C07C205/35 , C07C205/37 , C07C205/38 , C07C205/52 , C07C205/56 , C07C217/92 , C07C233/25 , C07C233/75 , C07C235/56 , C07C245/08 , C07C251/24 , C07C251/48 , C07C255/54 , C07C271/28 , C07C311/29 , C07C317/22 , C07C323/20 , C07C327/16 , C07D207/34 , C07D213/64 , C07D213/643 , C07D213/65 , C07D213/68 , C07D213/74 , C07D213/85 , C07D213/89 , C07D215/22 , C07D215/227 , C07D215/36 , C07D237/14 , C07D239/34 , C07D239/38 , C07D239/60 , C07D241/18 , C07D241/44 , C07D251/26 , C07D263/58 , C07D277/24 , C07D277/68 , C07D333/56 , C07D495/04 , C07D521/00 , C07F9/54
CPC分类号： C07D213/64 , A01N37/38 , A01N37/40 , A01N41/04 , A01N41/06 , A01N41/10 , A01N43/10 , A01N43/20 , A01N43/36 , A01N43/40 , A01N43/42 , A01N43/54 , A01N43/58 , A01N43/60 , A01N43/653 , A01N43/66 , A01N43/74 , A01N43/90 , A01N47/20 , A01N57/24 , C07C201/12 , C07C45/59 , C07C67/31 , C07D207/34 , C07D213/643 , C07D213/65 , C07D213/68 , C07D213/74 , C07D213/85 , C07D213/89 , C07D215/227 , C07D215/36 , C07D231/12 , C07D233/56 , C07D237/14 , C07D239/34 , C07D239/38 , C07D239/60 , C07D241/18 , C07D241/44 , C07D249/08 , C07D251/26 , C07D263/58 , C07D277/24 , C07D277/68 , C07D333/56 , C07D495/04 , C07F9/5456
摘要： Process for the preparation of a compound of general formula (I): ##STR1## by reacting a compound of general formula (II) ##STR2## (X is halide; rings M and N are optionally substituted) with an optionally substituted phenol in the presence of a base, or with an optionally substituted phenolate salt; preferably in the presence of a catalyst which is a transition metal, a transition metal salt or compound or a mixture thereof.

6. 发明授权

US4898982A Preparation of diaryl ethers and diaryl sulfides 失效
标题翻译：二芳基醚和二芳基硫化物的制备
公开(公告)号：US4898982A
公开(公告)日：1990-02-06
申请号：US121151
申请日：1987-11-16
申请人： Gregory P. Hussmann
发明人： Gregory P. Hussmann
IPC分类号： B01J27/25 , B01J23/12 , C07B61/00 , C07C41/00 , C07C41/09 , C07C43/257 , C07C67/00 , C07C319/14 , C07C323/30
CPC分类号： C07C321/00 , C07C41/09
摘要： A method is disclosed for the preparation of diaryl ethers and diaryl sulfides by heating a phenol, a thiophenol, a .beta.-hydroxy-substituted fused armomatic ring-system compound or a .beta.-thio-substituted fused aromatic ring-system compound in the presence of thoria deposited on a neutral support.

7. 发明授权

US4710487A Diesel exhaust gas catalyst 失效
标题翻译：柴油废气催化剂
公开(公告)号：US4710487A
公开(公告)日：1987-12-01
申请号：US827412
申请日：1986-02-07
申请人： Christian Koch
发明人： Christian Koch
IPC分类号： B01D53/86 , B01J23/83 , B01J23/10 , B01J23/12 , B01J23/74
CPC分类号： B01J23/83 , B01D53/865 , Y10S502/525
摘要： A catalyst for the reaction of hydrocarbons and gases and for the reduction of nitric oxides, includes the active substance thorium oxide in addition to LaCoO.sub.3. The catalyst has as the wash coat oxide-ceramic materials and spinels of the oxides of magnesium, aluminum, titanium and zirconium, with an addition of cerium oxide and lanthanum oxide, and preformed and acid-solubilized LaCoO.sub.3 as the active substance. The catalyst is formed without the active substance LaCoO.sub.3 for use as a high-temperature combustion catalyst. A process and apparatus is set forth for the application of the catalyst for after-burning of exhaust gases from diesel engines, with catalyst filler layers eccentrically disposed with respect to each other for the adsorption of soot particles, and with a catalyst honeycomb for after-burning and nitric oxide-reduction. The after-burning device is suitable also as a muffler.
摘要翻译：用于碳氢化合物和气体的反应和用于还原一氧化氮的催化剂除了LaCoO 3之外还包括活性物质氧化钍。该催化剂具有氧化镁，铝，钛和锆的氧化物的洗涤氧化物 - 陶瓷材料和尖晶石，添加了氧化铈和氧化镧，并且预先形成和酸溶解的LaCoO 3作为活性物质。形成催化剂，不用作高温燃烧催化剂的活性物质LaCoO 3。阐述了一种方法和装置，用于将来自柴油发动机的废气后燃烧的催化剂应用于催化剂填料层，其中催化剂填料层相对于彼此偏心设置以吸附烟灰颗粒，并且具有催化剂蜂窝体，燃烧和一氧化氮还原。后燃烧装置也适用于消声器。

8. 发明授权

US4621071A Composite catalyst for treatment of vehicular exhaust gases and process for the preparation of the catalyst 失效
标题翻译：用于处理车辆废气的复合催化剂和催化剂的制备方法
公开(公告)号：US4621071A
公开(公告)日：1986-11-04
申请号：US679449
申请日：1984-12-07
申请人： Gilbert Blanchard , Michel Prigent
发明人： Gilbert Blanchard , Michel Prigent
IPC分类号： B01D53/94 , B01J23/10 , B01J23/12 , B01J23/36 , B01J23/40 , B01J23/56 , B01J23/63 , B01J23/66 , B01J23/89 , B01J37/00 , B01J37/02 , B01J21/04 , B01J23/64
CPC分类号： B01J37/0009 , B01J23/56 , B01J23/66 , B01J37/0236
摘要： A composite active phase/support catalyst adapted for the treatment of internal combustion engine exhaust gases, the active phase of which comprising at least one metal from a first group comprising platinum, palladium, iridium, rhodium, ruthenium, rhenium, silver, gold or plurality thereof and at least one additional metal and the support therefor comprising binder/filler admixture, is facilely prepared by (i) intimately admixing the binder and filler support material with at least 50% by weight but less than all of said at least one first group metal, or precursor thereof, and/or of said at least one additional metal, (ii) forming the resulting admixture into catalyst shaped article, (iii) drying and optionally calcining said catalyst shaped article, (iv) incorporating the remainder of said at least one first group metal, or precursor thereof, and/or said at least one additional metal into said catalyst shaped article, and then (v) drying and activating the composite catalyst.
摘要翻译：一种适用于处理内燃机废气的复合活性相/载体催化剂，其活性相包含至少一种金属，所述第一组包括铂，钯，铱，铑，钌，铼，银，金或多种金属并且至少一种另外的金属及其包含粘合剂/填料混合物的载体通过以下方式容易地制备：（i）将粘合剂和填料载体材料与至少50重量％但小于所有所述至少一个第一组金属或其前体和/或所述至少一种另外的金属，（ii）将所形成的混合物形成催化剂成型制品，（iii）干燥和任选地煅烧所述催化剂成型制品，（iv）将剩余的所述的至少一种第一组金属或其前体，和/或所述至少一种另外的金属加入到所述催化剂成型制品中，然后（v）干燥和活化复合催化剂。

9. 发明授权

US4568663A Cobalt catalysts for the conversion of methanol to hydrocarbons and for Fischer-Tropsch synthesis 失效
标题翻译：用于将甲醇转化为烃和用于费 - 托合成的钴催化剂
公开(公告)号：US4568663A
公开(公告)日：1986-02-04
申请号：US626022
申请日：1984-06-29
申请人： Charles H. Mauldin
发明人： Charles H. Mauldin
IPC分类号： B01J23/75 , B01J23/83 , B01J23/889 , C07C1/04 , C07C1/20 , C10G3/00 , B01J21/06 , B01J23/12 , B01J23/36 , B01J23/74
CPC分类号： C07C1/0435 , B01J23/75 , B01J23/83 , B01J23/8896 , C07C1/20 , C10G3/45 , C10G3/48 , C07C2521/06 , C07C2523/10 , C07C2523/12 , C07C2523/36 , C07C2523/75 , C07C2523/83 , C07C2523/889 , C10G2300/1022 , Y02P20/52 , Y02P30/20
摘要： A rhenium promoted cobalt catalyst, especially a rhenium and thoria promoted cobalt catalyst, and process for the conversion of methanol to hydrocarbons. Methanol is contacted, preferably with added hydrogen, over said catalyst, or synthesis gas is contacted over said catalyst to produce, at reaction conditions, an admixture of C.sub.10 + linear paraffins and olefins. These hydrocarbons can be further refined to high quality middle distillate fuels, and other valuable products such as mogas, diesel fuel, jet fuel, lubes and speciality solvents, particularly premium middle distillate fuels of carbon number ranging from about C.sub.10 to about C.sub.20.
摘要翻译：铼促进钴催化剂，特别是铼和硫堇促进的钴催化剂，以及甲醇转化为烃的方法。甲醇在所述催化剂上接触，优选与加入的氢气接触，或者合成气在所述催化剂上接触，以在反应条件下产生C10 +直链烷烃和烯烃的混合物。这些碳氢化合物可以进一步精制成高质量的中间馏分燃料，以及其他有价值的产品，如摩尔瓦，柴油，喷气燃料，润滑剂和特种溶剂，特别是碳数为约C10至约C20的优质中间馏分燃料。

10. 发明授权

US4542122A Cobalt catalysts for the preparation of hydrocarbons from synthesis gas and from methanol 失效
标题翻译：用于从合成气和甲醇制备烃的钴催化剂
公开(公告)号：US4542122A
公开(公告)日：1985-09-17
申请号：US626013
申请日：1984-06-29
申请人： Virgil L. Payne , Charles H. Mauldin
发明人： Virgil L. Payne , Charles H. Mauldin
IPC分类号： B01J21/06 , B01J23/74 , B01J23/75 , B01J23/76 , B01J23/83 , B01J32/00 , C07B61/00 , C07C1/00 , C07C1/04 , C07C1/20 , C07C1/24 , C07C67/00 , C10G2/00 , C10G3/00 , B01J23/12
CPC分类号： B01J32/00 , B01J23/75 , B01J23/83 , C07C1/0435 , C07C1/20 , C10G3/45 , C10G3/48 , C10G3/50 , C07C2521/06 , C07C2523/12 , C07C2523/75 , C07C2523/83 , C10G2300/1022 , Y02P20/52 , Y02P30/20
摘要： A cobalt catalyst, especially a thoria promoted cobalt catalyst, formed by dispersing the cobalt, or cobalt and thoria, upon a titania or titania-containing support wherein the titania support is one having a rutile:anatase ratio of at least about 2:3. By passing methanol, or an admixture of carbon monoxide and hydrogen over the catalyst at reaction conditions, a distillate fuel constituted principally of an admixture of linear paraffin and olefins, particularly a C.sub.10 + distillate can be formed. The distillate can be further refined and upgraded to high quality fuels, and other products such as mogas, diesel fuel, jet fuel, lubes and specialty solvents, particularly premium middle distillate fuels of carbon numbers ranging from about C.sub.10 to about C.sub.20.
摘要翻译：通过将钴或钴和氧化钍分散在二氧化钛或二氧化钛的载体上而形成的钴催化剂，特别是硫酸盐促进的钴催化剂，其中二氧化钛载体是金红石：锐钛矿比为至少约2:3的载体。通过在反应条件下将甲醇或一氧化碳和氢气混合在催化剂上，可以形成主要由直链烷烃和烯烃，特别是C10 +馏出物的混合物构成的馏出燃料。馏出物可以进一步精炼和升级为高质量的燃料，以及其他产品，如摩尔瓦，柴油，喷气燃料，润滑剂和特种溶剂，特别是碳数为约C10至约C20的优质中间馏分燃料。

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