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21. 发明授权

US07060771B2 Transparent fluorine-containing copolymer 失效
标题翻译：透明含氟共聚物
公开(公告)号：US07060771B2
公开(公告)日：2006-06-13
申请号：US10178781
申请日：2002-06-25
申请人： Haruhiko Komoriya , Sunao Koga , Kentaro Tsutsumi , Kazuhiko Maeda
发明人： Haruhiko Komoriya , Sunao Koga , Kentaro Tsutsumi , Kazuhiko Maeda
IPC分类号： C08F118/20
CPC分类号： C08F220/22
摘要： The present invention relates to a fluorine-containing copolymer. This fluorine-containing copolymer includes (a) a first unit derived from α-trifluoromethyl acrylic ester represented by the following general formula (1); and (b) a second unit derived from a vinyl monomer, where R1 is an organic group containing at least one fluorine atom.
摘要翻译：本发明涉及含氟共聚物。该含氟共聚物包括（a）由以下通式（1）表示的α-三氟甲基丙烯酸酯衍生的第一单元; 和（b）衍生自乙烯基单体的第二单元，其中R 1是含有至少一个氟原子的有机基团。

22. 发明授权

US06174955B1 Water-based fluorine-containing paint 失效
标题翻译：水性含氟涂料
公开(公告)号：US06174955B1
公开(公告)日：2001-01-16
申请号：US09139272
申请日：1998-08-25
申请人： Yoshi Hirashima , Kazuhiko Maeda , Satoru Kobayashi , Kentaro Tsutsumi
发明人： Yoshi Hirashima , Kazuhiko Maeda , Satoru Kobayashi , Kentaro Tsutsumi
IPC分类号： C08L2712
CPC分类号： C09D127/12 , C08G18/6279 , C08G18/706 , C08G18/718 , C08L75/04 , C08L2666/28 , C08L2666/14
摘要： The invention provides a first water-based fluorine-containing paint including a water-based emulsion containing a fluorine-containing copolymer dispersed therein, and 1-50 parts by weight of a hardener per 100 parts by weight of the copolymer. The copolymer is prepared by copolymerizing 30-65 mol % of a fluoroolefin, 14-69 mol % of a copolymerizable vinyl-containing compound, and 1-30 mol % of a hydroxyl-containing compound and/or a polymerizable carboxyl-containing compound. The hardener is prepared by mixing 1 part by weight of a self-emulsifiable polyisocyanate with 0.01-1 part by weight of a compound containing in the molecule an oxyethylene unit and an alkoxysilyl group. When mixed with the emulsion, the hardener becomes well dispersed therein. The invention further provides a second water-based fluorine-containing paint including a water-based emulsion containing a fluorine-containing copolymer dispersed therein, and a hardener which is a compound containing in the molecule at least two hydrazino groups. The fluorine-containing copolymer is prepared by emulsion polymerization of 30-65 mol % of a fluoroolefin, 0.1-20 mol % of a polymerizable unsaturated carboxylic acid, 1-30 mol % of a polymerizable acetoacetylallyl compound, and 20-65 mol % of one of a vinyl ester and a vinyl ether. The second paint does not cure at ambient temperature, even after the hardener has been added thereto, and thus is usable as a one-package paint.
摘要翻译：本发明提供第一种水性含氟涂料，其包含含有分散在其中的含氟共聚物的水性乳液和每100份重量共聚物1-50份重量的硬化剂。该共聚物通过使30-65mol％的氟烯烃，14-69mol％的可共聚的含乙烯基化合物和1-30mol％的含羟基化合物和/或可聚合的含羧基化合物共聚而制备。通过将1重量份的自乳化多异氰酸酯与0.01-1重量份在分子中含有氧化乙烯单元和烷氧基甲硅烷基的化合物混合来制备固化剂。当与乳液混合时，固化剂变得很好地分散在其中。本发明还提供了包含分散在其中的含有含氟共聚物的水性乳液的第二水性含氟涂料，以及分子中含有至少两个肼基的化合物的固化剂。含氟共聚物通过30-65mol％的氟代烯烃，0.1-20mol％的可聚合不饱和羧酸，1-30mol％的可聚合乙酰乙烯基化合物和20-65mol％的可聚合乙酰乙烯基化合物的乳液聚合制备，乙烯基酯和乙烯基醚之一。第二种涂料即使在加入固化剂之后也不能在环境温度下固化，因此可用作单组分涂料。

23. 发明授权

US5880234A Curable fluorine-containing copolymer and coating liquid composition containing same 失效
标题翻译：可固化的含氟共聚物和含有它的涂布液组合物
公开(公告)号：US5880234A
公开(公告)日：1999-03-09
申请号：US831305
申请日：1997-04-01
申请人： Kazuhiko Maeda , Yukio Ikeda , Kentaro Tsutsumi , Yutaka Maruyama , Shuyo Akama , Michitaka Ohtani
发明人： Kazuhiko Maeda , Yukio Ikeda , Kentaro Tsutsumi , Yutaka Maruyama , Shuyo Akama , Michitaka Ohtani
IPC分类号： C08F214/18 , C08F218/10 , C08F12/22
CPC分类号： C08F218/10 , C08F214/184 , C08F214/186
摘要： The invention relates to a curable fluorine-containing copolymer prepared by copolymerizing a monomer mixture. This monomer mixture is in an amount of 100 mol % in total and includes (a) 10-60 mol % of a first polymerizable monomer that is one of hexafluoroisobutene and hexafluoroacetone, each of which has one hexafluoroisopropylidene group; (b) 10-70 mol % of a fatty acid vinyl ester that is represented by a general formula of CH.sub.2 .dbd.CH--OC (.dbd.O) --R.sup.1 where R.sup.1 is one of an alkyl group and --(CH.sub.2).sub.m --R.sup.2 --(CH.sub.2).sub.n --H where R.sup.2 is one of a cycloalkylene group and a divalent aromatic group, and m and n are respectively integers each ranging from 0 to 12, the alkyl group having a carbon atom number of from 1 to 22 and an optional branched chain, each of the cycloalkylene group and the divalent aromatic group having an optional substituent; (c) 1-60 mol % of a second polymerizable monomer that has a cross-linkable functional group and a polymerizable double bond, the cross-linkable functional group being one selected from the group consisting of hydroxyl group, carboxyl group, hydrolyzable organosilyl groups, epoxy groups, .beta.-ketoester groups; and (d) 0-20 mol %, of a third polymerizable monomer that is different from the first and second monomers and the fatty acid vinyl ester and is free of a cross-linkable functional group. A coated film prepared by the application of a varnish containing the fluorine-containing copolymer is superior in water repellency and stain resistance.
摘要翻译：本发明涉及通过共聚单体混合物制备的可固化含氟共聚物。该单体混合物的总量为100摩尔％，包括（a）10-60摩尔％的作为六氟异丁烯和六氟丙酮之一的第一可聚合单体，每个具有一个六氟异丙烯基; （b）10-70mol％由通式CH 2 = CH-OC（= O）-R1表示的脂肪酸乙烯基酯，其中R1是烷基和 - （CH2）m -R2- （CH2）nH，其中R2是亚环烷基和二价芳族基团之一，m和n分别为0-12的整数，碳原子数为1至22的烷基和任选的支链，各环亚烷基和具有任选取代基的二价芳基; （c）1-60摩尔％具有可交联官能团和可聚合双键的第二可聚合单体，所述可交联官能团选自羟基，羧基，可水解的有机甲硅烷基，环氧基团，β-酮酯基团; 和（d）0-20摩尔％的不同于第一和第二单体和脂肪酸乙烯基酯并且不含可交联官能团的第三可聚合单体。通过使用含有含氟共聚物的清漆制备的涂膜具有优异的防水性和耐污染性。

24. 发明授权

US5856394A Water-based fluorine-containing paint 失效
标题翻译：水性含氟涂料
公开(公告)号：US5856394A
公开(公告)日：1999-01-05
申请号：US647853
申请日：1996-05-15
申请人： Yoshi Hirashima , Kazuhiko Maeda , Satoru Kobayashi , Kentaro Tsutsumi
发明人： Yoshi Hirashima , Kazuhiko Maeda , Satoru Kobayashi , Kentaro Tsutsumi
IPC分类号： C08G18/62 , C08G18/70 , C08G18/71 , C08L75/04 , C09D127/12 , C08L27/12
CPC分类号： C09D127/12 , C08G18/6279 , C08G18/706 , C08G18/718 , C08L75/04
摘要： The invention provides a first water-based fluorine-containing paint including a water-based emulsion containing a fluorine-containing copolymer dispersed therein, and 1-50 parts by weight of a hardener per 100 parts by weight of the copolymer. The copolymer is prepared by copolymerizing 30-65 mol % of a fluoroolefin, 14-69 mol % of a copolymerizable vinyl-containing compound, and 1-30 mol % of a hydroxyl-containing compound and/or a polymerizable carboxyl-containing compound. The hardener is prepared by mixing 1 part by weight of a self-emulsifiable polyisocyanate with 0.01-1 part by weight of a compound containing in the molecule an oxyethylene unit and an alkoxysilyl group. When mixed with the emulsion, the hardener becomes well dispersed therein. The invention further provides a second water-based fluorine-containing paint including a water-based emulsion containing a fluorine-containing copolymer dispersed therein, and a hardener which is a compound containing in the molecule at least two hydrazino groups. The fluorine-containing copolymer is prepared by emulsion polymerization of 30-65 mol % of a fluoroolefin, 0.1-20 mol % of a polymerizable unsaturated carboxylic acid, 1-30 mol % of a polymerizable acetoacetylallyl compound, and 20-65 mol % of one of a vinyl ester and a vinyl ether. The second paint does not cure at ambient temperature, even after the hardener has been added thereto, and thus is usable as a one-package paint.
摘要翻译：本发明提供第一种水性含氟涂料，其包含含有分散在其中的含氟共聚物的水性乳液和每100份重量共聚物1-50份重量的硬化剂。该共聚物通过使30-65mol％的氟烯烃，14-69mol％的可共聚的含乙烯基化合物和1-30mol％的含羟基化合物和/或可聚合的含羧基化合物共聚而制备。通过将1重量份自乳化多异氰酸酯与0.01-1重量份在分子中含有氧化乙烯单元和烷氧基甲硅烷基的化合物混合来制备固化剂。当与乳液混合时，固化剂变得很好地分散在其中。本发明还提供了包含分散在其中的含有含氟共聚物的水性乳液的第二水性含氟涂料，以及分子中含有至少两个肼基的化合物的固化剂。含氟共聚物通过30-65mol％的氟代烯烃，0.1-20mol％的可聚合不饱和羧酸，1-30mol％的可聚合乙酰乙烯基化合物和20-65mol％的可聚合乙酰乙烯基化合物的乳液聚合制备，乙烯基酯和乙烯基醚之一。第二种涂料即使在加入固化剂之后也不能在环境温度下固化，因此可用作单组分涂料。

25. 发明授权

US4954589A Soluble and curable fluorine-containing copolymer suitable as paint vehicle 失效
标题翻译：可溶性和可固化含氟共聚物适合作为涂料载体
公开(公告)号：US4954589A
公开(公告)日：1990-09-04
申请号：US353032
申请日：1989-05-17
申请人： Kiyomi Sugawara , Kentaro Tsutsumi , Mikio Otani
发明人： Kiyomi Sugawara , Kentaro Tsutsumi , Mikio Otani
IPC分类号： C08F14/18 , C08F16/14 , C08F18/02 , C08F214/18 , C08F214/24 , C08F216/14 , C08F218/02 , C08F218/04 , C09D127/12 , C09D129/00 , C09D129/10 , C09D131/02 , C09D131/04 , C09D133/04 , C09D133/06
CPC分类号： C08F214/247 , C08F214/186 , C08F218/04
摘要： The invention provides a novel copolymer comprising 25-75 mol % of a fluoroolefin such as CTFE, 10-70 mol % of a vinyl or isopropenyl ester of fatty acid, such as finyl acetate or isopropenyl acetate, 3-40 mol % of a hydroxyl-containing allyl ether such as ethylene glycol monoallyl ether, and 0.1-20 mol % of a carboxyl-containing monomer such as finylacetic acid. This copolymer possesses favorable properties characteristic of fluoroesins, is soluble in various organic solvents and is curable at normal temperature by a polyisocyanate. Since the copolymer has carboxyl group, not only inorganic pigments but also organic pigments exhibit very good dispersibility in a solution of this copolymer in an organic solvent. The copolymer can be prepared by a single-stage reaction using a radical polymerization initiator.
摘要翻译：本发明提供一种包含25-75mol％的氟烯烃如CTFE，10-70mol％乙烯基或脂肪酸异丙烯酯的新型共聚物，例如乙酸芬脂酯或乙酸异丙烯酯，3-40mol％的羟基含有烯丙基醚如乙二醇单烯丙基醚和0.1-20摩尔％的含羧基的单体如甲基乙酸。该共聚物具有氟类蛋白的有利特性，可溶于各种有机溶剂，在常温下可通过多异氰酸酯固化。由于共聚物具有羧基，不仅无机颜料而且有机颜料在该共聚物在有机溶剂中的溶液中表现出非常好的分散性。共聚物可以通过使用自由基聚合引发剂的单阶段反应来制备。

26. 发明授权

US4965339A Method of preparing soluble aromatic polyimides and varnish compositions using same 失效
标题翻译：制备可溶性芳族聚酰亚胺和使用其的清漆组合物的方法
公开(公告)号：US4965339A
公开(公告)日：1990-10-23
申请号：US390887
申请日：1989-08-08
申请人： Yutaka Maruyama , Haruhiko Komoriya , Kentaro Tsutsumi
发明人： Yutaka Maruyama , Haruhiko Komoriya , Kentaro Tsutsumi
IPC分类号： C09D179/08 , C08G73/10
CPC分类号： C08G73/105 , C08G73/1007 , C08G73/1032
摘要： Aromatic polyimides having a repeating unit represented by the general formula (1) are prepared by cyclization reaction of corresponding polyamic acids in an organic solvent in the presence of a lower monocarboxylic acid anhydride and a tertiary amine, e.g. triethylamine. The polyimides obtained by this method have high solubilities in various organic polar solvents and are soluble also in some organic nonpolar solvents. A solution of a polyimide prepared by this method in an organic solvent provides a varnish composition useful for wide purposes. ##STR1## wherein Rf is a perfluoroalkyl group, R is a tetravalent organic group, and each -N.dbd. is at the meta- or para-position with respect to the aromatic ether bond --O--.
摘要翻译：具有由通式（1）表示的重复单元的芳族聚酰亚胺通过相应的聚酰胺酸在有机溶剂中，在较低的一元羧酸酐和叔胺的存在下进行环化反应来制备。三乙胺通过该方法获得的聚酰亚胺在各种有机极性溶剂中具有高溶解度，并且在一些有机非极性溶剂中也是可溶的。通过该方法制备的聚酰亚胺在有机溶剂中的溶液提供了用于广泛目的的清漆组合物。其中Rf是全氟烷基，R是四价有机基团，并且每个-N =相对于芳族醚键-O-位于对位或对位。

27. 发明授权

US07220873B2 Conjugated fatty acid containing monoglycerides and process for producing them 失效
标题翻译：含有单酸甘油酯的共轭脂肪酸及其制备方法
公开(公告)号：US07220873B2
公开(公告)日：2007-05-22
申请号：US10210207
申请日：2002-08-02
申请人： Yoshie Yamauchi , Takaya Yamamoto , Kentaro Tsutsumi , Yuji Shimada , Yomi Watanabe , Akio Sugihara , Yoshio Tominaga
发明人： Yoshie Yamauchi , Takaya Yamamoto , Kentaro Tsutsumi , Yuji Shimada , Yomi Watanabe , Akio Sugihara , Yoshio Tominaga
IPC分类号： C11C3/00
CPC分类号： C11C3/025 , A23D9/013 , C11C1/10 , C11C3/02 , C12P7/6472
摘要： This invention provides monoglycerides containing a conjugated fatty acid, and a process for producing the above described conjugated fatty acid containing monoglycerides in which all kinds of lipases can be used as catalysts.This invention relate to monoglycerides containing a conjugated fatty acid (preferably in an amount of 50% or more of fatty acids).This invention also relates to a process for producing the conjugated fatty acid containing monoglycerides, in which the conjugated fatty acid containing a free fatty acid and glycerol are subjected to the reaction of esterification, or of esterification and glycerolysis in the presence of lipase as a catalyst.
摘要翻译：本发明提供含有共轭脂肪酸的单酸甘油酯，以及含有单酸甘油酯的上述共轭脂肪酸的制造方法，其中可以使用各种脂肪酶作为催化剂。本发明涉及含有共轭脂肪酸的单酸甘油酯（优选为脂肪酸的50％以上的量）。本发明还涉及含有单酸甘油酯的共轭脂肪酸的制造方法，其中含有游离脂肪酸和甘油的共轭脂肪酸在脂肪酶作为催化剂存在下进行酯化反应或酯化和甘油分解。

28. 发明授权

US06403744B1 Fluorine-containing copolymer and composition for preparing low reflectance film 有权
标题翻译：含氟共聚物和制备低反射膜的组合物
公开(公告)号：US06403744B1
公开(公告)日：2002-06-11
申请号：US09640536
申请日：2000-08-17
申请人： Shuyo Akama , Hiromi Sugimoto , Kentaro Tsutsumi
发明人： Shuyo Akama , Hiromi Sugimoto , Kentaro Tsutsumi
IPC分类号： C08F21418
CPC分类号： C08F214/182 , C08F214/188
摘要： The invention relates to a fluorine-containing copolymer. This copolymer contains 1-99 mol % of a special first repeating unit of a cyclic perfluoro group; and 99-1 mol % of a second repeating unit of a bivalent organic group. The copolymer has a number average molecular weight of from 1,000 to 1,000,000 determined in a gel permeation chromatography using polystyrene as a standard material thereof. The invention further relates to a composition for forming a low reflectance film. This composition contains as a film-forming component a fluorine-containing polymer containing the first repeating unit. This polymer can be the above copolymer. A film formed by applying the composition to a substrate provides low reflectance and is improved in hardness.
摘要翻译：本发明涉及一种含氟共聚物。该共聚物含有1-99mol％的环状全氟基团的特殊的第一重复单元; 和99-1摩尔％的二价有机基团的第二重复单元。该共聚物的数均分子量为1,000〜1,000,000，在使用聚苯乙烯作为标准材料的凝胶渗透色谱中测定。本发明还涉及用于形成低反射率膜的组合物。该组合物含有含有第一重复单元的含氟聚合物作为成膜组分。该聚合物可以是上述共聚物。通过将组合物施加到基材上形成的膜提供低反射率并且硬度提高。

29. 发明授权

US5043390A Fluoroolefin-alkene base copolymer useful as paint vehicle 失效
标题翻译：用作涂料载体的氟烯烃 - 烯烃基共聚物
公开(公告)号：US5043390A
公开(公告)日：1991-08-27
申请号：US503921
申请日：1990-04-04
申请人： Toshio Koishi , Yutaka Maruyama , Mikio Ootani , Seichi Katsuragawa , Kentaro Tsutsumi , Kiyomi Sugawara
发明人： Toshio Koishi , Yutaka Maruyama , Mikio Ootani , Seichi Katsuragawa , Kentaro Tsutsumi , Kiyomi Sugawara
IPC分类号： C08F210/00 , C08F210/02 , C08F210/06 , C08F210/08 , C08F214/18
CPC分类号： C08F210/00 , C08F214/188 , C08F210/02 , C08F210/06 , C08F210/08
摘要： The invention provides a novel copolymer comprising 25-75 mol % of a fluoroolefin such as CTFE or TFE, 10-70 mol % of an alkene such as ethylene or propylene, 3-40 mol % of a hydroxyl-containing allyl ether such as ethylene glycol monolallyl ether and 0-20 mol % of a carboxyl-containing monomer such as vinylacetic acid. This copolymer possesses favorable properties characteristic of fluororesins, is soluble in organic solvents including aromatic solvents low in polarity, such as xylene, and is curable at relatively low temperatures. The copolymer is useful particularly as a paint vehicle. The water repellency of the copolymer in cured state can be enhanced by incorporating a fluorine-containing surface modifier in the copolymer.

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