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1. 发明授权

US06774164B2 Process for producing fluoroelastomers with fluorinated anionic surfactants 有权
标题翻译：用含氟阴离子表面活性剂生产含氟弹性体的方法
公开(公告)号：US06774164B2
公开(公告)日：2004-08-10
申请号：US09938695
申请日：2001-08-24
申请人： Donald Frederick Lyons , Albert Lloyd Moore , Phan Linh Tang
发明人： Donald Frederick Lyons , Albert Lloyd Moore , Phan Linh Tang
IPC分类号： C08F21418
CPC分类号： C08F214/184 , C08F14/18 , C08F2/16
摘要： A novel emulsion polymerization process for the production of fluoroelastomers is disclosed wherein a partially fluorinated anionic surfactant of the formula F—(CF2CF2)n—CH2CH2SO3M, where n is an integer from 2 to 9, or mixtures thereof, and M is a cation having a valence of 1, is used as the dispersing agent.
摘要翻译：公开了一种用于生产含氟弹性体的新型乳液聚合方法，其中式F-（CF 2 CF 2）n -CH 2 CH 2 SO 3 M的部分氟化阴离子表面活性剂，其中n为2至9的整数，或其混合物，M为具有使用1价，作为分散剂。

2. 发明授权

US06455658B1 Fluorocopolymer and film made therefrom 有权
标题翻译：含氟共聚物和由其制成的薄膜
公开(公告)号：US06455658B1
公开(公告)日：2002-09-24
申请号：US09254432
申请日：1999-03-09
申请人： Ken Okanishi , Keizo Shiotsuki , Ryoichi Fukagawa
发明人： Ken Okanishi , Keizo Shiotsuki , Ryoichi Fukagawa
IPC分类号： C08F21418
CPC分类号： C08J5/18 , C08F210/02 , C08F214/265 , C08J2327/18 , C08J2327/20 , C08F214/26 , C08F214/28 , C08F2500/12 , C08F2500/26
摘要： A fluorine-containing copolymer comprising ethylene, tetrafluoroethylene, a fluorovinyl compound of the formula: CH2═CFRf in which Rf is a fluoroalkyl group having 2 to 10 carbon atoms, and hexafluoropropylene, in which a molar ratio of tetrafluoroethylene to ethylene is from 40:60 to 90:10, the content of the above fluorovinyl compound of the formula: CH2═CFRf is from 0.1 to 10 mole % based on the whole copolymer, and the content of hexafluoropropylene is from 0.1 to 30 mole % based on the whole copolymer. This fluorine-containing copolymer can provide films having good transparency and high tear strength, and such films are useful as weather-resistant protective films, films for agricultural housings, films for constructions, and the like.
摘要翻译：包含乙烯，四氟乙烯，下式的氟乙烯基化合物的氟代乙烯基化合物，其中R f为具有2至10个碳原子的氟代烷基的氟代乙烯基化合物和六氟丙烯，其中四氟乙烯与乙烯的摩尔比为40： 60〜90:10，上述式：CH 2 = CFR f的氟乙烯基化合物的含量相对于全部共聚物为0.1〜10摩尔％，六氟丙烯的含量相对于全部共聚物为0.1〜30摩尔％。该含氟共聚物可以提供透明性好，撕裂强度高的膜，这些膜可用作耐候性保护膜，农用外壳用膜，建筑用膜等。

3. 发明授权

US06696534B2 Random copolymer compositions 失效
标题翻译：无规共聚物组合物
公开(公告)号：US06696534B2
公开(公告)日：2004-02-24
申请号：US10213763
申请日：2002-08-07
申请人： Dennis W. Smith , Hiren V. Shah , John Ballato , Stephen Foulger
发明人： Dennis W. Smith , Hiren V. Shah , John Ballato , Stephen Foulger
IPC分类号： C08F21418
CPC分类号： G02B6/1221 , C08F293/005 , C08G61/02 , C08L53/00 , Y10T428/24
摘要： Fluoropolymers consisting of alternating perfluorocyclobutane and aryl ether linkages possess suitable properties for optical waveguides and other devices using refractive properties of the polymers. Perfluorocyclobutane (PFCB) polymers having aryl groups alternating on an ether chain have shown useful physical properties for optical waveguide applications. Processes for micromolding such polymeric films by replicating a pattern or image directly from a silicon master, rather than from a polydimethyl siloxane (PDMS) mold, are disclosed.
摘要翻译：由交替的全氟环丁烷和芳基醚键组成的含氟聚合物对于使用聚合物的折射性质的光波导和其它器件具有合适的性能。具有在醚链上交替的芳基的全氟环丁烷（PFCB）聚合物已经显示出用于光波导应用的有用的物理性质。公开了通过从硅母料而不是聚二甲基硅氧烷（PDMS）模具直接复制图案或图像来微型成型这种聚合物膜的方法。

4. 发明授权

US06599997B2 Fluorine-containing adhesive and adhesive film and laminated article made by using same 有权
标题翻译：含氟粘合剂和粘合剂膜和使用它们制成的层压制品
公开(公告)号：US06599997B2
公开(公告)日：2003-07-29
申请号：US10189415
申请日：2002-07-08
申请人： Takayuki Araki , Shigehito Sagisaka , Yoshito Tanaka , Masahiro Kumegawa
发明人： Takayuki Araki , Shigehito Sagisaka , Yoshito Tanaka , Masahiro Kumegawa
IPC分类号： C08F21418
CPC分类号： B32B1/08 , B32B7/12 , B32B15/043 , C09J127/16 , Y10T428/3154 , Y10T428/31544 , Y10T428/31649 , Y10T428/31699 , Y10T428/31743 , Y10T428/3175 , Y10T428/31855 , Y10T428/31909
摘要： A fluorine-containing adhesive comprising a fluorine-containing ethylenic polymer (A) having functional group which has a crystalline melting point or glass transition temperature of not more than 270° C. and is prepared by copolymerizing (a) 0.05 to 30% by mole of at least one of fluorine-containing ethylenic monomers having at least one functional group selected from the group consisting of carboxyl and a carboxylic salt group and (b) 70 to 99.95% by mole of at least one of fluorine-containing ethylenic monomers which do not have the above-mentioned functional group and is copolymerizable with the component (a). To provide the fluorine-containing adhesive maintaining chemical resistance, solvent resistance, weather resistance and stain-proofing property and giving direct strong adhesion particularly to a substrate of metal, glass, resin, etc. and an adhesive film and laminated article which are produced from the fluorine-containing adhesive.
摘要翻译：含有具有官能团的含氟乙烯性聚合物（A）的含氟粘合剂，其具有结晶熔点或玻璃化转变温度不高于270℃，并且通过（a）0.05〜30摩尔％的至少一种具有至少一个选自羧基和羧酸盐基团的官能团的含氟乙烯性单体和（b）70〜99.95摩尔％的至少一种含氟乙烯性单体，其中，不具有上述官能团并且可与组分（a）共聚。提供维持耐化学性，耐溶剂性，耐候性和防污性的含氟粘合剂，特别是对金属，玻璃，树脂等的基材和粘合剂膜和层压制品的直接强粘合性，其由含氟粘合剂。

5. 发明授权

US06288172B1 Light diffusing adhesive 失效
标题翻译：光漫射胶
公开(公告)号：US06288172B1
公开(公告)日：2001-09-11
申请号：US08935481
申请日：1997-05-06
申请人： Richard J. Goetz , Andrew J. Ouderkirk
发明人： Richard J. Goetz , Andrew J. Ouderkirk
IPC分类号： C08F21418
CPC分类号： C09J7/38
摘要： A light diffusing adhesive comprising a mixture of a pressure-sensitive adhesive matrix having a refractive index of n1 filled with organic, polymeric microparticles having a refractive index n2, wherein the absolute difference in the refractive indices of matrix and microparticles, that is, |n1-n2| is greater than zero and typically in the range of 0.01 to 0.2. The weight ratio of matrix to microparticles, based on solids, is from about 1:1 to about 50:1, preferably from about 4:1 to about 25:1.
摘要翻译：一种光漫射粘合剂，其包含折射率为n1的压敏粘合剂基质与填充有折射率n2的有机聚合物微粒的混合物，其中基质和微粒的折射率的绝对差异为| n1 -n2 | 大于零，通常在0.01至0.2的范围内。基于固体的基质与微粒的重量比为约1：1至约50：1，优选约4：1至约25：1。

6. 发明授权

US06664354B2 Fluorochemical sulfonamide surfactants 有权
标题翻译：氟化磺酰胺表面活性剂
公开(公告)号：US06664354B2
公开(公告)日：2003-12-16
申请号：US10310300
申请日：2002-12-05
申请人： Patricia M. Savu , Sandra A. Etienne
发明人： Patricia M. Savu , Sandra A. Etienne
IPC分类号： C08F21418
CPC分类号： C08F8/44 , B01F17/0035 , C03C12/02 , C03C17/32 , C04B41/4846 , C04B2111/60 , C08F2/30 , C08F220/24 , C08F220/38 , C08F290/062 , C08F2220/1891 , C08F2220/286 , C08F2220/288 , C08F2220/387 , C08F2800/20 , C08F2810/50 , C08G18/42 , C08G18/73 , C08L33/14 , C09D7/63 , C09D7/65 , C09G1/00 , C11D1/004 , E04F15/12 , G03C1/385 , C04B41/4584 , C08F220/28 , C08F220/34 , C08F2220/585 , C08F220/06
摘要： Described are fluorochemical surfactants derived from nonafluorobutanesulfonyl fluoride that contain polyalkyleneoxy side chains and may be copolymerized with acrylic acid or methacrylic acid to form polyacrylates or polymethacrylates. The surfactants surprisingly lower the surface tension of water and other liquids in the same or similar low values achieved by premier surfactants such as those derived from perfluorooctane sulfonyl fluoride.
摘要翻译：描述了衍生自包含聚亚烷基氧基侧链的九氟丁磺酰氟的氟化物表面活性剂，并可与丙烯酸或甲基丙烯酸共聚以形成聚丙烯酸酯或聚甲基丙烯酸酯。表面活性剂令人惊讶地降低了水和其它液体的表面张力，而这些表面张力与由诸如衍生自全氟辛基磺酰氟的衍生物表面活性剂等主要表面活性剂所达到的相同或相似的低值。

7. 发明授权

US06518381B2 Tetrafluoroethylene polymer for stretching 有权
标题翻译：用于拉伸的四氟乙烯聚合物
公开(公告)号：US06518381B2
公开(公告)日：2003-02-11
申请号：US09970674
申请日：2001-10-05
申请人： Shigeki Kobayashi , Jun Hoshikawa , Kazuo Kato , Hiroki Kamiya , Hiroyuki Hirai
发明人： Shigeki Kobayashi , Jun Hoshikawa , Kazuo Kato , Hiroki Kamiya , Hiroyuki Hirai
IPC分类号： C08F21418
CPC分类号： C08F214/26 , Y10T428/249953
摘要： A tetrafluoroethylene polymer having high stretchability, a fibrillatable character and a non-melt fabricable quality, which has a standard specific gravity of at most 2.160, and a tensile break strength of from 32.0N (3.26 kgf) to 49.0N (5.0 kgf) or an endothermic ratio of at most 0.15 as calculated from the measurement by differential thermal analysis. The tetrafluoroethylene polymer is suitable for stretching operation after paste extrusion.
摘要翻译：具有高伸缩性，可原纤化特性和不熔融可加工品质的四氟乙烯聚合物，其标准比重至多为2.160，拉伸断裂强度为32.0N（3.26kgf）至49.0N（5.0kgf）或通过差热分析计算出的吸热比至多为0.15。四氟乙烯聚合物适用于糊料挤出后的拉伸操作。

8. 发明授权

US06500903B2 Fluoroelastomers 有权
标题翻译：氟弹性体
公开(公告)号：US06500903B2
公开(公告)日：2002-12-31
申请号：US09370254
申请日：1999-08-09
申请人： Ivan Wlassics , Marco Apostolo , Margherita Albano
发明人： Ivan Wlassics , Marco Apostolo , Margherita Albano
IPC分类号： C08F21418
CPC分类号： C08F214/222 , C08F214/262
摘要： Curable fluoroelastomers comprising monomeric units formed by triazine iodinated derivative having general formula: wherein Y′ is independently H, Cl, F, CH3, or CF3, m′ and t′ are 0 or 1, and m′+t′=0 or 1, preferably m′+t′=0; p′ is an integer and is equal to 1 when t′=1, or p′=0; X′ is independently H, Cl, F, alkyl or perfluoroalkyl C1-C3, preferably F; n′ is an integer between 2 and 20, preferably between 4 and 12, more preferably between 4 and 8.
摘要翻译：其中Y'独立地为H，Cl，F，CH 3或CF 3，m'和t'为0或1，m' ，优选m'+ t'= 0; p'是一个整数，当t'= 1或p'= 0时，它等于1; X'独立地是H，Cl，F，烷基或全氟烷基C1-C3，优选F; n'为2〜20，优选为4〜12，更优选为4〜8的整数。

9. 发明授权

US06822060B2 Process for producing a tetrafluoroethylene polymer excellent in strength 有权
标题翻译：制造强度优异的四氟乙烯聚合物的方法
公开(公告)号：US06822060B2
公开(公告)日：2004-11-23
申请号：US10072995
申请日：2002-02-12
申请人： Shigeki Kobayashi , Jun Hoshikawa , Kazuo Kato , Hiroki Kamiya , Hiroyuki Hirai
发明人： Shigeki Kobayashi , Jun Hoshikawa , Kazuo Kato , Hiroki Kamiya , Hiroyuki Hirai
IPC分类号： C08F21418
CPC分类号： C08F14/26 , Y10S526/915 , Y10S526/919 , C08F2/16
摘要： A process for producing a tetrafluoroethylene polymer, which comprises polymerizing tetrafluoroethylene in an aqueous medium in the presence of a dispersant, a stabilizer and a polymerization initiator, wherein the polymerization initiator is a redox polymerization initiator comprising a halogen acid salt YXO3/a sulfite Z2SO3 wherein X is a chlorine atom, a bromine atom or an iodine atom, Y is a hydrogen atom, ammonium, an alkali metal or an alkaline earth metal, and Z is ammonium, an alkali metal or an alkaline earth metal. By this process, it is possible to obtain a tetrafluoroethylene polymer which is suitable for a stretching operation after paste extrusion.
摘要翻译：一种制备四氟乙烯聚合物的方法，其包括在分散剂，稳定剂和聚合引发剂存在下在水性介质中聚合四氟乙烯，其中聚合引发剂是包含卤酸盐YXO 3 /亚硫酸盐Z 2 SO 3的氧化还原聚合引发剂，其中 X是氯原子，溴原子或碘原子，Y是氢原子，铵，碱金属或碱土金属，Z是铵，碱金属或碱土金属。通过该方法，可以获得适合于糊料挤出后的拉伸操作的四氟乙烯聚合物。

10. 发明授权

US06759131B2 Poly(chlorotrifluoroethylene/vinylidenefluoride/vinylester) copolymers with excellent long term ultraviolet light resistance 有权
标题翻译：具有优异长期耐紫外线性的聚（氯三氟乙烯/偏二氟乙烯/乙烯基酯）共聚物
公开(公告)号：US06759131B2
公开(公告)日：2004-07-06
申请号：US10061674
申请日：2002-02-01
申请人： Thomas F. McCarthy
发明人： Thomas F. McCarthy
IPC分类号： C08F21418
CPC分类号： C08F214/04 , C08F214/24 , Y10T428/3154 , Y10T428/31544
摘要： A composition containing a non-flammable chlorofluoro-olefin copolymer having a crystallinity index less than about 10% and a weight-average molecular weight greater than about 1,000,000 daltons, wherein the copolymer has at least two comonomer units of the formula: CX2CYA wherein each X is independently selected from H, Cl and F; Y is selected from H, Cl, F, O(CZ2)nCZ3, (CZ2)nCZ3, (OCZ2CZ2)nCZ3 and (O(CZ2)n)nCZ3, wherein each n is independently from about 1 to about 12 and each Z is independently selected from H, Cl and F; and A is selected from H, Cl and F, provided that for at least one comonomer unit, at least one of A, Y, either X or any Z is Cl. Substrates coated with the copolymer compositions are also disclosed.
摘要翻译：一种组合物，其含有结晶度小于约10％且重均分子量大于约1,000,000道尔顿的不易燃氯氟烯烃共聚物，其中所述共聚物具有至少两个下式的共聚单体单元：其中每个X为独立地选自H，Cl和F; Y选自H，Cl，F，O（CZ2）nCZ3，（CZ2）nCZ3，（OCZ2CZ2）nCZ3和（O（CZ2）n）nCZ3，其中每个n独立地为约1至约12，独立地选自H，Cl和F; 并且A选自H，Cl和F，条件是对于至少一个共聚单体单元，A，Y，X或任何Z中的至少一个是Cl。还公开了涂覆有共聚物组合物的基材。

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