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21. 发明授权

US4262140A Production of anhydrous or substantially anhydrous formic acid 失效
标题翻译：生产无水或基本无水的甲酸
公开(公告)号：US4262140A
公开(公告)日：1981-04-14
申请号：US99760
申请日：1979-12-03
申请人： Kaspar Bott , Gerd Kaibel , Herwig Hoffmann , Otto Kratzer , Rudolf Irnich
发明人： Kaspar Bott , Gerd Kaibel , Herwig Hoffmann , Otto Kratzer , Rudolf Irnich
IPC分类号： C07C53/02 , C07C51/00 , C07C51/09 , C07C51/44 , C07C51/48 , C07C67/00 , B01D3/34
CPC分类号： C07C51/44 , C07C51/09 , C07C51/48
摘要： A process for the production of anhydrous or substantially anhydrous formic acid by hydrolysis of methyl formate which is carried out in a column having an upper fractionating section, a middle hydrolysis section and a lower extraction section and in which(a) the hydrolysis is carried out in the middle section of the columm, with water and methyl formate in countercurrent,(b) the resulting formic acid is extracted, in the lower section of the column, by means of a carboxylic acid amide which is fed into the lower end of the middle section of the column,(c) the extract phase, consisting in the main of formic acid and the carboxylic acid amide, is distillatively dehydrated, or substantially dehydrated, in the lower section of the column,(d) the methanol and uncovered methyl formate are removed by fractional distillation in the upper section of the column and(e) the pure formic acid or concentrated aqueous formic acid is distilled from the anhydrous or substantially anhydrous extract phase in a second column, leaving the carboxylic acid amide.
摘要翻译：一种通过水解甲酸甲酯生产无水或基本上无水的甲酸的方法，该甲酸甲酯在具有上部分馏段，中间水解段和下部萃取段的塔中进行，其中（a）进行水解在水的中间部分，与水和甲酸甲酯逆流，（b）所得甲酸在柱的下部通过羧酸酰胺萃取，该羧酸酰胺进料到塔的中间部分，（c）主要由甲酸和羧酸酰胺组成的提取相在塔的下部进行蒸馏脱水或基本上脱水，（d）甲醇和未被覆盖的甲基甲酸盐在塔的上部通过分馏除去，（e）从无水或基本上无水的提取物中蒸馏出纯甲酸或浓缩的甲酸水溶液相在第二塔中，留下羧酸酰胺。

22. 发明授权

US4196147A Manufacture of N-alkylanilines 失效
标题翻译： N-烷基苯胺的制造
公开(公告)号：US4196147A
公开(公告)日：1980-04-01
申请号：US837938
申请日：1977-09-29
申请人： Martin Decker , Herwig Hoffmann , Leopold Hupfer , Herbert Toussaint
发明人： Martin Decker , Herwig Hoffmann , Leopold Hupfer , Herbert Toussaint
IPC分类号： C07C209/18 , C07C85/06
CPC分类号： C07C209/18
摘要： N-Alkylanilines are obtained by alkylating anilines with alcohols in the absence of hydrogen under a pressure substantially higher than the autogenous pressure of the reaction mixture, at from 50.degree. to 250.degree. C., preferably in the presence of a fixed catalyst containing cobalt, nickel and copper.
摘要翻译： N-烷基苯胺是通过在不存在氢气的条件下，在大约高于反应混合物的自生压力的压力下，在不存在氢气的条件下，将苯胺与50-250℃，优选在含有钴的固定催化剂存在下，镍和铜。

23. 发明授权

US4153425A .omega.-Disubstituted amino alkanoic acid-N-amides as fuel additives 失效
标题翻译： {107-二取代氨基链烷酸-N-酰胺作为燃料添加剂
公开(公告)号：US4153425A
公开(公告)日：1979-05-08
申请号：US697771
申请日：1976-06-21
申请人： Heinz Graefje , Guenther Nottes , Herbert Mueller , Guenther Daumiller , Herwig Hoffmann
发明人： Heinz Graefje , Guenther Nottes , Herbert Mueller , Guenther Daumiller , Herwig Hoffmann
IPC分类号： C07C231/00 , C07C67/00 , C07C231/14 , C07C237/04 , C07C237/06 , C10L1/224 , F02B1/04 , C10L1/18 , C07C103/18 , C10L1/22
CPC分类号： C10L1/224 , F02B1/04
摘要： The novel compounds .omega.-N-disubstituted aminoalkanoic acid N'-amides of the formula ##STR1## in which R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are identical or different and denote branched-chain or straight-chain alkyl radicals of from 7 to 20 carbon atoms, R.sup.2 and R.sup.4 may also denote a preferably mononuclear aralkyl or aryl radical and n denotes an integer of from 3 to 5, the total number of carbon atoms in the radicals R.sup.1 to R.sup.2 and in R.sup.3 and R.sup.4 being at least 16, are added in small quantities to gasoline and effect cleaning of the carburetor and obviate the formation of deposits on the valves.
摘要翻译：新颖的化合物式为“IMAGE”I的ω-N-二取代的氨基链烷酸N'-酰胺，其中R 1，R 2，R 3和R 4相同或不同，表示支链或直链烷基，其从7到 20个碳原子，R2和R4也可以表示优选单核芳烷基或芳基，n表示3至5的整数，基团R1至R2和R3和R4中的碳原子总数至少为16，少量添加到汽油中，并对化油器进行清洁，并消除了阀门上沉积物的形成。

24. 发明授权

US06765119B2 Method of producing saturated C3-C20-alcohols 有权
标题翻译：饱和C 3 -C 20醇的制备方法
公开(公告)号：US06765119B2
公开(公告)日：2004-07-20
申请号：US10276219
申请日：2002-11-14
申请人： Herwig Hoffmann , Michael Röper , Heinrich-Josef Blankertz , Max Strohmeyer , Helmut Walz , Helmut Zinke-Allmang
发明人： Herwig Hoffmann , Michael Röper , Heinrich-Josef Blankertz , Max Strohmeyer , Helmut Walz , Helmut Zinke-Allmang
IPC分类号： C07C2914
CPC分类号： C07C29/141 , C07C31/12
摘要： The invention relates to a process for the preparation of saturated C3-C20-alcohols in which a liquid hydrogenation feed comprising at least one C3-C20-aldehyde is passed over a bed of a hydrogenation catalyst in the presence of a hydrogen-containing gas, which comprises adding to the hydrogenation feed an amount, homogeneously soluble therein, of a salt-like base. The addition of base suppresses side reactions, such as acetalization, aldolization, Tischtschenko reaction or ether formation.
摘要翻译：本发明涉及一种制备饱和C 3 -C 20醇的方法，其中包含至少一种C 3 -C 20醛的液体氢化进料在含氢气体存在下通过氢化催化剂床，其包括向氢化进料中加入其中均匀溶解的盐类碱的量。碱的添加抑制副反应，如缩醛化，醛醇缩合，Tischtschenko反应或醚形成。

25. 发明授权

US4288640A Carrying out exothermic reactions between a gas and a liquid 失效
标题翻译：在气体和液体之间进行放热反应
公开(公告)号：US4288640A
公开(公告)日：1981-09-08
申请号：US707499
申请日：1976-07-22
申请人： Ludwig Schuster , Paul Raff , Herwig Hoffmann , Rolf Schneider , Erich Flickinger
发明人： Ludwig Schuster , Paul Raff , Herwig Hoffmann , Rolf Schneider , Erich Flickinger
IPC分类号： B01J8/02 , B01J19/00 , C07B31/00 , C07B61/00 , C07C29/42 , C07C37/07 , C07C67/00 , C07C209/36 , C07C33/046 , C07C33/042 , C07C39/08 , C07C87/52
CPC分类号： C07C37/07 , B01J19/0013 , B01J8/025 , C07C209/36 , C07C29/42 , B01J2219/00065 , B01J2219/00069 , B01J2219/0011
摘要： Process for carrying out exothermic reactions between a gas and a liquid in the presence of a solid catalyst by passing the gas and the liquid cocurrently through a packed reaction vessel, preferably of elongated shape, wherein the gas and liquid pass through the packed reaction vessel in transition flow.
摘要翻译：通过使气体和液体并流地通过填充反应容器，优选细长形状，在固体催化剂存在下，在气体和液体之间进行放热反应的方法，其中气体和液体通过包装的反应容器过渡流。

26. 发明授权

US4243799A Polymerization of tetrahydrofuran 失效
标题翻译：四氢呋喃的聚合
公开(公告)号：US4243799A
公开(公告)日：1981-01-06
申请号：US40202
申请日：1979-05-18
申请人： Herbert Mueller , Otto H. Huchler , Herwig Hoffmann
发明人： Herbert Mueller , Otto H. Huchler , Herwig Hoffmann
IPC分类号： C08G18/48 , C08G65/20 , C08G65/26
CPC分类号： C08G65/2657 , C08G18/4854 , C08G65/20 , C08G65/266
摘要： A process for the preparation of polybutylene glycol carboxylic acid diesters of the formulaR--CO--O--CH.sub.2 CH.sub.2 CH.sub.2 CH.sub.2 --O).sub.n CO--R.sup.1by polymerizing pretreated tetrahydrofuran in the presence of one or more carboxylic acids and/or carboxylic acid anhydrides and of a polymerization catalyst, especially antimony pentachloride or a bleaching earth containing less than 3% by weight of water, wherein the tetrahydrofuran is treated with a strong mineral acid, an organic sulfonic acid, silica gel and/or a bleaching earth prior to the polymerization.
摘要翻译：通过在一种或多种羧酸和/或羧酸酐的存在下聚合预处理的四氢呋喃和聚合的方法制备式R-CO-O-CH 2 CH 2 CH 2 CH 2 -O）nCO-R 1的聚丁二醇羧酸二酯的方法催化剂，特别是五氯化锑或含有小于3重量％水的漂白土，其中四氢呋喃在聚合之前用强无机酸，有机磺酸，硅胶和/或漂白土处理。

27. 发明授权

US4014914A Manufacture of 4,4'-diphenylmethane diisocyanate and a mixture of diisocyanates and polyisocyanates 失效
标题翻译：制备4,4 {40-二苯基甲烷二异氰酸酯和二异氰酸酯和多异氰酸酯的混合物
公开(公告)号：US4014914A
公开(公告)日：1977-03-29
申请号：US518076
申请日：1974-10-25
申请人： Hans Joachim Pistor , Herwig Hoffmann , Hans-Ingo Joschek , Gotthilf Wenner
发明人： Hans Joachim Pistor , Herwig Hoffmann , Hans-Ingo Joschek , Gotthilf Wenner
IPC分类号： C07C41/28 , C08G18/76 , C07C119/02
CPC分类号： C08G18/7664 , C07C263/10
摘要： Production of 4,4'-diphenylmethane diisocyanate and a mixture of diisocyanates and polyisocyanates by the phosgenation of pure 4,4'-diaminodiphenylmethane and a mixture of diamines and polyamines. 4,4'-Diaminodiphenylmethane is obtained by distillation of the mixture of products obtained from the reaction of aniline with formaldehyde and crystallization of the distillate from a solvent. The combined distillation residue and mother liquor from the crystallization form the mixture for reaction with phosgene to produce a mixture of diisocyanates and polyiisocyanates. This process produces a highly pure 4,4'-diphenylmethane diisocyanate which is particularly suitable for the production of polyurethanes serving as intermediates in the manufacture of rigid foams or as glue.
摘要翻译：通过纯的4,4'-二氨基二苯基甲烷和二胺和多胺的混合物的光气化生产4,4'-二苯基甲烷二异氰酸酯和二异氰酸酯和多异氰酸酯的混合物。通过蒸馏从苯胺与甲醛的反应获得的产物的混合物和馏出液从溶剂中的结晶，得到4,4'-二氨基二苯基甲烷。合并的蒸馏残余物和母液从结晶形成混合物以与光气反应以产生二异氰酸酯和聚异氰酸酯的混合物。该方法产生高纯度的4,4'-二苯基甲烷二异氰酸酯，其特别适用于生产用于制造刚性泡沫或作为胶水的中间体的聚氨酯。

28. 发明授权

US5123932A Motor fuel compositions containing alkoxylation products 失效
标题翻译：含有烷氧基化产物的电动机燃料组合物
公开(公告)号：US5123932A
公开(公告)日：1992-06-23
申请号：US520745
申请日：1990-05-09
申请人： Hans P. Rath , Herwig Hoffmann , Volker Vogt , Hans Horler , Helmut Mach , Juergen Thomas
发明人： Hans P. Rath , Herwig Hoffmann , Volker Vogt , Hans Horler , Helmut Mach , Juergen Thomas
IPC分类号： C08G65/28 , C10L1/14 , C10L1/18 , C10L1/198 , C10L1/22
CPC分类号： C10L1/1985 , C10L1/146 , C10L1/2383
摘要： Motor fuel compositions contain alkoxylation products of oxo oils or their fractions or esters thereof, which are alkoxylated with propene oxide and/or butene oxides and/or not more than minor aomunts of ethene oxide.
摘要翻译：汽油燃料组合物含有氧化油或其馏分或酯的烷氧基化产物，它们与氧化丙烯和/或氧化烯氧化烷基化和/或不超过乙烯氧化物的次要氧化。

29. 发明授权

US4709105A Preparation of C.sub.3 -C.sub.25 -alkanols 失效
标题翻译：制备C3-C25-链烷醇
公开(公告)号：US4709105A
公开(公告)日：1987-11-24
申请号：US932637
申请日：1986-11-19
申请人： Armin V. Grenacher , Max Strohmeyer , Herwig Hoffmann , Heinrich Elliehausen
发明人： Armin V. Grenacher , Max Strohmeyer , Herwig Hoffmann , Heinrich Elliehausen
IPC分类号： C07B61/00 , B01J23/00 , B01J23/88 , C07C27/00 , C07C29/14 , C07C29/141 , C07C31/02 , C07C67/00 , C07C31/125
CPC分类号： C07C29/141
摘要： Preparation of C.sub.3 - to C.sub.25 -alkanols by catalytic hydrogenation of corresponding crude C.sub.3 - to C.sub.25 -alkanols, as obtained in the cobalt-catalyzed hydroformylation of C.sub.2 - to C.sub.24 -olefins, by partial 80-95% hydrogenation conversion in a first stage using a silica supported nickel and molybdenum oxide catalyst and then completing the conversion in a second stage using a cobalt catalyst containing copper, manganese, molybdenum and,optionally other activating additives. The process is especially adapted to the economic preparation of C.sub.9 -C.sub.11 - and C.sub.13 -C.sub.15 -alkanols which are used to prepare high-grade plasticizer esters.
摘要翻译：通过在C2-至C24-烯烃的钴催化加氢甲酰基化中获得的相应的粗C3-至C25-链烷醇的催化氢化，通过在第一阶段中部分80-95％氢化转化使C3-至C25-链烷醇的制备二氧化硅负载的镍和氧化钼催化剂，然后使用含有铜，锰，钼和任选的其它活化添加剂的钴催化剂在第二阶段完成转化。该方法特别适用于用于制备高级增塑剂酯的C9-C11-和C13-C15-链烷醇的经济性制备。

30. 发明授权

US4370491A Continuous preparation of acetic acid esters 失效
标题翻译：连续制备乙酸酯
公开(公告)号：US4370491A
公开(公告)日：1983-01-25
申请号：US263470
申请日：1981-05-14
申请人： Kaspar Bott , Gerd Kaibel , Herwig Hoffmann , Rudolf Irnich , Eberhard Schaefer
发明人： Kaspar Bott , Gerd Kaibel , Herwig Hoffmann , Rudolf Irnich , Eberhard Schaefer
IPC分类号： C07C67/03 , B01D3/36 , C07C67/02 , C07C69/14 , C07C67/06
CPC分类号： C07C67/03 , Y10S203/06
摘要： A process for the preparation of acetic acid esters CH.sub.3 --CO--O--R.sup.1 (I, R.sup.1 =an organic radical other than methyl and ethyl) by alkali-catalyzed trans-esterification of an acetic acid ester CH.sub.3 --CO--O--R.sup.2 (II, R.sup.2 =methyl or ethyl) with an alcohol R.sup.1 --OH (III), accompanied by elimination of the alcohol R.sup.2 --OH (IV), wherein(a) the trans-esterification reaction is carried out in the middle section K.sub.M of a distillation column K, the alcohol III being fed as liquid into the upper zone and the ester II into the lower zone of K.sub.M,(b) the alkaline catalyst is introduced into the upper part K.sub.U of K,(c) the alcohol IV, or a mixture of IV and the ester II, is taken off the top of the column,(d) the mixture obtained from (c) (unless the alcohol IV alone is obtained) is separated in the column section K.sub.U or in a stripper column K.sub.S into IV and the azeotrope of II and IV, and the latter is recycled to the lower zone of K.sub.M,(e) the ester I is taken as vapor or liquid from the lower zone of the lower section K.sub.L of K and(f) the catalyst is either removed, or recycled to K.sub.U, in a conventional manner.
摘要翻译：通过乙酸酯CH3-CO-O-R2的碱催化反式酯化制备乙酸酯CH 3 -CO-O-R 1（I，R 1 =甲基和乙基以外的有机基）的方法 II，R 2 =甲基或乙基）与醇R 1 -OH（III）反应，同时除去醇R 2 -OH（Ⅳ），其中（a）酯交换反应在蒸馏塔K，醇III作为液体进料到上部区域，酯II进入KM的下部区域，（b）将碱性催化剂引入K的上部KU，（c）醇IV，或将IV和酯II的混合物从柱顶部取出，（d）从（c）获得的混合物（除非单独获得醇IV）在柱部分KU或汽提塔KS中分离进入IV和II和IV的共沸物，后者再循环到KM的下部区域，（e）将酯I作为蒸汽或液体从下部KL的下部区域中取出的K和（f）催化剂以常规方式被去除或再循环至KU。

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