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    • 22. 发明授权
    • Process for the preparation of fluorochlorohydrocarbon-free, low-density
polyurethan soft foams and soft elastic polyurethan molding foams and
polyisocyanate mixtures modified with urethan groups on
diphenylmethane-diisocyanate base
    • 用于制备氟代氯代烃,低密度聚氨酯软泡沫和柔性弹性聚氨酯成型泡沫的方法和在二苯基甲烷二异氰酸酯基础上用氨基甲酸酯基团改性的多异氰酸酯混合物
    • US5374667A
    • 1994-12-20
    • US24589
    • 1993-03-01
    • Werner HinzRuth ZschiescheHeinz-Dieter LutterBernd Bruchmann
    • Werner HinzRuth ZschiescheHeinz-Dieter LutterBernd Bruchmann
    • C08G18/10C08G18/48C08G18/76C08G18/80C08G18/00
    • C08G18/8035C08G18/10C08G18/4837C08G18/7664C08G2101/0008C08G2101/005C08G2101/0083Y10S521/914
    • The invention provides a method for the preparation of fluorochlorohydrocarbon(FCHC)-free polyurethane soft (molded) foam materials with low density, by reactingA) liquid polyisocyanate mixtures containing bound urethane groups, containing 22 to 30 weight percent of NCO groups, which in turn are prepared by reacting a mixture of diphenylmethane-diisocyanate and polyphenyl-polymethylene-polyisocyanates (raw MDI) with at least one polyoxypropylene-polyoxyethylene-polyol with a functionality between 2.5 and 3.5, a hydroxyl number between 50 and 90 and a polymerized ethylene oxide group concentration ranging from more than 30 to less than 50 weight percent, relative to the weight of the polymerized ethylene oxide and 1,2 propylene oxide groups, or by reacting of 4,4'diphenylmethane-diisocyanate (MDI) or and MDI-isomeric mixture with the above-named polyoxypropylene-polyoxyethylene-polyol to an NCO-group-containing quasi-prepolymer, and diluting this quasi-prepolymer with raw-MDI, withB) higher-molecular polyhydroxyl compounds and, if appropriateC) low-molecular chain lengthening and/or cross-linkage-promoting materialsD) propellants,E) catalysts as well as if appropriate,F) auxiliary materials and/or additives, as well as the polyisocyanate mixtures modified with urethane groups (A) which are utilizable in accordance with the process of the invention.
    • 本发明提供了一种通过使含有22-30%(重量)NCO基团的结合的氨基甲酸酯基团的液体多异氰酸酯混合物反应来制备低密度的氟氯烃(FCHC) - 软质(模塑)泡沫材料的方法, 通过使二苯基甲烷 - 二异氰酸酯和聚苯基 - 多亚甲基多异氰酸酯(原MDI)与至少一种官能度在2.5和3.5之间,羟基数在50和90之间的聚氧化丙烯 - 聚氧乙烯 - 多元醇与聚合的环氧乙烷 相对于聚合的环氧乙烷和1,2-环氧丙烷基团的重量,或通过4,4'-二苯基甲烷二异氰酸酯(MDI)或MDI异构体(MDI)的反应,组浓度范围从大于30至小于50重量% 与上述聚氧丙烯 - 聚氧乙烯 - 多元醇的混合物与含有NCO基的准预聚物混合,并用B-MDI稀释该准预聚物,B) 高分子量多羟基化合物,如果合适C)低分子链延长和/或交联促进材料D)推进剂,E)催化剂以及适当的F)辅助材料和/或添加剂,以及 用氨基甲酸酯基团(A)改性的多异氰酸酯混合物,其可根据本发明的方法使用。
    • 25. 发明授权
    • Method of and apparatus for rolling and simultaneous radiation treatment
of rod-shaped articles of the tobacco processing industry
    • 烟草加工业棒状制品轧制和同时辐射处理的方法和装置
    • US4827947A
    • 1989-05-09
    • US158306
    • 1988-02-19
    • Werner Hinz
    • Werner Hinz
    • A24C5/60B23K26/08
    • B23K26/0823A24C5/606
    • Successive filter cigarettes of unit length or multiple unit length are transported sidways on a first drum-shaped conveyor which cooperates in a filter tipping machine with a second drum-shaped conveyor to rotate successive cigarettes about their respective axes so that the rotating cigarettes come to a temporary halt in a predetermined portion of their path. Such cigarettes are acted upon the two or more laser beams or light beams which are equidistant from and angularly offset relative to each other in the circumferential direction of the cigarette which rotates about its axis so that a circumferentially complete portion of the rotating cigarette is acted upon by radiation while the cigarette completes a fraction of one revolution, namely an angle of 360 degrees divided by the number of beams. The first conveyor has peripheral advancing surfaces for individual cigarettes, and the length of each advancing surface in the circumferential direction of the first conveyor equals the circumferential length of a cigarette divided by the number of beams. The mutual spacing of cigarettes on the first conveyor is less than the mutual spacing of cigarettes on a conveyor which feeds successive untreated cigarettes to the first conveyor ahead of the rolling station and on a conveyor which receives successive treated cigarettes from the first conveyor downstream of the rolling station.
    • 单位长度或多个单位长度的连续过滤嘴香烟在第一个鼓形输送机上运输,在第二个鼓形输送机上,该过滤嘴香烟与一个第二鼓形输送机在一个过滤嘴连接机器中配合,以使连续的香烟围绕其各自的轴旋转,从而使旋转的香烟进入 在其路径的预定部分暂时停止。 这种香烟作用在两根或多根激光束或光束上,这些激光束或光束在香烟的圆周方向上相对于彼此等距离并且沿角度偏移,该卷烟的圆周方向绕其轴线旋转,使得旋转香烟的周向完整部分作用在 通过辐射,而香烟完成了一圈的一分之一,即360度的角度除以光束的数量。 第一输送机具有用于单个香烟的周边前进表面,并且第一输送机的圆周方向上的每个前进表面的长度等于香烟的圆周长度除以梁的数量。 香烟在第一输送机上的相互间距小于输送机上的香烟的相互间隔,该输送机将连续未经处理的香烟供给到轧制站前面的第一输送机,以及在从第一输送机下游的第一输送机接收连续处理的香烟的输送机上 滚动站。
    • 28. 发明授权
    • Continuous process for the production of sucrose based polyether polyols
    • 用于生产蔗糖基聚醚多元醇的连续方法
    • US06380367B1
    • 2002-04-30
    • US09443273
    • 1999-11-18
    • Werner HinzEdward Michael Dexheimer
    • Werner HinzEdward Michael Dexheimer
    • C07H304
    • C08G65/2606B01J19/242B01J19/243B01J2219/0002B01J2219/00033B01J2219/00094C08G65/2696
    • A continuous process for the formation of sucrose based polyols is disclosed. The process comprises the steps of continuously forming an aqueous sucrose solution which is continuously combined with a catalyst and an alkylene oxide and flowed through a first spiral reaction tube. The alkylene oxide substantially completely reacting with the aqueous sucrose solution occurs to form a pre-polymer reaction product in the first spiral reaction tube. The pre-polymer reaction product is continuously flowed from the first reaction tube and unreacted water from the pre-polymer reaction product is removed. The water stripped pre-polymer reaction product is continuously flowed through a second spiral reaction tube and additional alkylene oxide is continuously added to the second spiral reaction tube. The alkylene oxide reacts with the pre-polymer reaction product in the second spiral reaction tube to form a polyol. The polyol is flowed through additional spiral reaction tubes with addition of alkylene oxide and optionally additional catalyst to each of the additional spiral reaction tubes, thus forming a polyol.
    • 公开了形成蔗糖基多元醇的连续方法。 该方法包括连续形成蔗糖水溶液的步骤,其与催化剂和烯化氧连续地结合并流过第一螺旋反应管。 与蔗糖水溶液基本完全反应的环氧烷发生在第一螺旋反应管中形成预聚物反应产物。 预聚物反应产物从第一反应管连续流出,并且除去预聚物反应产物的未反应水。 水分离的预聚物反应产物连续流过第二螺旋反应管,并将另外的环氧烷连续加入到第二螺旋反应管中。 烯化氧与第二螺旋反应管中的预聚物反应产物反应形成多元醇。 多元醇通过另外的螺旋反应管流动,加入环氧烷和任选的另外的催化剂到每个附加的螺旋反应管,从而形成多元醇。