会员体验
专利管家(专利管理)
工作空间(专利管理)
风险监控(情报监控)
数据分析(专利分析)
侵权分析(诉讼无效)
联系我们
交流群
官方交流:
QQ群: 891211   
微信请扫码    >>>
现在联系顾问~
热词
    • 6. 发明授权
    • Process for preparing high purity monocarboxylic perfluoropolyethers
    • 制备高纯度单羧基全氟聚醚的方法
    • US08008523B2
    • 2011-08-30
    • US12296263
    • 2007-04-03
    • Giuseppe MarchionniUgo De PattoPier Antonio Guarda
    • Giuseppe MarchionniUgo De PattoPier Antonio Guarda
    • C07C69/66
    • C08G65/007C08G65/32
    • A process for preparing monocarboxylic perfluoropolyethers of formula: A-O—(RF)z—(CFY)t—C(O)OX (I) wherein: X is H, C1-C10 alkyl, or an aryl group; Y=F, CF3; t=1, 2 or 3; A is a C1-C4 perfluoroalkyl end group; z=0 or 1; RF is a perfluorooxyalkylene chain; having a number average molecular weight in the range 180-8,000; comprising the following steps: a) one or more distillations of perfluoropolyethers (PFPE) of formula T-O—(RF)z-T′ (II) wherein: z and RF are as above defined; T, T′, equal to or different from each other, are selected from acyl fluoride or carbonyl-containing functional end groups and non functional end groups to obtain one PFPE fraction of formula (II) wherein the difference between the minimum and the maximum molecular weight of the components is lower than or equal to 600; b) partial fluorination of the fraction obtained in a); c) esterification c1) and/or hydrolysis c2) of the mixture obtained in b); d) distillation of the product obtained in c2) or in c1).
    • 一种制备式A-O-(RF)z-(CFY)t-C(O)OX(I)的单羧基全氟聚醚的方法,其中:X为H,C 1 -C 10烷基或芳基; Y = F,CF3; t = 1,2或3; A是C1-C4全氟烷基端基; z = 0或1; RF是全氟代亚烷基链; 数均分子量在180-8,000范围内; 包括以下步骤:a)式T-O-(RF)z-T'(II)的全氟聚醚(PFPE)的一个或多个蒸馏,其中:z和RF如上所定义; T,T'彼此相同或不同,选自酰基氟或含羰基的官能端基和非官能端基,以获得一种式(II)的PFPE级分,其中最小和最大分子之间的差异 部件重量低于或等于600; b)在a)中获得的级分的部分氟化; c)在b)中获得的混合物的酯化c1)和/或水解c2); d)蒸馏在c2)或c1)中得到的产物。
    • 10. 发明授权
    • Perfluoropolyethers
    • 全氟聚醚
    • US07388646B2
    • 2008-06-17
    • US10953768
    • 2004-09-30
    • Mattia BassiPier Antonio Guarda
    • Mattia BassiPier Antonio Guarda
    • G03B27/42
    • C08G65/32C08G65/007C08G65/30G02B1/04G03F7/2041C08L71/00
    • Use in optical systems as liquids to transmit light at wave lengths lower than 250 nm, in particular at 157 nm, of perfluoropolyethers having the following formula: X1—O(CF2O)n(CF2CF2O)m(CF2CF2CF2O)p(CF2CF2CF2CF2O)q—X2  (I) wherein: the repeating units —CF2O—, —CF2CF2O—, —CF2CF2CF2O—, —CF2CF2CF2CF2O— are statistically distributed along the chain; —X1 and —X2 are perfluoroalkyl chain end groups equal to or different from each other, having formula —(CF2)zCF3 wherein z is 0 or an integer from 1 to 3; n, m, p, q are 0 or integers comprised between 1 and 100, with the proviso that: at least one among n, m, p and q is different from zero; the ratio between the oxygen atoms and the carbon atoms (O/C) is higher than 0.33; wherein the chlorine atoms, determined by 19F-NMR are substantially absent.
    • 在光学系统中作为液体使用波长低于250nm,特别是157nm的具有下式的全氟聚醚的光:<?in-line-formula description =“In-line formula”end =“lead” (CF 2 O 2)n(CF 2)2 O 2(CF 2 O 2) (CF 2)2 CF 2 O 2)(C 1 -C 4) (CF 2 CF 2)2 CF 2 C 2 O 2)q - (CH 2) (I)<?in-line-formula description =“In-line Formulas”end =“tail”?>其中:重复单元-CF < -CF 2,CF 2,O,-CF 2,CF 2,CF 2, O-,-CF 2 CF 2 O 2是沿着链统计分布的; -X 1和-X 2是相同或不同的全氟烷基链端基,其具有式 - (CF 2 N 2)