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    • 22. 发明授权
    • Rod-shaped or tubular amorphous Zr alloy made by die casting and method
for manufacturing said amorphous Zr alloy
    • 通过压铸制成的棒状或管状无定形Zr合金以及制造所述无定形Zr合金的方法
    • US5803996A
    • 1998-09-08
    • US651668
    • 1996-05-21
    • Akihisa InoueTsuyoshi MasumotoTao ZhangYoshiyuki Shinohara
    • Akihisa InoueTsuyoshi MasumotoTao ZhangYoshiyuki Shinohara
    • C22C16/00B81C99/00C22C45/10C22F1/18
    • C22C45/10
    • An alloy material 4 received in a melting hearth 1 is melted by high-density energy supplied from a heat source 5. The molten alloy is transferred to a forced-cooled die 3 having a cavity 2 defining the profile of a product, and quenched to an amorphous state. The alloy has the composition represented by the general formula of Zr.sub.100-a-b-c A.sub.a B.sub.b C.sub.c (wherein the mark A represents one or more elements selected from Ti, Hf, Al and Ga, the mark B represents one or more elements selected from Fe, Co, Ni and Cu, the mark C represents one or more elements selected from Pd, Pt, Au and Ag, and the marks a-c represent the atomic ratios of respective elements A-C under the conditions of a=5-20, b=15-45, c.ltoreq.10 and a+b+c=30-70. The differential temperature region .DELTA.T (=T.sub.x -T.sub.g) in the supercooled liquid phase of the Zr alloy represented by the difference between the crystallization point T.sub.x and the glass transition point T.sub.g, is preferably 100 K or more. The obtained amorphous alloy has a rod-shaped or tubular profile having a large cross section and being excellent in plastic workability.
    • 容纳在熔化炉床1中的合金材料4由从热源5供给的高密度能量熔化。熔融合金被转移到具有限定产品轮廓的空腔2的强制冷却模具3中, 无定形状态。 该合金具有由通式Zr100-ab-cAaBbCc表示的组成(其中,标记A表示选自Ti,Hf,Al和Ga中的一种或多种元素,标记B表示选自Fe,Co, Ni和Cu,标记C表示选自Pd,Pt,Au和Ag中的一种或多种元素,标记ac表示在a = 5-20,b = 15-45的条件下各元素AC的原子比, c + = 10-70,a + b + c = 30-70,Zr合金过冷液相中的温差区域DELTA T(= Tx-Tg)由结晶点Tx和玻璃化转变温度 点Tg优选为100K以上,得到的非晶合金具有截面积大,塑性加工性优异的棒状或管状。
    • 25. 发明授权
    • High strength aluminum alloy
    • 高强度铝合金
    • US5431751A
    • 1995-07-11
    • US13980
    • 1993-02-05
    • Yukio OkochiKazuaki SatoTetsuya SuganumaAkira KatoTsuyoshi MasumotoAkihisa Inoue
    • Yukio OkochiKazuaki SatoTetsuya SuganumaAkira KatoTsuyoshi MasumotoAkihisa Inoue
    • C22C21/00C22C45/08C22C21/12
    • C22C45/08C22C21/00
    • A high strength aluminum alloy is expressed by a general formula, Al.sub.a X.sub.b Mm.sub.c, in which "X" stands for at least one element selected from the group consisting of Ti, V, Cr, Mn, Fe, Co, Ni, Cu and Zr, "Mm" stands for a misch metal, a content "a" of aluminum falls in a range of from 95.2 to 97.5 atomic %, and a content "b" of "X" and a content "c" of the "Mm" fall in a hatched area enclosed by points "A," "B," "C" and "D" of accompanying FIG. 1 on atomic % basis, and whose metallic phase includes microcrystalline phases or mixed phases containing amorphous phases in a volume content of less than 50% and the balance of microcrystalline phases. As a result, the amorphous phases or the microcrystalline phases are dispersed uniformly in its base microcrystalline phases appropriately, and at the same time the thus generating base microcrystalline phases are reinforced by forming solid solutions including the "Mm" and the transition metal element "X" as well. Hence, the high strength aluminum alloy comes to have a low specific gravity and a high strength which have not been available from conventional Al amorphous alloys.
    • 高强度铝合金由通式AlaXbMmc表示,其中“X”表示选自由Ti,V,Cr,Mn,Fe,Co,Ni,Cu和Zr组成的组中的至少一种元素,“ Mm“表示混合金属,铝的含量”a“在95.2〜97.5原子%的范围内,”M“的含量”b“,”M“的含量”c“落在 由图A的点“A”,“B”,“C”和“D”所包围的阴影区域。 1,其金属相包含微晶相或含有体积含量小于50%的非晶相的混合相和微晶相的余量。 结果,非晶相或微晶相适当地分散在其基底微晶相中,同时通过形成包含“Mm”和过渡金属元素“X”的固溶体来增强如此产生的基底微晶相 “以及。 因此,高强度铝合金具有低常规的Al非晶态合金所不具备的低比重和高强度。
    • 26. 发明授权
    • Hard wear-resistant film and method for production thereof
    • 硬质耐磨膜及其制造方法
    • US5366564A
    • 1994-11-22
    • US120735
    • 1993-09-14
    • Hiroshi YamagataAkihisa InoueTsuyoshi Masumoto
    • Hiroshi YamagataAkihisa InoueTsuyoshi Masumoto
    • C23C14/00C23C14/06C23C14/14C23C14/22C23C14/24C23C14/32C23C14/34C22C21/00
    • C23C14/0641C23C14/0021C23C14/14Y10S148/902Y10T428/12764
    • A hard wear-resistant film is formed on a substrate in an atmosphere of an inert gas by using a target of a composition of Al.sub.a Ti.sub.b (wherein "a" and "b" stand for atomic percentages respectively in the ranges of 62 at %.ltoreq.a.ltoreq.85 at % and 15 at %.ltoreq.b.ltoreq.38 at %, providing a+b=100 at %) or Al.sub.c Ta.sub.d (wherein "c" and "d" stand for atomic percentages respectively in the ranges of 60 at %.ltoreq.c.ltoreq.80 at % and 20 at %.ltoreq.d.ltoreq.40 at %, providing c+d=100 at %) and by a sputtering process or ion plating process while varying continuously or stepwise the feed rate of a nitrogen-containing reaction gas into a chamber. The film consequently formed has a composition and structure thereof continuously or stepwise varied from a substantially amorphous metal of a part being in contact with the substrate to an (Al, Ti)N or (Al, Ta)N crystalline ceramic phase with the nitrogen content continuously or stepwise increased in the direction of the surface of the film.
    • 通过使用AlaTib组合物的靶(其中“a”和“b”分别代表62原子%的范围的原子百分比)在惰性气体的气氛中在基底上形成耐硬的耐磨膜, = a%,15 at%,b = 38 at%,提供+ b = 100 at%)或AlcTad(其中“c”和“d”分别表示原子百分比 范围为60at%,%C%= 80 at%,20 at%,d = 40 at%,提供c + d = 100at%),并通过溅射工艺或离子电镀工艺改变 将含氮反应气体的进料速率连续或逐步地进入室。 由此形成的膜的组成和结构从与基板接触的部分的基本非晶态金属连续或逐步变化为具有氮含量的(Al,Ti)N或(Al,Ta)N结晶陶瓷相 在膜的表面方向上连续或逐步增加。
    • 27. 发明授权
    • High-strength magnesium-based alloy
    • 高强度镁基合金
    • US5340416A
    • 1994-08-23
    • US997780
    • 1992-12-28
    • Toshisuke ShibataAkihisa InoueTsuyoshi Masumoto
    • Toshisuke ShibataAkihisa InoueTsuyoshi Masumoto
    • C22C23/00C22C23/02
    • C22C23/02
    • A high-strength magnesium-based alloy possessing a microcrystalline composition represented by the general formula: Mg.sub.a Al.sub.b M.sub.c or Mg.sub.a,Al.sub.b M.sub.c X.sub.d (wherein M stands for at least one element selected from the group consisting of Ga, Sr, and Ba, X stands for at least one element selected from the group consisting of Zn, Ce, Zr, and Ca, and a, a', b, c, and d stand for atomic percents respectively in the ranges of 78.ltoreq.a.ltoreq.94, 75.ltoreq.a'.ltoreq.94, 2.ltoreq.b.ltoreq.12, 1.ltoreq.c.ltoreq.10, and 0.1.ltoreq.d.ltoreq.3). This alloy can be advantageously produced by rapidly solidifying the melt of an alloy of the composition shown above by the liquid quenching method. It is useful as high-strength materials and highly refractory materials owing to its high hardness, strength, and heat-resistance. It is also useful as materials with high specific strength because of light weight and high strength.
    • 具有由通式MgaAlbMc或Mga,AlbMcXd表示的微晶组合物的高强度镁基合金(其中M表示选自Ga,Sr和Ba中的至少一种元素,X表示至少 选自Zn,Ce,Zr和Ca中的一种元素,a,a',b,c和d分别代表78的范围内的原子百分比, / = a'
    • 28. 发明授权
    • Thin aluminum-based alloy foil and wire and a process for producing same
    • 薄铝基合金箔和线及其制造方法
    • US5306363A
    • 1994-04-26
    • US574654
    • 1990-08-20
    • Tsuyoshi MasumotoAkihisa InoueHitoshi YamaguchiNoriaki MatsumotoKazuhiko Kita
    • Tsuyoshi MasumotoAkihisa InoueHitoshi YamaguchiNoriaki MatsumotoKazuhiko Kita
    • B21C1/00C21D8/02C21D8/06C22C45/08C22F1/00
    • C22C45/08
    • An aluminum-based alloy foil or thin aluminum-based alloy wire is produced from an amorphous material made by a quenching and solidifying process and having a composition represented by the general formula:Al.sub.a M.sub.b X.sub.cwherein M is one or more elements selected from a group consisting of V, Cr, Mn, Fe, Co, Ni, Cu, Zr, Ti, Mo, W, Ca, Li, Mg and Si; X is one or more elements selected from a group consisting of Y, Nb, Hf, Ta, La, Ce, Sm, Nd and Mm (misch metal); and a, b, and c are atomic percentages falling within the following range:50.ltoreq.a.ltoreq.950.5.ltoreq.b.ltoreq.35 and0.5.ltoreq.c.ltoreq.25Such foil or wire has a smooth surface and a very small and uniform foil thickness or wire diameter, contains at least 50% by volume of an amorphous phase, and has excellent strength and resistance to corrosion. The foil thickness and wire diameter are reduced in a rolling or drawing process at an elevated temperature over a short time period.
    • 铝基合金箔或薄铝基合金线由淬火和固化方法制成的无定形材料制成,具有由以下通式表示的组成:AlaMbXc,其中M是选自以下的一种或多种元素: V,Cr,Mn,Fe,Co,Ni,Cu,Zr,Ti,Mo,W,Ca,Li,Mg和Si; X是选自Y,Nb,Hf,Ta,La,Ce,Sm,Nd和Mm(混合稀土金属)中的一种或多种元素; 和a,b和c是原子百分比在以下范围内:50 <= a <= 95 0.5 <= b <= 35和0.5 <= c <= 25这种箔或线具有光滑的表面和非常小的 箔厚度均匀,线径均匀,含有至少50体积%的非晶相,具有优异的强度和耐腐蚀性。 箔片厚度和线径在轧制或拉伸过程中在较短的时间内在升高的温度下降低。