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1. 发明授权

US5423923A Hard film of amorphous Ti-Si alloy having fine tin particles 失效
标题翻译：具有细锡粒子的非晶Ti-Si合金硬膜
公开(公告)号：US5423923A
公开(公告)日：1995-06-13
申请号：US315620
申请日：1994-09-30
申请人： Hiroshi Yamagata , Tadashi Yamaguchi , Hideki Takeda , Nobuyuki Nishiyama , Katsutoshi Nozaki , Akihisa Inoue , Tsuyoshi Masumoto
发明人： Hiroshi Yamagata , Tadashi Yamaguchi , Hideki Takeda , Nobuyuki Nishiyama , Katsutoshi Nozaki , Akihisa Inoue , Tsuyoshi Masumoto
IPC分类号： C23C14/00 , C23C14/06 , C23C14/22 , C23C14/24 , C23C14/32 , C23C14/34 , C22C14/00 , C22C1/00 , C22C29/00
CPC分类号： C23C14/0021 , C23C14/0641 , C23C14/0688 , Y10T428/12486 , Y10T428/12576
摘要： Deposition of a hard film of Ti-Si-N composite material on a substrate is carried out by using a source of evaporation possessing a composition of Ti.sub.a Si.sub.b (wherein "a" and "b" stand for atomic percentages respectively falling in the ranges of 75 at % .ltoreq.a.ltoreq.85 at % and 15 at %.ltoreq.b.ltoreq.25 at %, providing a+b=100 at %). Deposition is effected by a sputtering process or ion plating process in an atmosphere of an inert gas containing a nitrogen-containing reaction gas while controlling the feed rate of the reaction gas into a chamber in such a manner that the partial pressure of nitrogen is kept constant or varied continuously or stepwise. By this method there can be obtained a film having fine TiN crystalline particles uniformly dispersed in the matrix phase of Ti-Si amorphous metal or a film of functionally gradient structure in which the ratio of fine TiN crystalline particles dispersed in the matrix phase increases continuously or stepwise in the direction of thickness of the film.
摘要翻译：通过使用具有TiaSib组成的蒸发源（其中“a”和“b”表示分别落在75的范围内的原子百分比），将Ti-Si-N复合材料的硬膜沉积在基底上 at％

2. 发明授权

US5366564A Hard wear-resistant film and method for production thereof 失效
标题翻译：硬质耐磨膜及其制造方法
公开(公告)号：US5366564A
公开(公告)日：1994-11-22
申请号：US120735
申请日：1993-09-14
申请人： Hiroshi Yamagata , Akihisa Inoue , Tsuyoshi Masumoto
发明人： Hiroshi Yamagata , Akihisa Inoue , Tsuyoshi Masumoto
IPC分类号： C23C14/00 , C23C14/06 , C23C14/14 , C23C14/22 , C23C14/24 , C23C14/32 , C23C14/34 , C22C21/00
CPC分类号： C23C14/0641 , C23C14/0021 , C23C14/14 , Y10S148/902 , Y10T428/12764
摘要： A hard wear-resistant film is formed on a substrate in an atmosphere of an inert gas by using a target of a composition of Al.sub.a Ti.sub.b (wherein "a" and "b" stand for atomic percentages respectively in the ranges of 62 at %.ltoreq.a.ltoreq.85 at % and 15 at %.ltoreq.b.ltoreq.38 at %, providing a+b=100 at %) or Al.sub.c Ta.sub.d (wherein "c" and "d" stand for atomic percentages respectively in the ranges of 60 at %.ltoreq.c.ltoreq.80 at % and 20 at %.ltoreq.d.ltoreq.40 at %, providing c+d=100 at %) and by a sputtering process or ion plating process while varying continuously or stepwise the feed rate of a nitrogen-containing reaction gas into a chamber. The film consequently formed has a composition and structure thereof continuously or stepwise varied from a substantially amorphous metal of a part being in contact with the substrate to an (Al, Ti)N or (Al, Ta)N crystalline ceramic phase with the nitrogen content continuously or stepwise increased in the direction of the surface of the film.
摘要翻译：通过使用AlaTib组合物的靶（其中“a”和“b”分别代表62原子％的范围的原子百分比）在惰性气体的气氛中在基底上形成耐硬的耐磨膜， = a％，15 at％，b = 38 at％，提供+ b = 100 at％）或AlcTad（其中“c”和“d”分别表示原子百分比范围为60at％，％C％= 80 at％，20 at％，d = 40 at％，提供c + d = 100at％），并通过溅射工艺或离子电镀工艺改变将含氮反应气体的进料速率连续或逐步地进入室。由此形成的膜的组成和结构从与基板接触的部分的基本非晶态金属连续或逐步变化为具有氮含量的（Al，Ti）N或（Al，Ta）N结晶陶瓷相在膜的表面方向上连续或逐步增加。

3. 发明授权

US5648174A Highly hard thin film and method for production thereof 失效
标题翻译：高硬度薄膜及其制造方法
公开(公告)号：US5648174A
公开(公告)日：1997-07-15
申请号：US420606
申请日：1995-04-12
申请人： Hiroshi Yamagata , Akihisa Inoue , Tsuyoshi Masumoto , Junichi Nagahora
发明人： Hiroshi Yamagata , Akihisa Inoue , Tsuyoshi Masumoto , Junichi Nagahora
IPC分类号： C23C14/00 , C23C14/06 , C23C14/14 , C23C14/58
CPC分类号： C23C14/5806 , C23C14/0042 , C23C14/06 , C23C14/0688 , C23C14/14 , C23C14/58 , C23C14/584 , Y10T428/24942 , Y10T428/25 , Y10T428/31678
摘要： A hard thin film having fine crystalline ceramic particles dispersed in a metallic matrix phase is disclosed. The production of the film is effected by first depositing a substantially amorphous film on a substrate and then heat-treating the deposited film. Deposition of the film on the substrate is carried out by using a source of evaporation having a composition represented by the general formula: Al.sub.a M.sub.b, wherein M stands for at least one element selected from the group consisting of Ti, Ta, V, Cr, Zr, Nb, Mo, Hf, W, Mn, Fe, Co, Ni, and Cu and "a" and "b" respectively stand for atomic % in the ranges of 60.ltoreq.a.ltoreq.98.5 and 1.5.ltoreq.b.ltoreq.40, providing a+b=100. Deposition is effected by a physical vapor deposition process in an atmosphere of an inert gas containing a reaction gas while controlling the feed rate of the reaction gas into a chamber in such a manner that the partial pressure of the react/on gas is kept constant or varied continuously or stepwise. By this method, there can be obtained a hard composite film having fine ceramic particles dispersed in a metallic matrix phase or a dense, hard, and composite film having a composition and structure obliquely varied from a substantially crystalline metallic phase to a crystalline ceramic phase in the direction of thickness of the film.
摘要翻译：公开了一种具有分散在金属基体相中的细晶体陶瓷颗粒的硬质薄膜。通过首先在基板上沉积基本上非晶的膜然后对沉积的膜进行热处理来实现膜的制备。通过使用具有由通式AlaMb表示的组成的蒸发源进行膜的沉积，其中M表示选自Ti，Ta，V，Cr，Zr中的至少一种元素，Nb，Mo，Hf，W，Mn，Fe，Co，Ni和Cu，“a”和“b”分别表示60≤a≤98.5的范围内的原子％ b = 40，提供+ b = 100。通过在包含反应气体的惰性气体的气氛中的物理气相沉积工艺进行沉积，同时将反应气体的进料速率控制在室内，使得反应/导入气体的分压保持恒定，或连续或逐步变化。通过该方法，可以获得具有分散在金属基体相中的细微陶瓷颗粒的硬质复合膜或致密的，硬的和复合的膜，其具有从基本上结晶的金属相到结晶陶瓷相倾斜变化的组成和结构膜的厚度方向。

4. 发明授权

US5405458A Method of producing hard film of Ti-Si-N composite material 失效
标题翻译：生产Ti-Si-N复合材料硬膜的方法
公开(公告)号：US5405458A
公开(公告)日：1995-04-11
申请号：US120523
申请日：1993-09-14
申请人： Hiroshi Yamagata , Tadashi Yamaguchi , Hideki Takeda , Nobuyuki Nishiyama , Katsutoshi Nozaki , Akihisa Inoue , Tsuyoshi Masumoto
发明人： Hiroshi Yamagata , Tadashi Yamaguchi , Hideki Takeda , Nobuyuki Nishiyama , Katsutoshi Nozaki , Akihisa Inoue , Tsuyoshi Masumoto
IPC分类号： C23C14/00 , C23C14/06 , C23C14/22 , C23C14/24 , C23C14/32 , C23C14/34 , C22C14/00 , C22C1/00 , C22C29/00
CPC分类号： C23C14/0021 , C23C14/0641 , C23C14/0688 , Y10T428/12486 , Y10T428/12576
摘要： Deposition of a hard film of Ti--Si--N composite material on a substrate is carried out by using a source of evaporation possessing a composition of Ti.sub.a Si.sub.b (wherein "a" and "b" stand for atomic percentages respectively falling in the ranges of 75 at %.ltoreq.a.ltoreq.85 at % and 15 at %.ltoreq.b.ltoreq.25 at %, providing a+b=100 at %). Deposition is effected by a sputtering process or ion plating process in an atmosphere of an inert gas containing a nitrogen-containing reaction gas while controlling the feed rate of the reaction gas into a chamber in such a manner that the partial pressure of nitrogen is kept constant or varied continuously or stepwise. By this method, there can be obtained a film having fine TiN crystalline particles uniformly dispersed in the matrix phase of Ti--Si amorphous metal or a film of functionally gradient structure in which the ratio of fine TiN crystalline particles dispersed in the matrix phase increases continuously or stepwise in the direction of thickness of the film.
摘要翻译：通过使用具有TiaSib组成的蒸发源（其中“a”和“b”表示分别落在75的范围内的原子百分比），将Ti-Si-N复合材料的硬膜沉积在基板上 at％

5. 发明授权

US06017403A High strength and high rigidity aluminum-based alloy 失效
标题翻译：高强度高刚性铝基合金
公开(公告)号：US06017403A
公开(公告)日：2000-01-25
申请号：US601949
申请日：1996-02-15
申请人： Tsuyoshi Masumoto , Akihisa Inoue , Yuma Horio
发明人： Tsuyoshi Masumoto , Akihisa Inoue , Yuma Horio
IPC分类号： C22C21/00
CPC分类号： C22C21/00
摘要： An aluminum-based alloy having the general formula Al.sub.x L.sub.y M.sub.z (wherein L is Mn or Cr; M is Ni, Co, and/or Cu; and x, y, and z, representing a composition ratio in atomic percentages, satisfy the relationships x+y+z=100, 75.ltoreq.x.ltoreq.95, 2.ltoreq.y.ltoreq.15, and 0.5.ltoreq.z.ltoreq.10) having a metallographic structure comprising a quasi-crystalline phase possesses high strength and high rigidity. In order to enhance the ductility and toughness of the aluminum-based alloy, the atomic percentage of M may be further limited to 0.5.ltoreq.z.ltoreq.4, and more preferably to 0.5.ltoreq.z.ltoreq.3. The aluminum-based alloy is useful as a structural material for aircraft, vehicles and ships, and for engine parts; as material for sashes, roofing materials, and exterior materials for use in construction; or as materials for use in marine equipment, nuclear reactors, and the like.
摘要翻译：具有通式AlxLyMz（其中L是Mn或Cr; M是Ni，Co和/或Cu;和表示原子百分比的组成比的x，y和z）的铝基合金满足关系x + 具有包含准结晶相的金相组织的y + z = 100,75，或者= x，y = x，z = 100，75

6. 发明授权

US6004407A Hard magnetic materials and method of producing the same 失效
标题翻译：硬磁材料及其制造方法
公开(公告)号：US6004407A
公开(公告)日：1999-12-21
申请号：US717468
申请日：1996-09-20
申请人： Akinobu Kojima , Akihiro Makino , Akihisa Inoue , Tsuyoshi Masumoto
发明人： Akinobu Kojima , Akihiro Makino , Akihisa Inoue , Tsuyoshi Masumoto
IPC分类号： H01F1/057
CPC分类号： B82Y25/00 , H01F1/0579
摘要： Hard magnetic materials of the present invention contain at least one element of Fe, Co and Ni as a main component, at least one element M of Zr, Nb, Ta and Hf, at least one rare earth element R and B. The texture of the materials has at least 70% of fine crystalline phase having an average grain size of 100 nm or less, and the residue having an amorphous phase, the fine crystalline phase mainly composed of bcc-Fe or bcc-Fe compound, Fe--B compound and/or R.sub.2 Fe.sub.14 B.sub.1.
摘要翻译：本发明的硬磁性材料含有Fe，Co和Ni作为主要成分的至少一种元素，Zr，Nb，Ta和Hf的至少一种元素M，至少一种稀土元素R和B。该材料具有至少70％的平均粒径为100nm以下的细晶相，残留物为非晶相，主要由bcc-Fe或bcc-Fe化合物构成的微晶相，Fe-B化合物和/或R2Fe14B1。

7. 发明授权

US5741373A Fe based soft magnetic alloy, magnetic materials containing same, and magnetic apparatus using the magnetic materials 失效
标题翻译： Fe基软磁合金，含有磁性材料的磁性材料，以及使用磁性材料的磁性装置
公开(公告)号：US5741373A
公开(公告)日：1998-04-21
申请号：US422720
申请日：1995-04-14
申请人： Kiyonori Suzuki , Akihiro Makino , Tsuyoshi Masumoto , Akihisa Inoue , Noriyuki Kataoka
发明人： Kiyonori Suzuki , Akihiro Makino , Tsuyoshi Masumoto , Akihisa Inoue , Noriyuki Kataoka
IPC分类号： G11B5/127 , G11B5/147 , H01F1/153 , H01F10/13 , H01F41/02 , H01F1/147
CPC分类号： H01F41/0226 , G11B5/127 , G11B5/147 , H01F1/15308 , H01F1/15341 , H01F1/15358 , H01F10/131 , H01F10/136
摘要： An Fe-based soft magnetic alloy having a high saturated magnetic flux density and having a composition represented by formula (I) below: (Fe.sub.1-a Q.sub.a).sub.b B.sub.x T.sub.y T'.sub.z (I) wherein Q represents at least one element selected from the group consisting of Co and Ni; T represents at least one element selected from the group consisting of Ti, Zr, Hf, V, Nb, Ta, Mo and W, with Zr and/or Hf being always included; T' represents at least one element selected from the group consisting of Cu, Ag, Au, Ni, Pd and Pt; a, b, x, y and z are real numbers satisfying relationships below: 0.ltoreq.a.ltoreq.0.05, 0.ltoreq.b.ltoreq.93 atomic %, 0.5.ltoreq.x.ltoreq.16 atomic %, 4.ltoreq.y.ltoreq.10 atomic %, 0.ltoreq.z.ltoreq.4.5 atomic % provided that when 0
摘要翻译：具有高饱和磁通密度且具有由下式（I）表示的组成的Fe基软磁合金：（Fe1-aQa）bBxTyT'z（I）其中Q表示选自以下的至少一种元素： Co和Ni; T表示选自Ti，Zr，Hf，V，Nb，Ta，Mo和W中的至少一种元素，其中始终包括Zr和/或Hf; T'表示选自Cu，Ag，Au，Ni，Pd和Pt中的至少一种元素; a，b，x，y和z是满足以下关系的实数：0

8. 发明授权

US5619174A Noise filter comprising a soft magnetic alloy ribbon core 失效
标题翻译：噪声滤波器包括软磁合金带芯
公开(公告)号：US5619174A
公开(公告)日：1997-04-08
申请号：US283133
申请日：1994-07-29
申请人： Youichi Kimura , Akihiro Makino , Tsuyoshi Masumoto , Akihisa Inoue
发明人： Youichi Kimura , Akihiro Makino , Tsuyoshi Masumoto , Akihisa Inoue
IPC分类号： C22C38/00 , C22C38/14 , H01F1/14 , H01F17/06 , H01F30/16 , H01F41/02 , H03H7/09 , H01F27/02
CPC分类号： H01F41/0226 , H01F17/062 , H01F30/16
摘要： A noise filter includes an annular magnetic core made of a soft magnetic alloy ribbon mainly made of Fe and containing B and at least one element selected from a group consisting of Ti, Zr, Hf, Nb, Ta, Mo and W, at least 50% of the soft magnetic alloy structure being composed of body-centered cubic structured fine grains having an average grain size of 30 nm or below, a casing for accommodating the magnetic core and having an insulating plate, a pair of coils separated from each other by the insulating plate, and an electronic circuit for connecting a core element made up of the magnetic core, the casing and the coils.
摘要翻译：噪声滤波器包括由主要由Fe构成并含有B的软磁性合金带和从由Ti，Zr，Hf，Nb，Ta，Mo和W组成的组中选择的至少一种元素制成的环形磁芯，至少50 软磁合金结构的％由平均粒径为30nm以下的体心立方结构细晶粒组成，用于容纳磁芯并具有绝缘板的壳体，通过绝缘板和用于连接由磁芯，壳体和线圈构成的芯体元件的电子电路。

9. 发明授权

US5474624A Method of manufacturing Fe-base soft magnetic alloy 失效
标题翻译：制备铁基软磁合金的方法
公开(公告)号：US5474624A
公开(公告)日：1995-12-12
申请号：US121715
申请日：1993-09-14
申请人： Kiyonori Suzuki , Akihiro Makino , Tsuyoshi Masumoto , Akihisa Inoue
发明人： Kiyonori Suzuki , Akihiro Makino , Tsuyoshi Masumoto , Akihisa Inoue
IPC分类号： C22C33/04 , C21D6/00 , C22C38/00 , C22C45/00 , C22C45/02 , H01F1/153 , H01F1/147
CPC分类号： C22C45/00 , H01F1/15308 , H01F1/15341
摘要： The present invention relates to a method of stably manufacturing a Fe-base soft magnetic alloy having steps of subjecting an amorphous alloy mainly composed of Fe to heat treatment in which the amorphous alloy is heated to 400.degree. to 750.degree. C. at a heating rate of 1.0.degree. C./minute or higher so that at least 50% or more of the structure of the amorphous alloy is made of fine crystalline grains formed into a body-centered cubic structure and having an average grain size of crystal of 30 nm or smaller as to have a high magnetic permeability and saturation magnetic flux density.
摘要翻译：本发明涉及一种稳定制造Fe基软磁性合金的方法，其特征在于，将以Fe为主成分的非晶态合金进行加热处理的加热处理的加热速度为400〜750℃ 为1.0℃/分钟以上，使非晶合金的结构的至少50％以上由细心晶体形成为体心立方结构，平均结晶粒径为30nm，具有较高的磁导率和饱和磁通密度。

10. 发明授权

US5423969A Sacrificial electrode material for corrosion prevention 失效
标题翻译：用于防腐的牺牲电极材料
公开(公告)号：US5423969A
公开(公告)日：1995-06-13
申请号：US217009
申请日：1994-03-23
申请人： Tsuyoshi Masumoto , Akihisa Inoue , Takashi Sakuma , Toshisuke Shibata
发明人： Tsuyoshi Masumoto , Akihisa Inoue , Takashi Sakuma , Toshisuke Shibata
IPC分类号： C22C23/00 , C22C45/00 , C23F13/00 , C23F13/14 , C25B11/04
CPC分类号： C23F13/14
摘要： The present invention provides a sacrificial electrode material which consists of a single phase amorphous structure or a structure consisting of an amorphous phase and a crystalline solid solution phase and provides electrochemical corrosion protection to metallic articles exposed to an aqueous electrolytic solution. The electrode material is prepared by rapidly quenching a magnesium-based alloy material from the liquid phase or vapor phase thereof, the magnesium-based alloy material consisting the general formula: Mg.sub.bal X1.sub.a X2.sub.b or Mg.sub.bal X1.sub.a, wherein X1 is at least one element selected from the group consisting of Al, Zn, Ga, Ca and In; X2 is at least one element selected from the group consisting of Mm (misch metal), Y and rare earth metal elements; a and b are, in atomic percentages, 5.0.ltoreq.a.ltoreq.35.0 and 3.0.ltoreq.b.ltoreq.25.0, respectively. The magnesium-based alloy material may further contain one or more transition metal elements in their total contents not exceeding 1.0 atomic %.
摘要翻译：本发明提供一种牺牲电极材料，其由单相无定形结构或由非晶相和结晶固溶体相组成的结构组成，并且对暴露于水性电解液的金属制品提供电化学腐蚀保护。通过从其液相或气相快速淬火镁基合金材料制备电极材料，镁基合金材料由以下通式组成：MgbalX1aX2b或MgbalX1a，其中X1是选自以下的至少一种元素：的Al，Zn，Ga，Ca和In; X2是选自由Mm（混合稀土金属），Y和稀土金属元素组成的组中的至少一种元素; a和b分别为原子百分比为5.0

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