专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

21. 发明授权

US06169199A Method for separating 6-aminocaproic acid nitrile from mixtures containing 6-aminocaproic acid nitrile and an imine 失效
标题翻译：从含有6-氨基己酸腈和亚胺的混合物中分离6-氨基己酸腈的方法
公开(公告)号：US06169199A
公开(公告)日：2001-01-02
申请号：US09367068
申请日：1999-08-09
申请人： Alwin Rehfinger , Hermann Luyken
发明人： Alwin Rehfinger , Hermann Luyken
IPC分类号： C07C25500
CPC分类号： C07C253/34
摘要： A process for distillative removal of 6-aminocapronitrile from mixtures (I) comprising 6-aminocapronitrile and an imine (II) comprises performing the distillation in a distillation column using an average mean residence time for the distillation mixture of at least 5 minutes on at least one level of the distillation column.
摘要翻译：包含6-氨基己腈和亚胺（II）的混合物（I）从6-氨基己腈中蒸馏除去6-氨基己腈的方法包括使用至少5分钟至少5分钟的蒸馏混合物的平均停留时间在蒸馏塔中进行蒸馏一级蒸馏塔。

22. 发明授权

US5756845A Preparation of 3-aminomethyl-3,5,5-trimethylcyclohexylamine 失效
标题翻译： 3-氨基甲基-3,5,5-三甲基环己胺的制备
公开(公告)号：US5756845A
公开(公告)日：1998-05-26
申请号：US608485
申请日：1996-02-28
申请人： Guido Voit , Tom Witzel , Boris Breitscheidel , Wolfgang Harder , Hermann Luyken , Axel Paul , Karl-Heinz Ross , Peter Wahl
发明人： Guido Voit , Tom Witzel , Boris Breitscheidel , Wolfgang Harder , Hermann Luyken , Axel Paul , Karl-Heinz Ross , Peter Wahl
IPC分类号： B01J23/46 , B01J23/75 , B01J23/755 , C07B61/00 , C07C209/48 , C07C211/36
CPC分类号： C07C209/48 , C07C2101/14
摘要： A process for the preparation of 3-aminomethyl-3,5,5-trimethylcyclohexylamine from 3-cyano-3,5,5-trimethylcyclohexanone which requires three spatially separated reaction spaces, in order to carry out the following three steps in sequence: a) reacting the 3-cyano-3,5,5-trimethylcyclohexanone with excess ammonia on acidic metal-oxide catalysts in a first reaction space at from 20.degree. to 150.degree. C. and from 50 to 300 bar, b) hydrogenating the resultant reaction products using hydrogen in a second reaction space in the presence of excess ammonia and preferably liquid ammonia on hydrogenation catalysts, optionally using basic components or on neutral or basic supports at from 50.degree. to 100.degree. C. and at from 50 to 300 bar, and c) hydrogenating the resultant reaction products in the presence of hydrogen and also ammonia in a third reaction space on hydrogenation catalysts, optionally using basic components or on neutral or basic supports at from 110.degree. to 160.degree. C. and at from 150 to 300 bar.These three steps in sequence provide a substantially complete reaction of the original 3-cyano-3,3,5-trimethylcyclohexanone reactant with a yield of 96% of the desired diamino product in which the cis-content of the diamine is 70%.
摘要翻译：从3-氰基-3,5,5-三甲基环己酮制备3-氨基甲基-3,5,5-三甲基环己胺的方法，其需要三个空间分离的反应空间，以便按顺序进行以下三个步骤：a ）在20至150℃和50至300巴的第一反应空间中使3-氰基-3,5,5-三甲基环己酮与过量的氨在酸性金属氧化物催化剂上反应，b）将所得反应物氢化在氢化催化剂存在下，在过量氨和优选液氨存在下在第二反应空间中使用氢的产物，任选使用碱性组分或在中性或碱性载体上在50至100℃和50至300巴条件下，以及 c）在氢化催化剂的第三反应空间中，在氢气和氨的存在下氢化所得反应产物，任选使用碱性组分或在中性或碱性载体上在110至160℃和150至300b ar。这三个步骤依次提供原始3-氰基-3,3,5-三甲基环己酮反应物的基本上完全的反应物，其中二胺的顺式含量为70％的所需二氨基产物的产率为96％。

23. 发明授权

US6022999A Preparation of 3-aminomethyl-3,5,5-trimethylcyclohexylamine having a cis/trans isomer ratio of at least 70:30 有权
标题翻译：具有顺式/反式异构体比例为70:30以上的3-氨基甲基-3,5,5-三甲基环己胺的制备
公开(公告)号：US6022999A
公开(公告)日：2000-02-08
申请号：US207623
申请日：1998-12-09
申请人： Guido Voit , Tom Witzel , Boris Breitscheidel , Hermann Luyken , Karl-Heinz Ross , Peter Wahl
发明人： Guido Voit , Tom Witzel , Boris Breitscheidel , Hermann Luyken , Karl-Heinz Ross , Peter Wahl
IPC分类号： C07C209/26 , C07C209/48 , C07C209/52 , C07C211/36 , C07C209/22
CPC分类号： C07C209/26 , C07C209/48 , C07C209/52
摘要： A process for the preparation of 3-aminomethyl-3,5,5-trimethylcyclohexylamine having a cis/trans isomer ratio of at least 70:30 bya) imination of 3-cyano-3,5,5-trimethylcyclohexanone with ammonia in the presence of an imination catalyst at temperatures of from 20.degree. to 150.degree. C. and pressures of from 1.5 to 30 MPa to form 3-cyano-3,5,5-trimethylcyclo-hexanone imine followed byb) hydrogenation of the 3-cyano-3,5,5-trimethylcyclohexanone imine in the presence of ammonia over a catalyst containing copper and/or a Group VIII metal at a temperature of from 80.degree. to 160.degree. C. and under a pressure of from 5 to 30 MPa,wherein the catalytic hydrogenation of the 3-cyano-3,5,5-trimethylcyclohexanone imine is carried out in the presence of an acid used in an amount such as to give an acid number of from 0.1 to 2, based on 3-cyano-3,5,5-trimethylcyclohexanone used.
摘要翻译：一种制备顺式/反式异构体比例至少为70:30的3-氨基甲基-3,5,5-三甲基环己胺的制备方法，通过以下步骤：a）将3-氰基-3,5,5-三甲基环己酮与氨在在20至150℃的温度和1.5至30MPa的压力下存在仿制催化剂以形成3-氰基-3,5,5-三甲基环己酮亚胺，随后b）氢化3-氰基 -3,5,5-三甲基环己酮亚胺在含有铜和/或Ⅷ族金属的催化剂的存在下在80至160℃的温度和5至30MPa的压力下进行，其中 3-氰基-3,5,5-三甲基环己酮亚胺的催化氢化在酸的存在下进行，所用酸的用量使得酸值为0.1-2，基于3-氰基-3 ，使用5,5-三甲基环己酮。

24. 发明授权

US07566800B2 Homogeneous isomerization of cis-2-pentene nitrile to form 3-pentene nitrile 失效
标题翻译：顺式-2-戊烯腈的均相异构化形成3-戊烯腈
公开(公告)号：US07566800B2
公开(公告)日：2009-07-28
申请号：US10586481
申请日：2005-01-27
申请人： Jens Scheidel , Christian Miller , Robert Baumann , Tim Jungkamp , Michael Bartsch , Gerd Haderlein , Hermann Luyken , Wolfgang Siegel , Peter Bassler
发明人： Jens Scheidel , Christian Miller , Robert Baumann , Tim Jungkamp , Michael Bartsch , Gerd Haderlein , Hermann Luyken , Wolfgang Siegel , Peter Bassler
IPC分类号： C07D291/00
CPC分类号： C07C253/30 , Y02P20/127 , C07C255/07
摘要： The invention relates to a method for isomerization of pentene nitrile in an educt flow, wherein isomerization is performed on a homogeneously dissolved catalyst.
摘要翻译：本发明涉及一种在流出物流中异戊烯腈的方法，其中异构化在均匀溶解的催化剂上进行。

25. 发明申请

US20060201798A1 Method for purifying hydrocyanic acid 失效
标题翻译：氢氰酸净化方法
公开(公告)号：US20060201798A1
公开(公告)日：2006-09-14
申请号：US10553537
申请日：2004-04-15
申请人： Michael Bartsch , Robert Baumann , Gerd Haderlein , Miguel Flores , Tim Jungkamp , Hermann Luyken , Jens Scheidel , Wolfgang Siegel , Dagmar Kunsmann-Keitel , Peter Bassler
发明人： Michael Bartsch , Robert Baumann , Gerd Haderlein , Miguel Flores , Tim Jungkamp , Hermann Luyken , Jens Scheidel , Wolfgang Siegel , Dagmar Kunsmann-Keitel , Peter Bassler
IPC分类号： C01C3/04
CPC分类号： C07C253/10 , B01J2219/0011 , C01C3/0295 , C07C255/04
摘要： A process for dewatering hydrocyanic acid by distillation, which comprises distilling crude hydrocyanic acid containing from 50 to 99.9% by weight of HCN, from 0.1 to 40% by weight of water, from 0 to 15% by weight of carbon oxides and optionally from 0.01 to 1% by weight of an involatile stablilizer, at a pressure of from 1 bar to 2.5 bar, a bottom temperature of from 100° C. to 130° C. and a top temperature of from 25° C. to 54° C., in the absence of a volatile stabilizer, in a distillation column to obtain a top draw stream containing purified, anhydrous hydrocyanic acid and carbon oxides and a bottom draw stream comprising water and, where appropriate, the involatile stabilizer.
摘要翻译：一种通过蒸馏使氢氰酸脱水的方法，该方法包括将含有50-99.9重量％HCN的粗制氢氰酸，0.1-40重量％的水，0-15重量％的碳氧化物和任选的0.01 至1重量％的非挥发性固化剂，压力为1巴至2.5巴，底部温度为100℃至130℃，顶部温度为25℃至54℃。在不存在挥发性稳定剂的情况下，在蒸馏塔中获得含有纯化的无水氢氰酸和碳氧化物的顶部牵引流和包含水的底部牵引流，以及适当时的非挥发性稳定剂。

26. 发明授权

US06828457B2 Method for reducing the content of an unsaturated amine in a mixture containing an amine and a nitrile 失效
标题翻译：减少含有胺和腈的混合物中不饱和胺含量的方法
公开(公告)号：US06828457B2
公开(公告)日：2004-12-07
申请号：US10432385
申请日：2003-05-21
申请人： Frank Ohlbach , Christoph Benisch , Hermann Luyken , Andreas Ansmann , Rolf-Hartmuth Fischer , Johann-Peter Melder , Peter Bassler , Stefan Maixner
发明人： Frank Ohlbach , Christoph Benisch , Hermann Luyken , Andreas Ansmann , Rolf-Hartmuth Fischer , Johann-Peter Melder , Peter Bassler , Stefan Maixner
IPC分类号： C07C25334
CPC分类号： C07C209/84 , C07C253/34
摘要： A process is provided for reducing the content of a monounsaturated aliphatic amine (III) in a mixture (IV) containing an aminonitrile (I) or a diamine (II), or mixtures thereof, and the amine (III), wherein a) the mixture (IV) is reacted with an anionic nucleophile (V), which contains a nucleophilic atom selected from the group comprising oxygen, nitrogen and sulfur, which is capable of taking up an H+ ion to form an acid with a pKa ranging from 7 to 11, measured in water at 25° C., and which has a relative nucleophilicity, measured in methyl perchlorate/methanol at 25° C., ranging from 3.4 to 4.7 when oxygen is the nucleophilic atom, ranging from 4.5 to 5.8 when nitrogen is the nucleophilic atom, and ranging from 5.5 to 6.8 when sulfur is the nucleophilic atom, in an amount ranging from 0.01 to 10 mol per mole of amine (III) in the mixture (IV), to give a mixture (VI), and b) the aminonitrile (I) or the diamine (II), or mixtures thereof, are distilled from the mixture (VI) at a temperature ranging from 50 to 170° C. and a pressure ranging from 0.5 to 100 kPa.
摘要翻译：提供了一种降低含有氨基腈（I）或二胺（II）或其混合物的混合物（IV）中的单不饱和脂族胺（III）和胺（III）的含量的方法，其中a）混合物（IV）与阴离子亲核试剂（V）反应，所述阴离子亲核试剂（V）含有选自氧，氮和硫的亲核原子，其能够吸收H +离子以形成pKa范围从 7至11，在25℃的水中测量，并且当氧是亲核原子时，在25℃的甲基高氯酸甲酯/甲醇中测量的范围为3.4至4.7，当氮气为4.5至5.8时，其具有相对的亲核性是亲核原子，当硫是亲核原子时，其摩尔数为5.5至6.8，其量为每摩尔混合物（IV）中的胺（III）为0.01至10摩尔，得到混合物（Ⅵ），和b）氨基腈（I）或二胺（II）或其混合物在温度下从混合物（VI）中蒸馏出 e范围为50至170℃，压力范围为0.5至100kPa。

27. 发明授权

US07935229B2 Extraction of nickel (0) complexes from nitrile mixtures with reduced rag formation 有权
标题翻译：从腈混合物中提取镍（0）配合物，并减少破布形成
公开(公告)号：US07935229B2
公开(公告)日：2011-05-03
申请号：US11577231
申请日：2005-10-12
申请人： Petra Deckert , Peter Bassler , Michael Bartsch , Gerd Haderlein , Hermann Luyken , Jens Scheidel , Peter Pfab , Tobias Aechtner , Wolfgang Siegel
发明人： Petra Deckert , Peter Bassler , Michael Bartsch , Gerd Haderlein , Hermann Luyken , Jens Scheidel , Peter Pfab , Tobias Aechtner , Wolfgang Siegel
IPC分类号： B01D3/34 , B01D11/04 , B01J31/40 , B01J38/56 , C07C253/32
CPC分类号： B01J31/4053 , B01D11/0434 , B01J31/1845 , B01J31/185 , B01J31/24 , B01J31/403 , B01J2231/323 , B01J2531/847 , C07C253/10 , C07C253/32 , Y02P20/584 , C07C255/04
摘要： A process for extractively removing homogeneously dissolved catalysts from a reaction effluent of a hydrocyanation of unsaturated mononitriles to dinitriles with a hydrocarbon H, including performing the steps of a) concentrating the reaction effluent before step b) by distillation at pressures of from 0.1 to 5000 mbar and temperatures of from 10 to 150° C., b) adding a hydrocarbon H to the concentrated reaction effluent to obtain a stream I, and c) feeding stream I, without prior separation of the liquid phases, into an extraction apparatus and extracting it at a temperature T with the hydrocarbon H to obtain a stream II comprising the hydrocarbon H enriched with the catalyst and a stream III having a low catalyst content.
摘要翻译：一种从均匀溶解的催化剂中将不饱和单腈的氢化氰化为碳氢化合物的反应流出物的方法，包括以下步骤：a）在步骤b）之前将反应流出物浓缩至0.1至5000毫巴和10至150℃的温度，b）向浓缩的反应流出物中加入烃H以获得流I，和c）将料流I未经预先分离的液相进入萃取装置并萃取在与烃H的温度T下，获得包含富含催化剂的烃H的流II和具有低催化剂含量的流III。

28. 发明授权

US07462263B2 Method for purifying hydrocyanic acid 失效
标题翻译：氢氰酸净化方法
公开(公告)号：US07462263B2
公开(公告)日：2008-12-09
申请号：US10553537
申请日：2004-04-15
申请人： Michael Bartsch , Robert Baumann , Gerd Haderlein , Miquel Angel Flores , Tim Jungkamp , Hermann Luyken , Jens Scheidel , Wolfgang Siegel , Dagmar Pascale Kunsmann-Keitel , Peter Bassler
发明人： Michael Bartsch , Robert Baumann , Gerd Haderlein , Miquel Angel Flores , Tim Jungkamp , Hermann Luyken , Jens Scheidel , Wolfgang Siegel , Dagmar Pascale Kunsmann-Keitel , Peter Bassler
IPC分类号： B01D3/00 , C01C3/04 , C07C253/34
CPC分类号： C07C253/10 , B01J2219/0011 , C01C3/0295 , C07C255/04
摘要： A process for dewatering hydrocyanic acid by distillation, which includes distilling crude hydrocyanic acid containing from 50 to 99.9% by weight of HCN, from 0.1 to 40% by weight of water, from 0 to 15% by weight of carbon oxides and optionally from 0.01 to 1% by weight of an involatile stabilizer, at a pressure of from 1 bar to 2.5 bar, a bottom temperature of from 100° C. to 130° C. and a top temperature of from 25° C. to 54° C., in the absence of a volatile stabilizer, in a distillation column to obtain a top draw stream containing purified, anhydrous hydrocyanic acid and carbon oxides and a bottom draw stream including water and, optionally, the involatile stabilizer.
摘要翻译：一种通过蒸馏对氢氰酸进行脱水的方法，包括将含有50-99.9重量％HCN的粗制氢氰酸，0.1-40重量％的水，0-15重量％的碳氧化物和任选的0.01 至1重量％的非挥发性稳定剂，压力为1巴至2.5巴，底部温度为100℃至130℃，顶部温度为25℃至54℃。在没有挥发性稳定剂的情况下，在蒸馏塔中获得含有纯化的无水氢氰酸和碳氧化物的顶部牵引流和包含水和任选的非挥发性稳定剂的底部牵引流。

29. 发明授权

US07294326B2 Hydrocyanic acid consisting of formamide 有权
标题翻译：氢氰酸由甲酰胺组成
公开(公告)号：US07294326B2
公开(公告)日：2007-11-13
申请号：US10537820
申请日：2003-12-03
申请人： Peter Bassler , Wolfgang Siegel , Guenther Achhammer , Anton Negele , Helmuth Menig , Wilhelm Ruppel , Peter Zehner , Hermann Luyken , Volker Vogt
发明人： Peter Bassler , Wolfgang Siegel , Guenther Achhammer , Anton Negele , Helmuth Menig , Wilhelm Ruppel , Peter Zehner , Hermann Luyken , Volker Vogt
IPC分类号： C01C3/02
CPC分类号： C01C3/0204 , B01J12/007 , B01J15/005 , B01J19/02 , B01J19/2415 , B01J23/866 , B01J2219/00135 , B01J2219/0236
摘要： The present invention relates to a process for preparing hydrocyanic acid (HCN) by catalytic dehydration of gaseous formamide in a reactor which has an internal reactor surface made of a steel comprising iron and chromium and nickel, and also to a reactor for preparing hydrocyanic acid by catalytic dehydration of gaseous formamide, which reactor has an internal reactor surface made of a steel comprising iron and chromium and nickel, and also to the use of the reactor of the present invention in a process for preparing hydrocyanic acid by catalytic dehydration of gaseous formamide.
摘要翻译：本发明涉及一种通过在反应器中催化脱水气态甲酰胺制备氢氰酸（HCN）的方法，该反应器具有由含铁和铬和镍的钢制成的内部反应器表面，并且还涉及通过以下步骤制备氢氰酸的反应器气态甲酰胺的催化脱水，该反应器具有由包含铁和铬和镍的钢制成的内部反应器表面，以及本发明的反应器在通过气态甲酰胺的催化脱水制备氢氰酸的方法中的用途。

30. 发明授权

US07115781B2 Iron-containing oxidic material suitable for use as hydrogenation catalyst precursor 有权
标题翻译：适用于氢化催化剂前体的含铁氧化物
公开(公告)号：US07115781B2
公开(公告)日：2006-10-03
申请号：US10493504
申请日：2002-10-18
申请人： Andreas Ansmann , Christoph Benisch , Peter Bassler , Rolf-Hartmuth Fischer , Stefan Maixner , Johann-Peter Melder , Hermann Luyken
发明人： Andreas Ansmann , Christoph Benisch , Peter Bassler , Rolf-Hartmuth Fischer , Stefan Maixner , Johann-Peter Melder , Hermann Luyken
IPC分类号： C07C209/62
CPC分类号： B01J23/745
摘要： An oxidic composition which is suitable as a catalyst having divalent and trivalent iron in an atomic ratio of divalent to trivalent iron in the range from greater than 0.5 to 5.5 and oxygen as a counterion to the divalent and trivalent iron. The catalyst composition is useful in the hydrogenation of nitriles to amines.
摘要翻译：适合作为具有二价和三价铁的二价和三价铁的氧化组合物，其二价至三价铁的原子比在大于0.5至5.5的范围内，氧与二价和三价铁的相反。催化剂组合物可用于将腈氢化成胺。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式