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1. 发明授权

US06881853B2 Method for producing propylene oxide 有权
标题翻译：生产环氧丙烷的方法
公开(公告)号：US06881853B2
公开(公告)日：2005-04-19
申请号：US10484204
申请日：2002-07-18
申请人： Joaquim Henrique Teles , Alwin Rehfinger , Anne Berg , Peter Rudolf , Norbert Rieber , Peter Bassler
发明人： Joaquim Henrique Teles , Alwin Rehfinger , Anne Berg , Peter Rudolf , Norbert Rieber , Peter Bassler
IPC分类号： C07D301/12
CPC分类号： C07D301/12 , Y02P20/582
摘要： A process for preparing propylene oxide comprises at least the following steps: (a) propene is reacted with a hydroperoxide in a solvent in the presence of a zeolite catalyst to give a mixture (M0), where the mixture (M0) comprises propylene oxide, solvent, unreacted propene, unreacted hydroperoxide and oxygen, (b) the propylene oxide is separated from the mixture (M0) so as to give a mixture (M1) which comprises unreacted propene and oxygen, (c) the mixture (M1) is brought into contact with a liquid medium comprising at least a solvent to give the mixtures (M2) and (M3), where the mixture (M3) comprises part of the unreacted propene and oxygen and the mixture (M2) comprises solvent and residual propene, and the mixture (M3) which has been separated off and comprises unreacted propene and oxygen has a ratio of oxygen to propene such that the mixture (M3) is not ignitable, and the mixture (M2) is fed to at least one reaction of propene with hydroperoxide.
摘要翻译：制备环氧丙烷的方法至少包括以下步骤：（a）在沸石催化剂存在下，使丙烯与溶剂中的氢过氧化物反应得到混合物（M 0），其中混合物（M 0）包含丙烯氧化物，溶剂，未反应的丙烯，未反应的氢过氧化物和氧气，（b）将环氧丙烷与混合物（M 0）分离，得到包含未反应的丙烯和氧的混合物（M 1），（c）混合物 M 1）与包含至少一种溶剂的液体介质接触以得到混合物（M 2）和（M 3），其中混合物（M 3）包含部分未反应的丙烯和氧气以及混合物（M 2）包括溶剂和残余丙烯，并且已经分离并包含未反应的丙烯和氧的混合物（M 3）具有氧与丙烯的比例，使得混合物（M 3）不可燃，并且混合物（M 2）进料至丙烯与氢过氧化物的至少一个反应。

2. 发明授权

US06756503B2 Method for the production of propylene oxide 有权
标题翻译：生产环氧丙烷的方法
公开(公告)号：US06756503B2
公开(公告)日：2004-06-29
申请号：US10312862
申请日：2003-01-02
申请人： Joaquim Henrique Teles , Alwin Rehfinger , Peter Bassler , Anne Wenzel , Norbert Rieber , Peter Rudolf
发明人： Joaquim Henrique Teles , Alwin Rehfinger , Peter Bassler , Anne Wenzel , Norbert Rieber , Peter Rudolf
IPC分类号： C07D30112
CPC分类号： C07D301/12 , Y02P20/582
摘要： A process for the preparation of propylene oxide in which (i) propene is reacted with hydrogen peroxide in the presence of methanol to give propylene oxide, giving a mixture (Gi) comprising propylene oxide, methanol, water and unreacted hydrogen peroxide, (ii) a mixture (Gii) comprising methanol, water and hydrogen peroxide is separated off from the mixture (Gi), giving a mixture (Ga) comprising propylene oxide, and (iii) water is separated off from the mixture (Gii), giving a mixture (Giii) comprising methanol and methyl formate.
摘要翻译：一种制备环氧丙烷的方法，其中（i）丙烯在甲醇存在下与过氧化氢反应得到环氧丙烷，得到包含环氧丙烷，甲醇，水和未反应的过氧化氢的混合物（Gi），（ii）从混合物（Gi）中分离出包含甲醇，水和过氧化氢的混合物（Gii），得到包含环氧丙烷的混合物（Ga），和（iii）从混合物（Gii）中分离出水，得到混合物（Giii），其包含甲醇和甲酸甲酯。

3. 发明授权

US06359178B1 Method for producing hexamethylene diamine 有权
标题翻译：六亚甲基二胺的制备方法
公开(公告)号：US06359178B1
公开(公告)日：2002-03-19
申请号：US09762798
申请日：2001-02-13
申请人： Rolf Fischer , Peter Bassler , Hermann Luyken , Frank Ohlbach , Johann-Peter Melder , Martin Merger , Andreas Ansmann , Alwin Rehfinger , Guido Voit
发明人： Rolf Fischer , Peter Bassler , Hermann Luyken , Frank Ohlbach , Johann-Peter Melder , Martin Merger , Andreas Ansmann , Alwin Rehfinger , Guido Voit
IPC分类号： C07C20948
CPC分类号： C07C209/48 , C07C211/12
摘要： A process for catalytic hydrogenation of adiponitrile to hexamethylenediamine at elevated temperature and elevated pressure in the presence of catalysts based on elemental iron as catalytically active component and ammonia as solvent comprises a) hydrogenating adiponitrile at from 70 to 220° C. and from 100 to 400 bar in the presence of catalysts based on elemental iron as catalytically active component and ammonia as solvent to obtain a mixture comprising adiponitrile, 6-aminocapronitrile, hexamethylenediamine and high boilers until the sum total of the 6-aminocapronitrile concentration and the adiponitrile concentration is within the range from 1 to 50% by weight, based on the ammonia-free hydrogenation mixture, b) removing ammonia from the hydrogenation effluent, c) removing hexamethylenediamine from the remaining mixture, d) separating 6-aminocapronitrile and adiponitrile from high boilers individually or together, and e) returning 6-aminocapronitrile, adiponitrile or mixtures thereof into step a).
摘要翻译：在基于作为催化活性组分的元素铁和作为溶剂的氨的催化剂存在下，在升高的温度和升高的压力下将己二腈催化氢化为己二胺的方法包括在70-220℃和100-400巴下氢化己二腈在基于作为催化活性成分的元素铁和作为溶剂的氨的催化剂存在下，得到包含己二腈，6-氨基己腈，六亚甲基二胺和高沸点剂的混合物，直到6-氨基己腈浓度和己二腈浓度的总和在范围内基于无氨氢化混合物，从1至50重量％，b）从氢化流出物中除去氨，c）从剩余的混合物中除去六亚甲基二胺，d）分别或一起从高锅炉中分离6-氨基己腈和己二腈，和），返回6-氨基己腈，己二腈或其混合物 n步骤a）。

4. 发明授权

US06114567A Preparation of aliphatic alpha, omega-aminonitriles 失效
标题翻译：脂肪族α，ω-氨基腈的制备
公开(公告)号：US06114567A
公开(公告)日：2000-09-05
申请号：US122102
申请日：1998-07-24
申请人： Klemens Flick , Johann-Peter Melder , Werner Schnurr , Klaus Ebel , Tom Witzel , Wolfgang Harder , Alwin Rehfinger , Rolf Fischer
发明人： Klemens Flick , Johann-Peter Melder , Werner Schnurr , Klaus Ebel , Tom Witzel , Wolfgang Harder , Alwin Rehfinger , Rolf Fischer
IPC分类号： B01J23/89 , B01J23/76 , B01J23/889 , B01J27/18 , B01J37/02 , C07B61/00 , C07C253/30 , C07C255/24
CPC分类号： B01J23/8898 , B01J23/76 , B01J23/8892 , B01J37/0201 , C07C253/30
摘要： Aliphatic alpha,omega-aminonitriles are prepared by partial hydrogenation of aliphatic alpha,omega-dinitriles at elevated temperatures and superatmospheric pressure in the presence of a solvent and of a catalyst by a process which comprises using a catalyst which(a) contains a compound based on a metal selected from the group consisting of nickel, cobalt, iron, ruthenium and rhodium and(b) contains from 0.01 to 25% by weight, based on (a), of a promoter based on a metal selected from the group consisting of palladium, platinum, iridium, osmium, copper, silver, gold, chromium, molybdenum, tungsten, manganese, rhenium, zinc, cadmium, lead, aluminum, tin, phosphorus, arsenic, antimony, bismuth and rare earth metals and(c) from 0 to 5% by weight, based on (a), of a compound based on an alkali metal or on an alkaline earth metal.with the proviso that the component (a) is not based on iron or iron and one of the metals selected from the group consisting of cobalt, ruthenium and rhodium when (b) is a promoter based on a metal selected from the group consisting of titanium, manganese, chromium and molybdenum, and with the further proviso that, when a compound based on only ruthenium or rhodium or ruthenium and rhodium or nickel and rhodium is selected as component (a), the promoter (b) may be dispensed with.
摘要翻译：脂肪族α，ω-氨基腈通过脂肪族α，ω-二腈在升高的温度和超大气压下，在溶剂和催化剂存在下通过包括使用（a）含有基于化合物的催化剂在选自镍，钴，铁，钌和铑的金属上，和（b）含有基于（a）0.01至25重量％的基于选自以下的金属的促进剂：钯，铂，铱，锇，铜，银，金，铬，钼，钨，锰，铼，锌，镉，铅，铝，锡，磷，砷，锑，铋和稀土金属和（c）基于（a）的0至5重量％的基于碱金属或碱土金属的化合物。条件是当（b）是基于选自钛的金属的促进剂时，组分（a）不是基于铁或铁和选自钴，钌和铑的金属之一，，锰，铬和钼，另外条件是，当选择仅基于钌或铑或钌和铑或镍和铑的化合物作为组分（a）时，可以省略促进剂（b）。

5. 发明授权

US06958304B2 Method for regenerating a zeolite catalyst 失效
标题翻译：再生沸石催化剂的方法
公开(公告)号：US06958304B2
公开(公告)日：2005-10-25
申请号：US10380070
申请日：2001-09-11
申请人： Joaquim Henrique Teles , Alwin Rehfinger , Peter Bassler , Anne Wenzel , Norbert Rieber , Ulrich Müller , Peter Rudolf
发明人： Joaquim Henrique Teles , Alwin Rehfinger , Peter Bassler , Anne Wenzel , Norbert Rieber , Ulrich Müller , Peter Rudolf
IPC分类号： B01J29/89 , B01J29/90 , B01J38/14 , B01J38/04 , B01J20/34 , B01J29/04 , C07D301/12
CPC分类号： B01J29/90 , B01J29/89 , B01J38/14
摘要： A process for the regeneration of a zeolite catalyst which comprises treating the catalyst thermally in the presence of a gas stream at temperatures above 120° C., the weight-based residence time of the gas stream over the catalyst during the thermal treatment being greater than 2 hours.
摘要翻译：一种沸石催化剂再生方法，其包括在温度高于120℃的气流存在下热处理催化剂，在热处理过程中气流在催化剂上的重量停留时间大于 2小时。

6. 发明授权

US06462220B1 Method for simultaneous preparation of 6-aminocapronitrile and hexamethylene diamine 有权
标题翻译：同时制备6-氨基己腈和六亚甲基二胺的方法
公开(公告)号：US06462220B1
公开(公告)日：2002-10-08
申请号：US09763710
申请日：2001-02-26
申请人： Hermann Luyken , Frank Ohlbach , Andreas Ansmann , Peter Bassler , Rolf Fischer , Johann-Peter Melder , Martin Merger , Alwin Rehfinger , Guido Voit , Günther Achhammer
发明人： Hermann Luyken , Frank Ohlbach , Andreas Ansmann , Peter Bassler , Rolf Fischer , Johann-Peter Melder , Martin Merger , Alwin Rehfinger , Guido Voit , Günther Achhammer
IPC分类号： C07C25525
CPC分类号： C07C253/30 , C07C209/48
摘要： A process for the coproduction of 6-aminocapronitrile and hexamethylenediamine starting from adiponitrile by a) hydrogenating adiponitrile in the presence of a catalyst comprising an element of the eighth transition group as catalytically active component, to obtain a mixture comprising 6-aminocapronitrile, hexamethylenediamine, adiponitrile and high boilers, b) distillatively removing hexamethylenediamine from the mixture comprising 6-aminocapronitrile, hexamethylenediamine, adiponitrile and high boilers, and either cl) distillatively removing 6-aminocapronitrile, and then d1) distillatively removing adiponitrile, or c2) simultaneously distillatively removing 6-aminocapronitrile and adiponitrile into separate fractions is characterized by base of column temperatures below 185° C. in steps d1) or c2).
摘要翻译：一种从己二腈开始共生产6-氨基己腈和六亚甲基二胺的方法，其中a）在包含第八过渡基团的元素的催化剂作为催化活性组分的存在下氢化己二腈，得到包含6-氨基己腈，己二胺，己二腈和高锅炉，b）从包含6-氨基己腈，己二胺，己二腈和高沸点的混合物中蒸馏除去六亚甲基二胺，并且将蒸馏除去6-氨基己腈，然后d1）蒸馏除去己二腈，或同时蒸馏除去6-氨基己腈和己二腈分离的馏分以步骤d1）或c2）中塔温度低于185℃的碱为特征。

7. 发明授权

US06300497B1 Method for separating an azepine derivative from a mixture containing an amine and an azepine derivative 失效
标题翻译：从含有胺和吖庚因衍生物的混合物中分离出吖庚因衍生物的方法
公开(公告)号：US06300497B1
公开(公告)日：2001-10-09
申请号：US09623699
申请日：2000-09-07
申请人： Alwin Rehfinger , Hermann Luyken
发明人： Alwin Rehfinger , Hermann Luyken
IPC分类号： C07D22304
CPC分类号： C07D223/12 , C07C209/48 , C07C209/86 , C07C253/34 , C07C211/12 , C07C255/24
摘要： A process for distillative removal of part or all of an azepine derivative (III) selected from the group consisting of aminohexylideneimine, tetrahydroazepine, hexylhexahydroazepine and aminohexylhexahydroazepine from a mixture (II) comprising an azepine derivative (III) and an amine (I) comprises conducting the distillation with an overhead temperature of from 160 to 250° C.
摘要翻译：从包含氮杂衍生物（III）和胺（I）的混合物（II）中蒸馏除去部分或全部选自由亚氮杂环亚胺，四氢氮杂，己基六氢吖庚因和氨基己基六氢吖庚因组成的组中的吖庚因衍生物（III）的方法包括导电塔顶温度为160-250℃的蒸馏

8. 发明授权

US06297394B1 Iron-based catalyst for hydrogenating alpha-, omega-dinitriles 有权
标题翻译：用于氢化α-，ω-二腈的铁基催化剂
公开(公告)号：US06297394B1
公开(公告)日：2001-10-02
申请号：US09622773
申请日：2000-08-23
申请人： Guido Voit , Rolf Fischer , Peter Bassler , Andreas Ansmann , Hermann Luyken , Martin Merger , Frank Ohlbach , Alwin Rehfinger
发明人： Guido Voit , Rolf Fischer , Peter Bassler , Andreas Ansmann , Hermann Luyken , Martin Merger , Frank Ohlbach , Alwin Rehfinger
IPC分类号： C07C20922
CPC分类号： C07C253/30 , B01J23/8892 , C07C209/48 , C07C211/12 , C07C255/24
摘要： A material useful as catalyst for the hydrogenation of alpha, Omega-dinitriles comprises a) iron or a compound based on iron or mixtures thereof, (b) from 0.001 to 0.3% by weight based on (a) of a promoter based on 2, 3, 4 or 5 elements selected from the group consisting of aluminum, silicon, zirconium, titanium and vanadium, (c) from 0 to 0.3% by weight based on (a) of a compound based on an alkali and/or alkaline earth metal, and also (d) from 0.001 to 1% by weight based on (a) of manganese.
摘要翻译：可用作α，ω-二腈的氢化催化剂的材料包括a）铁或基于铁或其混合物的化合物，（b）基于（a）基于2,3的启动子的0.001至0.3重量％，选自铝，硅，锆，钛和钒的4或5种元素，（c）基于（a）基于碱金属和/或碱土金属的化合物，0至0.3重量％以及（d）基于（a）锰的0.001至1重量％。

9. 发明授权

US5244929A Molded bodies comprised of macroporous ion exchange resins, and use of said bodies 失效
标题翻译：由大孔离子交换树脂构成的成型体，以及所述体的用途
公开(公告)号：US5244929A
公开(公告)日：1993-09-14
申请号：US882770
申请日：1992-05-11
申请人： Klaus Gottlieb , Wilfried Graf , Kuno Schadlich , Ulrich Hoffmann , Alwin Rehfinger , Jorg Flato
发明人： Klaus Gottlieb , Wilfried Graf , Kuno Schadlich , Ulrich Hoffmann , Alwin Rehfinger , Jorg Flato
IPC分类号： B01D3/00 , B01J8/00 , B01J19/30 , B01J31/08 , B01J31/10 , B01J31/28 , B01J47/00 , C07C29/04 , C07C41/06
CPC分类号： C07C41/06 , B01D3/009 , B01J19/30 , B01J31/10 , B01J31/28 , B01J47/007 , B01J8/008 , C07C29/04 , B01J2219/30203 , B01J2219/30207 , B01J2219/30215 , B01J2219/30223 , B01J2219/30466 , B01J2219/30475 , Y02P20/127
摘要： Molded bodies in the form of packing bodies comprising a macroporous strongly acid or basic ion exchange resin having a voids fraction of 5-95 vol % of the macro shape without pores, a BET surface area of 0.1-1,000 sq m/g, and an ion exchange capacity of 0.05-10 meq/g.
摘要翻译：包装体形式的成型体，其特征在于，具有大孔强酸或碱性离子交换树脂，孔隙率为无孔孔径的5-95体积％，BET表面积为0.1〜1,000平方米/克，离子交换容量为0.05-10meq / g。

10. 发明授权

US06852669B2 Hydrogenation catalyst 失效
标题翻译：氢化催化剂
公开(公告)号：US06852669B2
公开(公告)日：2005-02-08
申请号：US09851214
申请日：2001-05-08
申请人： Guido Voit , Rolf Fischer , Peter Bassler , Andreas Ansmann , Hermann Luyken , Martin Merger , Frank Ohlbach , Alwin Rehfinger
发明人： Guido Voit , Rolf Fischer , Peter Bassler , Andreas Ansmann , Hermann Luyken , Martin Merger , Frank Ohlbach , Alwin Rehfinger
IPC分类号： B01J23/889 , C07B61/00 , C07C209/48 , C07C211/12 , C07C253/30 , C07C255/24 , B01J23/74
CPC分类号： C07C253/30 , B01J23/8892 , C07C209/48 , C07C211/12 , C07C255/24
摘要： A material useful as catalyst for the hydrogenation of alpha, omega-dinitriles comprises(a) iron or a compound based on iron or mixtures thereof,(b) from 0.001 to 0.3% by weight based on (a) of a promoter based on 2, 3, 4 or 5 elements selected from the group consisting of aluminum, silicon, zirconium, titanium and vanadium,(c) from 0 to 0.3% by weight based on (a) of a compound based on an alkali and/or alkaline earth metal, and also(d) from 0.001 to 1% by weight based on (a) of manganese.
摘要翻译：可用作α，ω-二腈的氢化催化剂的材料包括（a）铁或基于铁或其混合物的铁或其混合物，（b）基于（a）基于2的促进剂的0.001至0.3重量％，选自铝，硅，锆，钛和钒的3,4或5种元素，（c）基于（a）基于碱和/或碱土金属的化合物，0至0.3重量％金属，以及（d）以（a）锰计为0.001〜1重量％。

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