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    • 27. 发明授权
    • Synthesizing thiocarbamic acid esters
    • 合成硫代氨基甲酸酯
    • US4497739A
    • 1985-02-05
    • US463553
    • 1983-02-03
    • Villiam GiroldiniCarlo Neri
    • Villiam GiroldiniCarlo Neri
    • C07B61/00B01J27/00C07C67/00C07C325/00C07C333/04C07D295/21C07C155/02C07D213/02
    • C07D295/21
    • A process for the synthesis of thiocarbamic acid esters by reacting amine compounds having a general formula ##STR1## wherein A is an arylene radical, simple or substituted by halogens hydrocarbon radicals, alkoxy groups, or can be an alkylene radical having from 1 to 15 carbon atoms, straight-line or branched, simple or substituted, whereas X can be hydrogen --NH.sub.2 or can be an H.sub.2 --N--Z group in which the bivalent function Z derives from alkyl, aryl, cycloaryl, alkaryl, aralkyl radicals which can be, in their turn, simple or substituted, R and R' equal or different can be hydrogen or alkyl, aryl, alkaryl radicals and otherwise, with carbon monoxide, in the presence of a catalyst composed of a metallic selenide. The thiocarbamic acid esters are known compounds that find applications as medicaments for plants and as intermediates for organic synthesis.
    • 通过使具有通式为“IMAGE”的胺化合物反应合成硫代氨基甲酸酯的方法,其中A是亚芳基,其简单或被卤素烃基,烷氧基取代,或者可以是具有1至15个碳原子的亚烷基 原子,直链或支链,简单或取代的,而X可以是氢-NH 2或可以是其中二价官能团Z衍生自烷基,芳基,环芳基,烷芳基,芳烷基的H 2 - NZ基团,其可以是, 它们的简单或取代的R和R'可以相同或不同,在由金属硒化物组成的催化剂的存在下,可以是氢或烷基,芳基,烷芳基等。 硫代氨基甲酸酯是已知的化合物,其可用作植物的药物和作为有机合成的中间体。