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1. 发明授权

US4497739A Synthesizing thiocarbamic acid esters 失效
标题翻译：合成硫代氨基甲酸酯
公开(公告)号：US4497739A
公开(公告)日：1985-02-05
申请号：US463553
申请日：1983-02-03
申请人： Villiam Giroldini , Carlo Neri
发明人： Villiam Giroldini , Carlo Neri
IPC分类号： C07B61/00 , B01J27/00 , C07C67/00 , C07C325/00 , C07C333/04 , C07D295/21 , C07C155/02 , C07D213/02
CPC分类号： C07D295/21
摘要： A process for the synthesis of thiocarbamic acid esters by reacting amine compounds having a general formula ##STR1## wherein A is an arylene radical, simple or substituted by halogens hydrocarbon radicals, alkoxy groups, or can be an alkylene radical having from 1 to 15 carbon atoms, straight-line or branched, simple or substituted, whereas X can be hydrogen --NH.sub.2 or can be an H.sub.2 --N--Z group in which the bivalent function Z derives from alkyl, aryl, cycloaryl, alkaryl, aralkyl radicals which can be, in their turn, simple or substituted, R and R' equal or different can be hydrogen or alkyl, aryl, alkaryl radicals and otherwise, with carbon monoxide, in the presence of a catalyst composed of a metallic selenide. The thiocarbamic acid esters are known compounds that find applications as medicaments for plants and as intermediates for organic synthesis.
摘要翻译：通过使具有通式为“IMAGE”的胺化合物反应合成硫代氨基甲酸酯的方法，其中A是亚芳基，其简单或被卤素烃基，烷氧基取代，或者可以是具有1至15个碳原子的亚烷基原子，直链或支链，简单或取代的，而X可以是氢-NH 2或可以是其中二价官能团Z衍生自烷基，芳基，环芳基，烷芳基，芳烷基的H 2 - NZ基团，其可以是，它们的简单或取代的R和R'可以相同或不同，在由金属硒化物组成的催化剂的存在下，可以是氢或烷基，芳基，烷芳基等。硫代氨基甲酸酯是已知的化合物，其可用作植物的药物和作为有机合成的中间体。

2. 发明授权

US4564691A Process for preparing substituted 2,3-dihydrobenzofuran 失效
标题翻译：取代2,3-二氢苯并呋喃的制备方法
公开(公告)号：US4564691A
公开(公告)日：1986-01-14
申请号：US602215
申请日：1984-04-19
申请人： Carlo Neri , Villiam Giroldini , Antonio Rinaldi , Mario Traversoni , Mario Clerici
发明人： Carlo Neri , Villiam Giroldini , Antonio Rinaldi , Mario Traversoni , Mario Clerici
IPC分类号： C07D307/72 , C07C37/20 , C07C39/15 , C07C39/16 , C07C39/367 , C07D307/79 , C07D307/86
CPC分类号： C07D307/79 , C07C37/20 , C07C39/16 , C07D307/86
摘要： A process is provided for preparing a substituted 2,3-dihydrobenzofuran of the general formula ##STR1## in which R.sub.a is hydrogen, halogen, alkyl, straight or branched having from 1 to 4 carbon atoms, aryl, alkaryl, --OH, --OR.sub.3, --N(R.sub.d).sub.2, where R.sub.3 and R.sub.d are alkyl, straight or branched having from 1 to 4 carbon atoms; R.sub.b is alkyl, straight or branched, having from 1 to 6 carbon atoms, aryl, alkaryl; and R.sub.c is hydrogen or the same as R.sub.b, by the rearrangement of a 1,1-bis(2-hydroxybenzene) alkyl and/or aryl-ethane, in the presence of catalytic amounts of a mineral acid or organic acid such as phosphoric, sulfuric or p-toluenesulfonic, at elevated temperatures from 180.degree. to 250.degree. C., and withdrawing the resulting products from the reaction mixture as they are formed. The starting 1,1-bis(2-hydroxybenzene) alkyl and/or aryl-ethane compounds may be obtained by the catalyzed reaction of a substituted biphenol with an aldehyde. The substituted 2,3-dihydrobenzofurans are useful in the manufacture of pesticides.
摘要翻译：提供了制备通式为“IMAGE”的取代2,3-二氢苯并呋喃的方法，其中Ra为氢，卤素，具有1-4个碳原子的直链或支链的烷基，芳基，烷芳基，-OH，-OR3 ，-N（Rd）2，其中R3和Rd是具有1至4个碳原子的直链或支链烷基; Rb是具有1-6个碳原子的直链或支链烷基，芳基，烷芳基; 和Rc是氢或与Rb相同，通过在催化量的无机酸或有机酸如磷酸的存在下重新配置1,1-双（2-羟基苯）烷基和/或芳基 - 乙烷，硫酸或对甲苯磺酸，在180℃至250℃的升高温度下，在反应混合物形成时从所得反应混合物中取出。起始的1,1-双（2-羟基苯）烷基和/或芳基 - 乙烷化合物可以通过取代的联苯酚与醛的催化反应获得。取代的2,3-二氢苯并呋喃可用于制造农药。

3. 发明授权

US4562266A Process for the preparation of 2,3-dihydro-2,2-dimethyl-7-benzofuranol 失效
标题翻译： 2,3-二氢-2,2-二甲基-7-苯并呋喃醇的制备方法
公开(公告)号：US4562266A
公开(公告)日：1985-12-31
申请号：US602214
申请日：1984-04-19
申请人： Carlo Neri , Villiam Giroldini , Mario Traversoni , Guido Guizzi , Emilio Perrotti , Antonio Rinaldi
发明人： Carlo Neri , Villiam Giroldini , Mario Traversoni , Guido Guizzi , Emilio Perrotti , Antonio Rinaldi
IPC分类号： C07D307/79 , C07C37/20 , C07D307/86
CPC分类号： C07C37/20 , C07C37/52 , C07D307/86
摘要： Process for the preparation of 2,3-dihydro-2,2-dimethyl-7-benzofuranol, comprising the reaction between catechol or 4-tert.butyl catechol and isobutyraldehyde in the presence of catalytic amounts of at least one compound selected from the group consisting of the oxides, hydroxides, alcoholates and carboxylates of metals belonging to the Groups IA, IIA, IIB and VIIB of the Periodic System of the Elements and the subsequent reaction of rearrangement of the products which have been obtained, optionally previously removing one or more low-boiling components, in the presence of a compound having acidic properties, of an organic or a mineral nature. The product is useful in the synthesis of pesticides.
摘要翻译：制备2,3-二氢-2,2-二甲基-7-苯并呋喃醇的方法，包括在催化量的至少一种选自下组的化合物的存在下，在儿茶酚或4-叔丁基邻苯二酚与异丁醛之间的反应由属于元素周期系统的IA，IIA，IIB和VIIB族的金属的氧化物，氢氧化物，醇化物和羧酸盐组成，以及随后的已经获得的产物的重排反应，任选地预先除去一个或多个在具有酸性的化合物的存在下，有机或矿物性质的低沸点成分。该产品可用于合成农药。

4. 发明授权

US4487952A Preparing carbamic acid esters 失效
标题翻译：制备氨基甲酸酯
公开(公告)号：US4487952A
公开(公告)日：1984-12-11
申请号：US463555
申请日：1983-02-03
申请人： Villiam Giroldini
发明人： Villiam Giroldini
IPC分类号： C07B61/00 , B01J27/00 , B01J31/00 , C07C67/00 , C07C239/00 , C07C269/00 , C07C271/06 , C07C125/063 , C07C125/07
CPC分类号： C07C271/06
摘要： Process for the preparation of esters of carbamic acids by carbonylation of aromatic nitrocompounds, with carbon monoxide, in the presence of alcohols and of catalyst consisting of metallic selenides.
摘要翻译：通过羰基化芳族硝基化合物与一氧化碳在醇和由金属硒化物组成的催化剂的存在下制备氨基甲酸酯的方法。

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