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    • 23. 发明授权
    • Release silicone emulsion composition
    • 释放硅氧烷乳液组合物
    • US5095067A
    • 1992-03-10
    • US184026
    • 1988-04-20
    • Yasuaki HaraFumio Okada
    • Yasuaki HaraFumio Okada
    • C08L83/07B01J13/00C08J3/24C09D183/04C09J7/02
    • C09D183/04
    • A release silicone emulsion composition comprising:(A) 100 parts by weight of a specific organovinylpolysiloxane;(B) from 1 to 50 parts by weight of a specific organohydrogenpolysiloxane;(C) from 0.5 part to 5 parts by weight of a platinum catalyst having a viscosity of 10 cSt or less at 25.degree. C.;(D) from 1.5 to 15 parts by weight of a nonionic emulsifying agent having an average HLB of from 10 to 20, pH of 6.5 or less and an ionic conductivity of 30 .mu..OMEGA..sup.-1 cm.sup.-1 or less; and(E) water.This composition has good pot life and curability. The cured film has good release properties and residual adhesive properties of adhesives.
    • 一种脱模硅氧烷乳液组合物,其包含:(A)100重量份的特定有机乙烯基聚硅氧烷; (B)1〜50重量份的特定有机氢聚硅氧烷; (C)在25℃下粘度为10cSt以下的铂催化剂为0.5〜5重量份。 (D)1.5〜15重量份的平均HLB为10〜20,pH值为6.5以下,离子电导率为30万欧姆〜1cm-1以下的非离子乳化剂。 和(E)水。 该组合物具有良好的适用期和固化性。 固化膜具有良好的剥离性能和粘合剂的残留粘合性能。
    • 24. 发明授权
    • Silicone-based antifoam composition and a method for the preparation of
the same
    • 基于硅酮的消泡剂组合物及其制备方法
    • US4741861A
    • 1988-05-03
    • US830568
    • 1986-02-18
    • Fumio OkadaNobuyuki TeraeKiyohiro Kondou
    • Fumio OkadaNobuyuki TeraeKiyohiro Kondou
    • B01D19/04B01D17/05
    • B01D19/0409
    • The silicone-based antifoam composition having excellent durability of the antifoam activity even under vigorous agitation or under an alkaline condition comprises three kinds of diorganopolysiloxanes, of which the first is free from aliphatic unsaturation, the second is terminated at both molecular chain ends each with a vinyl diorganosilyl group and the third is terminated at both molecular chain ends each with a diorganosilyl group having a silicon-bonded hydrogen atom, a finely divided silica powder, a platinum compound to catalyze the addition reaction between the silicon-bonded vinyl groups and silicon-bonded hydrogen atoms in the second and the third diorganopolysiloxanes, respectively, and an organosilane compound of the formula R.sup.1.sub.a Y.sub.b Si, in which R.sup.1 is a monovalent hydrocarbon group, Y is a hydroxy, carboxyl or hydrolyzable group and a and b are each 1, 2 or 3 with the proviso that a+b=4. When the composition, which is in the form of an aqueous emulsion or a dispersion in an organic solvent, is heated at an elevated temperature, the addition reaction takes place between the second and the third diorganopolysiloxanes to increase the stability and antifoam activity of the composition.
    • 即使在剧烈搅拌下或在碱性条件下,具有优异的消泡活性的耐久性的硅氧烷消泡剂组合物包括三种二有机聚硅氧烷,其中第一种不含脂族不饱和度,第二种有机聚硅氧烷在两个分子链末端终止, 乙烯基二有机甲硅烷基,第三个在两个分子链末端终止,每个末端分别具有与硅键合的氢原子的二有机甲硅烷基,细碎的二氧化硅粉末,铂化合物,以催化与硅键合的乙烯基之间的加成反应, 第二和第三二有机聚硅氧烷中的键合氢原子和式R1aYbSi的有机硅烷化合物,其中R1是一价烃基,Y是羟基,羧基或可水解基团,和a和b各自为1,2或 3,条件是a + b = 4。 当水性乳液或有机溶剂中的分散体的组合物在升高的温度下加热时,加成反应发生在第二和第三二有机聚硅氧烷之间,以提高组合物的稳定性和消泡活性 。